The application discloses a preparation method of a
lithium battery diaphragm with
high heat resistance, and relates to the technical field of
lithium battery diaphragms. The preparation method comprises the following raw materials in
mass fractions: 60-75 parts of
polyimide, 10-20 parts of aluminum
oxide, 3-8 parts of a heat-resistant modifier, 8-12 parts of PVDF-HFP, 5-8 parts of
liquid paraffin, and 0.5-1.5 parts of polyacrylammonium. The application performs pretreatment and modification on
boron nitride powder in the preparation process of the
lithium battery diaphragm, so that the diaphragm forms an effective heat conduction path, promotes the rapid transmission and
diffusion of heat, and improves the overall
heat resistance of the diaphragm. Meanwhile, the pretreatment and modification of the
boron nitride powder solve the problem that the original
boron nitride sheet layer is prone to agglomeration under the action of
van der Waals force and
hydrogen bonding, and is difficult to uniformly disperse in the
polymer matrix. In the preparation process, a segmented
drying method is adopted to realize resource recycling, and the method is different from traditional
acetone soaking and
dissolution liquid paraffin, so that the swelling of the base film is avoided.