1587results about How to "High flame retardant efficiency" patented technology

The invention discloses a halogen-free flame-retardant type injection molding-class polyolefin wood plastic composite material and a preparation method thereof. The composite material consists of the following components in percentage by mass: 25 to 80 percent of polyolefin resin, 5 to 60 percent of plant fiber, 0.5 to 20 percent of compatilizer, 0 to 30 percent of flexibilizer, 0.5 to 8 percent of dispersant, 5 to 40 percent of flame retardant and flame retardance synergist and 0 to 1 percent of antioxidant. Compared with the conventional wood plastic composite material, the halogen-free flame-retardant type injection molding-class polyolefin wood plastic composite material has the characteristics of simple production flow, little using amount of the flame retardant, good halogen-free flame retardant effect, wide range of molding modes and the like and is applicable to various injection molding products, such as electric appliance shells, automobile parts, furniture, buildings and other parts.

The invention discloses a microencapsulation expansion type flame retardant and application in an epoxy resin composite material thereof. The microencapsulation expansion type flame retardant uses ammonium polyphosphate as a capsule core and uses a thermosetting resin melamine-formaldehyde resin as a capsule material. The microencapsulation expansion type flame retardant epoxy resin composite material consists of the epoxy resin, a curing agent, a curing accelerator, the microencapsulation expansion type flame retardant and a flame-retardant carbon-forming accelerator. The microencapsulation expansion type flame retardant and the application are economic, simple and convenient; the flame retardant has good flame-retardant synergistic effects; and under the condition of little flame retardant addition, the composite material can pass V-0 level of UL-94 test, and the oxygen index reaches over 30.0 percent.

The invention belongs to the field of flame retardant materials, and particularly relates to a composite flame retardant containing a microcapsule-coated intumescent flame retardant and a preparation method. The composite flame retardant containing the microcapsule-coated intumescent flame retardant consists of the following components in percentage by mass: 60-94 percent of microcapsule intumescent flame retardant, 5-25 percent of flame-retardant synergist, 0.9-10 percent of smoke suppressant and 0.1-5 percent of hindered amine light stabilizer. The preparation method comprises the following steps: preparing the microcapsule-coated intumescent flame retardant; placing the microcapsule-coated intumescent flame retardant, the flame-retardant synergist, the smoke suppressant and the hindered amine light stabilizer into a high-speed mixer for mixing uniformly, and discharging to obtain the composite flame retardant containing the microcapsule-coated intumescent flame retardant. Multiple components in the composite flame retardant can play roles in retarding flame in a synergetic way, so that the flame retardance of a high polymer material is improved remarkably, the production of toxic and harmful smog in a burning process can be suppressed, and the flame retarding efficiency is increased greatly.

The invention discloses a halogen-free expansible flame-retardant thermoplastic resin composition, which is prepared by fusing and blending the following components in percentage by weight: 40 to 80 percent of thermoplastic resin, 18 to 25 percent of halogen-free expansible flame retardant, 0 to 5 percent of flame-retardant synergetic agent, 0 to 30 percent of glass fiber, 0 to 2 percent of coupling agent and 0.5 to 1 percent of antioxidant, wherein the thermoplastic resin is any one of polyamide 6, polyamide 66 and polylactic acid or glass fiber reinforced product thereof. The halogen-free expansible flame retardant in the flame-retardant thermoplastic resin composition has low additive amount and good flame retardancy, and the compound flame-retardant synergetic agent does not affect various inherent properties of the resin and can improve the flame retardancy of the material and reduce the cost of the material so as to fill the blank that the prior art has no thermoplastic resin compositions of halogen-free expansible flame-retardant polyamide, polylactic acid and the like.

The invention discloses an insulating and sheathing material of ultraviolet light crosslinking expanding type phosphorus nitrogen flaming resistance polyolefine cables and a preparation method thereof. The invention is characterized in that polyethylene/PEMA and/or ethylene vinyl acetate or maleic anhydride grafted ethylene vinyl acetate or acid amide grafted ethylene vinyl acetate copolymer are taken as base, added with expanding type phosphorus nitrogen halogen-free flame retardants, light trigger, polyfunctional group cross linker and chemical inhibitor and matched with flaming retardant synergistic agent, antismoke agent and processing aid, and then squeezed out and pelleted into photo-crosslinking flame retardant cable materials; and then the flame retardant cable materials are melted and extruded on a cable conductor wire core and clad into an insulating layer and a sheathing layer; hereupon the ultraviolet light irradiation crosslinking is carried on the insulating layer or the sheathing layer. Via detecting, the oxygen index of the insulating layer or the sheathing layer is larger than 30%, the vertical flaming experiment passes through UL-94 V0 level, the tensile strength is larger than 12Mpa, the elongation at break is larger than 350%, and the electric volume resistivity is larger than 8*10 omega.cm.

The invention provides a preparation method of a graphene based reinforced and flame-retarded recycled polyester staple fiber. The method comprises the following steps: preparing graphene master batch; preparing phosphate based halogen-free flame retardant master batch; weighing the graphene master batch and the phosphate based halogen-free flame retardant master batch, mixing with a recycled polyester raw material, drying, feeding molten dried raw materials into an impurity removal stirrer under the action of a screw extruder by a melt pump for carrying out homogenization impurity-removal treatment, feeding a homogenized and impurity-removal polyester melt into a secondary filter by the melt pump, enabling a filtered melt to pass through a mixed melt on a pipeline to enter a spinning manifold, carrying out drafting processing on a spun fiber to obtain the reinforced and flame-retarded recycled polyester fiber, cutting off bundles and packaging. The reinforced and flame-retarded recycled polyester chip has the good spinning forming property, the fiber quality is high, the using amount of a fire retardant can be effectively reduced under the synergistic effect of grapheme and the phosphate based flame retardant, the cost is reduced, the reinforcement effect can be achieved and the mechanical property of the fiber is effectively improved.

The invention discloses a styrene series non-halogen flame retardant injection-grade wood plastic composite and a preparation method thereof. The styrene series non-halogen flame retardant injection-grade wood plastic composite is prepared from the following components in percentage by mass: 25-60 percent of styrene series resin, 5-60 percent of plant fiber, 0.5-20 percent of compatilizer, 0-30 percent of flexibilizer, 0.5-8 percent of dispersing agent, 5-40 percent of fire retardant and synergetic fire retardant and 0-1 percent of antioxidant. Compared with the traditional wood plastic composite, the styrene series non-halogen flame retardant injection-grade wood plastic composite prepared by the invention has the characteristics of simple production flow, less consumption amount of fireretardant, good non-halogen flame retardant effect, wide range of moulding ways, and the like, and is suitable for various injection moulded parts such as shells of electric appliances, parts for vehicles, and parts for furniture and buildings, and the like.

The invention relates to the field of composite materials, in particular to a continuously-directional glass fiber reinforcement unsaturated polyester sheet molding compound. The continuously-directional glass fiber reinforcement unsaturated polyester sheet molding compound comprises the following components in part by weight: 15 to 50 parts of unsaturated polyester resin, 5 to 12 parts of low astringent, 8 to 20 parts of chopped glass fibers of 12 to 26 millimeters, 1.5 to 8 parts of directional continuous glass fibers, 10 to 50 parts of calcium carbonate, 10 to 50 parts of aluminum hydroxide, 0.2 to 1 part of organic peroxide, 1 to 4 parts of styrene, 0.2 to 1 part of thickening agent, and 1 to 3 parts of mold discharging agent. The continuously-directional glass fiber reinforcement unsaturated polyester sheet molding compound has the advantages of reasonable formula design, good flame retardance, high strength, low manufacturing cost and stable quality.

The invention discloses a core-shell type ammonium polyphosphate synergetic flame-retardant polyurethane elastic composite material and a preparation method thereof, which is characterized in that the polyurethane elastic composite material containing core-shell type ammonium polyphosphate can be obtained by melting and co-mixing 75-94.9% of polyurethane, 5-25% of core-shell type ammonium polyphosphate and 0.1-5% of synergistic agent at the temperature of 160-220 DEG C for 5-30 minutes by weight percentage. The composite material can ensure that the adding amount of flame retardant is reduced while ensuring the flame retardance effect, and the composite material has good resistance of melt drip, simultaneously improves the shortcoming of poor water resistance of the flame-retardant composite material containing the ammonium polyphosphate, enhances the compatibility of the flame retardant and a polyurethane elastomer and improves the mechanical properties of the material, such as tensile strength, fracture strength and flame retardance performance, thereby meeting the requirements of fire protection safety and engineering applications.

The invention discloses a thermoplastic low-smoke halogen-free flame-retardant environment-friendly sheath material for power cables and a preparation method thereof. The thermoplastic low-smoke halogen-free flame-retardant environment-friendly sheath material for power cables comprises the following components in parts by weight: 60-80 parts of EVA (ethylene-vinyl acetate), 20-30 parts of HDPE (high-density polyethylene), 10-15 parts of EPDM (ethylene-propylene-diene monomer), 15-25 parts of compatiblizing agent, 100-150 parts of halogen-free flame retardant, 0.5-1 part of antioxidant 1035, 0.5-1 part of antioxidant DSTP, 1-2 parts of ethylene bis stearamide, 3-5 parts of DCP (dicumyl peroxide), 2-4 parts of zinc oxide, 1-2 parts of calcium stearate, 10-20 parts of dimethyl methyl phosphonate, 30-40 parts of nano kaolin, 2-3 parts of stearic acid and 0.5-1 part of isopropyl tri(dioctylpyrophosphate)titanate. The sheath material disclosed by the invention has the advantages of excellent physical and mechanical properties, excellent flame retardancy, favorable high/low temperature resistance, favorable oil resistance, favorable solvent resistance, favorable wear resistance, favorable ozone resistance, favorable aging resistance, high flexibility, crack resistance and the like, is very durable, environment-friendly and pollution-free, and can completely satisfy the requirements for modern power cables.

The invention relates to an environmental protection based red mud combination modification synergism fire-retardant polyethylene, and belongs to the technical field of compressive utilization and fire-retardant plastics. The fire-retardant polyethylene is suitable for fire safety protection in important public places in the fields of electric products, building materials and transportation. The fire-retardant polyethylene consists of the following components in percentage by weight: 30 to 35 percent of polyethylene, 34 to 39 percent of red mud, 6 to 13 percent of red phosphorus, 5 to 17 percent of zinc borate, 3 to 8 percent of ethylene-vinyl acetate copolymer, 2 to 7 percent of grafted polyethylene, and 2 to 8 percent of silicone oil. The preparation process comprises the following steps of: grinding and drying the red mud; blending the ground red mud with other raw materials according to the blending ratio; mixing the mixture with polyethylene resin by fully stirring at a high speed; fusing, co-mixing and processing the mixture; and preparing a sample. The processing conditions comprise that: the roll temperature of a double-roller mixing mill is between 140 and 150 DEG C; and the forming temperature of the flat vulcanizing machine sample is between 120 and 130 DEG C, the heating time is between 4 and 8 minutes, and the pressure is between 10 and 20MPa. The fire-retardant system meets the requirements of industrial application on mechanical property, and simultaneously has comprehensive properties such as good fire-retardant effect, low cost, environmental protection and the like; moreover, the application field of the red mud is widened, and the red mud product with high added value is prepared.

The invention relates to a surface precipitation-free flame-retardant polypropylene compound and a preparation method thereof. The surface precipitation-free flame-retardant polypropylene compound comprises the following components by weight percent: 70-98.5% of polypropylene resin, 1-15% of melamine hydrobromide, 0.3-7% of phosphinates, 0.2-4% of flame retardant synergist, 0-2% of synergetic flame retardant, 0-1% of antioxidant and 0-1% of processing acid. The preparation method thereof is implemented as follows: weighting the above components based on proportion, evenly mixing, melt-mixing the above mixture, pelletizing and drying to obtain the product in the invention. The surface precipitation-free flame-retardant polypropylene compound has high flame retardant efficiency, good flowability, no precipitation, and high flame retardant rating up to UL94 V-0, and can satisfy the use requirements of flame retardant materials in building materials, electrical appliance casings, sockets, bellows, lighting lamps and the like.

The invention relates to the field of halogen-free flame-retardant electric wire cable shield materials, in particular to a flexible halogen-free flame-retardant polyphenyl ether electric wire cable shield material and a preparation method thereof. The flexible halogen-free flame-retardant polyphenyl ether electric wire cable shield material is characterized by comprising the following raw materials in percentage: 10 to 30 percent of polyphenyl ether resin; 15 to 35 percent of styrene elastomer; 5 to 10 percent of polyolefin; 8 to 15 percent of plasticizing agent; 3 to 8 percent of compatilizer; 15 to 25 percent of main flame retardant; 2 to 8 percent of synergistic flame retardant; 2 to 8 percent of smoke suppressant; 0.5 to 1 percent of lubricant; 0.5 to 1 percent of antioxygen; and 2 to 3 percent of masterbatch. The flexible halogen-free flame-retardant polyphenyl ether electric wire cable shield material has favorable mechanical property, flexibleness, flame retardant property, heat resistance and processability.

The invention relates to a method for preparing flame-retardant low-smoke halogen-free hot-vulcanized silicone rubber compounds for metro vehicles, which is characterized in that the method comprises the following technological process: adding methyl vinyl silicone rubber to a kneading machine; adding white carbon black and hydroxyl silicone oil; mixing the materials for 1+/-0.1 hour at a nitrogen-supplying speed of 5+/-0.1 cubic meter/hour at a temperature between 170 and 190 DEG C; cooling to 60+/-5 DEG C; adding porcelainizing powder, aluminum silicate, chloroplatinic acid, zinc stannate and aluminum hydroxide; continuing to mix for 0.5+/-0.05 hour; discharging the materials; filtering rubber in a rubber filter; cooling the obtained product to room temperature; adding 2,5-dimethyl-2,5-bis(tert-butylperoxy) hexane or peroxide bis(2,4-dichloro-benzoyl) serving as a curing agent to an open mill; mixing well; and obtaining the flame-retardant low-smoke halogen-free hot-vulcanized silicone rubber compounds for metro vehicles. As the method adopts halogen-free flame retardant and particularly adopts a porcelainizing smoke-cutting technique, smoke almost completely disappears after the product produced by the method burns for a plurality of minutes, and the inside of the product can be kept in good condition.

The invention discloses an enhanced toughened halogen-free flame-retardant polypropylene mixture and a preparation method thereof. The method comprises the steps of: diluting 0.5-3 parts by weight of surfactants with 20-30 parts by weight of absolute ethyl alcohol, then adding into 100 parts by weight of alkaline magnesium sulfate whiskers, mixing for 15-30 min in a mixer, and then drying in a dryer to obtain the modified alkaline magnesium sulfate whiskers, wherein the alkaline magnesium sulfate whiskers is required to be 10-60 mum in average length and less than 10 mu m in diameter; adding polypropylene resin firstly on an open type warming mill with double-roll temperature of 170-180 DEG C, sequentially adding an antioxidant, a toughened modifier, the modified alkaline magnesium sulfate whiskers, a synergistic flame retardant, a molten-drop prevention modifier and a compatibilization modifier after the polypropylene resin is molten and covers the rolls, and evenly mixing to obtain the enhanced toughened halogen-free flame-retardant polypropylene mixture. The polypropylene mixture prepared in the invention has the advantages of high strength, good toughness, low smoke, no toxicity, no molten drop, remarkable flame retardant property and the like.

The invention discloses a polyelectrolyte nanometer flame-retardant coating by adoption of layer-by-layer assembly and a preparation method thereof. The preparation method comprises following steps of: 1), preprocessing: putting and soaking base material into an acid solution and cleaning and drying base material with water; 2), self-assembly: putting and soaking pre-processed base material to a cationic polyelectrolyte solution in order to from a layer of ion membrane, taking out the layer of ion membrane and cleaning the ion membrane with water for drying, putting and soaking the ion membrane into the cationic polyelectrolyte solution in order to form an layer of anionic membrane, and cleaning the layer of anionic membrane with water and drying; sequentially repeating above self-assembly process for multiple times so that the polyelectrolyte nanometer flame-retardant coating is prepared by adoption of layer-by-layer assembly on the surface of the base material. The polyelectrolyte nanometer flame-retardant coating by adoption of layer-by-layer assembly and the preparation method thereof have following beneficial effects: the polyelectrolyte nanometer flame-retardant coating is green and eco-friendly and has a simple and feasible preparation method; damage to the internal structure of base material is avoided; high flame-retardant efficiency is obtained; and the preparation method is suitable for formation of flame-retardant coatings on material surfaces including fabric, wood, foam and plastics.

The invention discloses a method for preparing special aromatic polyoxadiazole and flame-retardant high-temperature resistant polyoxadiazole fiber thereof. The special aromatic polyoxadiazole is prepared by the following method that the special aromatic polyoxadiazole is prepared from terephthalic acid, compound of which the structural general formula is expressed as formula I and hydrazine salt serving as monomers through condensation polymerization reaction. The polyoxadiazole fiber with high flame retardancy and high temperature resistance is prepared by using the special aromatic polyoxadiazole as a raw material. The fiber number of the prepared polyoxadiazole fiber is 1 to 20 dtex, the breaking strength is 2.5 to 5 cN.dtex-1, the elongation at break is 10 to 40 percent, the initial modulus is 50 to 250 cN.dtex-1, the moisture regain is 5.0 to 12.0 percent, the limited oxygen index is 30 to 38 percent, and the initial decomposition temperature is above 480 DEG C. The fiber can be widely used in the fields of protective products, filter materials, electric insulating materials, frictional sealed materials, various industrial textiles, high-temperature resistant paper, aviation and aerospace materials and the like.

Nano-mesoporous molecular sieve synergistic intumescent flame-retardant rubber and a preparation method thereof relate to flame-retardant rubber and the preparation method thereof. The flame-retardant rubber provided by the invention comprises, by weight, 100 parts of a rubber matrix, 1.5-2.8 parts of a vulcanizing agent, 1-1.5 parts of a promoter CZ, 1-3 parts of stearic acid, 4.5-5 parts of zinc oxide, 1-2 parts of an antioxidant 4010, 1-3 parts of liquid paraffin, 30-40 parts of carbon black, 60-80 parts of an intumescent flame retardant, and 0-5 parts of nano-mesoporous molecular sieve. The preparation method provided by the invention comprises the following steps of: plasticating rubber in an open mill, successively adding eleaostearic acid, zinc oxide, the promoter CZ, the antioxidant 4010, the nano-mesoporous molecular sieve, carbon black, liquid paraffin, IFR and sulphur, mixing and discharging tablets, followed by sulfuration. By the adoption of the nano-mesoporous molecular sieve synergistic intumescent flame retardant, its excellent flame-retardant synergistic effect and interfacial compatibility effect greatly improve the flame-retardant performance and mechanical properties of the rubber material.

The invention discloses a halogen-free flame-retardant and cold-resistant PC/ABS (Poly Carbonate/Acrylonitrile Butadiene Styrene) material and a preparation method thereof. The halogen-free flame-retardant and cold-resistant PC/ABS material mainly comprises components of PC and ABS and further comprises a silicon fire retardant, a phosphorus fire retardant, an anti-dripping agent, a compatilizer, a flexibilizer, a lubricant, an antioxidant, and an anti-ultraviolet agent. A preparation process is a twin-screw melting extrusion pelletizing process. According to the preparation method disclosed by the invention, the silicon fire retardant and the phosphorus fire retardant are composited so that the fire resistance 1.2 mm of the obtained PC-ABS alloy material can meet the UL94V-0 class requirement in the United States. The compatilizer MBS (Methyl methacrylate-Butadiene-Styrene) not only enables the PC and the ABS to be better dissolved but also can be used for increasing the compatibility between the silicon fire retardant and a substrate. Therefore, not only can the impact property of the alloy be improved but also the flame retardant efficiency can be effectively improved. The alloy material has the good low-temperature impact property due to the flexibilizer. The silicon fire retardant has a fire retardant synergy effect and further has a smoke suppression effect, so that the fire resistance 1.2 mm of the obtained PC-ABS alloy material can meet the UL94V-0 class requirement in the United States.

The invention relates to a low-L value (less than 27) inflaming retarding ABS modified resin and a preparation method thereof. The resin comprises the components with the content (based on parts by weight): 100 parts of ABS resin, 10-25 parts of brominated flame retardant, 20-40 parts of inorganic inflaming retarding master batch, 0.1-0.5 part of anti-dripping agent, 0.2-1 part of antioxidant, 0.1-0.5 part of light stabilizer, 1-3 parts of lubricating agent and 1-4 parts of black master batch. Compared with the prior art, the invention has reasonable technique, overcomes the defect of high L value (namely, low degree of blackness) of the existing inflaming retarding ABS resin, and adopts the novel high-efficiency inflaming retarding synergistic effect technology. The invention leads the resin has higher degree of blackness by reasonably selecting the grain diameter of antimony trioxide, a carbon black lubricating dispersion system and the processing technique of a master batch method on the basis of maintaining the excellent performance of the inflaming retarding ABS resin, and has wide application prospect in the field of the requirement of high degree of blackness.