9399 results about "Compatibilization" patented technology

The invention relates to the field of electric heating materials, and provides a graphene-based heating coating and a preparation method thereof. The coating is prepared from functionalized graphene, a surface modified bismuth telluride nanobelt, polyaniline, bisphenol A epoxy acrylate, polyurethane acrylate, a dispersing agent, a flatting agent, a silane coupling agent, a defoaming agent and a propylene glycol methyl ether acetate / N-methyl pyrrolidone mixed solvent. The functionalized graphene is obtained by modifying a hyperbranched polyolefin-acryloyl-POSS copolymer, and carrying out ultrasonic stripping, centrifugal separation, gradient washing and vacuum drying; the surface-modified bismuth telluride nanobelt is modified by an amino silane coupling agent, so that the interfacial compatibility is improved. The preparation method comprises the steps of solvent premixing, nanofiller dispersion, ultrasonic homogenization, coupling agent modification, ultraviolet curing and thermocuring. The heating coating provided by the invention has high conductivity, excellent thermal stability and adhesive force, and can be widely applied to heating electric appliances and intelligent temperature control equipment.

The invention provides a photosensitive resin composition containing a photobleaching aminomethyl anthracene photosensitizer and application thereof.The structural main body anthracene ring of the photosensitizer introduces an aminomethyl functional group to the 9th and / or 10th site: through introduction of the aminomethyl functional group, while the electron cloud density of polycyclic aromatic hydrocarbon is maintained, the maximum absorption wavelength is subjected to red shift, and the photosensitive resin composition is especially suitable for a 405nm illumination system; the initiation efficiency is obviously improved; the exposure energy is reduced; compared with an existing DBA type photoinitiator, the problem of alkoxy carbon-oxygen bond breakage caused by p-pi conjugation of DBA is avoided, generation of small molecule fragments is effectively inhibited, defects are reduced, and the yield is increased. In addition, compared with DPHA and DAcOA, the photosensitizer also shows better solubility and formula compatibility. The preparation method has the characteristics of simple preparation process and low cost, and can be widely applied to the photocuring fields of dry films, paints, coatings, printing inks, forming materials and the like.

The invention provides a bismuth oxide-based epoxy resin composite material with a radiation shielding function as well as a preparation method and application of the bismuth oxide-based epoxy resin composite material. According to the preparation method disclosed by the invention, the bismuth oxide is subjected to surface modification, and after surface grafting modification by the coupling agent, the surface of the bismuth oxide is changed from strong hydrophilicity to strong hydrophobicity, so that the dispersity and interfacial compatibility of the bismuth oxide in an organic medium are remarkably improved. Secondly, preparing the composite material from the modified bismuth oxide, epoxy resin and a curing agent through a mechanical blending-vacuum defoaming combined process. On one hand, bismuth oxide, epoxy resin and a curing agent are uniformly mixed through mechanical blending; on the other hand, bubbles generated in the blending process are removed through vacuum negative pressure. The bismuth oxide in the composite material is uniformly distributed, no bubble exists in the body, and the surface is smooth and complete, so that the composite material has excellent gamma-ray shielding performance and good mechanical property. The process is simple, the yield is high, the product property is stable, and good economic benefits and environmental benefits are achieved.

The invention discloses a polypropylene composite material based on rare earth element modification and a preparation method and application thereof, and belongs to the technical field of medical instruments, and the polypropylene composite material comprises the following raw materials in parts by weight: 100 parts of medical grade PP, 3-8 parts of a rare earth organic complex, 5-10 parts of nano-hydroxyapatite, 2-5 parts of a maleic anhydride grafted PP compatilizer and 0.3-0.5 part of an antioxidant, the invention also provides specific preparation steps and application thereof. According to the invention, oxide + salt bimorphological rare earth and an organic ligand are complexed to form a rare earth organic complex, so that the problem of poor dispersity of inorganic rare earth is solved, and meanwhile, the material is endowed with antibacterial and antistatic functions; through a melt blending-in-situ fiber forming process, the rare earth complex forms gradient distribution in a polypropylene matrix, the surface layer is enriched with antibacterial components, and the inner layer is enhanced in mechanical property, so that a low-cost solution with high strength, antibacterial property and biocompatibility is provided for high-end medical instruments, and the market blank is filled.

The invention belongs to the technical field of flame retardants, and particularly relates to a high-thermal-stability polyphosphate flame retardant and a preparation method thereof. The DOPO is modified through the polyethylene glycol acrylate, methyl methacrylate and dicumyl peroxide composite solution, double bonds of the polyethylene glycol acrylate and P-H bonds of the DOPO can be subjected to nucleophilic addition to form stable C-P bonds, and thermal migration of the DOPO is hindered; dOPO has polymerization double bonds of methyl methacrylate and long carbon chains of polyethylene glycol acrylate, so that the compatibility of the polyphosphate flame retardant and a polymer substrate is improved, and phase separation is avoided; maleic anhydride grafted silicone oil is connected to the surface of an amino modified gamma-cyclodextrin-modified DOPO inclusion compound, so that the polyphosphate flame retardant has high thermal stability and high compatibility after long-chain alkyl modification; amino groups in the modified gamma-cyclodextrin react with maleic anhydride grafted silicone oil to generate an amido bond cross-linked network, so that the thermal migration of DOPO is reduced together, and the high thermal stability of the polyphosphate flame retardant is improved.

The invention relates to the technical field of polymeric membrane materials, and particularly discloses an antistatic polyethylene composite membrane and a preparation method thereof. Comprising the following raw materials in parts by weight: 100 parts of low-density polyethylene, 5-9 parts of high-density polyethylene, 10-20 parts of maleic anhydride grafted polyethylene, 8-15 parts of a polyvinyl alcohol modified material, 3-5 parts of antistatic modified carbon black, 0.5-1 part of an antioxidant and 1-2 parts of a dispersing agent, the polyethylene composite film has excellent dispersibility, can effectively enhance the mechanical properties of the polyethylene composite film through the synergistic effect of physical filling and chemical grafting, forms a layer of conductive network structure, namely a conductive film, on the surface of the material through the combined effect of the polyethylene composite film and the antistatic agent, prevents the generation and accumulation of static electricity, and has good compatibility among the raw materials. And the material has excellent mechanical property and antistatic property.

The invention discloses a preparation method of a curing agent with biological self-healing capability, which comprises the following steps: preparing a bacillus pasteurii bacterial solution, preparing the bacillus pasteurii bacterial solution into an endophytic spore solution, immersing polyvinyl alcohol fibers into a sodium alginate / endophytic spore solution, taking out the polyvinyl alcohol fibers, immediately immersing the polyvinyl alcohol fibers into a calcium acetate solution, drying the polyvinyl alcohol fibers to obtain core fibers with a hydrogel coating, and curing the core fibers with the hydrogel coating to obtain the curing agent with biological self-healing capability. The preparation method comprises the following steps: taking magnesium phosphate cement as a raw material, immediately immersing the magnesium phosphate cement into a chloroform solution of a polystyrene and polylactic acid polymer blend, drying to obtain a coated microbial liquid, premixing urea and glucose, doping the premixed urea and glucose into the magnesium phosphate cement, uniformly stirring, adding the coated microbial liquid, and uniformly stirring to obtain the product. According to the invention, phosphate cement is adopted as the curing agent, has the advantages of high strength, short setting time, strong durability, low alkalinity, good biocompatibility and the like, and compared with the curing agent in the prior art, the curing agent not only has a good curing effect, but also has a crack self-healing function, and is especially suitable for reinforcing foundation soil.

The invention relates to the technical field of high polymer material preparation, and discloses a bamboo fiber graft modified full-biodegradable composite membrane material preparation process which comprises the following steps: firstly, performing hot mixing and cooling on dried bamboo fiber powder, anhydrous citric acid, choline chloride, activated zinc oxide and pentaerythritol to prepare a bamboo fiber modified premix; then mixing the biodegradable polyester resin with the premix; adding the mixture into an extruder, injecting epoxidized soybean oil into a barrel through a liquid metering device, and performing melt extrusion granulation under a vacuum exhaust condition; and finally carrying out blow molding to form the film. Through in-situ reaction extrusion of multi-component synergism, surface grafting of bamboo fibers, chain extension of a polyester matrix and interface chemical bonding of the bamboo fibers and the polyester matrix are achieved, interface compatibility is effectively improved, degradation of the material in the processing process is inhibited, and the mechanical property and thermal stability of the composite film material are remarkably improved; the process is efficient and environment-friendly, and the cost is controllable.

The invention relates to the technical field of polypropylene, and discloses a high-strength polypropylene composite material as well as a preparation method and application thereof in an automobile bumper. The high-strength polypropylene composite material comprises the following components in parts by weight: 70-90 parts of polypropylene resin, 10-30 parts of polycarbonate resin, 25-40 parts of glass fibers, 3-10 parts of an allyl carbonate grafted polypropylene compatilizer and the like. The compatilizer contains carbonate groups similar to polycarbonate, so that the compatibility between polypropylene resin and polycarbonate resin is improved, and the compatilizer has higher mechanical properties. Moreover, the compatilizer contains carboxyl and can form interaction with the surface of the glass fiber, so that the compatibility between the glass fiber and the polypropylene resin is improved, the glass fiber has a better reinforcing effect, the tensile strength, the impact strength and the bending strength of the composite material are remarkably improved, and the compatilizer has good practical application in the aspects of automobile bumpers and the like.

The invention discloses a method for preparing a modified PHA composite material by using a twin-screw extruder and application of the modified PHA composite material. The method comprises the following steps: carrying out in-situ melt blending on polyhydroxyalkanoate (PHA), poly (butylene adipate terephthalate)-poly (butylene adipate terephthalate) (PBAT), polyvinyl alcohol (PVOH) and chain extenders in a twin-screw extruder, so that the chain extenders such as polyfunctional group epoxy or isocyanate react with molecular terminal groups of the PHA, the PBAT and the PVOH to form a partially crosslinked or grafted structure; therefore, the compatibility is enhanced, the thermal stability is improved, and the barrier property is remarkably improved. Experiments prove that the obtained modified PHA composite material has the characteristics of high strength, high elongation, excellent water and oxygen resistance and biodegradability, and meets the strict requirements of multiple fields such as food packaging, agricultural plastic mulching films, medical consumables and the like on mechanical properties and barrier properties. The preparation method is simple, convenient and efficient, and large-scale continuous production can be achieved on existing double-screw extrusion equipment.

The invention provides a composite solid-state electrolyte membrane and a preparation method and application thereof, and belongs to the field of lithium battery solid-state electrolytes.The preparation method comprises the steps that solid-state electrolyte powder and carbon precursor powder are pressed into a membrane and then subjected to gradient heating calcination, and a three-dimensional framework porous ceramic membrane is obtained; uniformly mixing a lithium salt, a polymer monomer and an initiator to prepare a polymerization solution; and dropwise adding the polymerization solution onto the three-dimensional skeleton porous ceramic membrane, and carrying out thermal polymerization to obtain the composite solid electrolyte membrane. Aiming at the inorganic solid electrolyte, the composite solid electrolyte membrane with high ionic conductivity and good interfacial compatibility is obtained in a mode of in-situ construction of the composite solid electrolyte membrane, and the problems that the inorganic solid electrolyte is low in ionic conductivity, poor in interface contact and not resistant to high pressure are effectively solved.

The invention relates to the field of textile materials, and particularly discloses a graphene enhanced polyester yarn and a preparation method thereof.The preparation method comprises the following steps that silicon dioxide aerogel serves as a porous carrier to be loaded with graphene, and a graphene-porous carrier composite material is prepared; the graphene-porous carrier composite material is subjected to modification treatment through vinyl trimethoxy silane and 3-amino propyl triethoxy silane, and then a modified graphene composite material is prepared; reacting the modified graphene composite material, a styrene monomer, an acrylate monomer and an initiator to prepare modified graphene; mixing the prepared modified graphene with polyester chips, and then carrying out melt spinning to prepare graphene enhanced polyester yarns; the invention further discloses the graphene enhanced polyester yarn prepared by adopting the preparation method. The preparation method has the characteristics that the dispersion of the graphene in the polyester is improved, and the direct interface compatibility of the graphene and the polyester fiber is improved, so that the mechanical property of the polyester yarn is improved.

The invention discloses a high-viscosity activated rubber powder grafted functionalized block copolymer composite modifier and preparation thereof, composite modified asphalt and preparation and application thereof, and belongs to the technical field of modified asphalt. The composite modifier disclosed by the invention is formed by grafting catechol / polyamine modified aminated rubber powder and an epoxidized block copolymer. A catechol / polyamine group and an amino group are subjected to a condensation reaction to jointly modify the surface of the rubber powder, so that the surface of the rubber powder has rich functional groups and active sites, the rubber powder and an epoxidized block copolymer are subjected to a chemical crosslinking reaction in the later period, and the effect of enhancing the full performance of asphalt by the composite modifier is achieved; the problems that the composite modifier and the modified asphalt are prone to agglomeration, poor in compatibility and the like are solved. A self-healing mixture prepared from the composite modified asphalt and a self-healing material together has synergistic effects of the composite modified asphalt and the self-healing material, so that the pavement performance and the use quality are effectively improved, the service life of a road is prolonged, the energy loss is reduced, and the composite modified asphalt has application value in the field of roads.

An aqueous ultraviolet-absorbing resin emulsion, and an aqueous resin emulsion composition containing the emulsion is provided, wherein the emulsion is excellent in compatibility with a synthetic resin and light resistance. Also, the emulsion improves stability in blending with an aqueous emulsion of the synthetic resin, and prevents bleed out of the ultraviolet-absorbing resin on the surface of a coating film. Further, the aqueous ultraviolet-absorbing resin emulsion imparts excellent alkali or solvent resistance to a synthetic resin poor in alkali or solvent resistance. More specifically, an aqueous resin emulsion composition comprising (I) an aqueous ultraviolet-absorbing resin emulsion and (II) an other aqueous resin emulsion is provided, wherein the emulsion (I) is obtained by urethanizing (A) a polyol component having an ultraviolet-absorbing group {e.g., 1,1-bis[3-(2H-benzotriazol-2-yl)-4-hydroxy-benzeneethanol]methane}, (B) a polyol if necessary, (C) an alkyl or aryl dialkanolamine compound, and (D) an organic polyisocyanate in (E) an organic solvent, diluting the reaction mixture with (F) an organic solvent having a boiling point lower than 100° C. to give a resin solution, neutralizing the resin solution with (G) a neutralizing agent, and dispersing the resultant in water.

The invention discloses reactive compatible ACR-PHA core-shell latex and application thereof, and belongs to the field of polymer chemistry and material science. The latex comprises composite particles with core-shell, gradient core-shell, raspberry-shaped or Janus heterostructure, interfaces of ACR phase and PHA phase of the latex are connected through covalent bonds, and the compatibility problem of physical blending is fundamentally solved. The latex particles have a Z-average particle size of 80-400 nm, a PDI of less than or equal to 0.30, and a minimum film formation temperature (MFFT) of-10 to 12 DEG C. The coating prepared by the invention has excellent high-humidity barrier stability (WVTR is less than or equal to 65g / m.d), low-temperature rapid heat sealability, water resistance, oil resistance and complete recoverability, does not contain PFAS, is an ideal alternative scheme of a traditional PE (Polyethylene) spraying film, and is suitable for the fields of food packaging paper, paper cups, bowls and the like.

The invention discloses a halogen-free flame-retardant TPU (thermoplastic polyurethane) material suitable for a charging pile cable and a preparation method of the halogen-free flame-retardant TPU material, belongs to the technical field of TPU material processing, and aims to solve the technical problem that the flame retardance and wear resistance of a TPU material for a cable in the prior art need to be further improved. The material comprises the following raw material components in parts by weight: 80-100 parts of a cross-linked thermoplastic elastomer, 10-20 parts of a modified filler, 10-20 parts of a flame-retardant chain extender, 3-5 parts of a stabilizer, 3-5 parts of an antioxidant, 3-5 parts of an ultraviolet light absorber and 3-5 parts of a lubricant, after the modified thermoplastic elastomer is prepared, the modified thermoplastic elastomer is activated and cross-linked with the flame-retardant cross-linking agent, a silane structure is introduced into the structure, the flame-retardant cross-linking agent and the modified filler enhance the flame-retardant capability of the material through a synergistic effect, and meanwhile, the compatibility of the material and an inorganic material is enhanced by hybridizing a polyurethane chain segment; the wear resistance, flame retardance and other properties of the material are improved.

The invention discloses a tissue adhesive based on mussel mucin as well as a preparation method and application thereof. The tissue adhesive is prepared from mussel mucin and an anionic compound containing a hydrophobic group, the mussel worm electrostatic self-assembly bionic composite material is developed on the basis of triple bionic principles of dopa adhesion of mussel byssus, electrostatic self-assembly polymerization of sandburg worms and hydrophobic acting force of barnacles. The preparation method of the tissue adhesive is simple, the tissue adhesive can be obtained only by mixing and oscillating the two stock solutions, the gel forming condition is simple and easy to implement, the pH range and the stock solution concentration range required by gel forming are large, the gel forming range is wide, the raw materials required in the preparation process are few, and the cost is low. Only two key raw materials including the mussel mucin and the anionic compound containing the hydrophobic group are needed, and the prepared tissue adhesive is high in adhesion speed and high in adhesion strength, has good cell compatibility and biological safety and can promote wound healing.

The invention relates to a dynamic-covalent hybrid cross-linked hydrogel material as well as a preparation method and application thereof. The preparation method comprises the following steps: dissolving a component A-phenylboronic acid modified polymer derivative in a biocompatible medium to obtain a solution A; dissolving a component B, namely a macromolecular derivative containing a vicinal diol group, into a biocompatible medium to obtain a solution B; dissolving a component C-double bond group modified polymer derivative in a biocompatible medium to obtain a solution C; and mixing the solution A, the solution B and the solution C with certain concentrations for a certain time, and performing illumination under a photoinitiator for a certain time to obtain the dynamic-covalent hybrid cross-linked hydrogel material. Compared with single dynamic bond crosslinking or covalent bond crosslinking, the prepared hydrogel material has machinability and mechanical stability; the hydrogel material has plasticity, shear thinning, self-repairing property and the like in the early stage of crosslinking; enough mechanical strength and long-term stability are realized in the later stage of crosslinking.

The invention discloses a preparation method and application of a water-based polyamide acid sizing agent, and belongs to the technical field of sizing agents. The method comprises the following steps: synthesizing polyamic acid in an organic solvent by adopting dianhydride and diamine in a polymerization manner, after the reaction is finished, cooling a polyamic acid solution to room temperature, transferring into a dropping funnel, dropwise adding into a solvent of which the volume is 10-25 times that of the solution, separating, completely dropwise adding, collecting a precipitate, and drying to obtain solid polyamic acid; and adding a low-grade ester or low-grade ketone solvent into the deionized water, adding the polyamide acid powder into the mixed solvent according to the solid content of 1-20wt.%, stirring at room temperature until the solid disappears, and standing for liquid separation to obtain a lower layer which is the polyamide acid water-based sizing agent. The sizing agent disclosed by the invention shows excellent dispersity and long-term stability. After sizing, polyamide acid on the surface of the carbon fiber is converted into polyimide through a thermal imidization reaction, so that the carbon fiber has high thermal stability and excellent compatibility.

The invention provides a composite solid electrolyte and a preparation method thereof, and belongs to the technical field of solid electrolyte materials. The solid electrolyte powder, the photosensitive resin monomer, the lithium salt, the plasticizer and the photoinitiator are used as raw materials to prepare the composite solid electrolyte, the plasticizer can be inserted between polymer chains, the compatibility of the solid electrolyte powder and a polymer is improved, electrode interface contact is improved, the flexibility of the composite solid electrolyte is improved, and the service life of the composite solid electrolyte is prolonged. The ionic conductivity of the composite solid electrolyte is further improved; the photosensitive resin monomer and the photoinitiator can be subjected to photopolymerization in-situ curing, so that the composite solid electrolyte has better mechanical property and flexibility, electrode interface contact is improved, and the ion conductivity is improved.

The present invention uses commercially available 3-aminopropylsilane coupling agent, diallylamino polyether acrylate, and an alkylating agent, or γ-propanesultone, or γ-butyrolactone as raw materials, and through an aza-Michael addition reaction and a quaternization reaction, a multifunctional silane coupling agent containing one or more quaternary ammonium cations, or sulfobetaine, or carboxybetaine in its molecular structure is prepared, which is used for the surface modification of bioactive glass, and the bioactivity, antibacterial and antifungal properties, and hydrophilicity enhancement effects after the surface modification of bioactive glass are obtained.

The invention provides an anti-aging flame-retardant epoxy resin coating and a preparation process thereof, and belongs to the technical field of coating preparation. The preparation process comprises the following steps: preparing the flame-retardant additive; preparing a coated modified black phosphorus nanosheet; preparing modified hollow glass beads; preparing the epoxy resin coating. The preparation method comprises the following steps: dissolving 3, 4-dihydroxy benzaldehyde and 2-amino-4-methylphenol in absolute ethyl alcohol, carrying out a heating reflux reaction, carrying out dehydration condensation on an aldehyde group in the 3, 4-dihydroxy benzaldehyde and an amino group in the 2-amino-4-methylphenol to generate an imine bond-containing intermediate, respectively dissolving the intermediate and phosphonitrilic chloride trimer, and carrying out a reaction to obtain the phosphonitrilic chloride trimer. The preparation method comprises the following steps: firstly, adding phosphonitrilic chloride into an intermediate, then mixing for reaction, enabling phenolic hydroxyl groups in the intermediate and phosphonitrilic chloride trimer to be subjected to nucleophilic substitution reaction to generate the flame-retardant additive containing phosphorus and a Schiff base structure, and the flame-retardant additive has relatively good compatibility with an epoxy resin matrix, is not easy to separate out and can effectively improve the flame-retardant property of the epoxy resin coating.

The invention belongs to the field of building decoration materials, and discloses a GRG gypsum composite reinforced material and a preparation method thereof. The high-strength concrete is prepared from the following components in parts by weight: 45 to 65 parts of alpha-semi-hydrated gypsum, 12 to 20 parts of composite reinforced fiber, 0.5 to 2 parts of graphene nanofiber, 2 to 5 parts of nano silica fume, 5 to 10 parts of ethylene-vinyl acetate copolymer latex powder, 1 to 2.5 parts of hydroxypropyl methyl cellulose, 0.1 to 0.8 part of polycarboxylic acid type water reducing agent, 1 to 4 parts of calcium stearate, 3 to 8 parts of vermiculite powder and 28 to 40 parts of deionized water. Aiming at the problems that an existing GRG material is insufficient in mechanical property, low in fireproof grade, poor in thermal performance, poor in durability and the like, a multi-dimensional synergistic enhancement system is constructed by adopting composite reinforced fibers, functional nanofiller and a gradient preparation process, the problems of dispersion and interfacial compatibility of the nanofiller are solved, and the comprehensive performance of the GRG material is improved. The performance breakthrough of high strength, high fire resistance, low heat conduction and long durability is realized.

The invention relates to the technical field of TPU (thermoplastic polyurethane) protective films, in particular to a fluoride-free antibacterial TPU protective film and a preparation method thereof. The fluoride-free antibacterial TPU protective film comprises the following raw materials in parts by weight: 35-40 parts of TPU particles, 10-15 parts of a balance regulator, 8-12 parts of an antibacterial agent, 3-6 parts of an antioxidant, 3-5 parts of a heat stabilizer and 2-3 parts of a lubricant. According to the TPU protective film disclosed by the invention, TPU particles are matched with the antibacterial agent, the antioxidant, the heat stabilizer and the lubricant to serve as functional aids, and the balance regulator and the filling agent doped with flaky boron nitride are added to coordinate, cooperate and jointly achieve synergistic effects, so that the product is excellent in raw material interfacial compatibility, and the antibacterial property, barrier property and mechanical property of the product are improved in a coordinated and balanced manner; and the product has remarkable weather-resistant and acid-corrosion-resistant stability effects.

The invention relates to the technical field of thermal management material preparation, solves the technical problems of loose heat conduction network structure and non-uniform heat conduction direction of a flexible composite phase change material, and particularly relates to a magnetic polymer-based flexible composite phase change material and a preparation method thereof. Comprising the following steps: preparing a modified polydimethylsiloxane prepolymer from a carbon nanotube dispersion liquid and a polydimethylsiloxane prepolymer; adopting a Pickering emulsion method to mix 42 # paraffin, the modified polydimethylsiloxane prepolymer and nano cellulose to prepare a composite phase change material emulsion; silver mirror reaction is adopted to carry out surface silver plating on the magnetic neodymium iron boron particles; the magnetic polymer-based flexible composite phase change material is prepared from the composite phase change material emulsion and the surface-silvered magnetic neodymium iron boron particles. The high flexibility and magnetism of the prepared material in a normal temperature state endow the material with a more convenient installation mode and lower contact thermal resistance, the heat conduction network structure and component compatibility of the material are improved, and the application requirements of a phase change thermal management technology can be met.

The invention provides an aerogel-based heat-preservation, heat-insulation and waterproof composite coating material for a building outer wall and a preparation method thereof, and belongs to the field of building materials. Through hydrophobic modified silicon dioxide aerogel, a lightweight heat insulation frame is provided, and the waterproofness and compatibility are improved; the mechanical property and the crack resistance are enhanced through the modified potassium titanate nanofibers, and self-adaptive heat insulation is achieved; the thermoelectric effect, the wear resistance and the thermal regulation performance are optimized through plasma treatment and polyaniline coated tungsten carbide nanoparticles; the heat management performance, the crack resistance and the comprehensive heat insulation and waterproof capacity are improved through graphene oxide composite modified boron nitride; the flexibility, the hydrophobicity and the interfacial compatibility are improved through organic silicon modified bisphenol A epoxy resin; and the performance of the coating is optimized through the synergistic effect of the components.

The invention discloses injectable hydrogel capable of rapidly stopping bleeding and a preparation method thereof. The injectable hydrogel is prepared from a natural high-molecular compound, a natural high-molecular polymer, an organic high-molecular polymer, a catechol-like organic compound, a cross-linking agent and ultrapure water. A natural high-molecular linear polymer is combined with an organic high-molecular polymer in a non-covalent bond manner to form a macromolecular polymer, and the macromolecular polymer is used as a main network skeleton of the hydrogel to provide strength support; the catechol-like organic compound and the natural high-molecular compound form a strong non-covalent effect in a polymer chain to enhance the strength, the hemostatic property, the antibacterial property, the adhesion and the self-healing property of the organogel; besides, under the action of the cross-linking agent, the catechol-like organic compound forms a free radical group to be subjected to free radical coupling with the macromolecular polymer, so that the effect of enhancing a hydrogel network is achieved, and meanwhile, hydrogen bonds, dipole-dipole interaction, static interaction and the like can be formed with polar functional groups on the surface. The hemostatic gel is rapid in hemostasis, simple to prepare, good in biocompatibility, good in antibacterial property, injectable and degradable.

The invention discloses preparation of DOPO-based hollow polymer microspheres and application of the DOPO-based hollow polymer microspheres in flame-retardant polymers, and belongs to the technical field of high polymer materials. The preparation method of the DOPO-based hollow polymer microspheres comprises the following steps: preparing a template core through self-stable precipitation polymerization, then polymerizing a DOPO-based flame-retardant monomer, an anhydride monomer and a cross-linking agent on the surface of the template core to construct a cross-linking shell layer in situ to obtain copolymer microspheres with a core-shell structure, and finally removing the template through solvent etching to obtain the DOPO-based hollow polymer microspheres. And the DOPO-based hollow polymer microspheres are prepared. The compatibility between the DOPO-based hollow polymer microspheres and a polymer matrix is greatly improved through rich anhydride groups on the surfaces of the DOPO-based hollow polymer microspheres, the flame retardant property of the polymer composite material is improved, the mechanical property of the polymer composite material is greatly improved, and due to the unique hollow structure of the polymer composite material, the flame retardant property of the polymer composite material is greatly improved. The polymer material is endowed with excellent transparency and low dielectric property.

The invention discloses a high-strength PET composite material and a preparation method thereof, and relates to the technical field of polymer materials. The invention first adds fumed silica during the preparation of graphene aerogel, and the siloxy groups on the surface of the fumed silica combine with the hydroxyl groups of the graphene oxide hydrogel, and the aerogel is mixed after heat treatment, which can improve the strength of the composite material and achieve excellent hydrophobic effect; secondly, dopamine is grafted on the surface of the aerogel, and the amino groups of the dopamine and the silanol groups of the silica undergo dehydration condensation to form a composite swelling layered silicate to prepare a hybrid filler; dopamine improves the dispersibility and compatibility of the filler in PET; when fine cracks appear in the composite material due to aging, the swelling layered silicate and the dopamine rainwater work together to achieve a self-repairing effect, and can also remove free radicals, so that the strength of the composite material is stable and the anti-aging performance is improved. The PET composite material prepared by the invention has high strength and anti-aging effects.