The invention belongs to the technical field of waste plastic
cracking, and particularly relates to a PVC
cracking dechlorination method and a catalyst used in the method. The used catalyst is X / ZSM-5; and the
mass of the
active component X is 8-16 wt% of the ZSM-5
molecular sieve. And adding a ZSM-5
molecular sieve into the precursor X
salt solution, heating in a water bath, stirring, carrying out rotary
evaporation,
drying and
roasting to obtain the catalyst. In the PVC
cracking dechlorination method, PVC is pretreated and then crushed into
solid particles, the
solid particles are put into a high-pressure feeding
pipe, and a catalyst X / ZSM-5 is put into a
fluidized bed; and after fluidizing the catalyst, blowing PVC into the reactor, and reacting in an
inert gas
atmosphere to obtain an oil product and olefin. According to the catalyst disclosed by the invention, the
active components are in the pore channels and the outer surfaces of the molecular sieves, so that the preparation method is simple, HCl in high-temperature cracked oil gas can be fixed, the
chlorine content in a gas-phase product and a liquid oil product can be reduced, the reaction time is short, the cost is low, the dechlorination process is strong, and the added value of the product is high.