The invention relates to an anti-aging spraying-free ABS (
Acrylonitrile Butadiene
Styrene) material and belongs to the technical field of spraying-free ABS materials. A sulfydryl modifier is creatively utilized to carry out surface treatment on the
pigment, surface sulfydryl is firstly constructed, then cis-1, 2-dimethylol
ethylene is used as a bridging agent, unsaturated double bonds of cis-1, 2-dimethylol
ethylene and the sulfydryl are subjected to a click reaction,
grafting of double-terminal hydroxyl groups is achieved,
hexamethylene diisocyanate is added, and the surface sulfydryl modified
pigment is prepared. The preparation method comprises the following steps: converting a double-terminal hydroxyl group into a double-terminal
isocyanate group based on the action of a hydroxyl group and an
isocyanate group, and finally finishing the modification of a polar group and an
antioxidant by taking a material prepared from
glycollic acid and 2, 2 '-thiobis (4-methyl-6-tert-butylphenol) according to a certain
mass ratio as a composite modifier, thereby obtaining the modified
pigment. The anti-aging spray-free ABS material is obtained by mixing the modified
polypropylene with the
lubricant and ABS, extruding and the like in sequence, and not only is good in aesthetic effect, but also is excellent in anti-aging performance.