998 results about "Uv absorbance" patented technology

The invention discloses a colorimetric and fluorescent dual-mode nano-enzyme sensor. The colorimetric and fluorescent dual-mode nano-enzyme sensor comprises nano-enzyme, hydrogen peroxide and a colorimetric probe, wherein the nano-enzyme is prepared from ZrCl4, 2-aminobiphenyl dicarboxylic acid and Cu (NO3) 2 by a one-pot method; the colorimetric probe is TMB, can oxidize colorless TMB into blue oxTMB, generates an ultraviolet absorption peak at 652 nm, and has a strong fluorescence emission peak at 405 + / -5 nm. The zirconium-based metal organic framework UiO-67-NH2 with high stability is used as a carrier, Zr < 4 + > sites are replaced by part of Cu < 2 + >, the fluorescent nano-enzyme with peroxidase activity is formed, and the problems that free enzyme is difficult to recover, the stability is low and the like are solved.

The invention relates to the technical field of functional fabrics, and discloses a high-strength waterproof anti-ultraviolet fabric and a preparation method thereof.The fabric is obtained by dipping base cloth into a finishing agent, and the base cloth is obtained by blending and weaving polyester fibers and ultra-high molecular weight polyethylene fibers; the finishing agent is obtained by stirring and mixing deionized water, anti-ultraviolet modified titanium dioxide, a softening agent, an antistatic agent and polyurethane resin, the polyester fibers and the ultra-high molecular weight polyethylene fibers in the fabric have the characteristic of high strength, and nano titanium dioxide and an anti-ultraviolet absorbent in the anti-ultraviolet modified titanium dioxide have a synergistic effect, so that the fabric has excellent anti-ultraviolet performance; the polyurethane resin in the finishing agent and the silane-modified nano titanium dioxide have a synergistic effect, a uniform mechanical network is formed on the surface, the polyurethane resin and the silane-modified nano titanium dioxide complement each other, the dispersity is good, the compactness and the adhesiveness are good, and excellent durability and waterproof performance are achieved.

The invention discloses a shielding protection adhesive tape for semiconductor integrated circuit packaging and a preparation method thereof, and relates to the technical field of semiconductor integrated circuit packaging. The shielding protective adhesive tape for packaging the semiconductor integrated circuit is prepared by taking polyimide as a base material and coating a coating, and the coating comprises the following raw materials in parts by weight: 3-5 parts of modified nano silicon dioxide, 30-40 parts of N, N-dimethylformamide, 1-3 parts of a curing agent and 1-3 parts of a curing agent. The invention discloses a high-temperature-resistant epoxy resin coating which is prepared from the following components in parts by weight: 25-30 parts of N, N-dimethylformamide, 25-30 parts of a modified acrylate copolymer, 17-26 parts of ethyl acetate, 12-15 parts of epoxy resin, 1-2 parts of a silane coupling agent KH-550, 0.5-1 part of an antioxidant 1010, 0.3-0.8 part of an ultraviolet absorbent UV-327, 1-2 parts of carboxyl-terminated nitrile rubber, 2-4 parts of decabromodiphenyl ether, 0.1-0.3 part of an organic siloxane defoaming agent, 0.2-0.5 part of an acrylate flatting agent and 10-11 parts of diaminodiphenyl sulfone. The adhesive tape contains the modified nano silicon dioxide, the modified acrylate copolymer and other components, so that the performance of the adhesive tape is guaranteed; pretreatment is meticulous, preparation steps are standard, and mass production is easy; a finished product can be effectively shielded, and the packaging yield and the product stability can be improved.

The invention belongs to the field of functional textile materials, and provides a cool-feeling anti-ultraviolet nylon fabric and a preparation method thereof, and the cool-feeling anti-ultraviolet nylon fabric adopts a design scheme of combining a boron nitride / titanium dioxide composite filler with a beta-hydroxyl ether type ultraviolet absorption silane coupling agent surface modification technology. Uniform loading of hexagonal boron nitride on the surface of anatase type titanium dioxide is realized through an in-situ heat treatment process, a composite structure with heat conduction and ultraviolet shielding functions is constructed, and a complete process flow of master batch preparation, melt spinning, weaving, after-treatment and the like is matched; the ultraviolet protection coefficient UPF of the fabric is not lower than 40, the UPF retention rate after 20 times of household washing cycles is not lower than 80%, and the cool feeling qmax at the contact moment is not lower than 0.20 W / cm, the technical problem that an existing nylon fabric is insufficient in ultraviolet resistance and cool feeling function is solved, and the fabric has wide industrial application value.

The invention relates to the field of color master batches, and discloses a color master batch with good colorability and high weather resistance as well as a preparation method and application of the color master batch, and the color master batch comprises the following components: polyolefin-based resin, core-shell structure carbon black particles, a hyperbranched dispersant, a grafted ultraviolet absorbent, a CeO2 / TiO2 composite photocatalytic additive and a dynamic cross-linking agent; the preparation method comprises the following steps: S1, carrying out functional modification treatment on the core-shell structure carbon black particles; s2, synthesizing a hyperbranched dispersant; s3, preparing a grafting type ultraviolet absorbent; s4, preparation of a CeO2 / TiO2 composite photocatalytic auxiliary agent; s5, premixing all the components; s6, performing double-screw dynamic cross-linking extrusion molding; and S7, cooling and granulating. The thermal stability of the color master batch is effectively improved by introducing the dynamic cross-linking agent and the ultraviolet absorbent, and the dynamic cross-linking agent forms a three-dimensional network structure by cross-linking resin molecules, so that the color master batch has better stability under a high-temperature condition.

The invention relates to a formamidine thiosulfate second-order nonlinear optical crystal and preparation and application thereof, the chemical formula of the crystal material is [CH (NH2) 2] 2SO3S, the molecular weight is 203.27, the crystal material belongs to an orthorhombic crystal system, the space group is P212121, the unit cell parameter is # imgabs 0 # alpha = beta = gamma = 90 degrees, Z = 4, and the unit cell volume is # imgabs 1 #. Under 1064nm laser irradiation, the frequency doubling intensity of the powder is about two times that of monopotassium phosphate crystals, and phase matching can be realized. In addition, the crystal material has a wide light transmission wave band, the ultraviolet absorption cut-off edge is 253 nm, the optical band gap is 4.90 eV, and the crystal material is easy to grow. The wavelength range of the coherent light source can be expanded by using optical frequency conversion technologies such as second harmonic generation and optical parametric amplification. Therefore, the crystal material has important application value in the fields of laser frequency conversion, photoelectric information storage and the like.

The invention relates to the technical field of organic material detection, in particular to an imine molecular sensor with a five-detection function, two-component gel as well as a preparation method and application of the imine molecular sensor. The imine molecular sensor has three signal responses of fluorescence on-off, ultraviolet absorption and color change to Fe < 3 + >, Co < 2 + > and Ni < 2 + > in a solution state, and has ultraviolet absorption and fluorescence on-off dual-detection performance to acid and alkali changes; the imine molecular sensor and cholesteryl half ester can form two-component gel through a heating-low-temperature ultrasonic cooling method; after Fe < 3 + >, Co < 2 + >, Ni < 2 + >, NaOH and HCl are respectively added, the orange of the gel becomes milky white, reddish brown, transparent red, milky white and milky white under sunlight, and the fluorescence of the orange of the gel disappears under an ultraviolet lamp, so that the rapid and sensitive detection of Fe < 3 + >, Co < 2 + >, Ni < 2 + >, acid and alkali under two states of the imine molecular solution and the gel is realized. The imine molecular sensor provided by the invention has the advantages of mild synthesis conditions, simple preparation and the like, and creates favorable conditions for popularization and application of the imine molecular sensor.

The invention provides a colorimetric / fluorescent dual-mode sensor, a preparation method of the colorimetric / fluorescent dual-mode sensor and application of the colorimetric / fluorescent dual-mode sensor in histamine detection. The colorimetric / fluorescent dual-mode sensor comprises a horseradish peroxidase-loaded metal organic framework (HRP-AIE-MOF), hydrogen peroxide and a chromogenic substrate o-phenylenediamine (OPD), horse radish peroxidase (HRP) in the HRP-coated AIE-MOF can oxidize colorless OPD into yellow 2, 3-diaminophenazine (DAP), an ultraviolet absorption peak is generated at 425 nm, a strong fluorescence emission peak is generated at 555 nm, the HRP-coated AIE-MOF has a strong fluorescence emission peak at 450 nm, and the HRP-coated AIE-MOF and a fluorescence signal of the DAP can form a ratio fluorescence sensor. According to the invention, the excellent catalytic ability of natural enzyme and the luminescence characteristic of AIE-MOF are integrated in one system, and high-sensitivity histamine detection is realized.

The invention discloses a high-corrosion-resistance powder coating and a preparation method thereof, and belongs to the technical field of powder coatings. Through modification of the resin system, the ultraviolet absorbent modified epoxy resin and the weather-resistant polyester resin are compounded, so that the ultraviolet resistance and the weather resistance of the resin system are remarkably improved, and the corrosion resistance reduction caused by light aging is avoided; the flake graphene forms an excellent physical barrier to block corrosion medium permeation, then chemical passivation of zinc phosphate is combined to inhibit electrochemical corrosion, the synergistic effect is achieved, the corrosion resistance is synergistically enhanced from the physical and chemical angles, the path of the corrosion medium is further prolonged in combination with the laminated structure of the glass flakes, and the corrosion resistance is improved. And meanwhile, the filler A and the filler B can also play a role in enhancing the mechanical strength of the coating, so that the powder coating with high corrosion resistance can be obtained on the whole.

The invention relates to a method for simultaneously detecting three related substances in an olpinapone starting material. According to the detection method, the three related substances in an opinapone starting material are simultaneously detected by using a gas chromatographic method of a hydrogen flame ionization detector. According to the detection method, the problem that three related substances cannot be detected simultaneously due to weak ultraviolet absorption and large difference under the liquid chromatography condition can be solved, the matrix effect generated by an opiapone starting material under the gas chromatography condition can be eliminated, the condition that the separation degree of the three related substances is poor is improved, and the detection accuracy is improved while the detection efficiency is improved. And the true and reliable quality of the initial material of the olpinapone is also ensured. The method can be used for simultaneously and quantitatively detecting three related substances higher than 0.02% in the initial material of the opinapone, and is high in sensitivity, good in separation degree, high in practicability and simple and rapid in detection process.

The invention discloses an organic / inorganic composite anti-ultraviolet polyamide 66 fiber master batch, a preparation method thereof and a functional fiber. The organic / inorganic composite anti-ultraviolet polyamide 66 fiber master batch is prepared from the following raw materials in parts by weight: 50-85 parts of polyamide 66 resin; 10 to 45 parts of an organic / inorganic composite anti-ultraviolet nano material; 0.5 to 10 parts of a fluorescent whitening agent; 0.2 to 5.0 parts of a dispersant; the organic / inorganic composite anti-ultraviolet nano material is prepared from an inorganic anti-ultraviolet material, a coupling agent and an organic ultraviolet absorbent. The fiber and the fabric which are made of the master batch have an anti-ultraviolet function, and also have higher strength, smaller fineness, soft luster, soft hand feeling and comfort.

The invention relates to the technical field of high polymer materials, in particular to a light-aging-resistant flame-retardant ABS material for an electric fitting box and a preparation method of the light-aging-resistant flame-retardant ABS material. Comprising the following raw materials: ABS resin, AS resin, ABS high rubber powder, CPE, bromotriazine, carrier-free antimony trioxide master batch, a flame retardant synergist, precipitated barium sulphate, titanium dioxide, a main antioxidant, an auxiliary antioxidant, a lubricant, an anti-dripping agent, a dispersing agent and an ultraviolet absorbent. The material has excellent flame retardant property, and the synergistic effect of the flame retardant components such as the bromotriazine and the like reaches a high flame retardant grade; the ultraviolet absorbent and the titanium dioxide can delay aging and stabilize the color; the melt flow rate is high, and the fluidity is improved through cooperation of high-melt-index ABS and low-molecular-weight AS resin; the mechanical property is good, and the raw materials cooperate to guarantee strength and toughness; the appearance quality is good, pocking marks are avoided, and the glossiness is good. The preparation process is simple, and conventional equipment and reasonable parameters ensure stability and operability.

In example implementations, a three-dimensional printing kit for printing a colorless three-dimensional object in a three-dimensional printing system is provided. The three-dimensional printing kit includes a build material and an aqueous ultraviolet (UV) fusing agent. The aqueous UV fusing agent includes water in greater than 50 weight percent of the aqueous UV fusing agent and a UV absorber cyclodextrin complex.

The invention discloses a coating liquid and a photovoltaic front panel. The coating liquid comprises a component A and a component B, the component A comprises the following raw materials in parts by weight: 15-35 parts of fluorocarbon resin; 20 to 40 parts of acrylic resin; 1 to 10 parts of matting resin; 1 to 5 parts of an ultraviolet absorbent; the component B comprises a curing agent, and the curing agent comprises-NCO groups. Therefore, when the coating liquid disclosed by the invention is coated on the photovoltaic front panel, powdering of the photovoltaic front panel caused by long-term ultraviolet irradiation can be effectively resisted, and meanwhile, the coating also has excellent scratch resistance, light transmission and water vapor barrier rate.

The invention provides a colorimetric / fluorescent dual-mode nano-enzyme sensor, a preparation method thereof and application of the colorimetric / fluorescent dual-mode nano-enzyme sensor in formaldehyde detection. The sensor comprises a metal organic framework nano-enzyme AIE-MOF coated PCN-222 loaded with an AIE-MOF material, hydrogen peroxide and a chromogenic substrate o-phenylenediamine OPD; the metal organic framework nano enzyme PCN-222 in the AIE-MOF-coated PCN-222 can oxidize colorless OPD into yellow 2, 3-diaminophenazine DAP, an ultraviolet absorption peak is generated at the position of 450 nm, a strong fluorescence emission peak is generated at the position of 560 nm, the AIE-MOF-coated PCN-222 has a strong fluorescence emission peak at the position of 446 nm, and the AIE-MOF-coated PCN-222 and a fluorescence signal of the DAP can form a ratio fluorescence sensor. According to the invention, the excellent catalytic ability of the nano-enzyme and the luminescence characteristic of AIE-MOF are integrated in one system, so that high-sensitivity formaldehyde detection is realized.

The present invention discloses an infrared-shielding polyurethane glass film and a preparation method thereof, relating to the field of polymer materials technology. When preparing the infrared-shielding polyurethane glass film, the present invention comprises reacting an organic nickel complex and 3-imidazole-1-propionic acid to produce a functionalized crosslinker; sequentially reacting 4-aminophenylacetonitrile with 3-hydroxypropyl acrylate and quinoline-4-carboxaldehyde to produce a UV-absorbing monomer; reacting polypropylene glycol, a UV-absorbing monomer, 1,4-butanediol, and 4-chloromethyl-1,3-phenylenediisocyanate to polymerize to produce polyurethane; reacting tungsten-doped titanium dioxide and chloropropyltriethoxysilane to produce modified titanium dioxide; and uniformly mixing the polyurethane, modified titanium dioxide, the functionalized crosslinker, and acetone, followed by coating and curing to produce the infrared-shielding polyurethane glass film. The infrared-shielding polyurethane glass film prepared by the present invention has excellent infrared shielding, anti-aging, antibacterial, and mechanical properties.

The invention discloses an anti-yellowing PVB (Polyvinyl Butyral) adhesive for laminated glass and a preparation method thereof, and relates to the technical field of adhesives. The yellowing-resistant PVB glue for the laminated glass has the advantages that the yellowing resistance is high; the modified PVB / nano silicon dioxide composite material is prepared from the following raw materials in parts by weight: 55 to 65 parts of modified PVB resin, 4 to 6 parts of modified nano silicon dioxide, 15 to 20 parts of dioctyl adipate, 0.5 to 1 part of a compound antioxidant, 0.3 to 0.8 part of an ultraviolet absorbent UV-327, 0.2 to 0.5 part of a silane coupling agent KH-560, 0.3 to 0.6 part of ethylene bis stearamide, 0.1 to 0.3 part of 2-benzimidazole methyl carbamate, 3 to 5 parts of tris (1-chloro-2-propyl) phosphate and 0.1 to 0.3 part of nano titanium dioxide. 5 to 8 parts of isopropanol; 0.8 to 1.2 parts of polycarbodiimide. The special modified PVB resin and the nano silicon dioxide are matched with the auxiliary agents such as the compound antioxidant, the anti-yellowing performance of the PVB glue for the laminated glass is remarkably improved through precise process preparation, the components have a synergistic effect, the process is controllable, the product performance is stable, and the cohesiveness is good.

The invention discloses an anti-ultraviolet high-flame-retardant polyester fiber and a preparation method thereof. The polyester fiber is prepared from the following raw materials in parts by weight: 100 parts of polyester chips, 20-60 parts of core-shell flame-retardant anti-ultraviolet particles and 2-4.5 parts of an anti-dripping agent. According to the invention, a porous alumina-titanium dioxide compound is used as a carrier, a magnesium hydroxide flame retardant, iron-doped carbon dots with photo-thermal performance and auxiliaries (an antioxidant and an ultraviolet light absorber) are combined with the carrier to construct a structural system loaded with multiple active components: functionalized flame-retardant particles, and then a polyurethane microporous membrane is coated, so that the flame-retardant polyurethane composite material is obtained. The core-shell type flame-retardant anti-ultraviolet particles are added into polyester fibers, so that the anti-ultraviolet performance and the flame-retardant performance of the polyester fibers can be remarkably improved. The polyester fiber provided by the invention can adaptively increase the release rate of the ultraviolet absorbent and the antioxidant when the ultraviolet property is enhanced in the environment, so that more optimized protection can be provided for a polyester fiber matrix at the moment.

The invention discloses a UV-cured high-weather-resistance optical thin film and a preparation method thereof, and relates to the technical field of optical thin films. The optical film is prepared by taking polyethylene glycol terephthalate as a base material and coating the base material with a UV curing coating, and the UV curing coating comprises the following raw materials in parts by weight: 15-20 parts of aliphatic polyurethane acrylate, 5-8 parts of perfluorobutyl ethyl acrylate, 8-12 parts of hydroxyethyl acrylate, 6-10 parts of 1, 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate, 1-3 parts of 1, 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate, 1-3 parts of 1, 2, 4-trimethyl-1, the invention relates to a UV (ultraviolet)-resistant coating which is prepared from the following raw materials in parts by weight: 1-2 parts of 2, 6-hexanediol diacrylate, 5-8 parts of trimethylolpropane triacrylate, 30-40 parts of modified epoxy acrylate, 1-2 parts of a silane coupling agent KH-570, 2-3 parts of a photoinitiator 1173, 0.5-1.2 parts of a modified ultraviolet absorbent UV-327, 0.8-1.5 parts of a hindered amine light stabilizer 540, 0.3-0.8 part of an antioxidant 1010, 0.09-0.12 part of an ultraviolet absorbent Tinuvin400 and 0.2-0.5 part of polyether modified polydimethylsiloxane. According to the UV-cured high-weather-resistance optical thin film, polyethylene glycol terephthalate is used as a base material, key raw materials such as a UV-cured coating with a scientific formula, modified epoxy acrylate and the like are finely prepared, a two-stage curing process is adopted, and the weather resistance is excellent.

The invention relates to a trimethylamine methanesulfonate second-order nonlinear optical crystal material and preparation and application thereof, the chemical formula of the crystal material is [(CH3) 3NH] < + > [SO3CH3] <->, the molecular weight is 154.21, the crystal material belongs to an orthorhombic crystal system, and the space group is Pca21 (No.29). According to the present invention, the powder frequency doubling effect of the nonlinear optical crystal [(CH3) 3NH] + [SO3CH3]-under 1064nm laser irradiation is about 0.5 time of the powder frequency doubling effect of the nonlinear optical crystal [(CH3) 3NH] + [SO3CH3]-under 1064nm laser irradiation, phase matching can be achieved, and the ultraviolet absorption cutoff edge is less than 200nm. The crystal material is easy to grow and shows important application value in the aspects of electro-optical modulation, holographic storage elements, frequency doubling devices and the like.

The invention provides a compression-molded light transparent high-heat wear-resistant rubber and plastic outsole and a preparation method thereof, and the compression-molded light transparent high-heat wear-resistant rubber and plastic outsole is prepared from the following materials in parts by mass: 50-60 parts of high-hardness thermoplastic resin; 10 to 20 parts of polydiene rubber; 20 to 30 parts of mixed polyurethane; 3-5 parts of a heat conduction auxiliary agent; 0.5-1 part of an anti-aging agent; 0.1 to 0.3 part of an ultraviolet absorbent; 0.1 to 0.3 part of a lubricant; and 0.3 to 0.5 part of a cross-linking agent. The limited components are internally mixed by an internal mixer and then are subjected to flat-plate mould pressing vulcanization to obtain the light transparent high-heat wear-resistant rubber and plastic outsole which is formed by mould pressing. According to the light transparent high-heat wear-resistant rubber and plastic outsole, nano spherical aluminum oxide is added as a heat-conducting additive, so that light scattering caused by refractive index difference between filler and a matrix and particle aggregation is effectively reduced, and the original transparent texture of the material is maintained to the greatest extent while the material is endowed with a heat-conducting function; the sole is especially suitable for high-strength sports shoes such as basketballs, racing running shoes and the like which have harsh requirements on sole performance.

The invention relates to the field of photovoltaic adhesive films, and discloses an anti-migration long-service-life light conversion adhesive film and a preparation method and application thereof.The anti-migration long-service-life light conversion adhesive film comprises a light conversion layer, an anti-migration layer and a UV cut-off layer which are sequentially arranged in an attached mode; the raw materials of the light conversion layer comprise first matrix resin and a light conversion agent; the raw materials of the anti-migration layer comprise second matrix resin and inorganic nano powder; the particle size D50 of the inorganic nano powder is 1-200nm, and the mass of the inorganic nano powder is 0.01-0.5% of the total mass of the anti-migration layer; the anti-migration layer is pre-crosslinked through electron beam irradiation; the raw materials of the UV cut-off layer comprise third matrix resin and an ultraviolet absorbent. The anti-migration layer added with the inorganic nano powder and pre-crosslinked through electron beam irradiation is arranged between the light conversion layer and the UV cut-off layer, the free volume of a crosslinked polymer can be effectively reduced by adding the inorganic nano powder and carrying out electron beam irradiation pre-crosslinking, and a migration channel of an auxiliary agent is blocked; mutual migration of the light conversion agent and the ultraviolet absorbent is effectively prevented.

The invention relates to the field of sealing strips, and discloses a high-foaming low-density composite sealing strip material and a preparation method thereof.The sealing strip material is prepared from ethylene propylene diene monomer, ethylene-vinyl acetate copolymer, modified composite filler, zinc oxide, stearic acid, paraffin oil, calcium oxide, an accelerant, sulfur and a foaming agent; the modified composite filler is prepared by performing acylating chlorination modification on a flame-retardant additive and a modified ultraviolet absorbent by using oxalyl chloride and then grafting with an aminated composite filler, the aminated composite filler is prepared by modifying silicon dioxide and titanium dioxide by using an amino silane coupling agent, and the flame-retardant additive utilizes 9, 10-di-tert-butyl-4-methylphenol. The ultraviolet absorbent is prepared by grafting 2, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, salicylaldehyde and pentaethylenehexamine which are used as raw materials, and the modified ultraviolet absorbent is prepared by reacting 2-(2, 4-dihydroxyphenyl)-2H-benzotriazole with phenylphosphonic dichloride. By adding the modified composite filler, the material is endowed with excellent mechanical properties, flame retardance and ultraviolet aging resistance.

The invention discloses an anti-ultraviolet automobile window film and a preparation method thereof, and relates to the field of high polymer materials. When the anti-ultraviolet automobile window film is prepared, methylcyclotetrasiloxane, octamethylcyclotetrasiloxane, 3-glycidyl propyl (dimethoxy) methylsilane and 1, 3-bis (3-aminopropyl)-1, 1, 3, 3-tetramethyldisiloxane are subjected to a reaction, and modified polysiloxane is prepared; the preparation method comprises the following steps: reacting benzo [1, 2-d: 5, 4-d '] bis (oxazole)-2, 6-dithiol with 4-aminobenzoyl chloride to prepare a modified ultraviolet absorbent; isophorone diisocyanate, polytetrahydrofuran ether glycol, the modified polypyrrole particles, the modified polysiloxane and the modified ultraviolet absorbent are subjected to a reaction, and the reaction product is spread in a mold. The anti-ultraviolet automobile window film prepared by the invention has good anti-ultraviolet, heat-insulating, flame-retardant and anti-aging properties and good mechanical properties.

The invention discloses a low-dielectric-constant polyamide material, and relates to the technical field of high polymer materials. The invention discloses a low-dielectric-constant polyamide material. The composite material is prepared from the following raw materials in parts by weight: 35 to 45 parts of polyamide 66, 5 to 10 parts of polytetrafluoroethylene micro powder, 8 to 12 parts of modified porous siloxane microspheres, 3 to 7 parts of modified nano zinc oxide, 10 to 15 parts of glass fibers, 4 to 8 parts of polyether-ether-ketone, 1 to 3 parts of graphene nanosheets, 3 to 5 parts of fluororubber, 1 to 2 parts of a titanate coupling agent, 0.3 to 0.7 part of an antioxidant 1010, 0.5 to 1.0 part of ethylene bis stearamide and 0.1 to 0.3 part of an ultraviolet absorbent UV-531. The low-dielectric-constant polyamide material has the remarkable advantages that the raw materials are scientifically proportioned, and various modified components are contained to enhance the performance; all the components are subjected to special treatment, so that the compatibility is good; the preparation process is rigorous, and the material has excellent dielectric properties; and the material also has good heat resistance and weather resistance and strong mechanical properties, and is suitable for various scenes with high dielectric constant requirements.

The invention discloses a method for detecting the purity of a phosphorus-containing flame retardant, and belongs to the technical field of flame retardant detection. The specific test method comprises the test steps of selecting a solvent, preparing a to-be-tested solution, determining the maximum absorption wavelength, determining absorbance, calculating the purity of a sample and the like, and analyzing and processing an experimental result. The solvent is filtered through a 600-mesh screen, the influence of impurities in the solvent on an experimental result is eliminated, and the scientificity of the experimental result is ensured by parallelly determining the average value recorded for three times; the testing method has the advantages of low cost, simplicity and convenience in operation, short detection period and the like, and can realize rapid detection of a plurality of samples based on multiple stations of an ultraviolet-spectrophotometer, so that the working efficiency is improved; meanwhile, the method for detecting the purity of the phosphorus-containing flame retardant provided by the invention can be used for comparing the quality of products from different manufacturers and the batch stability of the products at the same time, and is beneficial for enterprises to control the quality of the products.

The application discloses an antioxidant coating and a preparation method thereof, and relates to the technical field of coatings. The application first uses hydroxybenzotriazole to esterify and modify acrylic acid, and then uses the modified acrylic acid to prepare modified acrylic resin coating. The benzotriazole structure has high hardness and rigidity, and also has good ultraviolet absorption performance, which can reduce the degradation of the acrylic resin caused by ultraviolet rays and further improve the durability of the coating. The microcapsule wall material is modified by a hydrophobic compound, and then a new type of microcapsule wall material is prepared by coating an antioxidant. The microcapsule wall material modified by the hydrophobic compound can effectively prevent external moisture and oxygen from entering the microcapsule, improve the stability of the coating in a humid environment, and protect the antioxidant in the core material from the influence of the external environment. The antioxidant is slowly and continuously released in the coating, and the oxidation reaction of the coating is effectively inhibited for a long time. The antioxidant coating prepared by the application has the effects of wear resistance and durability.

The invention relates to the technical field of photovoltaic adhesive films, and discloses an anti-radiation photovoltaic packaging adhesive film, a preparation method thereof and a photovoltaic module. The adhesive film is of a multi-layer co-extrusion composite structure formed by co-extrusion molding and irradiation, and comprises an upper surface layer, a middle functional layer and a lower surface layer, the upper surface layer is a radiation-resistant polymer matrix (such as EVA-g-St, EVA-g-(alpha-MeSt), POE-g-St and an EVA / POE-aromatic resin blend); the middle functional layer comprises a packaging resin matrix, an anti-radiation agent (which is a nano-scale radiation protection material such as a rare earth oxide, a heavy metal oxide, a boron-containing compound and a polymer derivative of a benzotriazole type ultraviolet absorbent) and a stabilizer; and the lower surface layer is a bonding surface layer formed by light-transmitting bonding resin. The adhesive film is good in radiation resistance, the light transmittance, the cohesiveness, the elongation at break retention rate, the yellowing resistance, the power attenuation resistance of a component and the like after accelerated radiation are obviously improved, and the service life of the component under strong radiation can be prolonged.

The invention belongs to the field of coatings, and discloses a broad-spectrum ultraviolet absorbent with a sandwich structure as well as a preparation method and application of the broad-spectrum ultraviolet absorbent. An ultraviolet absorbent is adsorbed on the upper surface and the lower surface of graphene oxide through the action of a hydrogen bond and a pi-pi bond to form a compact ultraviolet absorbent layer, then the surface of graphene oxide is chemically modified through a diamine compound, amino is grafted, and the wide-spectrum ultraviolet absorbent of a'discrete point / surface / discrete point 'sandwich structure is obtained. The ultraviolet absorbent filler, the cardanol-based reactive diluent and the epoxy resin are compounded, so that the ultraviolet aging resistance, the barrier corrosion resistance and the hydrophobicity of the prepared composite coating are synergistically enhanced and exceed those of an anti-ultraviolet epoxy coating material reported at present.

The invention relates to the field of processing of full-biodegradable high polymer materials, in particular to a weather-resistant master batch and a preparation method and application thereof, and the weather-resistant master batch comprises the following components: 40-70 parts by weight of poly (butylene adipate-co-terephthalate); 10 to 20 parts of polylactic acid; 20-40 parts by weight of a supported ultraviolet absorbent; 15-25 parts by weight of modified talcum powder; 1-3 parts by weight of a light stabilizer; 1-3 parts by weight of a lubricant; 1-3 parts by weight of an antioxidant; the invention discloses a degradable mulching film and a preparation method thereof.The degradable mulching film is prepared from, by weight, 1-3 parts of a supported ultraviolet absorbent, 1-3 parts of modified talcum powder and 1-3 parts of a chain extender, the degradable mulching film comprises weather-proof master batches and poly (adipic acid) / butylene terephthalate, and the mass ratio of the weather-proof master batches to the poly (adipic acid) / butylene terephthalate is (5-15): (85-95). The ultraviolet aging resistance of the degradable mulching film is further improved.