928 results about "Crystal system" patented technology

Disclosed is a light emitting device employing non-stoichiometric tetragonal Alkaline Earth Silicate phosphors. The light emitting device comprises a light emitting diode emitting light of ultraviolet or visible light, and non-stoichiometric luminescent material disposed around the light emitting diode. The luminescent material adsorbs at least a portion of the light emitted from the light emitting diode and emits light having a different wavelength from the absorbed light. The non-stoichiometric luminescent material has tetragonal crystal structure, and contains more silicon in the crystal lattice than that in the crystal lattice of silicate phosphors having stoichiometric crystal structure. The luminescent material is represented as the formula (BauSrvCawCux)3−y(Zn,Mg,Mn)zSi1+bO5+2b:Euu. Light emitting devices having improved temperature and humidity stability can be provided by employing the non-stoichiometric tetragonal Alkaline Earth Silicate phosphors.

A piezoelectric body contains a ferroelectric substance phase having characteristics such that, in cases where an applied electric field is increased from the time free from electric field application, phase transition of the ferroelectric substance phase to a ferroelectric substance phase of a different crystal system occurs at least two times. The piezoelectric body should preferably be actuated under conditions such that a minimum applied electric field Emin and a maximum applied electric field Emax satisfy Formula (1):Emin<E1<Emax   (1)wherein the electric field E1 represents the electric field at which the first phase transition of the ferroelectric substance phase begins.

The invention relates to one solid electrolyte materials and its process method for fix lithium battery, which is characterized by the following: Li2S and other sulfur compound B / S and A / I according to certain mole proportion for compounds to form non-crystal system to provide space for lithium ion transmission to get higher ion conductive rate, wherein, the materials have wider heat stable range to provide one ideal electrolyte prepare materials for solid lithium ion battery.

The invention relates to one solid electrolyte materials and its process method for fix lithium battery, which is characterized by the following:four types of different sulfur compounds as Li2S:A / S:P2S5=6:0.1-4.0:1.5 for compound to form non-crystal system to provide more effective paths for lithium ion transmission to get higher ion conductive rate; the said A for Ag, Zn, Al or Zr with sample of Li2S-ZrS2-P2S5 with room ion battery conductive rate as 9.60X10-6S / cm and lower electron conductive rate under 150 degrees for 3.30X10-4S / cm.

The invention relates to a nonlinear optical crystal of a potassium borate chloride compound and a preparation method as well as application thereof. The chemical formula of the compound is K3B6O10Cl, and the molecular weight of the compound is 377.61. The crystal does not have a symmetric center and belongs to a trigonal system and a space group R3m, and cell parameters are as follows: a=10.0624(14), b=10.0624(14), c=8.8361(18), Z=3, and V=774.8 (2). The powder frequency-doubled effect reaches about 3 times of KDP(KH2PO4), the Mohs hardness is 4-5, and the light transmission waveband is 165nm-3460nm. A solid phase reaction method is used for synthesizing the compound, and a cosolvent method is used for growing the crystal. The crystal has the advantages of simple operation, low cost, large size, short growth cycle, few inclusion enclaves and larger mechanical hardness, and can be cut, polished, processed and saved easily. The crystal is used for generating twofold frequency or three-fold frequency or fourfold frequency or fivefold frequency harmonic light output for laser beams of which the wavelength is 1064nm.

An actuator device includes: a layer provided on a single crystal silicon (Si) substrate, and made of silicon dioxide (SiO2); at least one buffer layer provided on the layer made of silicon dioxide (SiO2); a base layer provided on the buffer layer, and made of lanthanum nickel oxide (LNO) having the (100) plane orientation; and a piezoelectric element. The piezoelectric element includes: a lower electrode provided on the base layer, and made of platinum (Pt) having the (100) plane orientation; a piezoelectric layer made of a ferroelectric layer whose plane orientation is the (100) orientation, the piezoelectric layer formed on the lower electrode by epitaxial growth where a crystal system of at least one kind selected from a group consisting of a tetragonal system, a monoclinic system and a rhombohedral system dominates the other crystal systems; and an upper electrode provided on the piezoelectric layer.

A piezoelectric device (1) comprises a piezoelectric body (13) and electrodes (12, 14) for applying an electric field in a predetermined direction across the piezoelectric body (13). The piezoelectric body (13) contains an inorganic compound polycrystal, which contains first ferroelectric substance crystals having orientational characteristics at the time free from electric field application and has characteristics such that, with application of at least a predetermined electric field E1, at least part of the first crystals undergoes phase transition to second ferroelectric substance crystals of a crystal system different from the crystal system of the first crystals. The piezoelectric device (1) is actuated under conditions such that a minimum applied electric field Emin and a maximum applied electric field Emax satisfy Emin<E1<Emax.

A piezoelectric body contains a ferroelectric substance phase having characteristics such that, in cases where an applied electric field is increased from the time free from electric field application, phase transition of the ferroelectric substance phase to a ferroelectric substance phase of a different crystal system occurs at least two times. The piezoelectric body should preferably be actuated under conditions such that a minimum applied electric field Emin and a maximum applied electric field Emax satisfy Formula (1)wherein the electric field E 1 represents the electric field at which the first phase transition of the ferroelectric substance phase begins.

The invention provides a hexagonal crystal system Y-type ferrite electromagnetic material and a preparation method thereof. The material is a Ba2Co2-xZnxFeyO22 (x is more than or equal to 0 and less than or equal to 2, and y is more than or equal to 10 and less than or equal to 14) ferrite material with hexagonal flaky morphology, and is obtained by uniformly mixing reactants and a reaction medium and calcining, wherein the reactants at least comprise a barium source, an iron source and a cobalt source; the reaction medium is one kind of chlorate or a mixture of two kinds of chlorate; the molar ratio of various elements in the reactants is that the ratio of Ba to Fe is 2:(10-14), and the ratio of Ba to Co is 2:(0-2); and the ratio of the mass of the reaction medium to the total mass of the reactants is (1-4):1. The invention has the advantages that the morphology of ferrite powder particles can be well controlled; inorganic molten salt is taken as the reaction medium, and the reactants are quickly dispersed and fully contacted in the molten salt by utilizing the dissolution of the reactants in the molten salt so as to reduce reaction temperature and improve reaction rate; the molten salt runs through generated barium ferrite particles in the reaction process, so the mutual agglomeration among the particles can be stopped; and the process is simple, the product is high in purity, the resultant temperature is low, the mechanical ball milling is not required, the doping is avoided, and the particle size distribution is narrow.

High efficiency viscosity-reducing agent which is used on THE thermal oil extraction technology, which is formed by the following raw materials with percentage by weight, firstly phenyl benzene, fused ring aromatic hydrocarbon or fused ring aromatic hydrocarbon derivative which does not contain chlorine element and sulfur element, secondly liquid petroleum product whose aromatic hydrocarbons content is no more than 5%, petroleum resin which is liquid state under the constant temperature or hydrocarbons natural aggregation which is particle state under the constant temperature, thirdly water-soluble anionic surface active agent, water-soluble non-ionic surface active agent, oil solubility anionic surface active agent or oil solubility non-ionic surface active agent, fourthly fusel oil, fifthly alcohol ether, sixthly oil solubility or water-soluble polymer which respectively has nonpolar portion which has eutectic crystal with ceresin wax molecular and polar portion which can make wax crystal system twisty on main chain and or branch chain, seventhly hyperoxide, eighthly carbamide, ammonium carbonate, ammonium acid carbonate or ammonium nitrite and ninthly ketone. The high efficiency viscosity-reducing agent has strong suitability, strong viscosity-reducing ability, safety and reliability, can largely reduce extract cost and increase the yield of oil pump, and increases the final recovery efficiency of oil reservoir.

The method of measuring crystallographic orientations, crystal systems or the like of the surface of a specimen has steps of: irradiating the specimen with an ion beam; measuring tho secondary electrons generated by the irradiation of the ion beam; repeating the irradiation of the ion beam and the measurement of the secondary electrons with each variation in an angle of incidence of the ion beam with respect to the specimen; and determining the crystalline state based on the variation in the amount of the secondary electrons corresponding to the variation of the angle of incidence.

A preparation method for bismuth(Bi)-tellurium(Te) nano-porous thermoelectric semiconductor material is disclosed, belonging to the technical field of the thermoelectric material. The preparation method comprises the following step: Bi-Te-based nano-powders Bi[2-x]Sb[x]Te[3-y]Se[y] (x=0-1.9, y=0-0.5) are placed in alcohol solution with a pore-forming agent sufficiently dissolved therein, in orderto be mixed by a method which combines ultrasonic wave with magnetic suspension agitation, the powders are sintered into bulk material by means of a discharge plasma sintering technology after being dried, and during the sintering, the pore-forming agent is utilized for sublimation and evaporation at the particular temperature so that the bulk material can form nano-sized pore structure therein inthe process of sintering in order to form the nano-porous material. The Bi-Te-based alloy belongs to rhombohedral crystal system structure. The preparation method has the advantages of simple preparation, easy operation, lower cost, accurate ingredient control, relatively uniform size and distribution of the nano pores and the like.

A piezoelectric film element is provided, which is capable of improving piezoelectric properties, having on a substrate at least a lower electrode, a lead-free piezoelectric film, and an upper electrode, wherein at least the lower electrode out of the lower electrode and the upper electrode has a crystal structure of a cubic crystal system, a tetragonal crystal system, an orthorhombic crystal system, a hexagonal crystal system, a monoclinic crystal system, a triclinic crystal system, a trigonal crystal system, or has a composition in which one of these crystals exists or two or more of them coexist, and crystal axes of the crystal structure are preferentially oriented to a specific axis smaller than or equal to two axes of these crystals, and a ratio c / a′ is set in a range of 0.992 or more and 0.999 or less, which is the ratio of a crystal lattice spacing c in a direction of a normal line to the substrate surface, with respect to a crystal lattice spacing a′ whose inclination angle from the substrate surface is in a range of 10° or more and 30° or less.

One embodiment of communication system comprises a crystal oscillator configured to output a reference clock; cellular radio frequency (RF) and baseband phase locked loops configured to receive the reference clock within a cellular module and compensate for calculated frequency errors between a received cellular downlink signal and a cellular local oscillator signal during operation of the cellular module; global positioning system (GPS) frequency compensation circuitry configured to receive the reference clock within a GPS module and compensate for calculated frequency errors during operation of the GPS module; and a temperature sensing circuit which includes a plurality of sensing resistors and is configured to output a signal corresponding to a temperature of a reference crystal which is translated to a frequency deviation, wherein the (GPS) frequency compensation circuitry is configured to offset the frequency deviation and output a temperate compensated signal to meet GPS clock frequency requirements.

The invention relates to a large size potassium strontium borate nonlinear optical crystal, the preparation and use thereof. The formula of the crystal is: KSr4B3O9, which belongs to rhombic system, the space group is Pna2(1), and the molecular weight is 566.01, and the crystal size is 10-60mmx10-60mmx10-60mm. The preparation contains the following steps of: evenly mixing the potassium strontium borate compound with a fusing assistant, heating, maintaining the constant temperature, cooling to the saturation temperature and obtaining a mixture solution, placing a seed crystal into the mixture solution, lowering the temperature to the saturation temperature to obtain the required crystal, and subsequently extracting the crystal from the liquid level, cooling to room temperature, and finally obtaining the large size potassium strontium borate nonlinear optical crystal. The nonlinear optical effect of the crystal is approximately the same as the KDP, the transparent optical band is 220nm-3000nm. The crystal is simple in operation, low in cost, large in crystal size, short in growth period, less in coating, high in laster damage threshold, good in mechanical property, firm, stable in physicochemical properties, uneasy to deliquescence, convenient for processing and storage, or the like. Accordingly, the nonlinear optical crystal of the invention can be abroadly applied in nonlinear optical devices such as frequency doubler, optical parametric oscillator or the like.

The invention provides a method for synthesizing a heteroatomic ZSM-5 molecular sieve. The method comprises the steps of (a) adding a gallium source and an aluminum source into a templating agent, then adding sodium hydroxide, and then mixing with a silicon source to form a sol-gel system; (2) crystallizing for 48-80 hours; (3) filtering, drying and roasting to remove the organic templating agent; and (4) carrying out ion exchange on molecular sieve powder by using an ammonium hydroxide solution to obtain the hydrogen-type molecular sieve. According to the synthesis method provided by the invention, the molecular sieve, which is synthesized directly from the inexpensive silicon source, gallium source, aluminum source, mineralizer and organic templating agent, is unnecessary to be subjected to subsequent micropore aperture adjustment. The synthesized heteroatomic ZSM-5 molecular sieve belongs to an MFI structure and no heterophase crystal systems appear. Compared with a conventional ZSM-5 molecular sieve, the heteroatomic ZSM-5 molecular sieve synthesized by the method provided by the invention has the advantages that biomass and polyethylene are rapidly pyrolyzed under the catalytic action of the heteroatomic ZSM-5 molecular sieve, the yield of monocyclic aromatic hydrocarbon is not reduced and the selectivity of benzene, toluene and p-xylene in aromatic hydrocarbon is improved by about 80%.

The invention discloses a white light LED, an enhanced light transfer powder, a phosphor powder and a method of producing phosphor powder that use a plurality of radiating color lights and include a white light nitride heterostructure. The invention provides a novel solid liquid of a luminescence material with a chemical formula BaαY3βAl2α+5βO4α+12β, where α and β have a value ranging 0.1˜4. The crystal lattice structure of the phosphor powder varies from cubic crystal system to monoclinic crystal system accroding to the change of the ratio of α and β. It shows significant yellow color and yellowish orange color and has very high quantum light emitting efficiency and enduring light emitting time. In such novel phosphor powder base, the invention further develops an enhanced light transfer apparatus that is a blue light heterostructure emiting a raidaion with a wavelength λ=450˜475 nm and comprised of polymers and phosphor powder particles filled therein, and the concentration of phosphor powder is 1%˜50%. The novel white semiconductor source has a very high light intensity (I>100 cd) and luminous flux, and its light emitting efficiency is up to 501 m / w.

A ferroelectric capacitor includes a lower electrode, a ferroelectric film provided over the lower electrode and having a perovskite-type structure and an upper electrode provided over the ferroelectric film. The ferroelectric film includes a first ferroelectric film part having a first crystal system and formed along at least one interface with at least one of the lower electrode and the upper electrode and a second ferroelectric film part having a second crystal system that is different from the first crystal system.

The invention belongs to the technical field of a microporous metal-organic framework material and particularly relates to a microporous metal-organic framework material based on isophthalic acid derivatives as well as a preparation method and an application thereof. The chemical formula of the microporous metal-organic framework material provided by the invention has a chemical formula of Zn(pybdc), wherein pybdc<2-> is deprotonated 5-(1-pyrrolidyl)-1,3-phthalic acid and n represents an infinite link of the structural unit. The metal-organic framework material provided by the invention is crystallized in a trigonal system and the space group is R-3m; the metal Zn<2+> is located in the center of a tetrahedron and is tetrachordinate. The microporous metal-organic framework material provided by the invention has a one-dimensional porous channel structure along the direction of axis c and a methylene group of a pentary pyrrole ring stretches into the porous channel; the window of the porous channel is about 4 angstroms and the porosity is 18.6%. The structure of the material provided by the invention has the porous channel, so that the material can be used for safely storing gas or solvent molecules.

Provided is a manufacturing method for preferentially-oriented oxide ceramics having a high degree of crystal orientation. The manufacturing method includes: obtaining slurry containing an oxide crystal B having magnetic anisotropy; applying a magnetic field to the oxide crystal B, and obtaining a compact of the oxide crystal B; and subjecting the compact to oxidation treatment to obtain preferentially-oriented oxide ceramics including a compact of an oxide crystal C having a crystal system that is different from a crystal system of one of a part and a whole of the oxide crystal B. By (1) reacting raw materials, (2) reducing the oxide crystal A, or (3) keeping the oxide crystal A at high temperature and quenching the oxide crystal A, the oxide crystal B is obtained to be used in the slurry.

The present invention relates to positive electrode active substance particles comprising a compound having at least a crystal system belonging to a space group of R−3m and a crystal system belonging to a space group of C2 / m, and boron, wherein the compound is a composite oxide comprising at least Li, Mn, and Co and / or Ni; a relative intensity ratio [(a) / (b)] of a maximum diffraction peak intensity (a) observed at 2θ=20.8±1° in a powder X-ray diffraction pattern of the positive electrode active substance as measured using a Cu-Ka ray to a maximum diffraction peak intensity (b) observed at 2θ=18.6±1° in the powder X-ray diffraction pattern, is 0.02 to 0.5; a content of Mn in the positive electrode active substance particles is controlled such that a molar ratio of Mn / (Ni+Co+Mn) therein is not less than 0.55; and the positive electrode active substance particles comprise the boron in an amount of 0.001 to 3% by weight. The positive electrode active substance particles of the present invention are produced by calcining a mixture comprising precursor particles comprising Mn, and Ni and / or Co, a lithium compound and a boron compound at a temperature of 500 to 1500° C. The positive electrode active substance particles of the present invention can provide a secondary battery which can be improved in charge / discharge capacity and cycle characteristics.

The invention relates to a chemical mechanical polishing abrasive particle CeO2 and a method for preparing the same, belonging to the rare earth powder material chemical preparation technical field. The invention is to prepare the CMP abrasive particle by utilization of cerous inorganic salt solution and homogeneous precipitation agent. The method comprises the following steps that: the cerous inorganic salt and the precipitation agent are prepared into solution with certain proportion; the solution is uniformly mixed through ultrasonic vibration; deposits are generated after the solution is heated to a certain temperature; serum is kept stand, aged, filtered and calcined, and then the CeO2 abrasive particle is prepared. The method also accelerates the nucleation rate through addition of surface active agent so as to reduce the reaction temperature, and simultaneously the nodulizing degree of the abrasive particle obtained is also good. The method prepares the CMP abrasive particle, wherein, the CMP abrasive particle belongs to the single-phase cubic crystal system; the space group is O<5>H-FM3M; the dispersibility is good; the grain fineness distribution is uniform; the shape is similar to a sphere; and the specific surface area BET is more than 0 and less than 50m<2> / g.

The invention relates to a large size lead borate bromine nonlinear optical crystal with high frequency-doubled effect and a preparation method and applications thereof. The molecular formula of the crystal is: Pb2B5O9Br, the crystal belongs to a rhombic system, and the molecular weight is 691.50; mixed solution is obtained by evenly mixing a lead borate bromine compound with a fluxing agent, heating, constant temperature, and cooling to the temperature above a saturation point; seed crystal is put into the mixed solution, the temperature is rapidly reduced to the saturation point, and the seed crystal is led to grow crystal in the solution; after growing to the required size, the crystal is lifted from the liquid surface, the temperature is reduced to room temperature, and the large size lead borate bromine nonlinear optical crystal is obtained. The preparation of the crystal is characterized by simple operation, short growth cycle and low cost. The prepared crystal has larger size, good chemical stability and thermal stability, no deliquescence at room temperature, good mechanical performance, easy processing and storage, and the like. The lead borate bromine nonlinear optical crystal can be widely used in nonlinear optical devices such as frequency-doubled conversion, optical parametric oscillator, and the like.

The invention discloses a method for preparing nanometer calcium carbonate, employing reversed phase and microemulsion system for reaction in liquid to prepare cubic crystal nanometer calcium carbonate. It mainly comprises following steps: mixing hydrocarbon solvent, emulsifying agent and alcohols; adding water-soluble calcium salt solution on condition of stirring; then adding emulsifying agent and stirring continuously, getting transparent emulsion; then adding solid powder of water-soluble carbonate and getting nanometer calcium carbonate emulsion; and getting final product after saponification. The invention changes the air-solid reaction between carbon dioxide and calcium hydroxide to reaction in liquid, which avoids mass transfer for air and liquid in current process; the calcium ion and carbonate positive ion are only used as carriers and do not consume chemical substance, which can reduce production cost; and the reverse microemulsion is used as reaction medium, which can short process and reduce investment. The cubic crystal nanometer calcium carbonate is characterized by homogenous crystal system and granular size.

The invention discloses a near blue fluorescent material and a preparation method thereof. The material is prepared through chemical reactions of quinoline carboxylic acid and 4,4'-bipyridine with conjugated extended pi bonds, and zinc ions with optical activity. The fluorescent material is a zinc quinoline carboxylic crystal with a molecular formula of C84H56N8O8Zn2. The crystal belongs to a crystal system of triclinic system, and a space group of P-1. Cell parameters of the crystal are that: alpha= 91.357 DEG, gamma=106.573 DEG, and beta=101.953DEG. The zinc ions have two coordination modes, one is a square pyramid coordination mode, wherein two nitrogen coordinating atoms come from two different 4,4'-bipyridines, and three oxygen coordinating atoms come from two different quinoline carboxylic acid ligands; the other is a octahedral coordination mode, wherein two nitrogen coordinating atoms come from two different 4,4'-bipyridines, and four oxygen coordinating atoms come from two different quinoline carboxylic acid ligands. The material is advantaged in that: the fluorescent material contains abundant optically active Zn (II) ions and conjugated extended bonds, and has good near blue light emission performance.

The invention discloses a convenient method for directionally cutting any crystal face of crystal, belonging to the technical field of crystal material cutting processing. The method is implemented by cutting out a plane arbitrarily to be as the reference plane, then determining longitudinal, transverse and normal indexes of the reference plane by using electron backscattered diffraction (EBSD) technology, then calculating the needed included angle between the reference plane and any crystal face, and finally regulating the crystal cutting direction to obtain the crystal face satisfying requirements by once cutting processing. With the EBSD technology adopted, the EBSD instrument and the traditional crystal material cutting device are combined, thus the crystal of any crystal system can be cut out any crystal face in directional way, namely, the needed crystal face is a high index diffraction face or an extinction face, the invention is especially suitable to the crystal with unknown reference plane orientation and larger crystal orientation deviation, and the bearing accuracy is high, the operation is simple and convenient and the crystal consumption is reduced.

The invention discloses a nicotine-mandelate complex crystal. A crystal molecular formula of the nicotine-mandelate complex crystal is C26H30N2O6; the nicotine-mandelate complex crystal belongs to anorthorhombic crystal system; a space group is P212121, and unit cell parameters are: a=9.5074(5) angstrom, b=12.7246(9) angstrom, c=20.4101(1) angstrom, and alpha=beta=gamma=90.00 degrees. The invention further discloses a preparation method of the nicotine-mandelate complex crystal, comprising the following steps: a, measuring and fetching nicotine and mandelic acid, dissolving the mandelic acidin a solvent, obtaining a saturated solution, placing the saturated solution of the mandelic acid in a water bath environment, stirring and adding the nicotine dropwise; b, transferring the reaction liquid obtained in step a to a light resistant container, performing ultrasonic treatment, shielding the reaction product from light, placing the reaction product at room temperature, enabling the reaction product to volatilize, and obtaining a nicotine mandelate crystal. The complex crystal has an obviously sustained-release effect in artificially simulated saliva. The invention further disclosestobacco products containing the nicotine-mandelate complex crystal. The tobacco products include gum-based chewing tobacco, a bagged mouth cigarette, an electronic cigarette liquid or a heated non-combustible cigarette.

The invention relates to a high-temperature-phase tellurium barium molybdate crystal as well as a preparation method and the applications thereof. The high-temperature-phase tellurium barium molybdate crystal belongs to an orthorhombic system, a space group is Pca21, a=14.8683 (2), b=5.66360 (10), c=17.6849 (3), ultraviolet-visible-near-infrared light is displayed through a light spectrum, intermediate infrared light is displayed through the light spectrum, the crystal permeates the wavelength range of 380-5530 nm, and infrared laser of 1064 nm is incident into the crystal at a room temperature to generate green light with the wavelength of 532 nm. A fluxing agent method is adopted for growth. The invention also provides the applications of the high-temperature-phase tellurium barium molybdate crystal as a nonlinear optical crystal, a birefringent crystal, a piezoelectric crystal, a ferroelectric crystal, a pyroelectric crystal or a laser substrate material.

The invention discloses a high magnetic-energy-product M type calcium series permanent magnetic ferrite material and a preparation method thereof. The high magnetic-energy-product M type calcium series permanent magnetic ferrite material is a hexagonal crystal system, and the chemical structural formula is R1-x-yCaxLayO.nFe(12-z) / nCoz / nO3, wherein x is greater than or equal to 0.001 and smaller than or equal to 0.4, y is greater than or equal to 0.001 and smaller than or equal to 0.5, z is greater than or equal to 0.01 and smaller than or equal to 2.0, 1-x-y is greater than 0.2 and smaller than or equal to 0.998, n is greater than or equal to 5.0 and smaller than or equal to 6.5. R is Sr or adopts Sr as the main component, and also contains one, two or three of Ba, lanthanide series Ce, Pr, La, Nd and Sm. When R is Sr and Ba, the content of Sr and Ba is less than or equal to 0.998. In addition to high residual magnetism and intrinsic coercivity, the high magnetic-energy-product M type calcium series permanent magnetic ferrite material provided by the invention also has higher magnetic induction coercivity and maximum magnetic energy product, and is particularly in favor of miniaturization of permanent magnetic ferrite devices.