282 results about "Crystal system" patented technology

The invention relates to the technical field of crystal material preparation, in particular to a layered selenide Ge3Sb2Se5 semiconductor material and a preparation method thereof. The preparation method of the layered selenide Ge3Sb2Se5 semiconductor material comprises the following steps: grinding a Ge3Sb4Se7 material, putting the ground Ge3Sb4Se7 material into a quartz tube, adding iodine particles, performing vacuum packaging in the quartz tube, putting one end, with raw materials, of the quartz tube into a high-temperature region, and putting one end, without raw materials, of the quartz tube into a low-temperature region; raising the temperature to 400 + / -25 DEG C at the low-temperature region end and 500 + / -25 DEG C at the high-temperature region end, preserving heat for 7 days, and naturally cooling to room temperature to obtain the Ge3Sb2Se5 semiconductor material. The crystal structure of the Ge3Sb2Se5 semiconductor material belongs to an orthorhombic system, and the Ge3Sb2Se5 semiconductor material has the characteristics of low thermal conductivity and low resistivity. According to the preparation method disclosed by the invention, the Ge3Sb2Se5 semiconductor material can be stably prepared, and a material is provided for physical property research of the Ge3Sb2Se5 semiconductor material and preparation of semiconductor photoelectric devices and the like.

The invention discloses a method for refining grains of a titanium alloy. According to the method, an original low-oxygen-content titanium alloy plate is subjected to cryogenic pretreatment, the temperature of the core of the original low-oxygen-content titanium alloy plate is reduced to a certain temperature, then the cryogenic low-oxygen-content titanium alloy plate is fed into a rolling mill, the single-pass reduction rate is controlled, cryogenic rolling is completed, high refinement and uniform distribution of crystal grains are achieved, and the low-oxygen-content titanium alloy plate is obtained. And the rolled titanium alloy plate is subjected to subzero treatment again, and the titanium alloy plate of the complex twin crystal structure formed by intersection of {11-22} and {10-11} twin crystals is obtained. The method has the beneficial effects that under the synergistic effect of low oxygen and deep cooling, even under the extremely small deformation amount, the cross effect of various twin crystal systems can be efficiently activated, a high-density and complex twin crystal structure is formed, high refinement and uniform distribution of crystal grains are achieved, then the mechanical strength and low-temperature toughness of the material are remarkably improved, and the service life of the material is prolonged. And the application requirements in a severe low-temperature service environment are met.

To provide a ceramic having a high coefficient of thermal expansion and a low dielectric constant.SOLUTION: 50.0 to 90.0 mass% of 2MgO and SiO2, a total of 8.0 mass% or more of one of 7.0 to 14.0 mass% of ZrO2 and 10.0 to 50.0 mass% of Al2O3 or both of 14.0 mass% or less of ZrO2 and 50.0 mass% or less of Al2O3, and 3.0 to 15.0 mass% of one or more selected from Y2O3, CaO, CeO2, and HfO2, wherein a crystalline structure of the is a cubic structure. ZrO2.SELECTED DRAWING: None

A quantum entanglement system comprising a laser system, a spontaneous parametric down conversion crystal system, and a thermal management system. The laser system is configured to generate a laser beam. The spontaneous parametric down conversion crystal system comprises a spontaneous parametric down conversion crystal configured to receive the laser beam at a spontaneous parametric down conversion crystal and generate an entangled photon pair in response to the spontaneous parametric down conversion crystal receiving the laser beam. The thermal management system is configured to maintain the spontaneous parametric down conversion crystal at an annealing temperature during a generation of the entangled photon pair. A translation system is configured to move a position of the spontaneous parametric down conversion crystal. A

Provided is a rare earth magnet alloy having a tetragonal R2Fe14B crystal structure, including: a main phase containing, as main constituent elements, at least one kind selected from the group consisting of: Nd; La; and Sm, Fe, and B; and a sub-phase containing, as main constituent elements, at least one kind selected from the group consisting of: Nd; La; and Sm, and O, wherein La substitutes for at least one of a Nd(f) site or a Nd(g) site, wherein Sm substitutes for at least one of a Nd(f) site or a Nd(g) site, wherein La segregates in the sub-phase, and wherein Sm is dispersed in the main phase and the sub-phase without segregation.

This invention discloses a polyoxometalate that catalyzes the Knoevenagel reaction, its preparation method, and its applications. The chemical formula of the polyoxometalate that catalyzes the Knoevenagel reaction is: H3[K(H2O)6][K2(H2O) 10 ]2[Cu(en)2(H2O)2][Cu(en)2(Nb6O 19 Cu(en))2·24H2O, where en = ethylenediamine; the polyoxometalate crystals catalyzing the Knoevenagel reaction belong to the triclinic crystal system with space group P-1; the polyoxometalates catalyzing the Knoevenagel reaction prepared in this invention exhibit excellent heterogeneous catalytic performance in the highly efficient Knoevenagel condensation reaction, showing high yield and high stability under isothermal conditions at a 1:1 substrate ratio and over a wide substrate range. The superior catalytic ability of the polyoxometalates catalyzing the Knoevenagel reaction can be attributed to the presence of dense and effective basic sites on the surface of the heteropolycationic chain, and the increased contact frequency between the organic-inorganic hybrid catalyst and the substrate.

The application discloses a preparation method of vanadium-doped and high-hydrated mangan-chromian spinel monocrystal under high temperature and high pressure. The cylindrical mangan-chromian spinel sample is prepared by taking solid rose triangular rhombic manganese carbonate crystal, solid chromium (III) acetate hydroxide crystalline powder, solid vanadium (IV) acetylacetonate oxide powder, solid oxalic acid powder, solid bixbyite powder, solid chromium hydroxide powder and liquid dilute nitric acid as starting raw materials; two pieces of water source sheets are made from the bixbyite powder and the chromium hydroxide powder with a weight ratio of 4:1; the two pieces of water source sheets are placed at two ends of the cylindrical mangan-chromian spinel sample and then are placed into a double-capsule structure experimental sample bin with an inner layer sleeve being a graphite tube and an outer layer sleeve being a gold-palladium alloy tube; the high temperature and high pressure reaction is carried out to obtain the mangan-chromian spinel monocrystal; and the preparation technology blank of the vanadium-doped and high-hydrated mangan-chromian spinel large-particle monocrystal under the current high temperature and high pressure conditions is solved.

The invention discloses a low-thermal-conductivity p-type liquid thermoelectric material and a preparation method thereof. The chemical formula of the low-thermal-conductivity p-type liquid thermoelectric material is Cu6GeTeS4, the low-thermal-conductivity p-type liquid thermoelectric material belongs to a cubic system and a space group, the low-thermal-conductivity p-type liquid thermoelectric material Cu6GeTeS4 forms an anion rigid framework by GeS4 tetrahedral elements isolated in unit cells and body-centered cubic Te, and Cu ions move in the framework. The p-type liquid thermoelectric material keeps a stable cubic phase at 300-873 K, and has low thermal conductivity and a high thermoelectric figure of merit; the ultra-low thermal conductivity of 0.69 to 0.57 W m <-1 > K <-1 > is realized at 300 to 873 K.

This invention provides an organic ferroelectric eutectic material, its preparation method, and its applications, relating to the field of ferroelectric materials technology. The organic ferroelectric eutectic material constructs a crystal system with "rigid constraint and flexible adaptation coexisting, dipole order and controllable polarization synchronously" through "molecular selection-supramolecular assembly-crystal structure regulation," achieving a synergistic effect of high Curie temperature, strong polarization characteristics, and excellent flexibility. The preparation method of the organic ferroelectric eutectic material utilizes a simplified "solvent dissolution-solvent evaporation" process, leveraging the mediating effect of the solvent to promote the supramolecular self-assembly of donor and acceptor molecules. This achieves the preparation of an organic ferroelectric eutectic material possessing both high Curie temperature, strong polarization characteristics, and excellent flexibility. The preparation method has multiple advantages, including "stable process, low cost, and suitability for large-area processing," making it a simple, efficient, and universally applicable preparation method suitable for large-scale industrial production.

This invention relates to the field of chemical pharmaceuticals, and more particularly to a mebendazole crystal form and its preparation method. The mebendazole crystal form has a single-crystal structure belonging to the triclinic crystal system; space group Triclinic P; cell parameters a = 6.10 Å, b = 15.69 Å, c = 20.35 Å; α = 94.14°; β = 97.22°, γ = 90.70°, V = 1926 Å. 3 The optimization and development of the crystalline form of p-toluimidazole provided by this invention is of great value.

The invention relates to a novel second-order nonlinear optical crystal-potassium cadmium germanate (K4Cd3Ge4O13), and belongs to the field of optical crystal materials. The crystal is prepared by adopting a high-temperature solid-phase method and a high-temperature solution method, belongs to an orthorhombic crystal system and a C2 space group, is accurate in measurement of cell parameters, and shows excellent nonlinear optical characteristics and a wide light transmission range. The ultraviolet cut-off edge of the crystal is 261 nm, the infrared spectrum permeability is not obviously reduced in the range of 4000-714 cm <-1 >, the transmission range of the crystal can effectively cover a key atmosphere transmission window of 3-5 microns, and the crystal has powder frequency doubling response equivalent to that of a KDP crystal and can be applied to an all-solid-state laser as a mid-infrared nonlinear optical crystal.

This invention belongs to the field of fuel cell technology, specifically relating to a method for preparing and applying a hydrogen-bonded organic framework material with high proton conductivity constructed from carboxylic acid-aminoguanidine. The chemical formula of this organic framework material is [(CN4H7)(C 10 [O8H5], this organic framework material belongs to the triclinic crystal system. P Space group 1, cell parameters: a =7.9901(4)Å, b =9.6412(3)Å, c =9.6724(4)Å, α =96.322(3)°, β =113.876(4)°, c =93.633(3)°. The hydrogen-bonded organic framework material constructed by carboxylic acid-aminoguanidine and the composite film prepared therefrom have high proton conductivity and are highly promising proton conduction materials.

The invention discloses a method and system for determining anisotropic thermoelectric performance of a material based on tensor inversion, and the method comprises the steps: obtaining an Euler angle of a single crystal or texture polycrystalline sample in any orientation through electron back scattering diffraction, and building a rotation matrix between a sample coordinate system and a crystal coordinate system; measuring thermoelectric parameters such as resistivity, thermal conductivity and / or Seebeck coefficient under the sample coordinate system; and constructing a linear equation set based on a second-order tensor rotation formula, and inversely solving an intrinsic thermoelectric tensor component under a crystal coordinate system. According to the method, the intrinsic anisotropic thermoelectric performance of the material along the crystal main axis can be accurately obtained without strict crystal orientation cutting, and the method has the advantages of being high in universality, high in precision, easy and convenient to operate and the like and is suitable for high-throughput characterization of complex crystal system materials and device optimization design.

The application discloses 4-nitrobenzoic acid imidazole quaternary ammonium salt and a preparation method and application thereof. The 4-nitrobenzoic acid imidazole quaternary ammonium salt provided by the application has a structure as shown in formula (I), is in a single crystal form, is in a triclinic crystal system, and belongs to a P-1 space group. The 4-nitrobenzoic acid imidazole quaternary ammonium salt has a significant bacteriostatic effect, good thermal stability, and can be applied to preparation of antibacterial materials as an antibacterial agent.

The invention belongs to the technical field of photothermal conversion materials, and discloses a preparation method and application of an inorganic-organic hybrid polyoxotungstate photothermal material with wide spectrum absorption. The structural formula of the photo-thermal material is Per4W10O32, the crystal structure belongs to a triclinic system, the space group is P-1, and the photo-thermal material has specific unit cell parameters. The preparation method comprises the following steps: oxidizing perylene molecules through constant current electrolysis in a mixed solvent system containing perylene molecules and a decatungstate precursor in an electrochemical oxidation manner, and assembling the oxidized perylene molecules with decatungstate anions to form bulk crystals; the photo-thermal material has continuous strong absorption in a region from ultraviolet light to short wave infrared, the photo-thermal conversion efficiency is as high as 98.24%, when the photo-thermal material is applied to the fields of solar driven interface photo-thermal evaporation and water treatment, the evaporation rate of a two-dimensional system is 1.89 kg.m <-2 >. H <-1 >, the evaporation rate of a three-dimensional hydrogel system is increased to 3.02 kg.m <-2 >. H <-1 >, salt deposition can be inhibited in long-term seawater desalination operation, and the photo-thermal material has a good application prospect. Fresh water quality meets drinking water standards.

The application discloses a kind of cubic system tricobalt tetroxide quantum dots solvent hot preparation method, comprising the following steps: the mixture is obtained by mixing with set proportion with the source of cobalt, alcohol, polyvinylpyrrolidone, deionized water and hydrogen peroxide;The mixture is heated to a preset temperature in a sealed container with a predetermined volume ratio and isothermal reaction for a set time;When the reaction is finished, the reaction product is cooled to room temperature and washed, and the cubic system tricobalt tetroxide quantum dots are obtained after drying.The cubic system tricobalt tetroxide quantum dots with specific crystal structure can be obtained under the optimal preparation conditions, and the tricobalt tetroxide quantum dots with high uniformity of particle size and particle dispersion can be obtained;It can be applied in catalysis, energy storage and sensing fields, and the preparation process is simple and easy to operate, with good repeatability, low energy consumption and low cost, and the process parameters can be scaled up or down, suitable for industrial mass production.

This invention discloses a method for preparing and applying a gold cluster scintillator protected by a stable luminescent free radical ligand. The scintillator material uses (3,5-dichloro-4-pyridine)bis(2,4,6-trichlorobenzene)methyl free radical (PyBTM) as a ligand, and a chain-like tetranuclear free radical cluster is constructed using a one-pot method. The chemical formula of the compound is [Au4(PNP)2(PyBTM)2](SbF6)4, belonging to the triclinic crystal system, space group R-3. This free radical cluster scintillator achieves 100% theoretical exciton utilization and a short radiation decay lifetime due to its unique doublet emission mechanism. These properties make it an ideal candidate material for overcoming the contradiction between high luminous yield and fast response in traditional scintillators. Due to the excellent thermal and water-oxygen stability of this system, it can be fabricated into a scintillator screen to further achieve high-quality X-ray imaging with a spatial resolution of up to 31 LP·mm. ‑1 This provides a general design strategy for high-performance radiation detection materials.

The invention relates to the technical field of photocatalysis, in particular to a strontium bismuth vanadium oxide photocatalyst and a preparation method and application thereof.The chemical formula of the photocatalyst is Sr3. 59Bi19.41 V4O42, the crystal structure of the photocatalyst belongs to an orthorhombic system, the space group of the photocatalyst is Immm, and the photocatalyst is of a unique layered structure composed of cation triple plate layers; the photocatalyst is synthesized by a molten salt method, and shows the activity of photocatalytic decomposition of water to produce oxygen under visible light. The preparation method comprises the following steps: mixing and grinding SrO, Bi2O3 and VO precursors with a molten salt medium, and then carrying out temperature programming calcination to synthesize a target product; the catalyst prepared by the method has the characteristics of high crystallinity, few defects and regular morphology, the photocatalytic oxygen production performance of the catalyst is remarkably superior to that of a same-component sample synthesized by a traditional solid-phase method, and photocatalytic water decomposition and oxygen production can be realized by taking a silver nitrate, ferric nitrate, ferric chloride or potassium ferricyanide aqueous solution as a sacrificial agent system under the irradiation of visible light with the wavelength of more than or equal to 420 nm.

The application provides a 2-amino terephthalic acid dimethyl ester-tetracyano benzene eutectic crystal as well as a preparation method and application thereof, the eutectic crystal is of a triclinic system, a space group is a cell parameter is alpha = 95.041 (2) °, beta = 90.337 (2) °, gamma = 97.670 (2) °, and a cell volume is The 2-amino terephthalic acid dimethyl ester-tetracyano benzene eutectic crystal provided by the application increases the solid melting point of the organic compound from 133.39 DEG C to 162.23 DEG C without changing the covalent bond of the compound, enhances the thermal stability, and meanwhile, the fluorescence emission color, the fluorescence lifetime and the quantum yield are obviously changed.

The invention belongs to the technical field of material science foundation, and discloses a method for predicting twinning transmission probability of different crystal systems. Aiming at the characteristic that cross-crystal system twinning transfer needs to experience distinct reconstruction mechanism characteristics in an allotropical system interface, by introducing crystal symmetry and twinning system variant spatial orientation, the minimum orientation difference from rotation of matrix crystal grains to generation of a parallel twinning system is determined, and the alignment difficulty of twinning faces and twinning directions of two crystal systems at the interface is quantified. The method breaks through the limitation of homomorphic system symmetry hypothesis, can analyze the microscopic matching mechanism of heteromorphic system interface twinning activation, and clarifies the constraint effect of lattice parameter difference on twinning system preferential activation and transmission. The method is suitable for strength and toughness collaborative optimization design of complex multiphase systems such as heterojunction interfaces.

This invention provides a positive electrode active material and its application. The positive electrode active material of this invention comprises matrix particles including lithium metal oxide and a graphite coating layer covering at least a portion of the surface of the matrix particles; the lithium metal oxide has the structure shown in Formula 1; in the X-ray diffraction pattern, the lithium metal oxide is a cubic crystal system in space group Cmca, and has a 002 peak with a 2θ of 17.9°–18.1° and a 131 peak with a 2θ of 67.0°–67.5°; Li n‑y Na y Co 1‑a M a O2, Equation 1, where 0.6 ≤ n ≤ 0.8, 0 < y ≤ 0.05, 0 ≤ a < 0.2; and M is a doping element. The unique composition and crystal structure of this positive electrode active material help improve the battery's specific capacity and cycle performance, especially under high-voltage conditions, enabling the battery to maintain excellent performance.

The invention relates to a hydrophobic tripeptide molecule, a crystal constructed by the hydrophobic tripeptide molecule and application of the hydrophobic tripeptide molecule in a piezoelectric device. The structural formula of the polypeptide molecule is shown as a formula (I). The polypeptide molecule can form a micron-sized crystal through a heating-cooling method, and the interior of the micron-sized crystal is of an asymmetric structure and is of a triclinic system. A crystal formed by the polypeptide molecule has a relatively high piezoelectric coefficient (21.5 pC / N), a sandwich type piezoelectric device is constructed by using the crystal, and the output voltage can reach 2.57 V, which is the highest value of an oligopeptide nano material prepared in an aqueous solution. Therefore, the invention provides a method for forming the tripeptide crystal, and provides a potential strategy for development of piezoelectric materials based on short peptide self-assembly. (I)

The invention relates to a niobium tantalum oxyfluoride acid ammonium salt second-order nonlinear optical crystalline material and preparation and application thereof, the chemical formula of the material is (NH4) 5 (NbOF4) (TaF7) 2, the crystalline material belongs to a tetragonal system, the space group is I4cm, and the cell parameters are alpha = beta = gamma = 90 degrees and Z = 2. Under 1064nm laser irradiation, the powder frequency-doubled effect of the nonlinear optical crystal (NH4) 5 (NbOF4) (TaF7) 2 can reach 3.5 times that of a KH2PO4 (KDP) crystal, under 532nm laser irradiation, the powder frequency-doubled effect of the nonlinear optical crystal (NH4) 5 (NbOF4) (TaF7) 2 is 0.35 times that of a beta-BaB2O4 (BBO) crystal, and phase matching can be realized. In addition, the ultraviolet absorption cutoff edge of the crystalline material is less than 195 nm, and the crystalline material shows moderate birefringence (0.095 at-546 nm). The crystalline material provided by the invention has important application value in the photoelectric fields of solid-state lasers, spectral analysis, precision manufacturing, optical communication and the like.

This invention discloses a barium borate crystal, its preparation method, and its applications. The barium borate crystal has the chemical formula Ba₂BeB₂O₆, a non-centrosymmetric structure, belongs to the orthorhombic crystal system, has the space group Pca₂₁, and its cell parameters are α = 90°, β = 90°, and γ = 90°. This barium borate crystal exhibits extremely low birefringence from the ultraviolet to the infrared band, and its extremely low birefringence supports its application on zero-order glass slides.

The present invention relates to compounds and their nonlinear optical (NLO) crystals of A3B11P2O23 (A=K, Rb, Cs, NH4), their producing method and uses thereof. The series of compounds have a chemical formula of A3B11P2O23 (A=K, Rb, Cs, NH4), which are namely K3B11P2O23, Rb3B11P2O23, Cs3B11P2O23 and (NH4)3B11P2O23. The series of NLO crystals having the chemical formula of A3B11P2O23 (A=K, Rb, Cs, NH4), belong to rhombohedral crystal system, and have a space group of R3, crystal cell parameters of a=b=10.016(5)-12.591(5) Å, c=12.105(6)-14.905(6) Å, Z=3. A3B11P2O23 (A=K, Rb, Cs, NH4) compounds were prepared by a solid-state reaction method or a hydrothermal method, and A3B11P2O23 (A=K, Rb, Cs, NH4) NLO crystals were prepared by a high-temperature solid-state reaction method, a hydrothermal method, or a solution method. T They meet the requirements for the frequency conversion of UV wavelength lasers and could be used to prepare nonlinear optical devices.

The invention provides a Bi < 25-x > Er < x > FeO40 piezo-electric crystal, a preparation method thereof and application of the Bi < 25-x > Er < x > FeO40 piezo-electric crystal in catalytic degradation of organic pollutants, the Bi < 25-x > Er < x > FeO40 piezo-electric crystal is a cubic crystal system, the space group is 123, and x is equal to 0.188-0.340. The Bi < 25-x > Er < x > FeO40 piezoelectric crystal can realize piezoelectric degradation of pollutants under stirring and dark conditions or under stirring and illumination conditions, and the piezoelectric catalytic degradation capability of the Bi < 25-x > Er < x > FeO40 piezoelectric crystal can be repaired under the dark and stirring conditions.

This invention discloses a slow-release sulfurizing agent Fe x S y Its preparation method and application as a rhenium extraction material: Step 1: The pyrite-doped metal roasting product is subjected to an oxidation-reduction reaction, and the raw material is dried and roasted to obtain the product; Step 2: The product is ground and screened to obtain the slow-release sulfiding agent Fe. x S y The slow-release sulfurizing agent Fe x S y Its application, as a slow-release sulfide material, is used in metal corrosion protection, heavy metal-containing wastewater treatment, and soil sulfide replenishment; this invention achieves S 2 The slow release of the substance controls the local effective concentration and forms highly active iron-sulfur chemical bonds. At the same time, the crystal structure is a low-stability crystal system, thus exhibiting high chemical reactivity, which has obvious technical advantages over existing rhenium extraction materials.

The invention discloses a multicolor stress luminescent material for handwriting anti-counterfeiting and a preparation method thereof, the chemical general formula is Lu3-xAl2Ga3O12: xTb < 3 + >, 0.25% < = x < = 3.0%; the crystal structure is an Ia-3d cubic system, and the active ion is Tb < 3 + >. The preparation method comprises the following steps: weighing a lutetium-containing compound raw material, an aluminum-containing compound raw material, a gallium-containing compound raw material and a terbium-containing compound raw material, grinding and uniformly mixing to obtain a mixture, presintering, heating and calcining, cooling to room temperature, and grinding to obtain the terbium ion-doped multicolor stress luminescent material. The terbium ion-doped multicolor stress luminescent material disclosed by the invention has good stress luminescence self-recovery performance, shows different responses of energy level transition to stress in a visible light range, and is adjustable in color. The material has a low-threshold excitation characteristic, can provide multicolor stress luminescence response, and meets multicolor anti-counterfeiting requirements under different stress conditions.

This invention belongs to the field of magnetic refrigeration technology, specifically relating to the application of a hexagonal crystal material Sr6GdSc(BO3)6 in ultra-low temperature magnetic refrigeration. This hexagonal crystal material Sr6GdSc(BO3)6 does not undergo a phase transition at temperatures above 100 mK and exhibits a large magnetocaloric effect near 1 K. The maximum magnetic entropy changes under magnetic field variations of 0–1 T, 0–2 T, and 0–3 T are 39.36 mJ·cm⁻¹, respectively. ‑3 · K ‑1 Or 9.01 J·kg ‑1 ·K ‑1 53.95 mJ·cm ‑3 ·K ‑1 Or 12.34 J·kg ‑1 ·K ‑1 and 59.49 mJ·cm ‑3 ·K ‑1 Or 13.61 J·kg ‑1 ·K ‑1 The hexagonal crystal material Sr6GdSc(BO3)6 of this invention exhibits significant magnetocaloric effects and superior low-temperature performance, and has great application prospects in the field of ultra-low temperature magnetic refrigeration technology.

The invention relates to a broad-band cyan luminescent material excited by purple light as well as a preparation method and application of the broad-band cyan luminescent material. The crystal structure of the broadband cyan luminescent material is a cubic system, the space group is Ia-3d, and the broadband cyan luminescent material belongs to a garnet structure type compound; the structural formula is CaLu1-xHfGa2Al3O12: xCe < 3 + >, wherein x is more than or equal to 0.005 and less than or equal to 0.20. The preparation method comprises the following steps: weighing a Ca-containing compound, a Lu-containing compound, an Hf-containing compound, a Ga-containing compound, an Al-containing compound and a Ce-containing compound according to a stoichiometric ratio of a chemical expression, grinding and uniformly mixing to obtain a mixture; pre-sintering the mixture in air to obtain an intermediate product; and grinding and dispersing the intermediate product again, and carrying out secondary sintering in a reducing atmosphere to finally obtain the broadband cyan luminescent material. Compared with the prior art, the broadband cyan luminescent material disclosed by the invention can emit cyan light covering a 420-600nm light region under excitation of purple light.