477 results about "Crystal system" patented technology

The invention relates to the technical field of fluorescence sensing development, in particular to a Cd (II)-based metal organic framework crystalline material as well as a preparation method and application thereof. The chemical formula of the Cd (II)-based metal organic framework crystalline material is {[Cd3 (H2O) 2 (DMA) 2 (5-CMOIA) 2]. 6 / 5H2O} n, the organic framework material is characterized by an X-ray single crystal diffractometer, and the result shows that the organic framework material is crystallized in a triclinic system P-1 space group, the asymmetric unit of the organic framework material is composed of three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions and three The complex is composed of two deprotonated (5-CMOIA) 3-ligands, two coordinated DMA solvent molecules, two coordinated water molecules and six fifths of crystal water molecules. The solid fluorescence spectrum of the Cd (II)-based metal organic framework crystalline material is measured, the fluorescence response of the Cd (II)-based metal organic framework crystalline material to metal ions in a solution is explored, and the result shows that the Cd (II)-based metal organic framework crystalline material can effectively recognize Hg < 2 + > from different ions and can be applied to the field of fluorescence sensing.

The invention discloses a series of alkali metal borate compounds and alkali metal borate crystals as well as a preparation method and application thereof, and belongs to the technical field of photoelectric functional crystal materials. The chemical general formula of the series of compounds and crystals thereof is A3RE (B3O6) 2, wherein A is K, Rb, Cs or NH4; rE = Sc and Y, the molecular weight is 355.93-744.48, the series of crystals belong to a trigonal system, the space group is P321, the cell parameters a = b = 10.5237 (13)-135237 (13), and # imgabs0 # Z = 3. The series of alkali metal borate compounds are synthesized by adopting a solid-phase reaction method or a hydrothermal method, and the series of crystals grow by adopting a high-temperature melt method or a hydrothermal method or a solution method. The series of materials can be used for manufacturing second harmonic generators, upper and lower frequency converters, optical parametric oscillators, polarizing prisms and the like.

The invention relates to the technical field of mineral image recognition, in particular to a training method of a mineral selection recognition model based on multi-feature fusion. The method comprises the following steps: acquiring a mineral image; mineral crystal structure information of the mineral image is identified, geometric type division is carried out on the mineral crystal structure information, and mineral crystal system types are obtained; performing mineral crystal symbiosis identification on the mineral image according to the type of the mineral crystal system, evaluating a mineral crystal symbiosis relationship, and generating mineral crystal symbiosis data; mineral crystal grain connectivity analysis is conducted on the mineral crystal symbiosis data, and the mineral porosity is detected. Performing point-line-plane defect feature detection on the mineral image according to the mineral crystal system type to generate mineral point-line-plane defect features; according to the method, the ore selection recognition model is constructed through the multi-modal feature fusion technology, so that comprehensive recognition and analysis of the crystal structure, the symbiotic relationship, the morphological features and the surface abrasion of the minerals are achieved, and therefore the accuracy and efficiency of ore selection are improved.

The invention relates to the technical field of crystal material preparation, in particular to a layered selenide Ge3Sb2Se5 semiconductor material and a preparation method thereof. The preparation method of the layered selenide Ge3Sb2Se5 semiconductor material comprises the following steps: grinding a Ge3Sb4Se7 material, putting the ground Ge3Sb4Se7 material into a quartz tube, adding iodine particles, performing vacuum packaging in the quartz tube, putting one end, with raw materials, of the quartz tube into a high-temperature region, and putting one end, without raw materials, of the quartz tube into a low-temperature region; raising the temperature to 400 + / -25 DEG C at the low-temperature region end and 500 + / -25 DEG C at the high-temperature region end, preserving heat for 7 days, and naturally cooling to room temperature to obtain the Ge3Sb2Se5 semiconductor material. The crystal structure of the Ge3Sb2Se5 semiconductor material belongs to an orthorhombic system, and the Ge3Sb2Se5 semiconductor material has the characteristics of low thermal conductivity and low resistivity. According to the preparation method disclosed by the invention, the Ge3Sb2Se5 semiconductor material can be stably prepared, and a material is provided for physical property research of the Ge3Sb2Se5 semiconductor material and preparation of semiconductor photoelectric devices and the like.

The invention discloses a gadolinium boron molybdate magnetic refrigeration material with triangular magnetic resistance and a preparation method and application of the gadolinium boron molybdate magnetic refrigeration material. The chemical formula of the material is Gd2B2MoO9, the material belongs to a triclinic system, and the space group is P-1; the crystal structure has the characteristic that nearest rare earth Gd ions have magnetic resistance file; the material is prepared by a solid phase method or a sol-gel method; the magnetic phase change temperature of the material is 0.7-0.9 K, the material shows a remarkable magnetothermal effect at low temperature, the maximum isothermal magnetic entropy change values of the material are 30.0-35.0 J / kg.K and 51.0-55.0 J / kg.K respectively under the magnetic field change of 0-2T and 0-5T, and the material can be applied to low-temperature magnetic refrigeration. The gadolinium boron molybdate Gd2B2MoO9 material with triangular magnetoresistance provided by the invention has the advantages of low raw material price, simple process and lower equipment requirement, and is suitable for industrial production.

The invention discloses a method for refining grains of a titanium alloy. According to the method, an original low-oxygen-content titanium alloy plate is subjected to cryogenic pretreatment, the temperature of the core of the original low-oxygen-content titanium alloy plate is reduced to a certain temperature, then the cryogenic low-oxygen-content titanium alloy plate is fed into a rolling mill, the single-pass reduction rate is controlled, cryogenic rolling is completed, high refinement and uniform distribution of crystal grains are achieved, and the low-oxygen-content titanium alloy plate is obtained. And the rolled titanium alloy plate is subjected to subzero treatment again, and the titanium alloy plate of the complex twin crystal structure formed by intersection of {11-22} and {10-11} twin crystals is obtained. The method has the beneficial effects that under the synergistic effect of low oxygen and deep cooling, even under the extremely small deformation amount, the cross effect of various twin crystal systems can be efficiently activated, a high-density and complex twin crystal structure is formed, high refinement and uniform distribution of crystal grains are achieved, then the mechanical strength and low-temperature toughness of the material are remarkably improved, and the service life of the material is prolonged. And the application requirements in a severe low-temperature service environment are met.

To provide an alumina aqueous dispersion useful in forming a refractory by firing ceramic or the like, without leaving residual carbon even when firing is carried out at a temperature of 600°C or below.SOLUTION: The present invention provides an alumina aqueous dispersion containing alumina particles as dispersed particles, i.e., an alumina aqueous dispersion satisfying the following characteristics: (1) an average particle size of the dispersed alumina particles measured on the basis of number of particles is in a range of 10 to 1000 nm, (2) crystal systems of the alumina particles when the alumina aqueous dispersion is dried at 100°C, are amorphous and / or x-alumina, (3) the pH of the alumina aqueous dispersion is in a range of 2.0 to 5.3, (4) the alumina aqueous dispersion contains an organic acid and an alkali, with the organic acid being formic acid or a combination of formic acid and acetic acid, and the alkali being ammonia and, (5) the concentration of alumina (Al2O3) contained in the alumina aqueous dispersion is 0.5 to 11.5 mass%, and a method of producing the same.SELECTED DRAWING: Figure 1

To provide a ceramic having a high coefficient of thermal expansion and a low dielectric constant.SOLUTION: 50.0 to 90.0 mass% of 2MgO and SiO2, a total of 8.0 mass% or more of one of 7.0 to 14.0 mass% of ZrO2 and 10.0 to 50.0 mass% of Al2O3 or both of 14.0 mass% or less of ZrO2 and 50.0 mass% or less of Al2O3, and 3.0 to 15.0 mass% of one or more selected from Y2O3, CaO, CeO2, and HfO2, wherein a crystalline structure of the is a cubic structure. ZrO2.SELECTED DRAWING: None

Embodiments can relate to an improved hydroflux, additive or electroless plating assisted densification cold sintering process to densify powdered metals at lower compaction pressures and lower temperatures (e.g., 520 MPa and 140° C.). The process can involve inducing dissolution precipitation mechanisms at powder interfaces by introducing a transport phase (formed by the introduction of water during the process to suppress melting temperatures) that is not an aqueous solution. Particle interfaces in the cold sinter fuse together by the presence of the additional transport phase, thereby reducing the temperatures and pressures needed for compaction. Some embodiments involve the use of elements to form a eutectic at the desired low temperature, thereby stabilizing certain crystal structure shapes of isometric crystal systems, inducing rapid densification, and facilitating pore smoothing. Embodiments of the process can be used to generate a green compact via sintering that exhibits improved green strength.

The invention discloses a halogen bond action auxiliary molecule self-assembly method. The method comprises the following steps: selecting an organic multi-system small molecule material containing a pyridine group at the tail end as a halogen bond receptor; selecting a derivative of 1, 4-diiodobenzene as a halogen bond donor; the halogen bond acceptor and the halogen bond donor are dissolved in a solvent, heating, stirring and ultrasonic treatment are performed, after the solution is clarified and transparent, an assembly solution is obtained, and the solvent is slowly evaporated by controlling the environment temperature to obtain the eutecticum. The invention discloses a preparation method of a eutectic film, which is characterized in that a eutectic system is prepared into the eutectic film matched with a device structure by regulating and controlling a decompression sublimation film forming process. According to the halogen bond action auxiliary molecule self-assembly method, the synthesis process of molecules can be greatly reduced, the controllable accumulation among the molecules can be greatly improved, and the halogen bond action auxiliary molecule self-assembly method can be applied to ultrahigh-density information storage.

The invention provides a preparation method and application of a compound cesium ammonium fluoborate and a cesium ammonium fluoborate nonlinear optical crystal. The chemical formula of the compound is CsNH4B8O12F2; the chemical formula of the crystal is CsNH4B8O12F2, the crystal belongs to a trigonal system, the space group is P321, and the unit cell parameters are as follows: a = b = 6.5858 (4) + / -0.02, c = 7.8163 (6) + / -0.02, alpha = beta = 90 degrees, gamma = 120 degrees and Z = 1. The crystal is grown by adopting a vacuum high-temperature solution method, a room-temperature solution method or a hydrothermal method, and the ultraviolet transmission cut-off edge of the crystal is lower than 190 nm. The nonlinear optical effect of the crystal is about 2.5 times of that of KH2PO4 (KDP), and the shortest I-type phase matching wavelength is 175.5 nm. The crystal has the advantages of simple preparation method, low toxicity of used initial raw materials, small harm to human bodies, stable physical and chemical properties, uniaxial crystal, easiness in application and the like. The method can be widely applied to nonlinear optical devices such as ultraviolet and deep ultraviolet all-solid-state lasers, optical parametric oscillators and the like.

A quantum entanglement system comprising a laser system, a spontaneous parametric down conversion crystal system, and a thermal management system. The laser system is configured to generate a laser beam. The spontaneous parametric down conversion crystal system comprises a spontaneous parametric down conversion crystal configured to receive the laser beam at a spontaneous parametric down conversion crystal and generate an entangled photon pair in response to the spontaneous parametric down conversion crystal receiving the laser beam. The thermal management system is configured to maintain the spontaneous parametric down conversion crystal at an annealing temperature during a generation of the entangled photon pair. A translation system is configured to move a position of the spontaneous parametric down conversion crystal. A

The present invention relates to composite tungsten oxide particles containing a composite tungsten oxide represented by the general formula MxWyOz (wherein M element is one or more elements selected from the group consisting of alkali metal elements, alkaline earth metal elements, rare earth elements, Mg, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Al, Ga, In, Tl, Si, Ge, Sn, Pb, Sb, B, F, P, S, Se, Br, Te, Ti, Nb, V, Mo, Ta, Re, Be, Hf, Os, Bi, and I, 0.20 < = x / y < = 0.37, 2.2 < = z / y < = 3.3), and having a hexagonal crystal system, in which when observed in STEM-HAADF 0.01% to 10% inclusive of the Z contrast of W atoms is reduced to 95% or less of the average value.

This invention relates to a compound, magnesium gallium selenide (MgHgGa4Se8), and a magnesium gallium selenide (MgHgGa4Se8) infrared nonlinear optical crystal, along with their preparation methods and applications. The compound has the molecular formula MgHgGa4Se8 and a molecular weight of 1135.46 g / mol. The crystal, also with the molecular formula MgHgGa4Se8 and a molecular weight of 1135.46 g / mol, lacks a center of symmetry, belongs to the tetragonal crystal system, and has a space group of MgHgGa4Se8. Its cell parameters are α = β = γ = 90°, Z = 1, and its volume is determined by the high-temperature melt method, chemical vapor transport method, or crucible lowering method. This crystal exhibits advantages such as significant nonlinear optical effects, good crystal growth habit, good mechanical properties, high hardness, resistance to breakage and deliquescence, and ease of processing and storage. It can be used to fabricate infrared nonlinear optical devices, which have important applications in optoelectronic warfare, laser communication, and medical fields.

Embodiments can relate to an improved hydroflux, additive or electroless plating assisted densification cold sintering process to densify powdered metals at lower compaction pressures and lower temperatures (e.g., 520 MPa and 140° C.). The process can involve inducing dissolution precipitation mechanisms at powder interfaces by introducing a transport phase (formed by the introduction of water during the process to suppress melting temperatures) that is not an aqueous solution. Particle interfaces in the cold sinter fuse together by the presence of the additional transport phase, thereby reducing the temperatures and pressures needed for compaction. Some embodiments involve the use of elements to form a eutectic at the desired low temperature, thereby stabilizing certain crystal structure shapes of isometric crystal systems, inducing rapid densification, and facilitating pore smoothing. Embodiments of the process can be used to generate a green compact via sintering that exhibits improved green strength.

The invention belongs to the technical field of chiral material preparation, and particularly relates to a one-dimensional bismuth-based chiral perovskite crystal and a preparation method and application thereof. The general formula of the chiral perovskite crystal is (R-beta-MPA) 2BiI5 or (S-beta-MPA) 2BiI5, the chemical formula of the chiral perovskite crystal is C18H28BiI5N2, the R-beta-MPA represents (R)-(+)-beta-methyl phenylethylamine, the S-beta-MPA represents (S)-(-)-beta-methyl phenylethylamine, the R-beta-MPA represents (R)-(+)-beta-methyl phenylethylamine, and the S-beta-MPA represents (S)-(-)-beta-methyl phenylethylamine. The crystallographic data of the (R-beta-MPA) 2BiI5 include that the crystal belongs to an orthorhombic crystal system and a P212121 space group, and the cell parameters are as follows: alpha is equal to 90 degrees, beta is equal to 90 degrees, and gamma is equal to 90 degrees; the crystallographic data of the (S-beta-MPA) 2BiI5 comprises that the crystal belongs to an orthorhombic crystal system and a P212121 space group, and the cell parameters are as follows: alpha is equal to 90 degrees, beta is equal to 90 degrees, and gamma is equal to 90 degrees.

Provided is a rare earth magnet alloy having a tetragonal R2Fe14B crystal structure, including: a main phase containing, as main constituent elements, at least one kind selected from the group consisting of: Nd; La; and Sm, Fe, and B; and a sub-phase containing, as main constituent elements, at least one kind selected from the group consisting of: Nd; La; and Sm, and O, wherein La substitutes for at least one of a Nd(f) site or a Nd(g) site, wherein Sm substitutes for at least one of a Nd(f) site or a Nd(g) site, wherein La segregates in the sub-phase, and wherein Sm is dispersed in the main phase and the sub-phase without segregation.

The invention relates to a rare earth based polyoxometallate, the chemical formula of which is [Ce (H2O) 9] [Cu (H2O) (2, 6-pdca)] 3H [SiW12O40]. 5H2O, and 2, 6-H2pdca = 2, 6-pyridinedicarboxylic acid. The compound belongs to a trigonal system and an R3 space group. Rare-earth-based polyoxometallate with peroxidase activity is combined with a copper-based metal organic framework (CuBTC) to form a rare-earth-based polyacid-loaded metal organic framework composite material with CuBTC as a carrier, and then research on the application aspect of colorimetric detection of H2O2 and ascorbic acid is carried out on the rare-earth-based polyacid-loaded metal organic framework composite material. The composite material not only expands the application range of the rare earth-based polyoxometallate-loaded metal organic framework material, but also shows the application prospect of the rare earth-based polyoxometallate-loaded metal organic framework material in clinical diagnosis and food safety monitoring, thereby providing valuable reference for further application in the future.

This invention discloses a polyoxometalate that catalyzes the Knoevenagel reaction, its preparation method, and its applications. The chemical formula of the polyoxometalate that catalyzes the Knoevenagel reaction is: H3[K(H2O)6][K2(H2O) 10 ]2[Cu(en)2(H2O)2][Cu(en)2(Nb6O 19 Cu(en))2·24H2O, where en = ethylenediamine; the polyoxometalate crystals catalyzing the Knoevenagel reaction belong to the triclinic crystal system with space group P-1; the polyoxometalates catalyzing the Knoevenagel reaction prepared in this invention exhibit excellent heterogeneous catalytic performance in the highly efficient Knoevenagel condensation reaction, showing high yield and high stability under isothermal conditions at a 1:1 substrate ratio and over a wide substrate range. The superior catalytic ability of the polyoxometalates catalyzing the Knoevenagel reaction can be attributed to the presence of dense and effective basic sites on the surface of the heteropolycationic chain, and the increased contact frequency between the organic-inorganic hybrid catalyst and the substrate.

The application discloses a preparation method of vanadium-doped and high-hydrated mangan-chromian spinel monocrystal under high temperature and high pressure. The cylindrical mangan-chromian spinel sample is prepared by taking solid rose triangular rhombic manganese carbonate crystal, solid chromium (III) acetate hydroxide crystalline powder, solid vanadium (IV) acetylacetonate oxide powder, solid oxalic acid powder, solid bixbyite powder, solid chromium hydroxide powder and liquid dilute nitric acid as starting raw materials; two pieces of water source sheets are made from the bixbyite powder and the chromium hydroxide powder with a weight ratio of 4:1; the two pieces of water source sheets are placed at two ends of the cylindrical mangan-chromian spinel sample and then are placed into a double-capsule structure experimental sample bin with an inner layer sleeve being a graphite tube and an outer layer sleeve being a gold-palladium alloy tube; the high temperature and high pressure reaction is carried out to obtain the mangan-chromian spinel monocrystal; and the preparation technology blank of the vanadium-doped and high-hydrated mangan-chromian spinel large-particle monocrystal under the current high temperature and high pressure conditions is solved.

The invention discloses a low-thermal-conductivity p-type liquid thermoelectric material and a preparation method thereof. The chemical formula of the low-thermal-conductivity p-type liquid thermoelectric material is Cu6GeTeS4, the low-thermal-conductivity p-type liquid thermoelectric material belongs to a cubic system and a space group, the low-thermal-conductivity p-type liquid thermoelectric material Cu6GeTeS4 forms an anion rigid framework by GeS4 tetrahedral elements isolated in unit cells and body-centered cubic Te, and Cu ions move in the framework. The p-type liquid thermoelectric material keeps a stable cubic phase at 300-873 K, and has low thermal conductivity and a high thermoelectric figure of merit; the ultra-low thermal conductivity of 0.69 to 0.57 W m <-1 > K <-1 > is realized at 300 to 873 K.

This invention provides an organic ferroelectric eutectic material, its preparation method, and its applications, relating to the field of ferroelectric materials technology. The organic ferroelectric eutectic material constructs a crystal system with "rigid constraint and flexible adaptation coexisting, dipole order and controllable polarization synchronously" through "molecular selection-supramolecular assembly-crystal structure regulation," achieving a synergistic effect of high Curie temperature, strong polarization characteristics, and excellent flexibility. The preparation method of the organic ferroelectric eutectic material utilizes a simplified "solvent dissolution-solvent evaporation" process, leveraging the mediating effect of the solvent to promote the supramolecular self-assembly of donor and acceptor molecules. This achieves the preparation of an organic ferroelectric eutectic material possessing both high Curie temperature, strong polarization characteristics, and excellent flexibility. The preparation method has multiple advantages, including "stable process, low cost, and suitability for large-area processing," making it a simple, efficient, and universally applicable preparation method suitable for large-scale industrial production.

This invention relates to the field of chemical pharmaceuticals, and more particularly to a mebendazole crystal form and its preparation method. The mebendazole crystal form has a single-crystal structure belonging to the triclinic crystal system; space group Triclinic P; cell parameters a = 6.10 Å, b = 15.69 Å, c = 20.35 Å; α = 94.14°; β = 97.22°, γ = 90.70°, V = 1926 Å. 3 The optimization and development of the crystalline form of p-toluimidazole provided by this invention is of great value.

The invention relates to a novel second-order nonlinear optical crystal-potassium cadmium germanate (K4Cd3Ge4O13), and belongs to the field of optical crystal materials. The crystal is prepared by adopting a high-temperature solid-phase method and a high-temperature solution method, belongs to an orthorhombic crystal system and a C2 space group, is accurate in measurement of cell parameters, and shows excellent nonlinear optical characteristics and a wide light transmission range. The ultraviolet cut-off edge of the crystal is 261 nm, the infrared spectrum permeability is not obviously reduced in the range of 4000-714 cm <-1 >, the transmission range of the crystal can effectively cover a key atmosphere transmission window of 3-5 microns, and the crystal has powder frequency doubling response equivalent to that of a KDP crystal and can be applied to an all-solid-state laser as a mid-infrared nonlinear optical crystal.

This invention belongs to the field of fuel cell technology, specifically relating to a method for preparing and applying a hydrogen-bonded organic framework material with high proton conductivity constructed from carboxylic acid-aminoguanidine. The chemical formula of this organic framework material is [(CN4H7)(C 10 [O8H5], this organic framework material belongs to the triclinic crystal system. P Space group 1, cell parameters: a =7.9901(4)Å, b =9.6412(3)Å, c =9.6724(4)Å, α =96.322(3)°, β =113.876(4)°, c =93.633(3)°. The hydrogen-bonded organic framework material constructed by carboxylic acid-aminoguanidine and the composite film prepared therefrom have high proton conductivity and are highly promising proton conduction materials.

The chemical formula of the polyacid compound is H14Na4 (CoC6H12N4) 3 (NaC6H12N4) (SbW9O33) 2.22 H2O, the crystal structure parameters of the polyacid compound are as follows: the molecular formula is C24Co3N16Na5O88Sb2W18, the molecular weight is 5764.94, the polyacid compound belongs to an orthogonal crystal system, the space group is P212121, the cell parameters are as follows: a / is 15.4423 (11), b / is 25.7133 (18), c / is 31.886 (2), alpha / degree, beta / degree and gamma / degree are all 90, and the cell volume / 3 is 12661.2 (16). The compound prepared by the invention is more prominent in antitumor activity, has a remarkable inhibition effect on hepatoma carcinoma cells, and provides an important basis for developing novel efficient antitumor drugs.

A cutting tool comprises a substrate and a coating disposed on the substrate, wherein the coating comprises a first layer, the first layer comprises a plurality of crystal grains, and the crystal grains are composed of Al x Ti 1‑x C y N 1‑y The invention relates to a method for manufacturing a film of a first embodiment of the present invention, wherein x is greater than 0.65 and less than 0.95, y is greater than 0 and less than 0.1, in a first region formed by a region sandwiched between the surface S1 of the first layer or an interface S2 on the surface side of the first layer and a first imaginary plane VS1, the average aspect ratio of the grains is less than 3.0, in a second region formed by a region sandwiched between the first imaginary plane VS1 and an interface S3 on the substrate side of the first layer, the average aspect ratio of the grains is greater than 3.0 and less than 10.0, the first imaginary plane VS1 passes through a point 1 μm away from the surface S1 or the interface S2 toward the substrate side and is parallel to the surface S1 or the interface S2, the grains include grains having a cubic crystal structure, the area ratio of the grains having a cubic crystal structure in the first layer is greater than 90%, the average aspect ratio and the area ratio are measured on a cross-section along a normal to the interface between the substrate and the coating, and the thickness of the first layer is greater than 2 μm and less than 20 μm.

This invention relates to a potassium hydroxyborate nonlinear optical crystal, its preparation method, and its applications. The crystal has the chemical formula K₂B₅O₈(OH), a molecular weight of 277.26, belongs to the orthorhombic crystal system, and has a space group of [missing information]. Pca 21, with unit cell parameters a=8.5523(8)Å, b=7.3326(7)Å, c=12.9739(10)Å, α=β=γ=90°, V=813.60(13)Å. 3 A nonlinear optical crystal composed of potassium hydroxyborate can be obtained using a mild hydrothermal (solvothermal) method through programmed or natural cooling. The frequency doubling effect of this crystal powder is approximately twice that of KDP (KH₂PO₄), and its ultraviolet cutoff edge is below 200 nm, making it suitable as a deep-ultraviolet nonlinear optical crystal. The crystal growth process offers advantages such as simple operation, low raw material toxicity, short growth cycle, low cost, and stable physicochemical properties. It has been widely applied in the fabrication of nonlinear optical devices such as frequency doubling generators, up- or down-frequency converters, or optical parametric oscillators.

This application discloses an inorganic compound crystal, its preparation method, and its applications. The inorganic compound crystal has the chemical formula Ga2(OH)(TeO3)(Te2O5)Br, belongs to the orthorhombic crystal system, has a space group of Pca21, and unit cell parameters α=β=γ=90°, Z=4. The inorganic compound crystal is prepared using a hydrothermal method. Under 1064nm laser irradiation, the powder frequency doubling intensity of the inorganic compound crystal Ga2(OH)(TeO3)(Te2O5)Br is 9.8 times that of KH2PO4(KDP), and phase matching can be achieved, indicating its significant potential application value as a nonlinear optical material.

The invention discloses a method and system for determining anisotropic thermoelectric performance of a material based on tensor inversion, and the method comprises the steps: obtaining an Euler angle of a single crystal or texture polycrystalline sample in any orientation through electron back scattering diffraction, and building a rotation matrix between a sample coordinate system and a crystal coordinate system; measuring thermoelectric parameters such as resistivity, thermal conductivity and / or Seebeck coefficient under the sample coordinate system; and constructing a linear equation set based on a second-order tensor rotation formula, and inversely solving an intrinsic thermoelectric tensor component under a crystal coordinate system. According to the method, the intrinsic anisotropic thermoelectric performance of the material along the crystal main axis can be accurately obtained without strict crystal orientation cutting, and the method has the advantages of being high in universality, high in precision, easy and convenient to operate and the like and is suitable for high-throughput characterization of complex crystal system materials and device optimization design.