2-dimethylamino terephthalic acid-tetracyano benzene co-crystal, its preparation method and application
The preparation of 2-aminoterephthalate dimethyl ester-tetracyanobenzene eutectic by slow solvent evaporation under low temperature conditions solves the problem of unpredictable luminescence color of molecular solids in the prior art, and achieves high thermal stability and excellent fluorescence performance control of the eutectic. The preparation process is simple and has high crystallinity.
CN118026870BActive Publication Date: 2026-07-24TIANJIN UNIV
Patent Information
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- TIANJIN UNIV
- Filing Date
- 2024-01-04
- Publication Date
- 2026-07-24
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Figure CN118026870B_ABST
Abstract
The application provides a 2-amino terephthalic acid dimethyl ester-tetracyano benzene eutectic crystal as well as a preparation method and application thereof, the eutectic crystal is of a triclinic system, a space group is a cell parameter is alpha = 95.041 (2) °, beta = 90.337 (2) °, gamma = 97.670 (2) °, and a cell volume is The 2-amino terephthalic acid dimethyl ester-tetracyano benzene eutectic crystal provided by the application increases the solid melting point of the organic compound from 133.39 DEG C to 162.23 DEG C without changing the covalent bond of the compound, enhances the thermal stability, and meanwhile, the fluorescence emission color, the fluorescence lifetime and the quantum yield are obviously changed.
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Citation Information
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