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8592results about "Carbon compounds" patented technology

Carbon dioxide absorbent and method for separation and recovery of carbon dioxide

To provide a carbon dioxide absorbing composition that is capable of reducing the energy for releasing carbon dioxide and maintaining the carbon dioxide absorption capacity over an extended period.SOLUTION: A carbon dioxide absorbing composition comprises an amine compound (A) and a polyalkylene glycol (B) having a number average molecular weight of 140 or more, wherein the carbon dioxide absorbing composition contains a low molecular weight glycol compound (C) having a number average molecular weight of less than 140 in an amount of 0 to 10 wt.% based on the weight of the polyalkylene glycol (B), and the content of the polyalkylene glycol (B) is 50 wt.% or more and 80 wt.% or less based on the total weight of the amine compound (A), the polyalkylene glycol (B), and the low molecular weight glycol compound (C).SELECTED DRAWING: None
Owner:SANYO CHEM IND LTD

Preparation method of carbon-coated lithium iron manganese phosphate positive electrode material

The invention provides a preparation method of a carbon-coated lithium iron manganese phosphate positive electrode material, and belongs to the technical field of battery positive electrode materials, and the preparation method comprises the following steps: co-precipitating a mixed solution of an iron source, a manganese source and a phosphorus source and a precipitant solution, and drying to obtain a manganese iron phosphate precursor; adding a lithium source, calcining in stages in an inert gas atmosphere, and grinding to obtain lithium manganese iron phosphate powder; the preparation method comprises the following steps: carrying out ball milling on lithium manganese iron phosphate powder and a fluxing agent, dispersing in a carbon source solution, uniformly wrapping a carbon source, drying, carrying out segmented calcination, and carrying out ball milling. The precursor nucleation coating uniformity is improved through segmented speed control reaction of a phosphorus source solution, a manganese source solution and an iron source solution; lithium source mixing and segmented calcination are adopted, and lithium volatilization is reduced; the modified nitrogen-doped porous carbon source is used for coating the lithium iron manganese phosphate powder to generate the lithium iron manganese phosphate positive electrode material, so that the conductivity of the lithium iron manganese phosphate positive electrode material is enhanced.
Owner:白银时代瑞象新材料科技有限公司

Metal element-doped nano silicon carbon as well as preparation method and application thereof

The invention discloses metal element-doped nano silicon carbon as well as a preparation method and application thereof, and relates to the field of negative electrode materials. The nano silicon carbon takes porous carbon as a carbon skeleton, and the porous carbon is sequentially attached with nano silicon and coated with a carbon material layer through a chemical vapor deposition method; the porous carbon is prepared by carbonizing resin containing metal nitride after alkali activation and pore forming, and the resin containing the metal nitride is prepared by condensation polymerization of a phenolic compound, an aldehyde compound and the metal nitride in the presence of a catalyst. The porous carbon is doped with the metal nitride in the resin polycondensation process, the conductivity of the nano silicon carbon is effectively improved, the powder resistance is reduced, holes in the surface of the porous carbon provide more expansion space for deposited nano silicon, a carbon material layer formed by subsequent deposition and coating provides a protection effect, the reaction between silicon and an electrolyte can be inhibited, and the service life of the nano silicon carbon is prolonged. A stable SEI film is formed, the cycling stability of the material is improved, the volume expansion rate of a pole piece is inhibited, and the cycling life and the stability of the battery are improved.
Owner:JINLONGYU NEW ENERGY (SHENZHEN) CO LTD

Method for improving rapid cooling efficiency of high-temperature graphite furnace

The technical scheme of the invention relates to the technical field of data processing, in particular to a method for improving the rapid cooling efficiency of a high-temperature graphite furnace, and the method comprises the steps: carrying out the time axis normalization processing based on a cubic spline interpolation algorithm, combining an adaptive Kalman filter, fusing multi-source data, and generating a time-synchronized three-dimensional temperature field reconstruction matrix; the problem of temperature field reconstruction lag caused by insufficient time sequence alignment precision of multi-modal sensing data is solved. And the reinforcement learning network dynamically optimizes the control parameter weight through the residual feature map, preferentially corrects the deviation of the rotating speed of the induced draft fan and the gas injection angle in a high-error region, and feeds back the deviation to the thermodynamic simulation model for online iterative updating of the specific heat capacity parameters of the material, so that model prediction and dynamic calibration of the actually measured thermal field are realized. Through multi-source data alignment, closed-loop feedback and cooperative control architecture, the timeliness and execution precision of cooling path planning are remarkably improved, and the cooling efficiency and equipment reliability of the high-temperature graphite furnace are optimized.
Owner:QINGDAO HEIMAO NEW MATERIAL RES INST CO LTD

Low-concentration chemical-physical coupling intelligent continuous porous carbon production method and system

The invention provides a low-concentration chemical-physical coupling intelligent continuous porous carbon production method and system. The method comprises the following steps: pretreatment: crushing a carbon source to obtain a carbon precursor; carbonizing: heating and carbonizing the carbon precursor in a fluidized bed reactor to obtain a carbonized product; chemical activation: dipping the carbonized product in a chemical activator solution to obtain a chemical activated product, and drying the chemical activated product; physical activation: mixing a reaction gas and an inert gas as an activation gas, placing the chemical activation product in the activation gas, and performing gas activation at a preset temperature to obtain a physical activation product; and post-processing. By coupling chemical activation with physical activation, the concentration of a chemical activation reagent can be reduced, and the wastewater amount and the pollutant concentration after reaction are reduced by reducing the dosage of the reagent, so that the wastewater treatment process is simplified, the treatment agent and energy consumption is reduced, and the treatment cost is reduced.
Owner:JIANGSU SUNPOWER HEAT EXCHANGER & PRESSURE VESSEL CO LTD

Ferrite composite multi-walled carbon nanotube wave-absorbing material and preparation method thereof

The invention relates to the technical field of wave-absorbing materials. Specifically, the invention relates to a ferrite composite multi-walled carbon nanotube wave-absorbing material and a preparation method thereof. The invention also relates to electronic equipment containing the ferrite composite multi-walled carbon nanotube wave-absorbing material. The ferrite composite multi-walled carbon nanotube wave-absorbing material prepared by the invention comprises a ferrite magnetic material with magnetic loss and a multi-walled carbon nanotube material with electrical loss, and the composite material introduces multiple electromagnetic energy loss modes through unique structural design and component synergy, so that the wave-absorbing performance of the material is enhanced. In addition, the preparation method disclosed by the invention is simple in process, low in requirement on equipment, green and environment-friendly, and free from any toxic and harmful by-products.
Owner:BEIJING JIN XUN HENG TONG TECH CO LTD

Functionalized graded porous carbon microspheres as well as preparation method and application thereof

The invention provides a functional graded porous carbon microsphere and a preparation method and application thereof, the preparation method comprises the following steps: S1, mixing a soft template, a phenolic compound, a cross-linking agent and a basic catalyst, and reacting to obtain a thermosetting phenolic resin microsphere; s2, carrying out pre-carbonization treatment on the thermosetting phenolic resin microspheres to obtain a carbonized material; s3, performing physical activation on the carbonized material to obtain graded porous carbon microspheres; s4, performing heat treatment on the graded porous carbon microspheres to obtain functionalized graded porous carbon microspheres; the preparation method has the characteristics of simple process, environmental protection and economical efficiency, the functionalized porous carbon microspheres prepared by the method are uniform in morphology, and the pore volume, pore diameter and pore structure of the functionalized graded porous carbon microspheres can be accurately regulated and controlled, so that the functionalized graded porous carbon microspheres meeting application requirements are obtained.
Owner:INSTITUTE OF PROCESS ENGINEERING CHINESE ACADEMY OF SCIENCES

Biomass-derived spherical porous carbon material and preparation method thereof, and silicon-carbon negative electrode material and preparation method thereof

The invention provides a biomass-derived spherical porous carbon material and a preparation method thereof, and a silicon-carbon negative electrode material and a preparation method thereof, and relates to the field of lithium ion batteries. The preparation method of the biomass-derived spherical porous carbon material comprises the following steps: carrying out pre-carbonization treatment on vinasse to obtain pre-carbonized vinasse, mixing the pre-carbonized vinasse with an acidic solution, and washing with water until the mixture is neutral to obtain pre-treated vinasse; mixing the pretreated vinasse with a pore-forming agent, a binder and water to prepare slurry, and performing spray drying on the slurry to obtain a spheroidized precursor; carrying out carbonization treatment on the spheroidized precursor; washing the carbonized spheroidized precursor with water until the spheroidized precursor is neutral, and drying the spheroidized precursor to obtain an intermediate; and activating the intermediate with water vapor to obtain the biomass-derived spherical porous carbon material. The material with a regular spherical and porous structure can be prepared, the material can be used for preparing a silicon-carbon negative electrode material with a stable structure, and the electrochemical performance of the silicon-carbon negative electrode material is improved.
Owner:SI CHUAN HUA YI QING CHUANG XIN CAI LIAO KE JI YOU XIAN GONG SI

Porous carbon material applied to silicon-carbon negative electrode as well as preparation method and application of porous carbon material

The invention discloses a porous carbon material applied to a silicon-carbon negative electrode as well as a preparation method and application of the porous carbon material, and belongs to the technical field of lithium ion batteries. Uniformly mixing asphalt and mixed acid, heating and fully reacting to obtain acid modified asphalt; dispersing the acid modified asphalt in deionized water to prepare an asphalt aqueous solution, sequentially adding melamine and KOH, uniformly dispersing to obtain a mixed solution, and drying to obtain precursor powder; carbonizing the precursor powder under the protection of nitrogen, and then introducing CO2 or water vapor or mixed gas of the CO2 and the water vapor for activation; and washing and drying the activated product to obtain the porous carbon material. The obtained material has excellent conductivity, stability and high silicon loading performance, and can be applied to the field of lithium ion battery negative electrode materials, a silicon-carbon negative electrode prepared by taking the porous carbon material as a carrier is applied to a lithium ion battery, and the technical effects of high capacity density and long circulation can be achieved.
Owner:HENAN ZIBEN NEW ENERGY TECH CO LTD

Resin-based self-activated porous carbon material as well as preparation method and application thereof

The invention relates to the technical field of lithium battery negative electrode materials, and particularly discloses a resin-based self-activated porous carbon material and a preparation method and application thereof.The preparation method comprises the following steps that a diphenol monomer, a diphenol monomer containing thioether bonds, formaldehyde or polyaldehyde and a catalyst A are subjected to a condensation polymerization reaction, and phenolic resin is obtained; and carbonizing the phenolic resin to obtain the resin-based self-activated porous carbon material. The phenolic resin is synthesized by utilizing the diphenol monomer containing the thioether bond, so that a thioether alkane side chain is introduced into the phenolic resin, and in the carbonization process of the phenolic resin, because the thioether bond is extremely easy to decompose at high temperature to generate gas, a phenolic resin framework can be subjected to pore forming; the prepared resin-based self-activated porous carbon material has high specific surface area and pore volume, controllable design of the internal pore structure of the resin-based porous carbon can be realized by controlling the structure and modification proportion of the thioether alkane side chain, and ideal pore distribution is obtained.
Owner:HEFEI GUOXUAN HIGH TECH POWER ENERGY CO LTD CO LTD

Porous carbon material as well as preparation method and application thereof

The invention discloses a porous carbon material as well as a preparation method and application thereof, and the porous carbon material is prepared by the following steps: by taking a silicon dioxide mesoporous hollow sphere as a hard template through a hard template method, carrying out condensation reaction on phenol and formaldehyde in the hollow part of the silicon dioxide mesoporous hollow sphere to form phenolic resin; and curing, carrying out carbon activation treatment and etching to obtain the spherical phenolic resin porous carbon material. The porous carbon material prepared by the preparation method disclosed by the invention has a relatively high specific surface area and a relatively uniform pore structure, and the cycle performance of a secondary battery can be improved when the porous carbon material disclosed by the invention is used for preparing a negative pole piece and assembling the negative pole piece into the secondary battery.
Owner:LIYANG TIANMU PILOT BATTERY MATERIAL TECH CO LTD

Multi-layer plating process for optimizing surface characteristics of base material

The invention discloses a multi-layer plating process for optimizing surface characteristics of a base material, which is characterized by comprising the following steps of: pretreating the surface of a plated base material, improving the surface smoothness of the base material, and removing dirt on the surface of the base material; electroplating the base material by using the nickel pre-plating solution; chemical plating: the base material subjected to pre-plating treatment is placed in a chemical composite plating solution for chemical plating; the chemical composite plating solution comprises a basic plating solution and second-phase particles, the second-phase particles are nano niobium carbide, and the second-phase particles are wrapped and embedded into an alloy plating layer in the chemical plating process, so that the second-phase particles are distributed in plating layer matrix metal in a discrete mode to form a discontinuous phase. The hard particles niobium carbide are added and are dispersed and distributed in a coating substrate (Ni-P alloy), the hard particles can effectively refine the substrate metal, so that the hardness of the substrate metal is improved, and the niobium carbide hard phase particles are high in hardness, excellent in wear resistance, large in yield limit and high in pressure resistance.
Owner:JIANGSU CREATIVE PLATECH MATERIALS CO LTD

Method for recycling lithium iron phosphate powder with iron salts and recovering all components

This invention discloses a method for leaching lithium iron phosphate mixed powder with iron salts and recovering all components, belonging to the field of battery recycling. The invention uses an iron salt solution to leach the mixed powder, obtaining a lithium-containing leachate and leaching residue. Ferrous ions in the leachate are regenerated into ferric iron through acidification and oxidation, and recycled for leaching the next batch of mixed powder. After reaching a preset number of cycles, the leachate is used for re-leaching multiple batches of leaching residue to improve the lithium leaching rate. Ultimately, a enriched solution containing Li, Fe, Cu, and Al and graphite-containing iron phosphate residue are obtained. Copper is recovered from the enriched solution through iron powder replacement, and a high-purity lithium chloride solution is obtained through extraction and separation, while ferric chloride (recycled) and aluminum chloride crystals are also recovered. The leaching residue is treated with hydrochloric acid to obtain regenerated graphite, and the pH is adjusted with alkali to obtain high-purity iron phosphate. This method achieves full component recovery under mild conditions, reducing separation steps and chemical consumption through a "leaching-regeneration-leaching" cycle mechanism, thus achieving both environmental and economic benefits.
Owner:ZHEJIANG UNIV +1

Porous carbon, preparation method thereof, negative electrode active material and application of negative electrode active material

The invention provides porous carbon and a preparation method thereof, and a negative electrode active material and application thereof. The porous carbon has a brand new structural design, abundant pores and reasonable pore size distribution, and can be used for providing a negative electrode active material with relatively high capacity and relatively good long-cycle structure stability.
Owner:BYD CO LTD

Silicon-carbon negative electrode material based on spherical starch porous carbon and preparation method of silicon-carbon negative electrode material

The invention belongs to the field of lithium battery electrode materials, and particularly relates to a silicon-carbon negative electrode material based on spherical starch porous carbon and a preparation method of the silicon-carbon negative electrode material. The preparation method comprises the following steps: carrying out esterification reaction on plant starch and an esterifying agent, carbonizing, crushing, activating with potassium hydroxide, pickling, and carrying out a vapor deposition silane technology to further prepare the silicon-carbon negative electrode material. The starch subjected to esterification reaction is used as a precursor, porous carbon is prepared through carbonization, activation and the like, the silicon-carbon negative electrode material is prepared through the vapor deposition silane technology, and the silicon-carbon negative electrode material not only has a spherical porous carbon skeleton, is low in volume effect and good in conductivity, but also is high in first charge and discharge capacity and first efficiency.
Owner:GANZHOU RUIFUTE TECHNOLOGY CO LTD +1

System and method for producing activated carbon material from cow dung

The present invention generally relates to a system for producing activated carbon from cow dung. The process begins with a drying and washing unit to pre-treat the raw material. Dried cow dung is then milled and sieved to a specific particle size. A second drying step prepares the sieved material for carbonization in a nitrogen atmosphere. The resulting carbonized material undergoes chemical activation using a sodium hydroxide solution. Subsequent pyrolysis in a nitrogen environment further develops the pore structure of the activated carbon. The pyrolyzed material is then washed with hydrochloric acid to remove impurities. A final drying step yields the desired activated carbon product, which is then crushed. This system provides a controlled and efficient method for converting cow dung into valuable activated carbon, offering a sustainable waste management solution and a source of high-quality material for various applications.
Owner:PRINCESS NORA BINT ABDULRAHMAN UNIV

Single-base resolution laminated two-dimensional material nanopore structure and DNA sequencing device and method

The invention belongs to the technical field of biomedical engineering, and particularly relates to a single-base resolution laminated two-dimensional material nanopore structure, a DNA sequencing device and a DNA sequencing method. The two-dimensional material nanopore structure comprises an insulating layer and conducting layers arranged on the upper side and the lower side of the insulating layer, through nanopores are formed in the insulating layer and the conducting layers, and the pore diameter of the nanopores is 2-5 nm; the insulating layer and the conductive layer are made of two-dimensional materials. The conductive layers on the two sides serve as upper and lower electrodes, and a power supply is connected between the upper and lower electrodes to form a phase conductive path which is provided with a longitudinal current detection element. A plurality of groups of two-dimensional material nanopore structures are stacked, and meanwhile, a plurality of groups of base pair signals are obtained. According to the invention, the advantages of small thickness, high physical strength and the like of the two-dimensional material nanopore are kept by using a few layers of two-dimensional material films, the vibration of the films is reduced by increasing the number of layers and improving the mechanical strength, so that the signal-to-noise ratio is improved, and the spatial resolution of the nanopore sensor is improved by designing the upper electrode and the lower electrode.
Owner:HUAZHONG UNIV OF SCI & TECH

Preparation method and application of petroleum asphalt-based porous carbon material

The invention provides a preparation method and application of a petroleum asphalt-based porous carbon material, and belongs to the technical field of porous carbon materials. The preparation method comprises the following steps: by taking petroleum asphalt as a carbon precursor, stirring and pre-oxidizing the petroleum asphalt and molten salt at a certain temperature, then pre-carbonizing, washing away the molten salt, and carbonizing with KOH to prepare the petroleum asphalt-based porous carbon material. The petroleum asphalt with low carbon yield (11%) is converted into the petroleum asphalt-based porous carbon material with obviously improved carbon yield (up to 30%) through an efficient and convenient method. When the petroleum asphalt-based porous carbon material prepared by the method provided by the invention is used as an electrode material of a lithium ion battery / zinc ion capacitor, the petroleum asphalt-based porous carbon material shows excellent electrochemical performance.
Owner:XINJIANG UNIVERSITY

Multi-stage carbon dioxide capturing and utilizing method and device

The invention discloses a multi-stage carbon dioxide capture and utilization method and device. CO2-containing high-temperature flue gas enters an adsorption reactor and passes through the adsorption reactor filled with a bifunctional catalyst, and CO2 in the flue gas is adsorbed and captured by a catalytic material in a catalyst bed layer; decarburized gas comes out of the adsorption reactor, exchanges heat with process gas from the conversion reactor in a heat exchanger, and enters the next stage of adsorption reactor after heat exchange, when the adsorption reactor reaches the saturated adsorption capacity of an adsorbent, CO2-containing high-temperature flue gas is switched to enter the first stage of conversion reactor, at the moment, reducing gas enters the adsorption reactor, and the CO2-containing high-temperature flue gas enters the second stage of conversion reactor; and the converted synthesis gas is sent out of the device. By means of the technical process, the energy utilization rate can be fully increased, the emission reduction cost can be effectively reduced, high energy consumption caused by trapping cooling / conversion heating can be avoided, and the problems of high cost for purification and transportation after CO2 capture and potential safety hazards caused by burying are solved.
Owner:CHINA PETROLEUM & CHEMICAL CORP +1

Metal-organic framework for electrochemical biosensor electrode, working electrode for electrochemical biosensor including same, electrochemical biosensor, and manufacturing methods therefor

The present invention relates to: an electrochemical biosensor capable of effectively and sensitively detecting alfuzosin; an electrode applied thereto; a metal-organic framework (MOF) which includes a zinc / cobalt oxide and is applied in manufacturing the electrode; and methods for manufacturing same.
Owner:SOONCHUNYANG UNIV IND ACAD COOP FOUND

Carbon dioxide trapping integrated system

The invention relates to a carbon dioxide capture integrated system which comprises a carbon dioxide lean flue gas rear-end treatment unit, a carbon dioxide rear-end treatment unit and a plurality of integrated modules connected in parallel, the integrated module comprises at least one reactor, each reactor comprises a conductive shell, a heating part and a reaction cavity used for containing a solid adsorption material, and the heating parts are arranged outside the conductive shells and conduct heating in an electromagnetic heating mode. The inner diameter of the reactor is 300-500 mm, and the height of the reactor is 2.5-3 times of the inner diameter. The reactor has an adsorption mode, a desorption mode and a shutdown mode which can be switched; the number of the integrated modules can be adjusted according to the carbon dioxide capturing requirement. According to the system, the installation number of the small integrated modules can be flexibly adjusted according to the carbon dioxide trapping requirement, the carbon dioxide trapping requirements of different scales are met, electromagnetic heating is adopted, rapid and uniform heating of the solid adsorption material is effectively achieved, the power consumption of the system is greatly reduced, and then the trapping efficiency and economical efficiency of the system are improved.
Owner:HUADIAN ELECTRIC POWER SCI INST CO LTD +3

Synthesis and use of tuned precatalyst for carbon-monoxide and carbon-dioxide based fischer-tropsch catalyst for controlled product distribution

PCT designated stage expiredWO2025133656A1Oxygen/ozone/oxide/hydroxideHydrocarbon from carbon oxides
The present invention belongs to the technical field of design and synthesis of carbon-monoxide and carbon-dioxide-based Fischer-Tropsch synthesis catalysts, and discloses a novel iron-based Fischer-Tropsch synthesis catalyst containing both iron and carbon and a synthesis method and use thereof. The present invention specifically relates to a catalyst mixture for use in hydrogenation of CO and / or CO2, which catalyst mixture comprises i) iron oxide promoted by alkali metal, alkaline earth metal or transition metal, and ii) iron carbide. The invention further relates to a method for production of iron carbide composite comprising different iron carbides, and the use of said carbide composite in combination with alkali metal, alkaline earth metal or transition metal promoted iron oxide for use in hydrogenation of CO and / or CO2.
Owner:SZEGEDI TUDOMANYEGYETEM

Carbon material, silicon-carbon composite material and application thereof

The invention relates to a carbon material and a silicon-carbon composite material, which are especially suitable for the field of lithium ion battery negative electrode materials. The carbon material particles are provided with compact outer surfaces and internal holes, the internal holes show that compact parts and hole parts can be observed on the internal cross sections of the carbon material particles, and the compact parts are continuous and partition and surround the hole parts; the hole parts are not communicated and are isolated and dispersed holes, the size of the holes is 10 nm to 4 microns, and the area of the holes accounts for 0.0001 to 20 percent of the area of the cross section. The invention also provides a silicon-carbon composite material which comprises the carbon material and silicon nanoparticles with the size of 2-5nm, and the internal pore size of the silicon-carbon composite material is 10nm-4mu m. The silicon-carbon composite material disclosed by the invention can be used as a negative electrode active material for a negative electrode of a lithium ion battery, and has excellent electrochemical performance.
Owner:LANXI ZHIDE ADVANCED MATERIALS CO LTD

Plant polysaccharide extract as well as preparation method and application thereof

The invention belongs to the technical field of pharmaceutic adjuvants, and particularly relates to a plant polysaccharide extract as well as a preparation method and application thereof. According to the method, pretreatment is carried out through the composite acid liquor composed of acetic acid and oxalic acid, meanwhile, efficient extraction is carried out through the deep-eutectic solvent, and impurity removal treatment is carried out in cooperation with modified activated carbon, so that the plant polysaccharide extract is efficiently obtained, and the extraction rate and purity of the extract are improved.
Owner:XI AN SOST BIOTECH CO LTD

Alkali-process activated carbon multi-stage synergistic potassium removal method

The invention relates to an alkaline activated carbon multi-stage synergistic potassium removal method, and belongs to the technical field of activated carbon materials. According to the method, a four-step synergistic process of water washing, acid pickling, ion exchange and nitrogen calcination is adopted, and a waste acid recycling closed-loop system is combined. The deep removal of residual potassium is realized through the synergistic effect of countercurrent water washing, pH (Potential of Hydrogen) staged regulation and control acid washing, deep potassium removal by ion exchange resin and nitrogen protection calcination, and meanwhile, the high specific surface area is maintained; the pickling waste liquid is neutralized, concentrated and crystallized to be converted into agricultural potash fertilizer, and mother liquid is recycled to form green circulation.
Owner:广东韩研活性炭科技股份有限公司

Coal-based porous carbon material as well as preparation method and application thereof

The invention belongs to the technical field of supercapacitor materials, and particularly relates to a coal-based porous carbon material and a preparation method and application thereof. In order to solve the problems of safety, batch stability and easy formation of a pore structure in a process for preparing porous carbon from coal, the method comprises the following steps: firstly, carrying out mixing and kneading treatment on fine-particle raw material coal and a liquid-phase doping agent, and then carrying out drying-low-carbon integrated treatment on the mixture; then activating the low-carbon material at a high temperature by means of water vapor, and then performing refined pore-forming on the cavity structure at a high temperature by means of carbon dioxide gas; after the activation reaction is finished, carrying out impurity removal treatment on the activated material with the high specific surface area by virtue of an acid-base solution; and depositing a layer of organic polymer on the surface of the purified material by adopting an atomic layer deposition technology, and forming a passivation layer on the polymer layer by virtue of high-temperature treatment, thereby obtaining the coal-based porous carbon material with stable performance and structure, and further applying the coal-based porous carbon material to the negative pole piece of the supercapacitor.
Owner:INST OF COAL CHEM CHINESE ACAD OF SCI

High-layer spacing porous carbon material based on coal pre-oxidation treatment and preparation method of high-layer spacing porous carbon material

The invention belongs to the technical field of carbon materials, and relates to a coal pre-oxidation treatment-based high-layer spacing porous carbon material and a preparation method thereof.A large number of oxygen-containing functional groups are constructed in coal through low-temperature pre-oxidation, and a cross-linked structure is constructed through the oxygen-containing functional groups in the coal low-temperature pyrolysis process; free movement, stacking and growth of aromatic lamellas are inhibited, a graphitization process of a carbon material is hindered, a foundation is laid for improvement of interlayer spacing, carbon is activated and etched by adopting excessive carbonate with relatively weak corrosivity, a large number of graded pore structures are generated, activated carbon with high specific surface area is generated, an oxygen-containing functional group structure generated by coal pre-oxidation is generated, and the carbon material is prepared. And uniform generation of subsequent pore structures is also facilitated. The coal-based carbon material obtained by coupling pre-oxidation with medium-temperature carbonate activation has higher interlayer spacing and specific surface area, and has a hierarchical porous structure.
Owner:XIAN THERMAL POWER RES INST CO LTD +2

High-concentration dispersion system and preparation method thereof

The invention relates to the technical field of conductive materials, in particular to a high-concentration dispersion system and a preparation method thereof. The high-concentration dispersion system comprises a conductive agent, a dispersing agent, a solvent and a viscosity reduction auxiliary agent, the conductive agent is modified carbon nanotubes, the dispersing agent is modified polyvinylpyrrolidone, the solvent is N-methyl pyrrolidone or deionized water, and the viscosity reduction auxiliary agent is piperazine anhydrous; wherein the modified carbon nano tube is obtained by mixing and heating a carbon nano tube and a mixed acid solution of nitric acid and sulfuric acid, then cooling, filtering, washing, drying, then dispersing in 75% ethanol, and finally adding 3-[3-carboxyl allylamido] propyltriethoxysilane for modification; the modified polyvinylpyrrolidone is obtained by heating polyvinylpyrrolidone at 310-330 DEG C and then oxidizing the polyvinylpyrrolidone. The conductive agent content of the high-concentration dispersion system is high, the conductive agent accounts for 15%-20% of the high-concentration dispersion system by mass, and the high-concentration dispersion system is low in viscosity, high in dispersity and good in conductivity.
Owner:SHANDONG JINGSHI DAZHAN NANO TECH CO LTD

Micro-mesoporous biomass porous carbon with high specific surface area as well as preparation method and application of micro-mesoporous biomass porous carbon

The invention discloses high-specific-surface-area micro-mesoporous biomass porous carbon as well as a preparation method and application thereof. The method comprises the following steps: performing hydrothermal catalytic reaction on tobacco stems in an H2O2 solution to loosen a compact structure and increase oxygen-containing functional groups, fully mixing pretreated tobacco stem hydrothermal carbon and sodium lignin sulfonate in an aqueous solution in a solid-liquid form, adding glutaraldehyde to perform cross-linking reaction, and drying to obtain the tobacco stem hydrothermal carbon / sodium lignin sulfonate composite material. The preparation method comprises the following steps: preparing CaCO3 and tobacco stem into a composite biomass charcoal source with a stable three-dimensional network structure, preparing a composite biomass / CaCO3 precursor through an in-situ coprecipitation method, and finally carrying out high-temperature carbonization to obtain the tobacco stem / lignin composite porous carbon with a micro-mesoporous structure, a high specific surface area and a stable structure. The porous carbon material not only has abundant and mutually communicated hierarchical porous structures and high specific surface area, but also contains abundant active oxygen-containing functional groups, so that the surface characteristics of the porous carbon are improved, more adsorption sites can be provided, and the adsorption performance of the porous carbon material is greatly improved.
Owner:SOUTH CHINA UNIV OF TECH

Method for recycling valuable materials from waste ternary lithium batteries

The invention discloses a method for recovering a valuable material from a waste ternary lithium battery, which directly uses a lithium battery inner core as a roasting raw material, simplifies a pretreatment process flow, improves the overall recovery process efficiency, and performs low-temperature reduction roasting by using pyrolysis tail gas generated by pyrolysis of a battery material (the lithium battery inner core) to realize waste reutilization. The organic binder in the organic diaphragm and the positive electrode material can be effectively removed, meanwhile, metal elements in the positive electrode material can be reduced, high-valence metal oxide can be reduced into metal elementary substances, in the subsequent leaching process, use of a reducing agent can be avoided, the metal ion leaching rate in the subsequent water leaching and acid leaching process is increased, and the leaching efficiency is improved. Efficient separation and recovery of lithium, nickel, cobalt, manganese, copper foil, aluminum foil and graphite are realized, and maximization of economic benefits and environmental benefits is realized.
Owner:GUANGZHOU INST OF ENERGY CONVERSION CHINESE ACAD OF SCI