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Rare earth up-conversion fluorescent material doped with luminescent center in different regions and preparation method thereof

The invention discloses a luminescent centre regionally doped rare earth upconversion luminescent material and a preparation method thereof, which relates to the technical field of structural design and preparation of luminescent materials. For solving the problems of small doping amount in the luminescent center and low luminescent efficiency of the rare earth upconversion luminescent material, the conventional materials of the same kind take NaYF4 as a matrix, are doped with rare earth sensitized ions and rare earth luminescent ions and has a core/shell structure and nanocrystalline micro structure, wherein a luminescent shell layer is coated outside the core/shell structure, and a sensitized layer is the outmost layer. The preparation method of the rare earth upconversion luminescent material comprises: after a trifluoroacetate thermal decomposition method is implemented, adding a luminescent shell layer precursor into solution of nanoparticle colloid with the luminescent core/shell structure, heating, and reacting to form the luminescent shell layer; cooling the product obtained by the previous step, adding a sensitized shell precursor layer, heating, reacting and obtaining a sensitized shell layer on the outside of the luminescent shell layer; and thus, obtaining the luminescent centre regionally doped rare earth upconversion luminescent material.
Owner:CHANGCHUN INST OF OPTICS FINE MECHANICS & PHYSICS CHINESE ACAD OF SCI
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