The invention discloses a
lithium ion battery phosphatic
composite cathode material and a preparation method thereof. The
composite material is a multinuclear
core shell structure composed of a plurality of cores and a housing layer, the cores are
lithium iron phosphate particles wrapped by
lithium vanadium phosphate and the housing layer is
amorphous carbon. Preparation of the
lithium iron phosphate particles wrapped by lithium
vanadium phosphate comprises the following steps: preparing precursor
sol with a
sol gel method, adding
lithium iron phosphate powder to disperse uniformly, carrying out
spray drying on the above mixture, calcining the above
resultant in
inert gas, and followed by cooling and
grinding to obtain the
lithium iron phosphate particles wrapped by lithium
vanadium phosphate. Preparation of the
composite cathode material comprises the following steps: dissolving a
carbon source compound into deionized water, adding core materials, dispersing the above
resultant uniformly, carrying out second
spray drying, calcining the above
resultant in
inert gas, and followed by cooling to obtain the
composite cathode material. The
composite material prepared in the invention has good electronic conduction performance, good ionic conduction performance and excellent
electrochemistry performance. Because of existence of lithium
vanadium phosphate, energetic density of a material is raised. Because of the multinuclear
core shell structure like nano / micro structures, the
composite material has good
processing performance, and tap density of the material is greatly raised.