The invention discloses a hard-carbon-doped negative
electrode material and a preparation method and application thereof, and the preparation method of the hard-carbon-doped negative
electrode material comprises the following steps: S1, carrying out heat treatment on a
nitrogen-containing precursor to obtain
graphite-phase
carbon nitride;
grinding into
powder, mixing with acid liquor, ultrasonically stirring, and washing to be neutral;
drying and adding water to obtain a suspension; s2, mixing and reacting a phenolic compound and an
aldehyde compound with an alkaline
aqueous solution, then uniformly mixing with the suspension, and carrying out
spray drying to obtain
dry powder; s3, NaF is placed in a high-frequency
plasma reaction bin to form steam, and NaF is deposited on the surface of the
dry powder; and S4, in the
atmosphere of protective gas, carrying out heat treatment on the
dry powder deposited with the NaF, and then carrying out
carbon coating. According to the hard carbon-doped negative
electrode material provided by the invention, NaF forms steam through a
plasma technology to uniformly coat the surface and pores of hard carbon, and then
carbon coating is performed through vapor deposition, so that the
binding force of NaF is increased, and the specific surface area of the hard carbon material is reduced, and therefore, the hard carbon-doped negative
electrode material has high first efficiency and long cycle performance.