1691 results about "HYDROSOL" patented technology

The present invention provides a photocatalyst-carrying structure which has a structure, wherein an adhesive layer is provided in between a photocatalyst layer and a substrate, the adhesive layer is composed of silicon-modified resin, polysiloxane-containing resin or colloidal silica-containing resin, and for forming the photocatalyst layer a composition comprising a metal oxide gel or a metal hydroxide gel and a photocatalyst is used. Further, the present invention also provides a photocatalyst coating agent for producing a photocatalyst-carrying structure which contains silicon compound, at least one metal oxide sol or metal hydroxide sol, and at least one photocatalyst powder or sol.

The invention provides a nano-bionic material for tissue repair and a preparation method thereof. The nano-bionic material comprises a nano-bionic bracket and hydrosol attached to the nano-bionic bracket, wherein one or more cell factors and/or cells are coated in the hydrosol. The preparation method of the nano-bionic material comprises the following steps of: preparing an electrospinning solution and a hydrosol solution containing the cell factors and/or the cells; preparing the nano-bionic bracket by using the electrospinning; printing the hydrosol solution containing the cell factors and/or the cells on the nano-bionic bracket by using a ink-jet printer; and the like, and repeating the electrospinning and the ink jet to obtain the nano-bionic material with different thicknesses. By combining with an electrospinning technology and a biological printing technology, the invention combines specific medicines and/or the cell factors and/or the cells in the nano-bracket and/or the surface of the nano-bracket, thereby greatly enhancing the effects of the nano-bionic material on tissue repair and tissue regeneration; in addition, the invention has broad application prospect.

The invention provides a high-performance thermal insulation material and a preparation method thereof. The thermal insulation material comprises silicon dioxide aerogel and a fiber material, wherein, the silicon dioxide aerogel takes silicon dioxide hydrosol as a raw material, and is prepared by adding a catalyst. The method comprises the following steps: sol preparing, sol dipping, gelating, gel ageing, hydrophobization treating and drying and the like. The method can conveniently and selectively prepare the materials of planes, abnormal-shape surfaces and multiple sizes, has simple and convenient operation and small environmental pollution. The material has excellent mechanical performance, good high-temperature stability and heat insulation performance, and has wide application prospect in the fields of civilian industries, space flight and aviation industries, military industries and the like.

Provided according to embodiments of the invention are NO-releasing sol-gel coating formed from a sol precursor solution comprising a backbone alkoxysilane and a diazeniumdiolate-modified alkoxysilane. Further provided are methods of producing NO-releasing sol-gel coatings. Such methods may include (a) co-condensing a sol precursor solution comprising a backbone alkoxysilane and a diazeniumdiolate-modified alkoxysilane in a solvent to form a sol; (b) coating a substrate with the sol; and (c) drying the sol to form the NO-releasing sol-gel coating.

The present invention discloses a preparation method for hydrophobic silica aerogel with industrial waterglass as a raw material, which comprises the following steps: diluting the industrial waterglass with water; neutralizing with an acid to obtain hydrosol; allowing the hydrosol to stand and age for 8-48 hours at normal temperature so as to form hydrogel; replacing the water in the hydrogel with anhydrous ethanol; allowing the hydrogel to react with organosilane compounds; performing surface modification and simultaneous solvent exchange with n-hexane; suction-filtering; washing; allowing to stand at normal temperature to obtain white hydrophobic silica aerogel powder. The preparation method has simple process and low cost, and the prepared aerogel has porous network-like structure which features a low density and a high specific surface area.

Ultraporous sol gel monoliths and methods for preparing the same are provided, having superior flow characteristics for chromatography and analytical chemistry applications. The methods for forming an ultra porous sol-gel monolith include (a) forming a solution comprising a porogen, a matrix dissolving catalyst and a sol gel precursor; (b) allowing the solution to form a gel; and (c) drying the gel at an elevated temperature. The ultraporous sol gel monoliths are characterized by a porosity of up to about 97%, a BET surface area of at least about 50 m²/g and substantially no micropores.

This invention relates to a 4 group metal oxide and to a method for preparation thereof and the 4 group metal oxide prepared by adding a particle growth inhibiter to a hydrosol a hydrogel or a dried product of a hydrous 4 group metal oxide represented by MO(2-x)(OH)2x (wherein M denotes a 4 group metal and x is a number greater than 0.1 or x>0.1) followed by drying and calcining has a specific surface area of 80 m<2>/g or more, a pore volume of 0.2 ml/g or more and a pore sharpness degree of 50% or more and excellent heat stability and is useful for a catalyst or a catalyst carrier in which a catalyst metal is dispersed to a high degree. This invention further relates to a porous 4 group metal oxide and to a method for preparation thereof and the 4 group metal oxide prepared by application of a pH swing operation is characterized by a large specific surface area, excellent heat stability, high dispersion of a catalyst metal and a controlled and sharp pore distribution and is useful for a catalyst or a catalyst carrier of excellent reaction selectivity.

The invention relates to a method for preparing nano-doped tin oxide sol, belonging to the technical field of semiconductor nano film preparation process. The method provided by the invention mainly uses a sol-gel method to prepare nano-doped SnO2 sol on compatible reaction condition via hydrothermal processing. In the method, tin salt is taken as main raw material, villaumite and antimony salt or two parts of antimony or two parts of villaumite in appropriate content are added as doping agent to obtain doped SnO2 sol. High temperature calcination is unnecessary in the synthesized process, and nano-doped SnO2 sol can be obtained with even grains and fine dispersivity. Spray finishing, spin coating, and dipping and drawing method can be carried out on the obtained sol to prepare nano-doped SnO2 film. The film can be applied into various fields, such as low emissivity glass, display equipment, gas sensor, transparency electrode of solar battery and the like.

A catalyst and method for producing hydrocarbons using a catalyst support having an improved hydrothermal stability, such as under Fischer-Tropsch synthesis conditions. The stabilized support is made by a method comprising treating a boehmite material in contact with at least one structural stabilizer. Contacting the boehmite with at least one structural stabilizer can include forming a mixture comprising the boehmite material and at the least one structural stabilizer. The mixture can be a sol or a slurry. The treating preferably includes drying or spray drying the mixture, and calcining in an oxidizing atmosphere to obtain the stabilized support. Preferred structural stabilizers can include an element, such as cobalt, magnesium, zirconium, boron, aluminum, barium, silicon, lanthanum, oxides thereof, or combinations thereof; or can include precipitated oxides, such as a co-precipitated silica-alumina.

The invention discloses a preparation method of integrated large-hole alumina, belonging to a preparation technique of integrated multi-hole inorganic oxide. The method comprises the following process: reverse concentrated emulsion method is adopted to prepare integrated large-hole organic template taking cinnamene and divinylbenzene as monomer; aluminum isopropoxide or pseudoboehmite is primarily used for preparing Al2O3 hydrosol; the Al2O3 hydrosol is filled into the integrated large-hole organic template; the filled integrated organic/inorganic composites are dried and then are roasted to remove the template, so as to obtain the integrated large-hole alumina. The invention has the advantages of simple and feasible preparation process, moreover the prepared integrated large-hole alumina has micrometer grade communicated large-hole channels (1-50um). The invention is applicable for catalyst carrier, absorption materials and separation materials.

The invention relates to a fluorine-free superhydrophobic finishing agent containing modified nano silicon dioxide hydrosol and application thereof. The finishing agent is prepared by the following steps of: (1) mixing a precursor, an anionic surfactant and water and stirring violently at the temperature of between 20 and 50 DEG C; and (2) slowly adding ammonia water serving as a catalyst dropwise, stirring, adding long-chain alkylsiloxane serving as a modifier and stirring continually so as to obtain modified SiO2 hydrosol. The finishing agent has a stable property, avoids the pollution of an organic solvent and has high water repellency when used for performing superhydrophobic finishing on textiles.

The invention discloses a method for preparing a cathode material of a sodium-ion battery, namely sodium vanadium fluorophosphates. The method comprises the following steps: using a vanadium source, a phosphorus source and a carbon source as main synthetic raw materials; dissolving into deionized water according to the molar ratio 1:1:1.2 of vanadium: phosphorus: carbon, heating in water bath, and continuously stirring to obtain light green pulp; after vacuum drying, grinding, then transferring into a tube furnace, preburning in an inert atmosphere at a certain temperature rise rate, cooling and then taking out to obtain black VPO4/C precursor powder; mixing the VPO4/C with NaF according to a stoichiometric ratio, ball-milling for 3 hours, sending into the tube furnace, then roasting in the inert atmosphere at the certain temperature rise rate, and cooling along with the furnace to obtain a positive active material NaVPO4F/C. According to the invention, cheap and easily-obtained pentavalent vanadium oxide or trivalent vanadium oxide is used as the main raw materials to prepare the sodium vanadium fluorophosphates cathode material through a sol gel activated auxiliary two-step high-temperature solid phase method, and the sodium vanadium fluorophosphates cathode material has the advantages of good stability, uniform particle size and good electrochemical performance. Meanwhile, the method has the advantages of simple synthesis process, short period and low cost and is convenient for large-scale production.

The invention provides a medical anti-sticking membrane and a preparation method thereof. The anti-sticking membrane comprises a nanometer frame and hydrosol attached thereon. The hydrosol is internally packed with one or several kinds of styptic medicament or/and anti-sticking medicament. The invention also provides a preparation method of the anti-sticking membrane, comprising the following steps of: preparing electro-spinning solution, styptic medicament and/or anti-sticking medicament-containing hydrosol solution and crosslinker solution; receiving static spinning with the crosslinker solution to obtain the nanometer frame; printing the styptic medicament and/or anti-sticking medicament-containing hydrosol solution onto the nanometer frame by an ink-jet printer, and solidifying the hydrosol solution to obtain the anti-sticking membrane. The anti-sticking membrane has good capability and biological compatibility, and nontoxicity as well as nonirritant, can be completely degraded and absorbed, is compounded with controllably released styptic medicament or/and anti-sticking medicament, has controllable degrading time and speed, and conquers defects of the prior art.

The present invention discloses one kind of nanometer monodispersive silica sol prepared with metal silicon powder and through reaction with water under the catalysis of certain amount of alkali catalyst at temperature of 50-95 deg.c. During the preparation, alkali solution adding speed is so controlled that the newly produced silicon sol precursor concentration is in the new nucleus forming concentration. Compared with available silica sol preparing process, the present invention has the advantages of homogeneous size distribution of nanometer silica sol, capacity of designing the sol size, simple preparation process, low cost and easy precise control.

The invention provides a nanometer bionic wound-surface cover and a preparation method thereof. The nanometer bionic wound-surface cover comprises a nanometer bionic bracket and hydrosol attached to the bracket, wherein the hydrosol covers one or a plurality of cytokines. The preparation method for the nanometer bionic wound-surface cover provided by the invention comprises the steps of preparingan electrostatic-spinning solution, a cytokine-containing hydrosol solution and a crosslinker solution, preparing the nanometer bionic bracket by use of electrostatic spinning, using an ink-jet printer to print the cytokine-containing hydrosol solution onto the nanometer bionic bracket, and the like, wherein electrostatic spinning and printing can be repeated so as to form the wound-surface covers different in thickness. The preparation method adopts an in-situ autologous stem-cell engineering technique and adopts stem-cell chemotactic factors to attract autologous stem cells to directionally migrate, enter a wound surface and be differentiated according to designed requirements, thereby avoiding inconvenience caused by using viable cells, achieving rehabilitation effects the same with orbetter than that of using the viable cells and having broad application prospects.

A method for preparing a porous metal film transparent conducting electrode based on a cracking template method comprises the following steps: (1) synthesizing cracking liquid: taking tetrabutyl titanate as a raw material to synthesize microcrystalline titanium dioxide collosol, and obtaining the cracking liquid, (2) fabricating a cracking template: uniformly depositing a cracking film on a substrate with the cracking liquid by a spin-coating method or a lifting method, controlling a temperature condition to allow the cracking film to be cracked naturally to form the cracking template, (3) depositing a metal film: depositing the dense metal film on the cracking template by a magnetron sputtering manner, and (4) removing the cracking template: removing the cracking template from the substrate, cleaning the surface, and forming the porous metal film transparent electrode on the substrate. The transparent conducting electrode prepared with the method has excellent photoelectric properties and higher mechanical and environmental stability; a preparation technology is simple; the resource consumption is low; the transparent conducting electrode is a favorable replacer of the traditional metal oxide electrode; the efficiency of a solar cell can be improved; and the cost can be lowered.

The present invention belongs to the field of inorganic metal oxide, and is especially process of preparing nanometer titania/silica photocatalyst sol and transparent photocatalyzing film. The anatase type nanometer titania/silica photocatalyst sol is prepared with inorganic low concentration titanium compound solution as material at normal pressure and 40-100 deg.c. The sol has high hydrophilicity, high photocatalyzing activity, high transparency and particle size of 15-30 nm. The sol may be painted onto substrate of different properties to form self-cleaning transparent photocatalyzing film with high hardness and high antifouling and antiseptic performance. The sol has high stability, small and homogeneous size and high performance; and the preparation process has low cost and simple operation and is suitable for large scale production and application.

The invention discloses Lyophobic and oleophylic micro nano-coatings applied to oil filtering dehydration and a preparation method thereof. Base material of the coatings is metal mesh grid with 50-1800 meshes, the surface of the metal mesh grid is coated with a layer of dense micro nano-coating which is dense thin film composed of nano silica global particles with partical size ranging from 90nm to 500nm.In the method of the invention, the sol-gel method is adopted, tetraethyl ester serves as the precursor, ammonia water serves as the catalyst, ethanol serves as the solvent, alkyl oxosilane serves as lyophobic modifier, the method of hydrolytie polycondensation is adopted to obtain lyophobic nano silica sol, the process of impregnation or spraying is adopted to coat the gel on the metal mesh grid with 50-1800 meshes, after thermal treatment, oil-water separation net with lyophobic and oleophylic properties is obtained. The method of the invention features simple process, no harm to the environment, no need of fluorine material, wide application to coalescing separator as a separation filter element and the function of filtration and dehydration of oil.

The invention provides artificial articular cartilage based on autologous cells and a preparation method thereof. The artificial articular cartilage comprises a nano bionic support and hydrosol adhered to the nano bionic support, wherein one or more cytokines are coated into the hydrosol. The invention also provides the method for preparing the artificial articular cartilage, which comprises the following steps: preparing an electrostatic spinning solution, a cytokine-containing hydrosol solution and a crosslinking agent solution; using the crosslinking agent solution to receive electrostatic spinning so as to prepare the nano bionic support; and using an ink jet printer to print the cytokine-containing hydrosol solution on the nano bionic support, and curing the hydrosol to obtain the artificial articular cartilage. The three-dimensional support adopted by the invention has ideal degradation speed and is degraded after the regeneration of an articular cartilage layer, can meet the requirement of actual clinical application, can be completely degraded, and has good abrasion resistance and lubricity so as to be capable of replacing the cartilage before the regeneration of the articular cartilage layer.