249results about How to "Excellent water repellency" patented technology

The invention relates to a fluorine-free superhydrophobic finishing agent containing modified nano silicon dioxide hydrosol and application thereof. The finishing agent is prepared by the following steps of: (1) mixing a precursor, an anionic surfactant and water and stirring violently at the temperature of between 20 and 50 DEG C; and (2) slowly adding ammonia water serving as a catalyst dropwise, stirring, adding long-chain alkylsiloxane serving as a modifier and stirring continually so as to obtain modified SiO2 hydrosol. The finishing agent has a stable property, avoids the pollution of an organic solvent and has high water repellency when used for performing superhydrophobic finishing on textiles.

The present invention discloses the preparation process and application of fluorocarbon chain-containing acrylate and its copolymer. The preparation process of the fluorocarbon chain-containing acrylate includes the steps of: 1. synthesizing Rf(CH2CF2)mix; 2. synthesizing fluoric alcohol Rf-(CH2CF2)m(CH2)nOH; and 3. synthesizing fluorocarbon chain-containing acrylate. The present invention is used in surface water-repellent and oil-repellent treatment of fabric, metal, paper, glass, plastic, rubber, ceramic, etc. The present invention is one kind of high performance green water-repellent and oil-repellent agent with excellent water-repellent, oil-repellent and antifouling functions and degradability.

The invention relates to a fluorine-free nano durable super hydrophobicity finishing method for cellulose fabric, which comprises the following steps: (1) preparing hydrous medium solution containing tetra-alkyl ester silicate, polycarboxylic acid and a crosslinked catalyst, oscillating and stirring the hydrous medium solution to obtain SiO2 sol, soaking and rolling the cellulose fabric twice respectively, and curing the cellulose fabric; and (2) preparing non-aqueous solvent solution of alkyl siloxane catalyzed and hydrolyzed by using inorganic acid or organic acid water solution, soaking the cellulose fabric in the solution, and curing the cellulose fabric. The method is simple and safe, has low performance requirement on equipment, is easy for industrialization, and is particularly applicable to the hydrophobicity finishing of the cellulose fabric.

The invention relates to a water-repellent, oil-repellent, sun-proof, anti-bend torsion and cold-resistant matt-leather-membrane aqueous coating adhesive for textiles and a preparation method of the matt-leather-membrane aqueous coating adhesive. The preparation method comprises the steps of emulsifying isooctyl acrylate, isobornyl methacrylate, glycidyl methacrylate, trifluoroethyl methacrylate, vinyl trimethoxysilane, hydroxypropyl acrylate, fatty alcohol ethoxylate XL90 and dodecyl benzene sulfonate to trigger polymerization, and compounding a thickening agent, namely an associated polyurethane flatting rheological agent, a cross-linking agent, namely terminated isocyanate, a flatting agent, namely polymethyl urea resin and silicon dioxide with the particle size of 2-7 microns, so as to obtain the matt-leather-membrane aqueous coating adhesive.

The invention relates to a fluorine-silicon modified waterborne alkyd resin and a preparing method thereof. The fluorine-silicon modified waterborne alkyd resin is prepared from vegetable oil fatty acid, organic acid anhydride, polyol, fluorinated allyl monomers, isocyanate, hydroxyl-terminated organic silicon, acrylic monomers and deionized water. Single-component waterborne paint, double-component waterborne paint and room-temperature curing paint can be blended with the fluorine-silicon modified waterborne alkyd resin prepared through the method. The prepared fluorine-silicon modified waterborne alkyd resin has the performance such as high adhesion, stain resistance, high hardness, water resistance, durability, hydrophobicity and self-cleaning performance, and can be widely applied to waterborne wood paint, waterborne industrial paint, waterborne anti-fouling paint, waterborne corrosion resistance paint, waterborne special engineering paint such as radar dome materials, wind power generation, nuclear power and vessel paint and the like.

The invention relates to a method for preparing nylon-PEDOT (poly(3,4-ethylenedioxythiophene)) compound conductive fabric through in-situ polymerization. The method comprises the following steps of: 1) pretreating a nylon fabric by using acidic solution, and padding the nylon fabric for times, wherein the dipping time is 5-15 minutes and the padding residual rate is 60-90 percent; and 2) dipping the nylon fabric in mixed solution containing ferric chloride, sodium polystyrenesulfonate and 3, 4-ethylenedioxythiophene (EDOT), keeping reaction temperature to be 30-90DEG C, keeping reaction time to be 1-20h, and after reaction is ended, taking out, washing and drying the fabric to obtain the nylon-PEDOT compound conductive fabric. By adopting the method, in combination with a padding technology which is commonly used for dyeing and finishing, the PEDOT can be enabled to rapidly enter the internal part of nylon fibers, the reaction time is shortened and the environmental pollution is small; and the nylon-PEDOT compound conductive fabric can be applied to the fields of textile chemical sensing and biological remediation materials, electromagnetic shielding materials and the like.

Disclosed is a liquid chemical for forming a water repellent protective film on a wafer that has at its surface a finely uneven pattern and contains silicon element at least at a part of the uneven pattern, the water repellent protective film being formed at least on surfaces of recessed portions of the uneven pattern at the time of cleaning the wafer. The liquid chemical contains: a silicon compound (A) represented by the general formula R¹_aSi(H)_b(X)_4−a−b and an acid; or a silicon compound (C) represented by the general formula R⁷_gSi(H)_h(CH₃)_w(Z)_{4−g−h−w} and a base that contains no more than 35 mass % of water. The total amount of water in the liquid chemical is no greater than 1000 mass ppm relative to the total amount of the liquid chemical. The liquid chemical can improve a cleaning step that easily induces pattern collapse.

The invention relates to a surface antifouling corrosion-resistant protectant for glass fiber reinforced plastic and other polymer products. The surface antifouling corrosion resistant protectant for glass fiber reinforced plastic and other polymer products, which is provided by the invention, is composed of fluoro-alkyl silane, long-chain alkyl silane, nanometer SiO2, alkyl silicate, alcohol, inorganic acid catalysts and de-ionized water or distilled water. The surface antifouling corrosion resistant protectant for glass fiber reinforced plastic and other polymer products, which is provided by the invention, can form a layer of low surface water-repellent, oil-proof, antifouling, anti-sticking, anti-ultraviolet and corrosion-resistant coat film on the surfaces of the glass fiber reinforced plastic and the other polymer products, the water contact angle can reach as high as 149 DEG, the purposes of effective reduction of rain accumulation as well as the attachment of atmospheric dust, guano, etc. on the surfaces of the glass fiber reinforced plastic and the other polymer products, acid rain corrosion damage resistance, salt mist corrosion damage resistance, ultraviolet corrosion damage resistance and reduction of use and maintenance cost are achieved.

The invention discloses a photo-curing-based water and oil repellent finishing method for a fabric, belonging to the technical field of fabric finishing, and aiming to overcome the shortcomings of high baking temperature, high production energy consumption and low processing efficiency in conventional after-finishing and achieve the water and oil repellent functional finishing of the fabric under a photo-curing condition. A process specifically comprises the following steps of (1) synthesizing a fluorine-containing urethane acrylate prepolymer, namely carrying out reaction on isocyanate and hydroxyethyl acrylate and carrying out reaction on a reaction product and a fluorine-containing polyether type diol long chain to obtain the prepolymer, or carrying out reaction on isocyanate and fluorine-containing polyether type diol and then adding the hydroxyethyl acrylate into a system; and (2) preparing a photo-curable resin system from the prepolymer, a reactive diluent, a photoinitiator, a solvent and the like, coating and rolling-compacting the photo-curable resin system on the surface of the fabric, and irradiating the fabric for a certain time by using ultraviolet light to finish curing of a resin with water and oil repellent effects on the surface of the fabric. According to the method, the water and oil repellent performance of the finished fabric is improved, and the strength of the fabric is slightly weakened; compared with a conventional thermal-baking-based chemical finishing method, the photo-curing-based water and oil repellent finishing method for the fabric has the advantages that the process flow is short, the energy consumption is low and the efficiency is high.

The invention discloses a textile subjected to water repellency treatment and a production method for the textile. The textile mainly comprises cationic dye-dyeable modified polyester fibers and/or nylon fibers; the single fiber surface of the textile is at least covered with a resin film formed by water-repellent C6 fluororesin and water-repellent non-fluororesin; the surfaces of the cationic dye-dyeable modified polyester fibers and/or nylon fibers have anionic groups. The textile has durable washability and high water repellency.

A fluorine-containing polymer comprising repeating units derived from: (A) a fluorine-containing monomer represented by the general formula: CH2=C(-X)-C(=O)-Y-Z-Rf wherein X is a hydrogen atom, a monovalent organic group or a halogen atom, Y is -O- or -NH-; Z is a direct bond or a divalent organic group; Rf is a fluoroalkyl group having 1 to 20 carbon atoms; and (B) a (meth)acrylate monomer having a cyclic hydrocarbon group provides a water- and oil-repellent agent which imparts excellent water repellency, oil repellency and stain-proofing properties to a substrate.

The invention discloses a polyurethane-compounded cement-based expanded-perlite heat preservation plate and a preparing method thereof. The polyurethane composite cement-based expanded-perlite heat preservation plate is prepared from 50-100 parts of expanded perlite, 40-90 parts of cement, 5-10 parts of two-component polyurethane adhesive, 0.1-0.5 part of coupling agent, 0.1-0.25 part of fiber, 0.1-0.5 part of reusable dispersion emulsion powder, 40-90 parts of water, 0.5-2 parts of early strength agent and 0.1-0.5 part of water reducing agent. According to the polyurethane-compounded cement-based expanded-perlite heat preservation plate and the preparing method thereof, cement mortar is modified through polyurethane, polyurethane resin and the cement are evenly dispersed into the expanded perlite, hydration of the cement and solidification of polyurethane are carried out at the same time, and the mutually-filled whole structure is formed; the expanded perlite and the polyurethane cement-based composite are combined, and the polyurethane composite cement-based expanded-perlite heat preservation plate is prepared in a compression-molding mode; the defects of the expanded perlite are effectively overcome, and meanwhile the advantages and the like of the water resistance and heat preservation performance of the polyurethane material, the low heat conductivity of the expanded perlite, the high weather resistance of concrete and the liker are used.

The invention provides a paint latex composition, a water-resistance/oil-resistance paper sheet and a production method thereof. An organic polysiloxane comprising at least two silicon-bonded hydroxyl groups, the reaction product of an amino-containing organoalkoxysilanea dicarboxylic anhydride and an dicarboxylic acid ahhydride, an organic polysiloxane containing long-chain alkyl and alkoxy groups, but free of hydroxyl groups are emulsified and dispersed in water in the presence of a surfactant to form a coating emulsion composition.

The invention discloses a preparation and application method for a polyurethane modified acrylate water repellent, and belongs to the technical field of macromolecules. According to the preparation and application method, an emulsion polymerization technology is adopted, diisocyanate, polymer dihydric alcohol and a hydrophilic chain extender are subjected to pre-polymerization and chain extension,an end-capping reagent is added for end-capping, then neutralization is carried out, water is added for emulsification, in the absence of an emulsifier, a product and an aliphatic acrylate monomer are subjected to copolymerization so as to prepare an anionic polyurethane modified acrylate composite emulsion, and the anionic polyurethane modified acrylate composite emulsion is used for textile finishing. The preparation and application method has the advantages that a long alkane chain endows fabric with the water repellent property, after the fabric is treated, a layer of water repellent filmis formed on the surface of the fabric, so that the water repellent capacity of the fabric is greatly improved, and polyurethane is added, the fabric can be endowed with the soft and full hand feeling; and in addition, the VOC emission amount is extremely low, and the method is suitable for environmental protection requirements.

The invention discloses an anti-raise specialistic floor and a production method thereof. The floor comprises a substrate (1), wherein a finish paint layer (2), a resin layer (3) and a primer layer (4) are sequentially laid above the substrate (1) from top to bottom; a back paint layer (5) is laid below the substrate (1); wood fiber conduits (6) of the substrate (1) are filled with resin (7); the substrate (1) is provided with a tongue-and-groove (8); and the surface of the tongue-and-groove (8) is laid with a wax layer (9). In the production process of the floor, a finished product is obtained through the production steps of: hacking, sanding, back paint coating, resin permeating, primer coating, resin retouching, finish paint coating, tongue-and-groove wax sealing, and the like. The product has excellent characteristics of preventing expansion, contraction and raising. The wood fiber conduits of various surfaces are effectively sealed, which can effectively prevent water from entering and draining to ensure that the floor per se has relatively stable internal environment so as to prevent the solid wood floor from raising, deforming and cracking.

The invention specifically relates to water-based lotus-leaf-structured hydrophobic over-printing varnish for wallpaper and a preparation method of the over-printing varnish, and belongs to the technical field of ink. The technical problem to be solved is to provide an over-printing varnish by using which the surface of a wallpaper product can be smooth, bright and wear-proof and the lotus leaf type waterproof and moisture-roof effects can be realized, and a preparation method of the over-printing varnish. In order to solving the technical problem, the technical scheme adopted is as follows: the water-based lotus-leaf-structured hydrophobic over-printing varnish for the wallpaper is prepared from raw materials including a modified organic silicon polymer emulsion, a non-film-forming acrylate emulsion, an styrene-acrylic emulsion, neutralizing amine, propylene glycol, a water-based coalescing agent, a water-based leveling wetting agent, a mineral defoamer, a water-based nanoscale organosilicon waterproofing agent, a waterborne polyurethane thickening agent, deionized water and an organic silicon defoamer; the raw materials are stirred and mixed in a specific order to form the over-printing varnish.

The invention relates to a preparation method of a perfluoro-short-carbon-chain-containing water-repellent oil-repellent finishing agent, which comprises the following steps: preparing N-propylperfluorohexylsulfamidoethylacrylate; dissolving fluorine-containing acrylic acid monomer, octadecyl acrylate and propylene-2-hydroxyethyl ester in a solvent to obtain a monomer mixed solution, adding half of emulsifier into the monomer mixed solution to carry out pre-emulsification, thereby obtaining a pre-emulsification monomer; carrying out pre-emulsification on water and the rest half of emulsifier, heating to 65-90 DEG C, adding half of initiator solution, adding half of pre-emulsification monomer after 4-5 minutes to react, adding the rest half of pre-emulsification monomer while slowly adding the rest of initiator, continuing the reaction for 4-8 hours after dropwise addition is finished, cooling to room temperature after the reaction is finished, and filtering to obtain the finishing agent. The finishing agent has high stability, and is free of restricted components which are harmful to the human body and environment; and the finished fabric has favorable water repellency, oil repellency and anti-fouling property.

The invention provides fluoride-free and water-repellent fabric and a fluoride-free and water-repellent finishing method of the fabric and belongs to the technical field of after-finishing of textile products. The method comprises steps as follows: a sol solution A is prepared with a conventional method; graphene oxide with a single-layer structure is dispersed in water, and a solution B with the concentration of 0.1%-0.5% in percentage by mass is prepared; the solution B and the solution A in a volume ratio or a mass ratio being 1:10 are mixed, and a composite finishing solution is obtained; basic fabric is placed in the finishing solution C and is processed for 10-1000 min at the temperature in a range from room temperature to 90 DEG C, unnecessary solution is removed through rolling, and then the basic fabric is subjected to reduction treatment, washed with deionized water and prebaked for 3-30 min at the temperature of 50-90 DEG C; the basic fabric is post-baked for 10-100 min at the temperature of 95-130 DEG C. Based on the technological steps of the invention, the fluoride-free and water-repellent fabric with a surface contact angle being 110-152 degrees can be obtained.

The invention discloses a preparation method for a non-woven fabric for a protective garment. The preparation method comprises: cleaning and drying a polypropylene composite non-woven fabric, carryingout plasma treatment, placing the non-woven fabric in air to obtain a material A, uniformly mixing 10-hydroxy-cyclohexyl-phenyl ketone, a fluorine-containing acrylic resin, octadecyl methacrylate, glycidyl acrylate, borneol acrylate, fatty alcohol polyoxyethylene ether, ethylene glycol dimethacrylate and water to obtain a material B, adding the material A into the material B, carrying out ultraviolet light irradiation for a grafting reaction, carrying out washing and drying to obtain a material C, uniformly mixing p-aminobenzotrifluoride, n-octylamine, alkylaminoglucitol, 4-amino-1, 2, 4-triazole and dioxane, adding the material C into the mixture, carrying out a reaction process, carrying out washing and drying to obtain a material D, adding graphene oxide into water, adjusting pH to greater than 7, carrying out ultrasonic treatment, adding glucose into the reaction product for a reaction, mixing the product, hydroxylamine hydrochloride, allicin, a zinc complex, lentinan and a silk fibroin, adding the material D into the mixture, and carrying out padding and drying.

The invention discloses a production method of waterproof organosilicon modified solvent-free polyurethane synthetic leather. The production method comprises the following steps: firstly, adding a component A containing hydroxyl and a component B containing an isocyanate group into a reaction still, and reacting by stirring to obtain foaming slurry; secondly, adopting a dry process production line of the synthetic leather, blade coating the foaming slurry on release paper to form a coating, and then laminating the coating with a base fabric by a gap fitting mode through a laminating machine; thirdly, feeding a mixture into a drying oven for cooking to obtain the waterproof organosilicon modified solvent-free polyurethane synthetic leather. According to the production method disclosed by the invention, the waterproof organosilicon modified solvent-free polyurethane synthetic leather is produced by adopting a double foaming technology, a polyurethane in-situ polymerization waterproof technology, a heat-sensitive catalyst asynchronous catalysis technology and a single-pole constant temperature heating scrape coating technology; the production technology is environmentally friendly, simple, and stable; the quality of a product is good; a contact angle of water droplets on the surface of the synthetic leather is as high as 107 degrees, and static water seepage prevention can be kept for 15 days; the waterproof organosilicon modified solvent-free polyurethane synthetic leather can be used as a high-end functional yacht seat covering material.

The invention provides energy saving fireproof paint and a preparation method thereof. The energy saving fireproof paint comprises the following components in parts by weight: 20-30 parts of a fire retardant, 7-12 parts of a carburization agent, 7-12 parts of a foaming agent, 9-15 parts of an inorganic hollow material, 10-22 parts of titanium dioxide, 31-43 parts of a cross-linking agent, 3-5 parts of an anti-aging agent, 2-5 parts of magnesium hydroxide, and 2-5 parts of diatomite. The energy saving fireproof paint has the advantages of solar heat reflection, heat insulation, water resistance, and corrosion resistance, and the advantages are identical to the advantages of energy saving paint; at the same time the energy saving fireproof paint has the advantages of self-extinguishing, flame retardation, formation of a compact heat insulating protective layer by expansion during fire hazard, and the like, and the advantages are identical to the advantages of fireproof paint.