130results about How to "Improve dispersion stability" patented technology

The invention belongs to the technical field of high-voltage electric appliance material preparation, and particularly relates to a zinc oxide resistor disc and a preparation method and application thereof. The preparation method comprises the following steps: (1) pre-sintering zinc oxide powder; (2) mixing the zinc oxide powder obtained in the step (1), an auxiliary agent and a dispersion liquid, and carrying out ball milling to obtain slurry; the particle size D50 of the slurry is 0.8-1.2 [mu] m, and the dispersity is greater than or equal to 95%; (3) performing spray drying and granulation on the slurry to obtain granulation powder; (4) carrying out molding and first sintering on the granulated powder to obtain a resistor disc semi-finished product; the first sintering adopts sectional sintering; and (5) forming an electrode layer on at least one surface of the resistor disc semi-finished product by adopting a vacuum sputtering and / or electrophoretic deposition process, and performing secondary sintering and annealing. The contact resistance of the zinc oxide resistor disc is less than or equal to 5m omega; and after 1000 hours of aging in a 85 DEG C + 85% RH environment, the leakage current increase is less than or equal to 2 [mu] A, and the performance degradation rate is less than or equal to 5%.

The present application relates to the technical field of biological medicine, and discloses inhalable aptamer modified molybdenum disulfide nanoflower compound and application thereof.The compound comprises a molybdenum disulfide nanoflower core, a dendritic polylysine modification layer attached to the surface of the molybdenum disulfide nanoflower, doxorubicin loaded on the molybdenum disulfide nanoflower and / or the dendritic polylysine modification layer, and AS1411 aptamer combined on the outer surface of the dendritic polylysine modification layer by electrostatic assembly.The compound can be delivered to a lung lesion by atomization inhalation or aerosol inhalation, and undergoes responsive structural change under the action of hydrogen peroxide in a tumor microenvironment, generates active oxygen, and promotes the release of doxorubicin, so as to realize the synergistic antitumor effect of chemotherapy and chemical dynamic therapy.The compound has good colloidal stability, drug loading capacity, active targeting ability and lung local delivery potential, and can be used for preparing inhalation preparations or local administration preparations for treating lung cancer.

This invention discloses a nanoRNA delivery system and its application in the control of Sclerotinia sclerotinia disease, relating to the field of biotechnology. The preparation method of the nanoRNA delivery system includes the following steps: mixing chitosan, sucrose, and aspartic acid uniformly and then subjecting them to a hydrothermal reaction to obtain a quantum dot-chitosan degradation product complex; mixing the quantum dot-chitosan degradation product complex with double-stranded RNA to obtain the nanoRNA delivery system; the double-stranded RNA is used to silence Sclerotinia sclerotinia virulence-related transcription factor genes. The nanoRNA delivery system provided by this invention can effectively protect RNA and exhibits a very high inhibitory effect on Sclerotinia sclerotinia in plants, providing a novel technical solution for the green and precise control of Sclerotinia sclerotinia disease.

The invention provides a coating with optical permeability and a preparation method thereof. The coating with optical permeability is prepared from the following raw materials in parts by mass: 25 parts of water-based acrylate copolymer emulsion, 25 to 35 parts of water, 0.8 to 1.5 parts of transparent functional particles, 16 to 20 parts of functional modified inorganic filler, 5.5 to 7.5 parts of boric acid ester-silanol-hydroxyl three-function cross-linked gel precursor solution, 0.2 to 0.5 part of thickening agent, 0.2 to 0.4 part of defoaming agent, 0.5 to 1 part of dispersing agent and 0.1 to 0.3 part of preservative. 0.2 to 0.5 part of an organic amine alcohol compound; the transparent functional particles comprise at least one of glass sand and cross-linked polymethyl methacrylate microspheres; the functional modified inorganic filler comprises at least one of amino silane modified snowflake white quartz sand and amino silane modified calcined sand white marble. The coating with optical permeability is suitable for the field of indoor and outdoor decoration.

The invention relates to high-solid-content AlN ceramic slurry for tape casting, a substrate and a preparation method of the substrate, and belongs to the field of ceramic substrates. The ceramic slurry is prepared from the following components in percentage by mass: 60 to 68 weight percent of high-purity AlN powder, 3 to 6 weight percent of dispersing agent, 3 to 5 weight percent of binding agent, 4 to 6 weight percent of plasticizer, 3 to 6 weight percent of sintering aid and 32 to 45 weight percent of solvent, the mass ratio of the plasticizer to the binder ranges from 3: 5 to 4: 5. By regulating and controlling the proportion of the dispersing agent in the AlN ceramic slurry and the solid content of the high-purity AlN powder, the slurry has excellent flowability, dispersity and stability while maintaining high solid content, and is suitable for a tape casting process. The AlN ceramic substrate prepared through sintering is high in density and excellent in heat conductivity, and engineering application can be achieved.

The application discloses a rice straw-based liquid mulch emulsion and a preparation method and application thereof. The preparation method comprises the following steps: adding pretreated rice straw into a sodium hydroxide solution for alkali treatment, so as to obtain rice straw fibers and a silicon-containing black liquor; washing and bleaching the rice straw fibers, so as to obtain bleached rice straw fibers; first standing the silicon-containing black liquor, then adjusting the pH value, and continuing to stand, so as to obtain a silicon-containing dispersion liquid; mixing the bleached rice straw fibers with an alkaline alcohol solution and activating, then adding chloroacetic acid for etherification reaction, so as to obtain carboxymethyl cellulose; mixing a polyvinyl alcohol solution and the carboxymethyl cellulose solution, and adding the silicon-containing dispersion liquid under stirring, and then supplementing water, so as to obtain the rice straw-based liquid mulch emulsion. The rice straw-based liquid mulch emulsion prepared by the application can be applied to the covering of cultivation soil, has the advantages of excellent film forming strength, toughness, light shielding and soil covering adaptability, and the like, and has the advantages of wide raw material sources, simple preparation process and suitability for large-scale popularization.

The invention provides a nano-composite anti-seepage coating for goaf sealing and a preparation method and application thereof. The impermeable coating comprises the following components in percentage by mass: 10 to 30 percent of nano silica sol subjected to surface organic modification, 15 to 35 percent of styrene-butadiene latex subjected to pH buffer stabilization, 0.5 to 10 percent of functional nano material subjected to surface activation treatment, 20 to 60 percent of superfine sand and the balance of short fiber, inorganic powder filler and auxiliaries. The method comprises raw material pretreatment; step-by-step gradient blending is performed; and functions are compounded. According to the application, the nano-composite anti-seepage coating is applied to surrounding rock reinforcement, crack plugging or anti-seepage sealing engineering of a coal mine goaf. The slurry has the advantages of being high in deep infiltration capacity, excellent in surface film forming and internal compatibility and stable in performance, an internal infiltration reinforcing layer and a surface sealing layer can be formed at the same time after construction, and an integrated double-layer anti-seepage network is formed.

This invention discloses a low surface energy active-passive synergistic antifouling coating and its preparation method, belonging to the field of marine antifouling materials technology. The preparation method of the antifouling coating includes the following steps: S1, mixing acetone and xylene and stirring under a nitrogen atmosphere to form a mixed solvent; S2, adding vinyl-terminated silicone resin and acrylic resin to the mixed solvent, stirring and heating to obtain a coating base liquid; S3, adding an initiator to the coating base liquid and continuously stirring and heating to react; S4, after the reaction is complete and the coating base liquid cools, adding functional fillers to form a coating liquid; S5, coating the coating liquid and drying to obtain a low surface energy active-passive synergistic antifouling coating. The low surface energy active-passive synergistic antifouling coating prepared by this invention solves the problem in existing marine antifouling technologies where the single antifouling mechanism prevents the simultaneous consideration of environmental friendliness and long-term effectiveness, and has broad application prospects in the field of marine antifouling materials technology.

This application discloses a high-coverage calcium carbonate-titanium dioxide composite pigment and its preparation method. The composite pigment includes a calcium carbonate core layer and a titanium dioxide shell layer coating the outer surface of the calcium carbonate core layer. The calcium carbonate core layer is obtained by sequentially acid-activating and modifying a calcium carbonate base layer with a hydrophilic additive. The hydrophilic additive is selected from at least one of polyhydroxy compounds, polyelectrolytes, or small molecule surfactants. The small molecule surfactant contains carboxyl or sulfonic acid groups, and its molecular weight is ≤1000. The calcium carbonate-titanium dioxide composite pigment provided by this application exhibits a strong interfacial bond between calcium carbonate and titanium dioxide, and the titanium dioxide shell layer is not easily detached, resulting in high titanium dioxide utilization and fully leveraging the high hiding power of titanium dioxide to improve the hiding power of the composite pigment. Furthermore, the strong interfacial compatibility between calcium carbonate and titanium dioxide and excellent dispersion stability in aqueous systems improve the applicability of the composite pigment in aqueous systems.

The application belongs to the technical field of polymer preparation, and particularly relates to a high-strength self-supporting polypyrrole nano array and a preparation method and application thereof. The preparation method comprises the following steps: (1) first, dispersing a hydroxypropyl-beta-cyclodextrin and polyethylene glycol aqueous solution onto an ice surface, and then adding a pyrrole monomer to form a dispersion liquid; (2) adding an acid solution containing an oxidizing agent to the dispersion liquid, and obtaining the high-strength self-supporting polypyrrole nano array after reaction. The application directly uses a macroscopic ice block as a hard template for polypyrrole preparation, and introduces a cyclic molecule hydroxypropyl-beta-cyclodextrin with hydrophilic and hydrophobic dual functions and polyethylene glycol with a linear polymer chain as an array growth aid, so that a high-strength polypyrrole nano sheet array with a self-supporting structure is prepared through a one-step polymerization method. The high-strength polypyrrole nano sheet array can be used as a conductive filler of polyurethane in the field of 3D printing technology, and greatly improves the mechanical properties and antistatic ability of products.

The invention discloses a method for synthesizing ziram. The method comprises the following steps: S1, stirring a compound surfactant and zinc oxide to obtain a dispersion liquid; s2, sealing and pressurizing, and adding dimethylamine for reaction to obtain a dimethylamine salt mixture; and S3, dropwise adding carbon disulfide, performing condensation reaction, and removing impurities to obtain the ziram, wherein the compound surfactant contains at least one of a nonionic surfactant, an anionic surfactant or a macromolecular surfactant. According to the method, the efficient and green synthesis of the ziram is realized through the synergistic effect of a compound surfactant system, a sealed pressurized reaction and a progressive charging sequence.

The invention discloses a viscosity modified material for keeping the homogeneity of self-compacting concrete, a preparation method and application. The material comprises the following components in parts by mass: fly ash, slag powder, metakaolin, cellulose ether, limestone powder, zeolite powder, an air entraining agent, a functional component A and a functional component B, wherein the functional component A is prepared by compounding and drying nano silica fume, modified carbon nanotubes subjected to ultrasonic dispersion by sodium dodecyl benzene sulfonate / absolute ethyl alcohol and tungsten disulfide subjected to activation-silanization-polycarboxylic acid modification treatment, and the functional component B is prepared by shearing and uniformly mixing magnesium oxide and a calcium expanding agent at a high speed. The material can improve the viscosity, delay segregation and bleeding and reduce the water use sensitivity under the condition that the yield stress is not obviously improved, meanwhile, the early strength development is promoted, the volume stability is improved, and the durability such as chloride ion permeation resistance is improved, so that the homogeneity and quality consistency of a component in the pouring process and after hardening are guaranteed.

This invention belongs to the field of scalp care formulation technology, and discloses a soothing, antibacterial, anti-hair loss, and hair-strengthening formulation with peptides and plant active ingredients, and its preparation method. The formulation includes a stabilized peptide-plant active ingredient pre-complex liquid, a matrix moisturizer, a scalp conditioner, a thickener, a pH adjuster, a preservative, and deionized water. The pre-complex liquid is prepared by pre-dispersion, weakly acidic pre-complexation, and stabilization treatment of licorice extract, scutellaria baicalensis extract, rosemary extract, hydrolyzed keratin peptides, plant-derived hydrolyzed peptides, glycerin, 1,3-propanediol, β-glucan, and sodium hyaluronate. In preparation, a plant active ingredient pre-dispersion liquid is first formed, then a low-molecular-weight peptide complex is added, followed by β-glucan and sodium hyaluronate for stabilization, and finally mixed with the formulation matrix and the pH is adjusted. This invention is beneficial for improving the dispersion stability, scalp and hair surface retention, and antibacterial persistence of plant active ingredients, and is suitable for soothing, antibacterial, anti-hair loss, and hair-strengthening care.

The application discloses a colloidal cerium oxide polishing liquid and a preparation method thereof, and steps are as follows: S1. Dissolving a soluble cerium salt in deionized water, and respectively dissolving a surfactant, a suspension aid and an imidazole modifier in the deionized water and stirring and clarifying, mixing all the solutions, and performing ultrasonic stirring and high-pressure homogenizer circulation treatment to prepare a modified reaction precursor; S2. Continuously stirring the precursor, adding a precipitant at a uniform speed, and stirring after aging by heating to form a colloidal cerium oxide nanosphere solution with a nanosphere appearance; S3. Centrifuging the solution, washing and freeze-drying the solid to obtain a cerium oxide powder, mixing and stirring the powder and deionized water to disperse, and preparing the colloidal cerium oxide polishing liquid. The polishing liquid has uniform particle size, stable dispersion, a high SiO2 / Si3N4 selection ratio, can reduce wafer scratches, guarantee stable polishing performance, and is suitable for the chemical mechanical polishing demand of a semiconductor wafer shallow trench isolation process.

The application discloses a drainage bag with an antibacterial functional layer and a preparation process thereof, and relates to the technical field of medical materials, and comprises the following steps: adding modified montmorillonite into N, N'-dimethylacetamide, uniformly mixing through ultrasonic, adding a polyurethane film, ultrasonic immersion for 60-120 min, drying, and obtaining a drainage bag substrate; adding polylactic acid into N, N-dimethylformamide, uniformly stirring and mixing, adding modified nano zinc oxide, uniformly mixing through ultrasonic, and then performing electrospinning to obtain an antibacterial coating fiber film; placing the antibacterial coating fiber film on the inner side surface of the drainage bag substrate, high-frequency heat sealing, assembling, and obtaining the drainage bag.

(Problem) To provide a liquid composition which is excellent in solubility of a thickening agent and dispersion stability of metal fine particles and is excellent in shape retention at the time of wiring formation. (Solution) A liquid composition according to the present invention is characterized by comprising: metal fine particles, a dispersion medium, and cellulose having an alkoxyhydroxypropyl group.

This invention relates to the field of health food technology, specifically to a method for preparing a tea oil-based paste and its beverage. This invention develops a tea oil-based paste that can be directly mixed with water. By compounding multiple components such as protein, polysaccharides, and curcumin, and using high-pressure homogenization technology to construct a stable tea oil dispersion system, it significantly improves the problems of oil separation and greasy taste in tea oil beverages. The unsaturated fatty acids and natural antioxidants abundant in tea oil in this invention optimize the nutritional structure of the beverage from both fatty acid composition and functional activity perspectives. After mixing the tea oil-based paste with water, a tea oil-based instant beverage with both nutritional value and good mixing properties can be obtained, aligning with the modern consumer market trend of healthier, more functional, and more convenient beverages.

This invention discloses a self-healing, anti-corrosion, and cooling coating and its preparation method. The preparation method includes: TiO2 surface activation treatment; in-situ construction of a mesoporous silica shell and loading of a corrosion inhibitor; surface silane modification; and coating and curing after blending the obtained filler with resin and curing agent. The coating consists of a polymer resin matrix and a multifunctional core-shell nanocomposite material uniformly dispersed therein; the composite material has a three-level structure of core-shell-interface layer: titanium dioxide as the core, mesoporous silica loaded with corrosion inhibitor as the functional shell, and a silane coupling agent as the interfacial compatibility layer. Through multi-level structural design, this invention enables a single filler to simultaneously achieve high solar reflectance, high infrared emission, and intelligent release of corrosion inhibitors. The coating combines a physical barrier, active corrosion prevention, and radiation cooling triple protection mechanism, and can be widely used for long-term protection of outdoor metal or non-metal substrates.

The application discloses a kind of water-based dispersant and preparation method thereof, belong to pigment dispersant technical field.The water-based dispersant is random copolymer obtained by radical copolymerization of maleic acid mono-aromatic ester intermediate and hydrophilic polymerizable monomer, and hydrophilic carboxyl group and hydrophobic benzyl side chain or phenylethyl side chain are distributed in the side group of its molecular main chain.The dispersant is prepared by esterification, neutralization and water phase copolymerization three-step reaction, the preparation process of the application is green and environmentally friendly, no organic solvent residue, the obtained dispersant realizes pigment anchoring through the π-π conjugation of hydrophobic side chain, and the hydrophilic carboxylate group realizes electrostatic stabilization, and the double synergistic effect significantly improves dispersibility and storage stability, especially suitable for phthalocyanine blue and other aromatic ring-containing pigments dispersion, and can be widely applied in the field of paint, ink and the like.

This invention relates to the technical field of functional finishing of nonwoven fabrics, specifically to a microcapsule preparation process and a functional finishing process for nonwoven fabrics. The microcapsule preparation process includes the following steps: dissolving bisphenol A in an aqueous sodium hydroxide solution to prepare a mixed solution; dissolving polytetrafluoroethylene emulsion and a water- and oil-repellent agent in a mixed solution of hexamethylene diisocyanate and trichloroethane; slowly and completely adding the mixed trichloroethane emulsion to the sodium hydroxide and bisphenol A mixed solution, stirring thoroughly to ensure uniform dispersion; heating the uniformly dispersed mixed solution to 45-55°C, causing hexamethylene diisocyanate and bisphenol A to undergo a condensation reaction at the particle interface, forming microcapsules with polyurethane as the wall material and a water- and oil-repellent agent as the core material. The microcapsules of this invention, used in the finishing process of nonwoven fabrics, can improve the stability of the treatment agent dispersion, while simultaneously improving the compatibility between components, the water- and oil-repellent properties of the woven fabric, and production efficiency.

The invention relates to the technical field of biomedical materials, in particular to a gadolinium oxide-based nano preparation as well as a preparation method and application thereof. The preparation method of the preparation comprises the following steps: preparing gadolinium oxide nanoparticles through a hydrothermal method and amination modification, and dissolving the gadolinium oxide nanoparticles in deionized water to obtain a contrast agent solution; dropwise adding the nano-particles into a gold source solution under stirring at a certain temperature to obtain nano-particles with core-shell structures; and finally, slowly adding the synthesized dispersant solution of the water-soluble polymer into the core-shell nanoparticle solution to obtain a gadolinium oxide-based nano preparation solution. And performing post-treatment such as dialysis, freeze drying and the like to obtain the core-shell structure nanoparticles based on the gadolinium oxide nano preparation. The invention relates to a gadolinium oxide-based nano preparation for cancer diagnosis and treatment, gadolinium oxide is used as an MRI contrast agent, and a gold shell is grown on the periphery of the gadolinium oxide as a photo-thermal preparation; the hydrogel has the characteristics of good biocompatibility and the like, and has an important practical prospect in the field of preparation of diagnosis and treatment integrated medicines.

This invention relates to the field of coating technology, and proposes an aerogel anti-condensation coating and its preparation method. An aerogel anti-condensation coating comprises the following raw materials in parts by weight: 40-60 parts of elastic silicone-acrylic emulsion, 5-7 parts of aerogel, 10-12 parts of polyurethane acrylic resin, 5-10 parts of silica, 5-10 parts of heat-insulating filler, 2-3 parts of film-forming aid, 1-1.5 parts of dispersant, 0.5-1 part of defoamer, 1-2 parts of thickener, and 30-40 parts of water; the heat-insulating filler has a core-shell structure, consisting of a core material and a shell material; the shell material comprises the following raw materials in parts by weight: 9-11 parts of melamine and 7-9 parts of formaldehyde aqueous solution; the core material comprises the following raw materials in parts by weight: 6-8 parts of white oil, 7-9 parts of hexadecane, and 5-7 parts of microcrystalline wax. This technical solution solves the problem of poor heat insulation performance in aerogel anti-condensation coatings in related technologies.

This invention relates to the field of biomedical technology, specifically to nanoparticles for treating retinal ischemia-reperfusion injury, their preparation method, pharmaceutical composition, and uses. The nanoparticles consist of a zeolite imidazole ester-8 core encapsulating baicalin and a polydopamine shell coating its surface, prepared via in-situ self-polymerization. The nanoparticles utilize the polydopamine shell to scavenge reactive oxygen species and prolong intraocular residence time, while their core responsively degrades in a weakly acidic pathological microenvironment, precisely releasing baicalin, thereby synergistically exerting antioxidant, anti-inflammatory, and anti-apoptotic effects. Experiments show that these nanoparticles can effectively reduce oxidative damage and inflammation in the model retina, significantly inhibit ganglion cell apoptosis, and restore electroretinogram function, providing a novel multi-target therapeutic strategy for retinal ischemic diseases.

This invention relates to the field of micro / nano manufacturing technology, and in particular to a high-refractive-index fluidized nanoparticle, a hybrid photoresist, a patterned coating, and methods for preparing the respective. The high-refractive-index fluidized nanoparticle comprises a core, the core being modified with a first ligand and a second ligand; the first ligand is one or more selected from methacrylic acid, 4-pentenoic acid, methacryloxypropyltrimethoxysilane, and sodium methacrylate sulfonate; the second ligand is one or more selected from piperidine, N,N-diisopropylethylamine, 1,5,7-triazabicyclo[4.4.0]decene-5-ene, tetramethylguanidine, triethylamine, and tetrahydropyrrole. This invention, through the design of ultra-small metal oxide nanoparticles and innovative organic ligands, successfully solves the technical contradiction of traditional photoresist materials in achieving high resolution, high refractive index, and low curing shrinkage.

The invention provides silver-based conductive paste for a flexible electronic device, a preparation method and application, and relates to the technical field of new materials. The preparation method comprises the following steps: carrying out surface modification treatment on original nano silver powder by adopting organic acid to obtain modified nano silver powder; preparing an organic silicon rubber carrier which is composed of an organic solvent, a silane coupling agent and an additive; the modified nano silver powder is mixed with an organic silicon rubber carrier, homogenization treatment is carried out, the silver-based conductive paste is obtained, and the silver-based conductive paste has excellent dispersity and stability. According to the preparation method, agglomeration of the nano-silver particles is effectively prevented, the conductivity and applicability of the nano-silver paste are remarkably improved, and the preparation method is suitable for multiple fields such as electronic packaging.

The invention provides graphene, a preparation method thereof and graphene slurry. The preparation method of the graphene comprises the following steps: obtaining graphite; carrying out acid treatment on the graphite to disperse the graphite in concentrated sulfuric acid to obtain a graphite dispersion liquid; carrying out oxidation treatment on graphite to enable the graphite dispersion liquid to be sequentially mixed with potassium permanganate and hydrogen peroxide for reaction, and carrying out suction filtration to obtain graphene oxide; carrying out solvation treatment on the graphene oxide, and adding the graphene oxide into a strong-polarity aprotic solvent to carry out purification modification, so as to obtain pretreated graphene oxide; and carrying out reduction operation on the pretreated graphene oxide. According to the preparation method of the graphene, the preparation of the graphene with relatively high conductivity and relatively good dispersion stability can be realized.

The present invention relates to a method for modifying the wettability of a carbon allotrope, comprising the steps of: preparing a carbon allotrope; a step for preparing a solvent capable of inducing the generation of hydrophilic radicals or hydrophobic radicals; a step for bringing the carbon allotrope into contact with the solvent; a step of supplying energy to the solvent using an energy supply source; and a step of generating a hydrophilic radical or a hydrophobic radical of the solvent by the energy supplied to the solvent, the generated radical being bonded to the end of the carbon allotrope.

The invention discloses an art glaze based on ceramic waste and a preparation method thereof, and relates to the technical field of ceramic glazes, the art glaze is prepared from the following components by weight: 30-50 parts of frit, 5-15 parts of quartz, 10-20 parts of calcite, 3-6 parts of burnt zinc, 6-10 parts of titanium dioxide, 25-35 parts of barium carbonate, 10-25 parts of modified ceramic powder, 2-4 parts of iron oxide red, and 3-6 parts of talc. According to the invention, high-valued recycling of the ceramic waste is realized, waste is turned into wealth, the production cost and environmental load are remarkably reduced, and the obtained art glaze is flat and bright in glaze surface, unsophisticated and elegant in color and lustre, warm and moist in texture like jade, and excellent in thermal shock resistance and weather resistance. According to the technology, the problems that a traditional glaze layer is prone to cracking and pinhole defects are effectively solved, double improvement of environmental protection benefits and product quality is achieved, and the technology has extremely high market popularization value.

This invention belongs to the field of fluorine-free functional ceramic coating technology, and discloses a fluorine-free ceramic non-stick coating for aluminum-based cookware and its preparation method. The coating is composed of composite ceramic powder, a food-grade fluorine-free composite sintering aid composed of cerium oxide and lanthanum oxide pretreated with sodium citrate, food-grade nano-hydroxyapatite pretreated with a silane coupling agent, nano-alumina, a sinterable inorganic precursor, and deionized water in parts by weight. The preparation method includes substrate pretreatment, modified substance pretreatment, slurry preparation, coating, and low-temperature sintering steps. This invention achieves low-temperature sintering, avoids softening of the aluminum-based substrate, reduces energy consumption, and produces a coating with high density, excellent corrosion resistance and aging resistance, no harmful components are released, good non-stick properties, and is suitable for the industrial production requirements of aluminum-based cookware. Furthermore, it is fluorine-free, meeting food safety and environmental protection requirements.

The application discloses a perfluorosulfonic acid resin coating liquid, which comprises 20-41 parts of perfluorosulfonic acid resin, 59-80 parts of high-boiling-point solvent and 0.001-1 part of anticoagulant by weight, wherein the anticoagulant is one of LiOH, NaOH, KOH, RbOH and CsOH. By introducing inorganic alkali as an anticoagulant, the sulfonic acid group (-SO3H) in the perfluorosulfonic acid resin is converted into a sulfonate form (-SO3 ‑ ) with a higher degree of ionization by reacting with the sulfonic acid group (-SO3H), thereby significantly enhancing the dissociation and dispersion stability of the perfluorosulfonic acid resin in the coating liquid, inhibiting local gelation caused by acidic agglomeration, and enabling the coating liquid to carry a higher solid content without gelation.