This invention discloses a CNT composite negative
electrode sheet for
sulfide all-
solid-state batteries and its preparation method, belonging to the field of all-
solid-state battery technology. The negative
electrode sheet includes a negative
current collector and an active modification layer loaded on its surface. The active modification layer is composed of a binder,
metal nanoparticles, a carbon conductive phase, and a CNT supporting phase. The
mass ratio of
metal nanoparticles, carbon conductive phase, and CNTs is (0.5–4):(5–7):(0.2–1), and the binder content accounts for 3 wt%–10 wt% of the
dry weight of the modification layer. The preparation method employs a two-step ball milling method: first, the
solvent and each
powder are pre-mixed and ball-milled; then, a binder
slurry is added and ball-milled a second time. The resulting
slurry is coated onto the surface of the
current collector and dried to obtain the
electrode sheet. This invention constructs a three-dimensional
network structure using CNTs, enhancing the
mechanical strength of the modification layer and inducing uniform
lithium deposition, effectively suppressing
lithium dendrite growth. This technology is simple, provides uniform dispersion, and can significantly improve the cycle stability and safety performance of
sulfide all-
solid-state batteries, making it suitable for high-energy-density
energy storage scenarios.