3750 results about "Rutile" patented technology

Provided are a capacitor of a semiconductor device using a TiO₂ dielectric layer and a method of fabricating the capacitor. The capacitor includes a Ru bottom electrode formed on a semiconductor substrate, an rutile-structures RuO₂ pretreated layer which is formed by oxidizing the Ru bottom electrode, a TiO₂ dielectric layer which has a rutile crystal structure corresponding to the rutile crystal structure of the RuO₂ pretreated layer and is doped with an impurity, and a top electrode formed on the TiO₂ dielectric layer. The method includes forming a Ru bottom electrode on a semiconductor substrate, forming a rutile-structured RuO₂ pretreated layer by oxidizing a surface of the Ru bottom electrode, forming a TiO₂ dielectric layer to have a rutile crystal structure corresponding to the rutile crystal structure of the RuO₂ pretreated layer on the a RuO₂ pretreated layer and doping the TiO₂ dielectric layer with an impurity, and forming a top electrode on the TiO₂ dielectric layer.

The invention discloses recovery process of honeycomb type selective catalytic reduction (SCR) waste catalyst. The process includes the following steps: a, preprocessing the SCR waste catalyst and leaching at the high temperature and under high pressure; b, adding hydrochloric acid into leaching liquid, adjusting pH, and removing impurities; c, adding hydrochloric acid into the leaching liquid, reacting, calcining and preparing rutile titanium dioxide; d, preparing ammonium paratungstate; e, preparing ammonium metavanadate; and f, recycling and treating waste water. Main products of ammonium paratungstate, ammonium metavanadate and rutile titanium dioxide obtained in the process are high in purity and recovery rate. By-products of silicon magnesium slags, salty mud, high-concentration sodium chloride liquid and barium sulfate dregs are high-purity harmless useful goods. The process is free of harmful secondary pollutant emission, environment-friendly and capable of circulating, has high economical and social benefit and is practicable.

The invention provides a method for preparing a titanium dioxide nano belt, belonging to the nano material technical field. The prior methods for preparing the titanium dioxide nano belt comprise the hydro-thermal method and the combination method of the sol-gel method and the hydro-thermal method. The prior electrostatic spinning method is applied to the preparation of nano fibers. The invention comprises three steps that: 1. a spinning solution is prepared; the mixture of polymethylmethacrylate and vinylpyrrolidone is used as a macromolecule template, and the mixture of chloroform and N,N-dimethylformamide is used as a solvent; 2. a titanium alkoxide/ macromolecule template compound nano belt is prepared; the electrostatic spinning method is used, and the technical parameters are as follows: the voltage is between 15 and 25kV and the curing distance is between 15 and 30cm; 3. a TiO2 nano belt is prepared; the heat treatment method is used, and the technical parameters are as follows: the rate of temperature rise is between 0.5 and 2 DEG C/min and the heat preservation time at the temperature of between 500 and 900 DEG C is between 10 and 15h; for the TiO2 nano belt prepared, the width is between 5 and 15mu m, the thickness is between 30 and 60nm and the length is more than 200mu m; the TiO2 nano belt comprises a pure phase anatase type TiO2 nano belt and a pure phase rutile type TiO2 nano belt.

The invention relates to a multifunctional high-efficiency heat-preservation heat-insulation coating material. The compositions in percentage by weight of the coating material are: 10 to 20 percent of water, 0.1 to 0.2 percent of multifunctional auxiliary agent, 0.1 to 0.2 percent of wetting agent, 0.5 to 0.8 percent of dispersing agent, 0.3 to 0.5 percent of antifoam agent, 1.5 to 3.0 percent of propylene glycol, 16 to 20 percent of rutile-type titanium pigment, 3 to 5 percent of mica powder, 6 to 8 percent of hollow glass microballoon, 3 to 5 percent of infrared powder, 3 to 4 percent of fire retardant, 35 to 40 percent of elastic acrylic acid emulsion, 3 to 5 percent of opaque polymer, 0.5 to 0.8 percent of film-forming auxiliary agent, 0.2 to 0.3 percent of bactericide and preservative and 0.3 to 0.6 percent of thickening agent. The multifunctional high-efficiency heat-preservation heat-insulation coating material is of aqueous monocomponent and does no harm to human body and the environment so as to be an environment-friendly product; meanwhile, the coating material also has excellent waterproof and fire-retardation functions, convenient and quick construction, excellent adhesion strength, outstanding crack resistance, infrequent pollution and service life as long as 15 years; moreover, during practical use, the coating material can effectively reduce solar heat accumulated in a house by approximately 8 to 15 DEG C, and can greatly reduce energy consumption.

The invention relates to heat insulating and energy saving coating used for the vehicle, and the preparation method thereof. The invention takes organic resin film forming material as the main material, the coating at least includes infrared reflection pigment, hollow ceramic micro-spheres and silicon dioxide aerogel, an organic resin film having low sunlight absorption rate is formed in the coating through the organic resin film forming material with high transparency, the visible light and the near infrared ray in the sunlight are reflected through the infrared reflection pigment, the rutile type titanium dioxide and the hollow ceramic micro-spheres, and simultaneously a compact vacuum layer and an inert gas layer are formed on the surface of a coated object through the hollow ceramic micro-spheres and the silicon dioxide aerogel, so as to effectively isolate the radiant heat of the sun, and to reduce the heat conduction of air, and finally the heat insulating and energy saving coating used for the vehicle is formed, which not only can effectively reflect the energy in the sunlight, but also can effectively isolate the radiant heat of the sun and reduce the heat conduction of air, and simultaneously has good weather resistant performance, chemicals resistant performance, mechanical property and decorative property.

The process of producing silica aerogel block adopts the materials including polysiloxane E-40 as Si source, ethanol, water and hydrofluoric acid; and includes preparing silica aerogel grain via sol-gel and surface modification process at normal pressure, mixing the grain with calcium silicate slurry, rutile type titanium dioxide powder, ceramic fiber, glass fiber and porous cement via powerful stirring, and pressing into block with aerogel content greater than 90 vol%. High strength skeleton may be embedded into the block if necessary. The present invention may be used in insulation, sound isolation and adsorption.

One of many universal requirements of dental or orthopedic implants, wherever they are used in the vital body, is that the implant system should be biologically functioning. To achieve the biological functionality, the implant should meet several requirements for compatibility. These include biological compatibility and mechanical compatibility. It has now been recognized that morphological compatibility and crystallographic compatibility should be added to these two compatibility requirements. Hence, the present invention provides a method of forming a certain type of crystalline structure of titanium oxide and controlled surface roughness to meet both morphological and crystallographic compatibilities. It has been further determined that a chemical treatment (using sodium hydroxide) alone or followed by in-air oxidation, or acid treatment (a mixed aqueous solution of hydrofluoric acid and nitric acid), followed by sodium hydroxide treatment, furthermore followed by in-air oxidation provide for advantageous surface modifications to create a complex mixture of rutile with anatase and/or brookite types of titanium oxide and provide a most favorable surface for wettability and an acceptable range of surface roughness.

A coating material capable of forming a high-quality thin film having a regulated refractive index; a coating film formed from the coating material; an antireflection coating comprising the coating film; an antireflection film to which the antireflection coating is applied; and an image display. The coating composition comprises (1) rutile-form titanium oxide having primary particle diameter of 0.01 to 0.1 mum and coated with an inorganic compound for reducing or eliminating the photocatalytic activity and with an organic compound having an anionic polar group and/or an organometallic compound, (2) a binder ingredient curable with an ionizing radiation, (3) a dispersant having an anionic polar group, and (4) an organic solvent. The coating film formed from the coating composition is suitable for forming a light-transmitting layer constituting or contained in a single- or multi-layer antireflection coating (17), in particular, a medium-refractive-index layer (18), high-refractive-index layer (19), or hard coat layer (16) having a high refractive index.

The invention provides a photocatalytic air fresh coating and a preparation method thereof, and belongs to the field of indoor coating material, in particular to a coating for purifying air through a photocatalytic material and an anion generating material. The coating comprises the following raw materials in weight portion: 20 to 32 portions of deionized water, 1 to 2.0 portions of antifreeze agent, 0.1 to 0.2 portion of wetting agent, 0.5 to 0.6 portion of dispersing agent, 0.2 portion of preservative, 0.1 to 0.2 portion of pH regulator, 1 portion of nano titanium dioxide, 2 to 2.5 portions of the anion generating material, 20 to 25 portions of rutile titanium dioxide powder, 2 to 2.5 portions of diatomite, 12 to 15 portions of coarse whiting, 1 to 2 portions of film forming auxiliary, 25 to 45 portions of acrylic acid latex and 1 to 2 portions of thickening agent. The coating can keep the indoor air fresh for a long time and reach the first class indoor air environment standard of the nation. The anion releasing quantity of the coating reaches 2,626/cm<3> and the antibacterium and bacteriostasis ratio of the coating reaches more than 97 percent.

A method for producing fine particles of metal oxide characterized in that metal halide is hydrolyzed in the presence of organic solvent. According to this invention, under hydrolysis of titanium tetrachrolide, anatase type titanium oxide can be obtained by selecting hydrophilic organic solvent, and rutile type titanium oxide can be obtained by selecting hydrophobic organic solvent.

Nanomaterials of the JT phase of the titanium oxide TiO_2-x, where 0≦x≦1 having as a building block a crystalline structure with an orthorhombic symmetry and described by at least one of the space groups 59 Pmmn, 63 Amma, 71 Immm or 63 Bmmb. These nanomaterials are in the form of nanofibers, nanowires, nanorods, nanoscrolls and/or nanotubes. The nanomaterials are obtained from a hydrogen titanate and/or a mixed sodium and hydrogen titanate precursor compound that is isostructural to the JT crystalline structure. The titanates are the hydrogenated, the protonated, the hydrated and/or the alkalinized phases of the JT crystalline phase that are obtained from titanium compounds such as titanium oxide with an anatase crystalline structure, amorphous titanium oxide, and titanium oxide with a rutile crystalline structure, and/or directly from the rutile mineral and/or from ilmenite. The titanates are submitted to dynamic thermal treatment in an inert, oxidizing or reducing atmosphere to produce the JT phase of the TiO_2-x, where 0≦x≦1 with an orthorhombic structure.

The invention relates to a method for preparing rutile-phase vanadium dioxide powder, in particular to a method for preparing rutile-phase vanadium dioxide powder through a hydrothermal method. The method for preparing rutile-phase vanadium dioxide powder adopts the conditions of different vanadium materials, dopants and doping ratios, and the like, to obtain rutile-phase vanadium dioxide powders with good crystallization performance and in shapes of grains, nanometer rods and snowflake-shaped grains. The temperature for transforming the powder from semiconductor phase to conductor phase can be reduced approximately to the room temperature.

A general-use white color reflecting material, and a process for production thereof are provided. The white color reflecting material, without troublesome surface treatment such as formation of a reflective layer by plating, is capable of reflecting a near-ultraviolet ray of a wavelength region of 380 nm or longer or a near-infrared ray sufficiently without light leakage; does not become yellow even when exposed to near-ultraviolet rays; has excellent lightfastness, heat resistance, and weatherability; has high mechanical strength and chemical stability; is capable of maintaining a high degree of whiteness; and is easily moldable at a low cost. Further a white color reflecting material used as an ink composition for producing the white color reflecting material in a film shape is also provided. The white color reflecting material comprises; a silicone resin or silicone rubber formed from titanium oxide-containing silicone composition, in which anatase-type or rutile-type titanium oxide particles are dispersed.

The invention relates to a nickel-based welding electrode which comprises the following component by weight percent (wt%): 50.0-68.0% of Ni, 18.0-23.0% of Cr, 6.0-11.0% of Mo, 3.0-6.0% of Nb, 2.50-9.00% of Fe, 0.01-0.1% of C, 0.10-1.00% of Mn, 0.010-0.10% of Si, 0.015% of S or less, 0.015% of P or less, 0.01-0.10% of Cu, 0.003-0.010% of Co and the balance of impurities. The coat of the nickel-based welding electrode comprises the following components by weight percent of the welding core: 12-18% of marble, 10-15% of fluorite, 12-18% of barium carbonate, 5.0-6.4% of rutile, 3.5-5.0% of ferroniobium, 3.3-4.5 of chromium metal powder, 0.45-0.65% of sodium carbonate, 0.45-0.65% of electrolytic manganese and 1.3-1.8% of zircon sand, and the adhesion agent is 10-20% of the total weight of the power. The nickel-based welding electrode is prepared by mixing, wrapping mixture on the welding core and baking at low and high temperature. The nickel-based welding electrode disclosed by the invention is used for nickel-chromium-molybdenum alloy steel welding, ensures that the excellent mechanical properties, the excellent corrosion resistance, the excellent thermal crack resistance and the hightensile strength of the welding seam match with those of the base material, has good welding process performance, guarantees attractive molding and can be used for the welding of the steel (with 9% of Ni) working at low temperature.

The invention provides a nano-modified highly stain-resistant elastic paint and a preparation method thereof, belonging to the technical field of building paint preparation. The composition and mass percent of the elastic coating provided by the present invention are: emulsion 40-50; water-based nano-colloidal silicon; 2-5; ultrafine aluminum carbonate; 15-25; modified nano-calcium carbonate 5-10; rutile titanium White powder; 8~15; pH regulator; 0.30~35; film-forming aid 0.50~0.65; elastic defoamer; 0.35~0.40; wetting agent 0.20~0.30; ; Leveling agent; 0.30~0.45; Bactericidal preservative; 0.10~0.15; Thickener; 0.10~0.20; Water; Balance. The nano-modified highly stain-resistant elastic paint provided by the present invention well achieves a balance among elasticity, stain resistance, water resistance, adhesion and practicability.

A photoelectrocatalytic oxidizing device having a photoanode being constructed from a conducting metal such as Ti as the support electrode. Alternatively, the photoanode is a composite electrode comprising a conducting metal such as Ti as the support electrode coated with a thin film of sintered nanoporous TiO₂. The device is useful in methods for treating an aqueous solution such as groundwater, wastewater, drinking water, ballast water, aquarium water, and aquaculture water to reduce amounts of a contaminant. The method being directed at reducing the amount and concentration of contaminants in an aqueous solution comprising providing an aqueous solution comprising at least one contaminant, and, photoelectrocatalytically oxidizing the contaminant, wherein the contaminant is oxidized by a free radical produced by a photoanode constructed from an anatase polymorph of Ti, a rutile polymorph of Ti, or a nanoporous film of TiO₂.

The present invention involves increasing the quantum efficiency in titania photocatalysts for photocatalytic (oxidation of acetaldehyde) and photosynthetic (photosplitting of water) reactions by integrating the titania photocatalyst with a polar mineral having surface electrical fields due to pyroelectric and piezoelectric effects, and by adjusting the nanostructure of the photocatalyst materials. The photocatalytic reactivity of titania powder is increased due to the effect of electric field present on the surface of polar mineral material on the photocatalytic effect of commercial titania with respect to photolysis of water. Additionally, the photocatalytic performance of pure phase rutile and anatase nanostructures with well defined morphologies was found to improved with respect to certain photocatalytic reactions in comparison with non-structured titania.