The invention discloses preparation and application of an anionic
covalent organic framework film material, and belongs to the field of preparation of environment-friendly separation materials. Comprising the following steps: 1, soaking an AAO support body in deionized water for 1 hour at
room temperature; 2, taking out the soaked AAO support body, and airing; 3, accurately weighing two construction monomers, namely 2, 5-diaminobenzene
sulfonic acid and 2, 4, 6-trihydroxy-1, 3, 5-benzenetricarboxaldehyde, adding a mixed
solvent, namely
dimethyl sulfoxide and N-methyl pyrrolidone, and carrying out ultrasonic treatment for 15 minutes, so that the two
monomer powders are completely dissolved to form a homogeneous solution; 4, placing an AAO substrate at the bottom of the reaction solution, and carrying out a
hydrothermal reaction; 5,
fishing out the AAO substrate to obtain a COF film with complete morphology; 6,
acetone and absolute ethyl
alcohol are sequentially used for washing, standing is conducted at the
room temperature, and the TpPa-SO3H / AAO nano-
porous membrane is obtained. The thin
film material provided by the invention has high
crystallinity and good stability, and shows efficient
metal ion selectivity, and the
separation factor of Li < + > / Mg < 2 + > is as high as 15 in a two-component mixed
system of LiCl and MgCl2.