13134 results about "Polymerization" patented technology

The invention relates to the field of preparation of novel compounds, and discloses a glycoside group-containing compound as well as a preparation method and application thereof. The glycoside group-containing compound has a structure as shown in a formula (1). The polymer obtained by polymerizing the compound can improve the water-drive recovery efficiency of conventional oil reservoirs and common heavy oil reservoirs. # imgabs0 #

The invention relates to the technical field of functional materials, in particular to a hollow multi-shell material as well as a low-temperature preparation method and application thereof, which comprises the following steps: 1) mixing a water or alcohol solution of a precursor A with an oil phase to prepare a water-in-oil emulsion, or dispersing the water solution of the precursor A into liquid drops by a spraying method; 2) freezing the emulsion or liquid drops obtained in the step 1) at low temperature to obtain ice template particles containing a precursor A; (3) adding the ice template particles obtained in the step (2) into a precursor B solution, controlling the temperature by a program, melting the ice template, and carrying out precipitation or polymerization reaction on A and B to obtain metal fluoride, carbonate or other hollow multi-shell materials; and 4) using the hollow multi-shell layer obtained in the step 3) as an electrolyte additive. The electrolyte additive can improve the viscosity of an electrolyte, improve the ionic conductivity, stabilize a solid electrolyte interface film, effectively inhibit the growth of lithium dendrites, improve the coulombic efficiency of a battery and prolong the cycle life of the battery.

The invention belongs to the technical field of aerogel materials, and particularly relates to high-performance antistatic aerogel for 3D printing as well as a preparation method and application thereof. According to the invention, inorganic hollow nanoparticles are selected as a nucleating modifier for in-situ polymerization of aniline monomers in a polyamide solution, so that polyaniline-coated inorganic hollow nanoparticles are uniformly dispersed in polyamide, and the aerogel composite material with polyamide as a continuous phase and polyaniline-coated inorganic hollow nanoparticles as a conductive and reinforced phase is formed. The use of the hollow inorganic nanoparticles avoids the problem that the solid inorganic nanoparticles lose the characteristics of the inorganic nanoparticles due to high specific gravity and high surface energy, and easy agglomeration or adsorption with other substances in the preparation process of the solid inorganic nanoparticles. The inorganic hollow nanoparticles are adopted as a nucleating modifier, so that the problems of agglomeration of solid nanoparticles and dispersion in a polyamide matrix are well solved.

The invention discloses high-toughness ultra-high performance concrete and a preparation method thereof, and relates to the technical field of polymer modified materials thereof. The concrete is composed of a cementitious material composite system, a fiber-reinforced system and a polymer modifier, the cementitious material comprises Portland cement, nano-silica, a rice hull ash-based auxiliary cementitious material and gradient grading quartz powder, and the fiber system adopts steel fiber / basalt fiber / polypropylene fiber multi-scale composite reinforcement. And a polyurethane emulsion interface modifier is matched. During preparation, a dry mixing-fiber dispersion-wet mixing three-stage process is combined with a microfluidization emulsification and segmented polymerization technology, so that uniform dispersion of fibers and matrix-fiber interface reinforcement are realized. The scheme has high strength, high toughness and industrial feasibility, and is suitable for harsh engineering scenes such as bridge joints and explosion-proof structures.

A production method for an aqueous dispersion according to the present invention comprises polymerizing a first monomer that includes tetrafluoroethylene in the presence of a compound represented by formula (X) and a polymerization initiator under conditions in which an aqueous medium is present but an emulsifier that includes fluorine atoms is substantially absent to produce an aqueous dispersion that includes particles of a first fluorine-containing polymer that has an average particle diameter of no more than 500 nm and does not have a melting point.　Formula (X): C(X1)(X2)=C(X3)-L-Z. In formula (X), X1, X2, and X3 are each independently a hydrogen atom, a fluorine atom, a perfluoromethyl group, or an alkyl group, L is a single bond or a divalent linking group, and Z is an anionic group or a salt of an anionic group.

The invention provides a method for enhancing interface bonding and corrosion resistance of a basalt fiber composite material, and belongs to the field of fiber surface modification chemical methods. The method is realized through the following steps: firstly, treating basalt fibers by utilizing an organic solvent through high-temperature reflux to prepare desized basalt fibers; then, the desized basalt fibers are immersed in a dopamine solution to be subjected to auto-polymerization, and basalt fibers with a polydopamine coating are prepared; sequentially immersing the basalt fiber coated with the polydopamine into a zinc salt solution and a 2-methylimidazole solution, so as to prepare a ZIF-8 modified basalt fiber; and finally, mixing the ZIF-8 modified basalt fiber with resin through electrostatic coating, and molding by adopting a segmented hot-pressing method to obtain the basalt fiber composite material. According to the method, a composite structure formed by the synergistic effect of a dopamine self-polymerization layer and ZIF-8 is introduced into the surface of the basalt fiber, so that the interface bonding force between the fiber and resin and the corrosion resistance of the composite material are greatly enhanced.

The invention relates to the technical field of wood detection, and particularly discloses a wood furniture material rapid detection system, which utilizes a portable spectrum scanner to collect spectrum scanning images of a wood furniture material to be detected from a plurality of positions, and introduces a spectrum image processing technology based on deep learning. Spectral feature extraction, correlation analysis of spectral features of all the positions and complementary information enhanced polymerization processing are performed on the spectral scanning images of the multiple positions, so that global spectral feature description of the to-be-detected wooden furniture material is constructed; based on matching analysis between the spectral characteristics of the wooden furniture material to be detected and the spectral characteristics of the known wood type, rapid and accurate detection of the wooden furniture material is realized. In this way, the limitation of a traditional wood identification method and the defects of an existing spectrum detection method can be effectively overcome, and the accuracy and efficiency of wood furniture material detection are improved.

The invention provides a silicon-carbon material and a preparation method thereof, a porous carbon substrate, a negative electrode material and a battery, and relates to the technical field of battery materials. The core point provided by the invention is controllable synthesis of the porous carbon substrate in the silicon-carbon material, a phenolic monomer and an aldehyde monomer are polymerized in the presence of a catalyst and a dispersing agent, meanwhile, a doping agent and a pre-carbonized biomass carbon precursor are added into a solution, the phenolic resin formed by polymerization is of a spherical structure, and the silicon-carbon composite material is obtained. Homogeneous doping of elements is completed in the synthesis process, the added biomass carbon precursor is of a blocky structure, matching of carbon-based particles of different structures can better exert respective beneficial effects and complement each other, the battery performance is comprehensively improved, and the battery has excellent cycle performance and conductivity.

The invention relates to the field of membrane materials, and discloses an epoxy modified starch-based degradable membrane and a preparation method thereof, the epoxy modified starch-based degradable membrane comprises epoxidized starch, modified nanocellulose and a plasticizer; the modified nano cellulose is prepared by mixing a modified composite filler, a nano cellulose dispersion liquid and a zinc acetate dihydrate aqueous solution; the nano-cellulose dispersion liquid is prepared by adhering polytannic acid formed by oxidation and self-polymerization of tannic acid to the surface of nano-cellulose; the modified composite filler is prepared by performing carboxylation modification on nano titanium dioxide coated fumed silica nanoparticles by using succinic anhydride and gamma-aminopropyltriethoxysilane, then reacting with polyethyleneimine to obtain an aminated composite filler, and finally grafting glycidyl dodecyl dimethyl ammonium chloride to the surface of the aminated composite filler. The prepared film material is high in tensile strength, has certain hydrophobicity, and has good heat resistance, antibacterial property and flame retardant property.

The invention discloses unsaturated polyester resin for imitation jade handicrafts and a preparation method thereof, and belongs to the technical field of polyester resin. Comprising the following components: diethylene glycol, methylpropanediol, propylene glycol, maleic anhydride, phthalic anhydride, an antioxidant, a polymerization inhibitor, paraffin, a stabilizer, an ultraviolet light absorber, a whitening agent and a diluent. The weight ratio of the propylene glycol to the methyl propylene glycol is (1.0-1.3): 1, and the methyl propylene glycol accounts for 20-22% of the total amount of the dihydric alcohol; the weight ratio of maleic anhydride to phthalic anhydride is (0.46-0.52): 1; the preparation method comprises 1) adding the raw materials and the antioxidant into a reactor, carrying out heating, carrying out heat preservation for 0.5-1.0 h and continuing heating, 2) carrying out a reaction for 2-3 h after heating, carrying out dehydration until an acid value is 20-25 mgKOH / g, and 3) carrying out cooling, adding the auxiliary agent and carrying out uniform mixing so that the unsaturated polyester resin is obtained.

The invention discloses metal element-doped nano silicon carbon as well as a preparation method and application thereof, and relates to the field of negative electrode materials. The nano silicon carbon takes porous carbon as a carbon skeleton, and the porous carbon is sequentially attached with nano silicon and coated with a carbon material layer through a chemical vapor deposition method; the porous carbon is prepared by carbonizing resin containing metal nitride after alkali activation and pore forming, and the resin containing the metal nitride is prepared by condensation polymerization of a phenolic compound, an aldehyde compound and the metal nitride in the presence of a catalyst. The porous carbon is doped with the metal nitride in the resin polycondensation process, the conductivity of the nano silicon carbon is effectively improved, the powder resistance is reduced, holes in the surface of the porous carbon provide more expansion space for deposited nano silicon, a carbon material layer formed by subsequent deposition and coating provides a protection effect, the reaction between silicon and an electrolyte can be inhibited, and the service life of the nano silicon carbon is prolonged. A stable SEI film is formed, the cycling stability of the material is improved, the volume expansion rate of a pole piece is inhibited, and the cycling life and the stability of the battery are improved.

The invention discloses a p-type or n-type COF film, the film thickness is 50 nm to 5 m, the aperture is 0.7 nm to 4 nm, and the film has a regular pore channel structure and light response performance. According to the invention, proper monomers are selected, and liquid-solid interface polymerization reaction is carried out, so that COF membranes grow along the tube wall, and p-type and n-type COF membranes are respectively prepared. The growth direction of the film is inconsistent with the transmission direction of the monomer and the catalyst, and the process can effectively promote the dissolution growth and self-repair of the COF film, so that the crystallinity and stacking orientation of the film are improved, and the structural characteristics of the COF film are optimized. The obtained COF film has a remarkable advantage of light-driven ion pump performance. The obtained COF membrane is used for preparing a desalting device.

The invention relates to the technical field of fracturing fluids, and discloses a preparation method of a temperature-resistant and salt-resistant fracturing fluid, which comprises the following steps: carrying out polymerization reaction on acrylamide, acrylic acid and an acrylamide sulfonic acid monomer to obtain a polymer thickening agent, and compounding the polymer thickening agent with a cross-linking agent, a clay stabilizer and the like to obtain the temperature-resistant and salt-resistant fracturing fluid. The polymer thickening agent contains long-chain alkyl, a physical cross-linked spatial network structure can be formed through a hydrophobic association effect, the hydrodynamic volume is increased, a good tackifying effect is achieved, and after high-speed shearing, the long-chain alkyl can be cross-linked again to form a spatial network structure, so that a solution still keeps very high apparent viscosity, and the viscosity of the solution is improved. Good anti-shearing performance is realized. The acrylamide sulfonic acid monomer contains a sulfonate group and is used as a temperature-resistant and salt-resistant monomer, so that the polymer thickening agent has good temperature resistance and salt resistance, and the fracturing fluid still keeps relatively high apparent viscosity after being subjected to high-temperature heat treatment and in formation water with high salinity.

The invention belongs to the technical field of solid-state lithium batteries, and relates to a fluorinated double-salt cross-linked solid-state electrolyte adaptive to a lithium-free negative electrode, a solid-state lithium battery and a preparation method thereof.The preparation method comprises the steps that double-lithium salt is dissolved in a fluorinated solvent to obtain an electrolyte, then a monomer, a cross-linking agent and an initiator are added, the mixture is stirred to be uniform to obtain a precursor solution, and the precursor solution is prepared; and assembling the precursor solution, a positive electrode, a negative electrode and a solid-state electrolyte composite diaphragm into a battery, and performing gradient polymerization to form the solid-state lithium battery. According to the invention, the ionic conductivity of the solid electrolyte is more than 5 * 10 <-4 > S / cm and the oxidation potential of the solid electrolyte is more than 5.8 V by adopting a fluorinated solvent consisting of fluorinated carbonate and fluorinated carboxylate and a double-lithium-salt synergistic system and combining an in-situ interface fusion technology, so that the solid electrolyte can be matched with a 4.8 V high-voltage lithium-rich manganese-based positive electrode and a lithium-free negative electrode; and the energy density and the safety of the solid-state lithium battery are improved. The electrolyte scheme is low in cost, high in safety and good in positive and negative electrode matching performance, can be compatible with an existing battery production line, and is convenient for large-scale production.

The invention provides a composite solid-state electrolyte membrane and a preparation method and application thereof, and belongs to the field of lithium battery solid-state electrolytes.The preparation method comprises the steps that solid-state electrolyte powder and carbon precursor powder are pressed into a membrane and then subjected to gradient heating calcination, and a three-dimensional framework porous ceramic membrane is obtained; uniformly mixing a lithium salt, a polymer monomer and an initiator to prepare a polymerization solution; and dropwise adding the polymerization solution onto the three-dimensional skeleton porous ceramic membrane, and carrying out thermal polymerization to obtain the composite solid electrolyte membrane. Aiming at the inorganic solid electrolyte, the composite solid electrolyte membrane with high ionic conductivity and good interfacial compatibility is obtained in a mode of in-situ construction of the composite solid electrolyte membrane, and the problems that the inorganic solid electrolyte is low in ionic conductivity, poor in interface contact and not resistant to high pressure are effectively solved.

The invention relates to the field of vacuum bag materials, in particular to an anti-freezing vacuum bag capable of keeping freshness of fresh food and a preparation method of the anti-freezing vacuum bag. The anti-freezing vacuum bag capable of keeping the freshness of the fresh food comprises the following raw materials: matrix resin, a solid filler, a polymerization compound additive, an antioxidant, a reinforcing agent, a toughening agent and the like. The vacuum bag material not only has good mechanical properties, but also can keep good strength stability in a low-temperature use environment, the probability of embrittlement, damage, softening and mechanical property reduction is greatly reduced, meanwhile, the barrier property of the vacuum bag material to molecules such as moisture and oxygen can be guaranteed, and the service life of the vacuum bag material is prolonged. The vacuum bag has excellent environmental moisture and temperature resistance in the long-term use process, the effective ice crystal resisting effect is achieved, the performance requirements of existing consumers for high-performance vacuum fresh-keeping materials are fully met, and very excellent application prospects are achieved.

The invention provides a multi-sensor weld penetration state recognition method for improving an attention mechanism, relates to the technical field of weld recognition, and solves the technical problem of inaccurate weld quality judgment caused by insufficient recognition precision of a single signal on a penetration state in the prior art. According to the technical scheme, a sound signal in the welding process and a molten pool image in the welding process are collected; effective sound signals are extracted, and then the sound signals are visualized by using a Gramer angle field method; performing de-exposure processing on the overexposure area through a decoupling polymerization exposure correction model; a channel attention and space attention mechanism is introduced into sound and image feature extraction, deformable convolution self-adaptive sampling is utilized, a double-cross attention fusion strategy is combined to fuse multi-source information, fusion penetration state classification is completed, and therefore the quality of a welding seam is judged. According to the method, the penetration state can be accurately classified through the sound signal extracted in the welding process and the molten pool image, and a certain thought is provided for weld quality detection.

The invention discloses a polyimidazolone compound as well as a preparation method and application thereof. The preparation method comprises the following steps: dissolving a bilateral alkyne ester compound, amidine hydrochloride, a catalyst and a desalting agent in an organic solvent, and carrying out polymerization reaction to obtain the polyimidazolone compound. The polyimidazolone compound with the five-membered ring is selectively generated, and the method has the advantages that monomers are easy to obtain, operation is easy, and by-products are low in toxicity. The polyimidazolone compound prepared by the invention has better machinability and has potential application value in the aspects of metal ion detection and biogenic amine detection.

The invention relates to a waterborne polyurethane sizing agent, a preparation method thereof and a carbon fiber, and belongs to the technical field of carbon fiber preparation. The preparation method of the waterborne polyurethane sizing agent comprises the following steps: S10, dispersing and mixing amino modified polydimethylsiloxane and graphene oxide in an organic solvent, carrying out grafting reaction, and carrying out vacuum drying to obtain amino modified polydimethylsiloxane grafted graphene oxide; s20, mixing polyether glycol, diisocyanate and a hydrophilic chain extender, and carrying out a first reaction to obtain a first reaction solution; mixing the first reaction liquid, a small molecule chain extender and amino modified polydimethylsiloxane grafted graphene oxide for second reaction to obtain a polymerization system; and carrying out a neutralization reaction on the polymerization system and a neutralizer, and dispersing in water to obtain the waterborne polyurethane sizing agent. The waterborne polyurethane sizing agent can effectively increase the surface roughness of carbon fibers and improve the interfacial shear strength between the carbon fibers and a resin matrix.

The invention discloses flaky silver-coated aluminum powder of a core-shell structure and a preparation method and application of the flaky silver-coated aluminum powder, and particularly relates to the field of electromagnetic shielding materials. Comprising the following steps: carrying out pretreatment of removing an oxidation film on flaky aluminum powder; dispersing the pretreated flaky aluminum powder in a tris (hydroxymethyl) aminomethane hydrochloride aqueous solution, and adding dopamine hydrochloride to carry out polymerization reaction to obtain flaky aluminum powder coated with a polydopamine layer; the flaky aluminum powder coated with the polydopamine layer is subjected to activating treatment through silver nitrate, and activated flaky aluminum powder is obtained; the activated flaky aluminum powder and a silver-ammonia solution are mixed, a reduction solution is added for a silver mirror reaction, flaky silver-coated aluminum powder is obtained, and the structure of the flaky silver-coated aluminum powder is that the surface of the flaky aluminum powder is sequentially coated with a polydopamine layer and a silver shell layer from inside to outside. And the environmental stability and the corrosion resistance of the flaky silver-coated aluminum powder are improved.

The invention belongs to the technical field of oilfield chemistry, and discloses a cross-linking agent for degradable gel and a preparation method and application thereof.The preparation method comprises the steps that a compound A is dissolved in an organic solvent and stirred to be uniform, and a first solution is obtained; adding a polymerization inhibitor and a compound B into the first solution, and uniformly stirring at room temperature to obtain a second solution; the second solution is sequentially subjected to heating stirring, diethyl ether washing, ethanol recrystallization, suction filtration and drying, and the cross-linking agent for gel is obtained. According to the invention, a non-conjugated aromatic system is added into a cross-linking agent structure, so that the prepared gel can be automatically degraded under a certain temperature condition; ammonium ions and halide ions are added into a cross-linking agent structure, so that the anti-pollution performance of the gel is enhanced, and the problems that existing gel is difficult to degrade and poor in anti-pollution performance are solved.

The invention belongs to the technical field of flame-retardant macromolecules, and particularly relates to intrinsic heat-conducting flame-retardant recycled epoxy resin and a preparation method thereof. The preparation method comprises the following steps: (1) carrying out a reaction on diethanol amine and 9, 10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide (DOPO) to obtain an intermediate A; and (2) carrying out condensation polymerization on the intermediate A and phenylphosphonic acid to prepare the phosphate-terminated polyester flame retardant (PEF). And (3) carrying out epoxidation on 4, 4 '-biphenol to prepare the liquid crystal epoxy precursor LEP. And (4) mixing PEF, LEP and 3, 3 '-dithiodipropionic acid, and heating and curing to prepare the epoxy resin. The prepared epoxy resin has intrinsic heat conduction, flame retardance and efficient recoverability, and is a high polymer material with great potential.

The invention relates to the field of quantum dot ink, and discloses diffusion plate printing quantum dot ink and a preparation method thereof.The diffusion plate printing quantum dot ink comprises acrylic resin, hyperbranched polyester resin, a quantum dot material, modified boron nitride, a reactive diluent, a photoinitiator, a wetting agent and a defoaming agent; the hyperbranched polyester resin is prepared by reacting hyperbranched polyester acrylate and a sulfydryl-terminated silicon-containing reaction monomer, wherein the hyperbranched polyester acrylate is prepared by reacting pentaerythritol with 2, 2-dimethylolpropionic acid and then carrying out esterification reaction with acrylic acid; the sulfydryl-terminated silicon-containing reaction monomer is prepared by reacting eugenol with 1, 1, 3, 3-tetramethyldisiloxane and then carrying out esterification reaction with 3-mercaptopropionic acid; the modified boron nitride is prepared by modifying a cationic polymer which is prepared by carrying out a Mannich reaction on triethylene tetramine, formaldehyde and acetone and then carrying out a condensation polymerization reaction with formaldehyde. After the ink prepared by the invention is cured, a coating film is high in hardness, adhesive force and heat conductivity coefficient, and good in flexibility, heat resistance and migration barrier property.

The invention discloses a lithium battery polymer solid electrolyte membrane capable of rapidly polymerizing at room temperature as well as a preparation method and application thereof, and belongs to the field of polymer electrolyte. The preparation method of the lithium battery polymer solid electrolyte membrane provided by the invention comprises the following steps: uniformly mixing polyethylene glycol methyl ether methacrylate and acrylonitrile according to a preset proportion to obtain a blended solution; sequentially adding lithium bis (trifluoromethanesulfonimide), divinylbenzene and benzoin diethyl ether into the blended solution, and uniformly mixing to obtain a precursor solution; and coating the precursor solution, and carrying out ultraviolet curing to obtain the lithium battery polymer solid electrolyte membrane. According to the lithium battery polymer solid electrolyte membrane provided by the invention, the voltage withstanding characteristic and the high ion conduction performance of the polymer electrolyte can be simultaneously improved, and the lithium battery polymer solid electrolyte membrane has a great gain on battery circulation and stability.

The invention discloses a tissue adhesive based on mussel mucin as well as a preparation method and application thereof. The tissue adhesive is prepared from mussel mucin and an anionic compound containing a hydrophobic group, the mussel worm electrostatic self-assembly bionic composite material is developed on the basis of triple bionic principles of dopa adhesion of mussel byssus, electrostatic self-assembly polymerization of sandburg worms and hydrophobic acting force of barnacles. The preparation method of the tissue adhesive is simple, the tissue adhesive can be obtained only by mixing and oscillating the two stock solutions, the gel forming condition is simple and easy to implement, the pH range and the stock solution concentration range required by gel forming are large, the gel forming range is wide, the raw materials required in the preparation process are few, and the cost is low. Only two key raw materials including the mussel mucin and the anionic compound containing the hydrophobic group are needed, and the prepared tissue adhesive is high in adhesion speed and high in adhesion strength, has good cell compatibility and biological safety and can promote wound healing.

The invention relates to the technical field of all-solid-state lithium metal batteries, in particular to a cellulose paper-based polymer solid electrolyte as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing N-methylacetamide and lithium bis (trifluoromethanesulfonyl) imide to obtain a eutectic solvent; the preparation method comprises the following steps: mixing a eutectic solvent, polyethylene glycol oxalate, acrylamide and a thermal initiator to obtain a eutectic polymer electrolyte precursor; and soaking cellulose paper in the eutectic polymer electrolyte precursor, and carrying out hot-pressing polymerization to obtain the cellulose paper-based polymer solid electrolyte. The cellulose paper-based polymer solid electrolyte prepared by the invention is soft in texture and can be better attached to an electrode, the problem of poor contact between the electrode and an electrolyte interface is solved, and the interface impedance is reduced by fusing the characteristics of low viscosity and high conductivity of the eutectic solvent and the supporting effect of the cellulose paper; the ion transmission efficiency is improved, and conditions are provided for long-term stable circulation of the battery.

The invention discloses a positive electrode material of an upward flow type electrochemical dephosphorization system, and the preparation method comprises the following steps: preparing a polyaniline-coated ZIF-8 derived carbon loaded magnesium-aluminum double-metal hydroxide electrode material, and the preparation process comprises ZIF-8 carbonization in a nitrogen atmosphere, aniline oxidation polymerization, and loading of magnesium-aluminum double-metal hydroxide by a coprecipitation method; the electro-adsorption positive electrode material belongs to a polyaniline magnesium aluminum double-metal hydroxide mesoporous synergistic platform in ZIF-8 derived carbon, and has a nano frame with strong pore accessibility and high electrochemical activity; the synergistic process comprises attraction of polyaniline to phosphate ions and trapping of the magnesium-aluminum double-metal hydroxide. The electrode prepared by the method has a unique mesoporous framework, a large number of phosphorus removal sites are obtained on the surface of the electrode, a rapid ion storage behavior mainly based on a capacitance control process is realized on a solid-liquid interface, phosphate in water can be effectively separated in an electro-adsorption system, and the method is a pollution control process with a clear mechanism.

The invention discloses a high-performance guanidine gum fracturing fluid system for deep coal rock gas backlog fracturing and application, and relates to the technical field of oil and gas reservoir chemistry, the high-performance guanidine gum fracturing fluid system for deep coal rock gas backlog fracturing comprises the following components: 0.05-0.35% of graft modified guanidine gum, 0-0.3% of multiple cross-linking agent, 0-0.2% of conditioning agent, 0.1-0.3% of functional additive, 0-0.1% of gel breaker, and the balance of water, the grafting modified guanidine gum is prepared by performing functional group modification and side chain grafting polymerization on guanidine gum raw powder, the number of chemical crosslinking groups and branched chains is remarkably increased, after the grafting modified guanidine gum is compounded with a matched multiple crosslinking agent, the chemical and physical synergistic crosslinking effect is remarkably enhanced, and the performance of the fracturing fluid is greatly improved; the high-performance guanidine gum fracturing fluid system for deep coal rock gas backlog fracturing, provided by the invention, has the characteristics of low component dosage, low cost, low residue content, good swelling performance, good resistance reduction performance, good sand carrying performance, controllable mixing construction and controllable online crosslinking, and can effectively meet the construction requirements of coal rock gas backlog fracturing.

Embodiments herein generally relate to protein-based surface coatings. In some examples, disclosed embodiments relate to a process for synthesizing a protein-based surface coating, comprising conjugating acrylate or (meth-)acrylate monomer to serum albumin molecules. In at least one example, the conjugation step comprises: reducing native serum albumin molecules to produce free thiol groups; reacting the reduced serum albumin with (meth-)acrylate or acrylate monomers to react carbon-carbon double bonds with the free thiol groups; and inducing (meth-)acrylate or acrylate polymerization.

The invention provides a preparation method of an h-BN / PI high-temperature-resistant anticorrosive coating, and relates to the technical field of polymer composites.The preparation method of the h-BN / PI high-temperature-resistant anticorrosive coating comprises the steps that under the protection of inert atmosphere, aromatic diamine containing impurity element five-membered rings and aromatic dianhydride containing ether bonds are taken and subjected to a polymerization reaction in a polar aprotic solvent, and the h-BN / PI high-temperature-resistant anticorrosive coating is obtained. A polyamide acid solution is obtained; performing ultrasonic-assisted liquid phase stripping on the micron-sized hexagonal boron nitride to obtain single-layer hexagonal boron nitride; adding the single-layer hexagonal boron nitride into the polyamide acid solution for multiple times, and uniformly stirring to obtain a hexagonal boron nitride / polyimide composite solution; and coating the hexagonal boron nitride / polyimide composite liquid on a to-be-coated surface, and carrying out gradient heating curing to obtain the h-BN / PI high-temperature-resistant anticorrosive coating. The h-BN / PI high-temperature-resistant anticorrosive coating based on interaction of multiple hydrogen bonds has relatively good high temperature resistance, relatively good resistance mechanical property and excellent corrosion resistance.