1122 results about "Grafting" patented technology

The invention relates to the technical field of high polymer material preparation, and discloses a bamboo fiber graft modified full-biodegradable composite membrane material preparation process which comprises the following steps: firstly, performing hot mixing and cooling on dried bamboo fiber powder, anhydrous citric acid, choline chloride, activated zinc oxide and pentaerythritol to prepare a bamboo fiber modified premix; then mixing the biodegradable polyester resin with the premix; adding the mixture into an extruder, injecting epoxidized soybean oil into a barrel through a liquid metering device, and performing melt extrusion granulation under a vacuum exhaust condition; and finally carrying out blow molding to form the film. Through in-situ reaction extrusion of multi-component synergism, surface grafting of bamboo fibers, chain extension of a polyester matrix and interface chemical bonding of the bamboo fibers and the polyester matrix are achieved, interface compatibility is effectively improved, degradation of the material in the processing process is inhibited, and the mechanical property and thermal stability of the composite film material are remarkably improved; the process is efficient and environment-friendly, and the cost is controllable.

The invention discloses a preparation method of a natural fiber prepreg with an improved impregnation effect, and relates to the technical field of composite material preparation, the method comprises the following steps: carrying out synergistic modification through fiber surface plasma activation and silane grafting, and combining a gradient pressure-temperature coupling impregnation system and ultrasonic-assisted permeation to prepare the natural fiber prepreg with the improved impregnation effect. And gradient filling and interface chemical bonding strengthening of the resin in the fiber bundle are realized. The core process comprises the following steps: pretreating fibers to improve surface energy and roughness, introducing a reactive diluent and a block copolymer into a resin system to regulate and control viscosity and transport capacity, constructing a pressure gradient by a multi-stage compression roller to drive resin to permeate into a bundle core, promoting uniform impregnation by infrared temperature control and ultrasonic cavitation, and finally obtaining uniform resin distribution and porosity lt. The interlayer shear strength is gt; and the high-performance prepreg is stable in batch under the pressure of 45 MPa. Reliable technical support and process guarantee are provided for large-scale engineering application of the high-performance natural fiber composite material.

The invention relates to the field of optical protection materials, and provides a transparent film with laser eavesdropping prevention performance and a preparation method thereof.The transparent film is composed of surface-modified doped tungsten oxide nanosheets, amino-isocyanate bifunctional lithium niobate nanowires, urethane acrylate, an ultraviolet light absorber, a silane coupling agent, a dispersing agent and a flatting agent; the molybdenum-doped tungsten oxide nanosheets are obtained through silane coupling modification after hydrothermal synthesis, and the lithium niobate nanowires are prepared through a gradient modification process of hydrothermal synthesis-silane coupling-isocyanate grafting-phenol end capping. A modified nano material is uniformly dispersed in a resin matrix through an ultrasonic dispersion composite technology, and through blade coating forming, ultraviolet curing and constant-temperature and constant-humidity post-treatment, compared with the prior art, the scheme overcomes the problems that a traditional protective film is insufficient in optical transparency, laser eavesdropping prevention function and dynamic viscoelasticity, and is suitable for the field of high-end security and protection.

The invention discloses a light telegraph pole cement material and a preparation method thereof, and relates to the technical field of cement concrete. The method comprises the following steps: firstly, carrying out acid pickling, silane coupling agent grafting and nanoparticle vacuum impregnation treatment on shale ceramsite to obtain modified light ceramsite; the preparation method comprises the following steps: ultrasonically dispersing graphene oxide, compounding with Portland cement clinker and modified fly ash, and reacting with epoxy resin emulsion, a curing agent and a silane coupling agent to prepare organic-inorganic composite modified cement; the bamboo skeleton is subjected to silane coupling agent pretreatment to obtain a modified skeleton; then, mixing composite cement, an additive and water into slurry, adding the modified ceramsite and aggregate, and performing high-speed stirring and ultrasonic dispersion to form homogeneous concrete slurry; and finally, putting the modified bamboo skeleton into a mold, injecting the slurry, and performing centrifugal forming, steam curing and natural curing to obtain the cement material. The prepared lightweight telegraph pole cement material has excellent mechanical strength.

The invention relates to the technical field of fibers, and discloses an antistatic warm-keeping fiber and a preparation method thereof. The preparation method comprises the following steps: carrying out graft modification on a far infrared material graphene oxide through functionalized POSS, introducing the modified graphene oxide and an ionic liquid into polypropylene, carrying out melt grafting to prepare an antistatic polypropylene master batch, introducing the master batch into polypropylene slices for spinning, and carrying out a synergistic antistatic effect of an inorganic antistatic agent graphene and an organic antistatic agent ionic liquid to prepare a composite material. The prepared fiber has antistatic performance and far infrared heating performance, and meanwhile, the POSS structure with excellent thermal stability is introduced, so that the heat resistance of the fiber is further improved.

The invention relates to the technical field of proton exchange membranes, and provides a covalent grafted heteropoly acid modified perfluorosulfonic acid membrane as well as a preparation method and application thereof. According to the invention, polypropylene glycol monoalkyl ether and Keggin type vacancy heteropoly acid are subjected to covalent grafting, and then the obtained covalent grafted heteropoly acid is used as an additive to modify the perfluorosulfonic acid membrane, so that the leakage problem of heteropoly acid in the proton exchange membrane can be effectively relieved, and meanwhile, the excellent proton conduction performance of heteropoly acid is also retained; moreover, the polypropylene glycol monoalkyl ether has relatively large molecular weight, so that the heteropoly acid can be anchored more firmly in the perfluorosulfonic acid membrane, and the proton conduction capability of the heteropoly acid is fully exerted. The result of the embodiment shows that the covalent grafted heteropoly acid modified perfluorosulfonic acid membrane provided by the invention shows excellent proton conduction performance and chemical stability, and has a wide application prospect.

The invention relates to the technical field of packaging materials, in particular to a chip inductor packaging material and a preparation method thereof. The packaging material is prepared from epoxy resin serving as a matrix, composite boron nitride modified hollow glass beads, spherical silica powder, a silane coupling agent, a curing agent, an accelerant and a defoaming agent. Wherein the boron nitride modified hollow glass beads are obtained by constructing a boron nitride functional layer through branched polyamidoamine grafting and a melamine-boric acid in-situ method and carrying out high-temperature calcination. By means of the innovative structural design, efficient bonding of a filler interface and ordered construction of a heat conduction path are achieved, the heat conduction performance and the mechanical strength of the composite material are remarkably improved, and the dielectric constant and the dielectric loss are effectively reduced. The packaging material provided by the invention has excellent electrical, thermal and mechanical comprehensive performance, meets the requirements of light weight and high reliability packaging of a new generation of high-performance chip inductor devices, and has important industrialization and application prospects.

The invention discloses an epoxy resin tack coat oil material suitable for a steel bridge deck, which constructs a multi-scale toughening composite system through the synergistic effect of an epoxy-terminated polyurethane elastomer toughening agent (molecular-scale chemical grafting) and a nano-scale elastomer filler (nano dispersion toughening), and solves the problem of rigidity-flexibility imbalance of the traditional epoxy tack coat oil. The material has the advantages of fast curing (surface drying at 25 DEG C is less than or equal to 4 hours), high toughness (the elongation at break is greater than or equal to 250%) and excellent weather resistance (the performance retention rate is greater than or equal to 85% after ultraviolet aging for 500 hours), and is suitable for interlayer interface bonding of steel bridge deck pit slot and crack repair. According to the preparation method, uniform dispersion and interface chemical bonding of the nanofiller are achieved through a segmented stirring process, the comprehensive performance of the material is remarkably improved, and the important engineering application value is achieved.

The invention relates to the technical field of pavement materials, in particular to a solid waste-based cementing material stable coal-based solid waste road base material and a preparation method thereof. According to the material, secondary modified regenerated coarse and fine aggregate is used as a framework, coal gangue powder and granulated blast furnace slag micro powder are matched, and two-step engineering of dopamine / double-amino-terminated polyethylene glycol co-deposition grafting and high-modulus silicate pre-coating is adopted, so that the synergistic improvement of the surface wettability and the interface density of the aggregate is realized. The system is cooperated with low-modulus excitation liquid and polypropylene fibers, and the mixing uniformity of the material and the quality of an interface transition area are optimized through a thin-pulp stone-wrapping and densification segmentation process. The material gives consideration to high resilience modulus, rut resistance and durability, significantly reduces the problems of high water absorption, weak interface, early cracks and the like of the recycled aggregate, is adaptive to a traditional road construction window, and has good application prospects.

The invention relates to the technical field of functional fabrics, in particular to an electromagnetic shielding flame-retardant fabric and a preparation method thereof. The preparation method comprises the following steps: S1, mixing an activated phosphate ester solution with polyaniline for reaction, and then adding a cross-linking agent for reaction to obtain a composite grafting agent; s2, the Ti < 3 > C < 2 > T < x > and the composite grafting agent are subjected to a reaction, and multifunctional grafting modified Ti < 3 > C < 2 > T < x > is obtained; and S3, immersing a polyester fabric into a dispersion liquid containing the multifunctional grafting modified Ti3C2Tx, and drying to obtain the electromagnetic shielding flame-retardant fabric. According to the preparation method, Ti3C2Tx is subjected to multifunctional grafting modification by adopting a halogen-free flame retardant and a water-based process, and the Ti3C2Tx is combined with triethyl phosphate and polyaniline to prepare the composite material with dual functions of electromagnetic shielding and flame retardance. The composite material is adopted to modify polyester fabric, and fabric with efficient electromagnetic shielding and flame retardant functions and high mechanical strength can be prepared.

The invention relates to the technical field of aerogel, in particular to flexible flame-retardant aerogel and a preparation method thereof.The flexible flame-retardant aerogel is prepared from modified graphene, modified polyvinyl alcohol, silver nanowires, phytic acid and epoxy resin E-51; the furan group is introduced into the aerogel through the modified graphene, the furan group and the maleimide group are subjected to a D-A reaction, an adhesive is prevented from being used when the aerogel is bonded with a screen backboard, the D-A reaction is reversible, and lossless reworking can be realized. PVA and epoxy resin E-51 are added together, so that the heat resistance and mechanical strength of the material are improved. PVA is grafted with a large-steric-hindrance amine group, weak interaction with a furan group is generated, side reaction with an epoxy group of epoxy resin E-51 is avoided, and when aerogel is bonded to an OLED screen backboard, the protective layer is reversibly released, so that D-A reaction can be smoothly carried out. The hydrophobic treatment of the modified graphene and the modified grafting of the polyethylene to the mPEG can effectively improve the agglomeration of the modified graphene and ensure the uniform dispersion of the modified graphene.

The invention relates to the technical field of composite materials, and particularly discloses a SiO2-coated LDHs nano composite material with high adsorption efficiency and a preparation method thereof.The preparation method comprises the steps that SiO2 nano particles are modified through double coupling agents, chitosan and F127 double template agents are combined to synthesize an LDHs precursor, and then the LDHs precursor is prepared into the SiO2-coated LDHs nano composite material. In-situ growth of a core-shell structure is realized by using a micro-channel reactor, an interface is strengthened by depositing Al2O3 through ALD, and interlayer ions are finally pre-loaded through hierarchical pore carbonization and thermo-sensitive-light response polymer grafting, so that the SiO2 (at) LDHs composite material with triple interface protection, a hierarchical pore structure and an intelligent response function is formed, the adsorption capacity and the cycling stability are remarkably improved, and the application range is wide. And the production cost is greatly reduced.

The invention provides an ultra-high molecular weight polyethylene fiber resin composite material interface regulation composition which comprises the following components in parts by weight: 100 parts of ultra-high molecular weight polyethylene fiber, 12 parts of polyethylene, 0.6 part of a compatilizer, 0.03 part of an initiator, 2.5 parts of gallic acid, 1 part of tetraethylenepentamine and 5 parts of nano silicon dioxide. The compatilizer is used for melt grafting with polyethylene, and the initiator is used for initiating melt grafting of the compatilizer and polyethylene. The invention also provides a method for carrying out interface regulation and control by adopting the interface regulation and control composition and an ultra-high molecular weight polyethylene fiber resin composite material prepared by the method. The ultra-high molecular weight polyethylene fiber resin composite material obtained by carrying out interface regulation and control treatment on the ultra-high molecular weight polyethylene fiber resin composite material interface regulation and control composition has a good interface state, excellent mechanical properties and good impact resistance.

The invention discloses a crown ether grafted polyarylether sulfone ion separation membrane as well as a preparation method and application thereof, and belongs to the technical field of ion separation membranes, collaborative optimization is realized through crown ether accurate grafting and ultrathin ordered membrane formation: a main chain of polyarylether sulfone is grafted with 4 '-aminobenzo-12-crown-4 to form an inherent channel adapted to Li, and the specific surface area of the main chain is increased; the ultrathin film is prepared by a water surface spreading method, and the ion transmission path is shortened. Finally, in a LiCl / MgCl system, Liion flux has high selectivity, high permeation-high selectivity cooperation is preliminarily realized, the chemical synthesis step can be amplified to a kilogram level, and after a DPAES-g-CE / dichloromethane solution is dropwise added to the water surface, the DPAES-g-CE / dichloromethane solution is rapidly spread to form a film without precise equipment; the raw materials are industrial-grade monomers and have no toxic residues, the membrane can be recycled and reused through dichloromethane, the equipment cost is reduced by about 90%, and industrialization is easy; the main chain of the polyaryl ether sulfone is high in rigidity and resistant to high temperature and chemical corrosion; crown ether grafting avoids molecular chain agglomeration, and the swelling rate is far lower than that of a traditional sulfonated membrane.

The invention discloses a flame-retardant thermoplastic polyurethane elastomer material and a preparation method thereof, and belongs to the technical field of modified nano materials. The preparation method comprises the following steps: dissolving melamine, phytic acid and boron nitride in deionized water, carrying out oil bath, adding a coupling agent, stirring, carrying out vacuum filtration, washing with water, and drying to obtain a layered nano flame retardant; the preparation method comprises the following steps: dispersing a flame retardant in deionized water containing a nonionic dispersant, and carrying out ultrasonic treatment; the preparation method comprises the following steps: reacting polyether polyol with diisocyanate to obtain a primary prepolymer; adding other auxiliary agents, stirring, and carrying out gradient heating polymerization; and injecting into a mold, curing for 6-12 hours at 105-125 DEG C, and drying for 12-24 hours at 80-90 DEG C. A phosphorus-nitrogen-silicon ternary synergistic flame-retardant system is introduced, the boron nitride nanosheet surface grafting and dynamic pre-polymerization-gradient heating process is optimized, the dispersity is improved, and smoke suppression and thermal stability are achieved. Compared with the prior art, the flame retardant efficiency is high, the mechanical property is excellent, and environmental friendliness is achieved.

The invention provides an exosome enrichment method based on a modified cellulose material, which comprises the following steps: carrying out TEMPO oxidation on plant residue cellulose to prepare a cellulose material with a carboxyl structure; the cellulose structure is further refined by adopting mechanical shearing and high-pressure homogenizing means, so that the specific surface area and the dispersion stability are remarkably improved; through polyethyleneimine PEI grafting, a large number of amino functional groups are introduced, the surface electropositivity of the material is enhanced, and efficient adsorption and enrichment of exosomes with negative charges are achieved. The invention also provides the exosome prepared by the method. The modified cellulose material disclosed by the invention is wide in source, simple and convenient to prepare and mild in enrichment process, the separation purity and the enrichment efficiency of the exosome can be remarkably improved, and the modified cellulose material has good biocompatibility and environmental friendliness; compared with existing ultracentrifugation, density gradient centrifugation and immunoaffinity separation methods, the method has the advantages that the operation process is simplified, the equipment dependence and reagent cost are reduced, and the potential of large-scale production and clinical application is achieved.

The invention provides a multi-variety fusion grafting control method for Chinese rose flowers, a server, a medium and a product, and relates to the technical field of Chinese rose fusion control application. The method comprises the following steps: firstly, acquiring a plurality of candidate grafting schemes, collecting rootstock monitoring data and to-be-scion Chinese rose plant information in combination with the schemes, inputting the rootstock monitoring data and the to-be-scion Chinese rose plant information into a growth feature matching prediction model formed by deep learning training according to historical grafting records, scion variety features, grafting results and expert experience, and performing scion grafting. Calculating the growth characteristic matching degree of the to-be-scion and the rootstock, and screening out candidate to-be-scion plant information according to the growth characteristic matching degree; combining the rootstock data and the candidate information to obtain a growth condition score through a fusion growth prediction model, and selecting a scheme with the highest score as an optimal scheme; and finally generating guidance data and sending the guidance data to a user side. By implementing the method, the Chinese rose growth characteristic matching degree can be accurately determined, so that the combination with high matching degree is screened out, the grafting success rate is greatly improved, and grafting failures caused by compatibility problems are reduced.

The utility model relates to the technical field of plant grafting, and discloses a fruit tree grafting auxiliary device which comprises a semi-ring plate and an auxiliary plate, pressure plates are arranged in the semi-ring plate and the auxiliary plate, first springs are fixedly connected between the semi-ring plate and the pressure plates and between the auxiliary plate and the pressure plates, first clamping grooves are formed in the semi-ring plate and the auxiliary plate, and the first clamping grooves and the second clamping grooves are formed in the semi-ring plate and the auxiliary plate. Son buckles are arranged in the semi-ring plate and the auxiliary plate, the side walls of the son buckles are fixedly connected into the first clamping grooves, and second clamping grooves are formed in the semi-ring plate and the auxiliary plate. According to the device, the son buckle and the mother buckle are clamped through pressure, the two semi-ring plates are closed, the internal pressure plate extrudes and fixes branches at the grafting position, the first spring has elasticity and can adapt to branches with different thicknesses, the auxiliary plate further fixes the branches outside the grafting position, the grafted branches are conveniently fixed, and the stability and the tree survival rate are improved.

The invention relates to the technical field of preparation of high-moisture-absorption warm-keeping anti-wrinkle flexible cloth, in particular to high-moisture-absorption warm-keeping anti-wrinkle flexible cloth and a preparation process thereof.According to the designed moisture-absorption skin-friendly layer, alkali decrement treatment and silane coupling agent grafting treatment are combined, and the natural antibacterial property of coffee grounds is reserved; the shape memory polymer fibers of the anti-wrinkle layer deform when the temperature is larger than or equal to the glass transition temperature, the shape is fixed after cooling, a nanometer adhesive is melted in the hot pressing process to fill gaps of a framework, and the elastic recovery rate after repeated folding is far higher than 85%. The high porosity and low heat conductivity coefficient of aerogel fibers of the warm-keeping layer are combined with the heat storage and temperature regulation functions of phase change microcapsules, so that the air permeability of the warm-keeping layer is remarkably improved; all the layers are chemically bonded through plasmas to form covalent bond combination, so that the phenomenon of layering after multiple times of water washing or bending is effectively avoided.

The invention belongs to the technical field of high polymer materials, and particularly relates to a maleic anhydride grafted polyethylene composition with high grafting rate and low gel content as well as a preparation method and application thereof. The maleic anhydride grafted polyethylene composition is prepared from raw materials such as linear low-density polyethylene, EVA (Ethylene Vinyl Acetate), r-PP (Resin-Propene Polymer), a compound initiator and MAH (Maleic Anhydride). In the maleic anhydride grafted polyethylene composition, the r-PP and the compound initiator are used as an initiation system to synergistically improve the reaction degree so as to improve the grafting rate; in addition, the synergistic initiator system reduces the dosage of a compound initiator, so that the influence of a cage shielding effect caused by excessive initiators on the gel content of the product is avoided while the cost is reduced; the grafting rate is further improved by adding a small amount of EVA. Therefore, when a product with a high grafting rate (greater than 0.9%) is obtained, the gel content is low (less than 4%), a blow-molded casting product has few crystal points, and the product also has good mechanical properties and can be better applied to the field of high-end functional adhesives.

The invention discloses a water glass-based full-life super-amphiphobic radiation refrigeration block material, which is prepared from the following raw materials in parts by weight: 1.5 to 3 parts of C-F long-chain modified micro-nano particles, 0.5 to 1.5 parts of water glass-based binder, 0.1 to 0.3 part of nano silicon dioxide sol and 0.05 to 0.16 part of curing catalyst, the C-F long-chain modified micro-nano particles are obtained by sequentially carrying out silane coupling agent grafting modification and fluorosilane grafting modification on nano particles with high sunlight reflectivity and micro particles with high sunlight emissivity. The super-amphiphobic function is converted into a three-dimensional block material from a two-dimensional coating, stress distribution optimization and interface bonding energy improvement are achieved while the ultra-low surface energy characteristic is kept, the problems of optical performance degradation and the like caused by surface pollution of the radiation refrigeration material are effectively solved, the mechanical durability of the material is essentially improved, and the service life of the radiation refrigeration material is prolonged. And the radiation refrigeration system can maintain stable performance in the whole life cycle.

The invention discloses a high-durability reflective hot-melt road marking coating and a preparation method thereof, and belongs to the technical field of coatings. The coating is prepared from the following raw materials in parts by weight: 15-25 parts of modified petroleum resin, 2-5 parts of a plasticizer, 5-15 parts of glass beads, 5-10 parts of pigment, 45-60 parts of filler, 3-8 parts of a durability enhancer and 0.5-1.5 parts of an antioxidant. The modified petroleum resin is obtained by hydrolyzing silane monomers in a specific molar ratio to prepare an epoxy-terminated organic silicon oligomer and then chemically grafting the epoxy-terminated organic silicon oligomer with petroleum resin. The durability reinforcing agent is prepared by compounding nano silicon dioxide, elastic polymer micro powder and a silane coupling agent according to the mass ratio of (1-2): (1-2): 1. Through the synergistic effect of resin modification and the composite reinforcing agent, the coating has excellent wear resistance, high adhesive force, excellent low-temperature flexibility and lasting light reflection performance, and is controllable in cost, convenient to construct and wide in application prospect.

The invention discloses a modified FeSiCr soft magnetic material, a preparation method thereof and application of the modified FeSiCr soft magnetic material in marine environment devices, and belongs to the technical field of soft magnetic materials. Comprising flaky FeSiCr soft magnetic powder, and a Ni-P alloy layer, a dopamine-quaternary ammonium salt copolymer grafting layer, a tannic acid-metal ion layer, a nano SiO2-Al2O3 layer and a polysiloxane resin-boron nitride layer which sequentially coat the FeSiCr soft magnetic powder from inside to outside, and the preparation method comprises the steps of chemical plating, grafting modification, sol-gel sintering and hot press molding. Through the synergistic effect of the five coating layers, the modified FeSiCr soft magnetic material achieves comprehensive improvement of corrosion resistance, antibacterial property, insulativity and magnetic performance in the marine environment, is suitable for marine anti-corrosion wave-absorbing coatings, high-frequency electromagnetic elements and other scenes, and has the advantages of being long-acting in service, high in environmental adaptability and the like.

The invention relates to the technical field of wire and cable insulating materials, and provides a room-temperature self-crosslinking flame-retardant insulating material and a preparation method thereof.The preparation method comprises the steps that a magnetic metal hydroxide flame retardant is prepared through a sol-gel method, and modified vinyl silane is prepared through a ring-opening polymerization reaction; the preparation method comprises the following steps: performing ordered grafting granulation on polyolefin resin, a magnetic metal hydroxide flame retardant and modified vinyl silane to prepare matrix granules; and blending the matrix granules with the catalytic granules, carrying out extrusion molding on the blended granules, and standing at room temperature to obtain the room-temperature self-crosslinking flame-retardant insulating material. According to the room-temperature self-crosslinking flame-retardant insulated cable and the preparation method thereof, the flame retardant property can be improved, the crosslinking efficiency and cost can be optimized, and the mechanical property and the insulating property can be optimized.

The application discloses a preparation method of active chitosan quaternary ammonium salt modified cellulose fabric based on a dispersion system, and belongs to the field of textile chemistry. The effective grafting of chitosan quaternary ammonium salt and nitrogen-containing heterocyclic monomers is realized by using a dispersion system, the active sites on the chitosan quaternary ammonium salt are increased, the covalent grafting effect of the active chitosan quaternary ammonium salt and the cellulose fabric is improved, the cellulose fabric is endowed with durable antibacterial function, the dyeing performance of the cellulose fabric in natural dyes and active dyes is improved, and when the cellulose fabric prepared by the method is dyed by using active dyes, the amount of neutral salt can be reduced.

The invention discloses a high and low temperature resistant polyamide cable tie and a preparation method thereof, and relates to the technical field of polyamide cable ties. The high and low temperature resistant polyamide cable tie comprises the following components in parts by weight: 40 to 60 parts of polyamide-6, 12 to 15 parts of a modifier, 5 to 15 parts of polyether-ether-ketone, 15 to 20 parts of modified glass fiber, 5 to 10 parts of a flexibilizer, 0.5 to 1 part of an antioxidant and 0.3 to 0.6 part of a lubricant. By controlling reaction conditions, lignin is prevented from being dissolved, modification grafting is carried out on the surface of the lignin, a sulfonate group, a polyether-ether-ketone chain segment, a polydimethylsiloxane chain segment and an anhydride structure are introduced, meanwhile, the rigid structure of the lignin is kept, and then the modifier is prepared. The modifier can further cooperate with polyether-ether-ketone, modified glass fibers and a flexibilizer to effectively improve the mechanical properties and high and low temperature resistance of polyamide-6.

The invention belongs to the technical field of fiber felts, and particularly relates to a preparation method of a bamboo / wood / PP fiber felt for automotive interiors and a composite material of the bamboo / wood / PP fiber felt.The bamboo / wood / PP fiber felt is formed by opening, scattering, fully mixing and carding mixed fibers composed of wood fibers and modified bamboo fibers and PP fibers to form a fiber net, and then the fiber net is needled to form a dense felt material; wherein the modified bamboo fiber is prepared by the following steps: mixing 3, 5-di-tert-butyl-4-hydroxybenzaldehyde, methyl undecyl ketone, a sodium hydroxide solution and ethanol for reaction to obtain a hindered phenol material; mixing and reacting the hindered phenol material, chloroplatinic acid and tetrahydrofuran to obtain a long-chain alkyl hindered phenol grafted material; bamboo fibers, an ethanol solution and the long-chain alkyl hindered phenol grafting material are mixed and react, and modified bamboo fibers are obtained; the ultraviolet light stability of the bamboo / wood / PP fiber felt for the automotive trim is improved, and the tensile property of the bamboo / wood / PP fiber felt for the automotive trim can be greatly enhanced.

The invention discloses a catechol side group-containing polylysine derivative as well as a preparation method and application thereof. The preparation method comprises the following steps: (1) dissolving catechol acid in an organic phase, firstly adding NHS, stirring and dissolving until the materials are uniformly mixed, then adding EDC.HCl, and stirring and reacting to obtain a catechol-NHS intermediate solution; (2) dissolving polylysine or a salt thereof in a water phase, and adjusting the pH value to 6.0-7.0 by using an alkaline solution to obtain a solution of polylysine or a salt thereof; and (3) adding the intermediate solution obtained in the step (1) into the polylysine or the salt solution thereof obtained in the step (2), and maintaining the pH value of the reaction system at 5.0-6.0 by using an alkaline solution to obtain the catechol side group-containing polylysine derivative. The preparation method is short in reaction time and mild in reaction condition, and the obtained product is high in grafting rate and high in raw material conversion rate and has a good application prospect in the aspects of tissue adhesives and the like.

The invention discloses a carbon fiber reinforced wear-resistant polyether-ether-ketone composite material and a preparation method thereof, and belongs to the technical field of polymer composite materials. According to the invention, the modified carbon fiber is obtained by one-step synergistic treatment of carbon fiber through oxidizing agent oxidation-silane grafting-nano oxide loading. In the carbon fiber reinforced wear-resistant PEEK composite material, specific modified carbon fibers are used as reinforcing fibers, so that the high-temperature performance of a PEEK matrix can be enhanced, the high-temperature wear resistance can be improved, and meanwhile, high mechanical properties are kept. The material performance synergism is excellent, and through the synergistic effect of the modified carbon fiber (enhanced interface), the nano oxide (enhanced matrix) and the inorganic lubricating material (lubrication barrier), the problem that high-temperature wear resistance and mechanical performance are difficult to consider at the same time in the prior art can be solved. In addition, the invention also has obvious cost and environmental protection advantages.

The invention belongs to the technical field of membranes, and discloses a monovalent / divalent cation selective separation membrane based on an intrinsic microporous polymer, and the preparation route of the membrane is as follows: taking an ether-free polymer synthesized by super acid catalysis as a precursor, introducing an ion exchange site into the polymer by utilizing grafting of a sulfonated monomer, and preparing the monovalent / divalent cation selective separation membrane based on the intrinsic microporous polymer. And improving the separation performance of monovalent ions / divalent ions by using an alkoxy chain graft with specific interaction on the monovalent ions, and greatly improving the mechanical strength of the membrane by using the interaction of hydrogen bonds between main and side chains, thereby finally obtaining the monovalent / divalent cation selective separation membrane. According to the present invention, the industrial production difficulty is significantly reduced by the full solvation reaction membrane synthesis route, the selectivity of the prepared membrane material is superior to the selectivity of the commercial membrane of the same type, the extremely high mechanical strength is maintained, and the large-scale production and application potential is provided.