794 results about "Grafting" patented technology

The invention relates to the technical field of high polymer material preparation, and discloses a bamboo fiber graft modified full-biodegradable composite membrane material preparation process which comprises the following steps: firstly, performing hot mixing and cooling on dried bamboo fiber powder, anhydrous citric acid, choline chloride, activated zinc oxide and pentaerythritol to prepare a bamboo fiber modified premix; then mixing the biodegradable polyester resin with the premix; adding the mixture into an extruder, injecting epoxidized soybean oil into a barrel through a liquid metering device, and performing melt extrusion granulation under a vacuum exhaust condition; and finally carrying out blow molding to form the film. Through in-situ reaction extrusion of multi-component synergism, surface grafting of bamboo fibers, chain extension of a polyester matrix and interface chemical bonding of the bamboo fibers and the polyester matrix are achieved, interface compatibility is effectively improved, degradation of the material in the processing process is inhibited, and the mechanical property and thermal stability of the composite film material are remarkably improved; the process is efficient and environment-friendly, and the cost is controllable.

The invention discloses a preparation method of a natural fiber prepreg with an improved impregnation effect, and relates to the technical field of composite material preparation, the method comprises the following steps: carrying out synergistic modification through fiber surface plasma activation and silane grafting, and combining a gradient pressure-temperature coupling impregnation system and ultrasonic-assisted permeation to prepare the natural fiber prepreg with the improved impregnation effect. And gradient filling and interface chemical bonding strengthening of the resin in the fiber bundle are realized. The core process comprises the following steps: pretreating fibers to improve surface energy and roughness, introducing a reactive diluent and a block copolymer into a resin system to regulate and control viscosity and transport capacity, constructing a pressure gradient by a multi-stage compression roller to drive resin to permeate into a bundle core, promoting uniform impregnation by infrared temperature control and ultrasonic cavitation, and finally obtaining uniform resin distribution and porosity lt. The interlayer shear strength is gt; and the high-performance prepreg is stable in batch under the pressure of 45 MPa. Reliable technical support and process guarantee are provided for large-scale engineering application of the high-performance natural fiber composite material.

The invention discloses a light telegraph pole cement material and a preparation method thereof, and relates to the technical field of cement concrete. The method comprises the following steps: firstly, carrying out acid pickling, silane coupling agent grafting and nanoparticle vacuum impregnation treatment on shale ceramsite to obtain modified light ceramsite; the preparation method comprises the following steps: ultrasonically dispersing graphene oxide, compounding with Portland cement clinker and modified fly ash, and reacting with epoxy resin emulsion, a curing agent and a silane coupling agent to prepare organic-inorganic composite modified cement; the bamboo skeleton is subjected to silane coupling agent pretreatment to obtain a modified skeleton; then, mixing composite cement, an additive and water into slurry, adding the modified ceramsite and aggregate, and performing high-speed stirring and ultrasonic dispersion to form homogeneous concrete slurry; and finally, putting the modified bamboo skeleton into a mold, injecting the slurry, and performing centrifugal forming, steam curing and natural curing to obtain the cement material. The prepared lightweight telegraph pole cement material has excellent mechanical strength.

The invention relates to the technical field of fibers, and discloses an antistatic warm-keeping fiber and a preparation method thereof. The preparation method comprises the following steps: carrying out graft modification on a far infrared material graphene oxide through functionalized POSS, introducing the modified graphene oxide and an ionic liquid into polypropylene, carrying out melt grafting to prepare an antistatic polypropylene master batch, introducing the master batch into polypropylene slices for spinning, and carrying out a synergistic antistatic effect of an inorganic antistatic agent graphene and an organic antistatic agent ionic liquid to prepare a composite material. The prepared fiber has antistatic performance and far infrared heating performance, and meanwhile, the POSS structure with excellent thermal stability is introduced, so that the heat resistance of the fiber is further improved.

The invention relates to the technical field of pavement materials, in particular to a solid waste-based cementing material stable coal-based solid waste road base material and a preparation method thereof. According to the material, secondary modified regenerated coarse and fine aggregate is used as a framework, coal gangue powder and granulated blast furnace slag micro powder are matched, and two-step engineering of dopamine / double-amino-terminated polyethylene glycol co-deposition grafting and high-modulus silicate pre-coating is adopted, so that the synergistic improvement of the surface wettability and the interface density of the aggregate is realized. The system is cooperated with low-modulus excitation liquid and polypropylene fibers, and the mixing uniformity of the material and the quality of an interface transition area are optimized through a thin-pulp stone-wrapping and densification segmentation process. The material gives consideration to high resilience modulus, rut resistance and durability, significantly reduces the problems of high water absorption, weak interface, early cracks and the like of the recycled aggregate, is adaptive to a traditional road construction window, and has good application prospects.

The invention relates to the technical field of aerogel, in particular to flexible flame-retardant aerogel and a preparation method thereof.The flexible flame-retardant aerogel is prepared from modified graphene, modified polyvinyl alcohol, silver nanowires, phytic acid and epoxy resin E-51; the furan group is introduced into the aerogel through the modified graphene, the furan group and the maleimide group are subjected to a D-A reaction, an adhesive is prevented from being used when the aerogel is bonded with a screen backboard, the D-A reaction is reversible, and lossless reworking can be realized. PVA and epoxy resin E-51 are added together, so that the heat resistance and mechanical strength of the material are improved. PVA is grafted with a large-steric-hindrance amine group, weak interaction with a furan group is generated, side reaction with an epoxy group of epoxy resin E-51 is avoided, and when aerogel is bonded to an OLED screen backboard, the protective layer is reversibly released, so that D-A reaction can be smoothly carried out. The hydrophobic treatment of the modified graphene and the modified grafting of the polyethylene to the mPEG can effectively improve the agglomeration of the modified graphene and ensure the uniform dispersion of the modified graphene.

The invention discloses a crown ether grafted polyarylether sulfone ion separation membrane as well as a preparation method and application thereof, and belongs to the technical field of ion separation membranes, collaborative optimization is realized through crown ether accurate grafting and ultrathin ordered membrane formation: a main chain of polyarylether sulfone is grafted with 4 '-aminobenzo-12-crown-4 to form an inherent channel adapted to Li, and the specific surface area of the main chain is increased; the ultrathin film is prepared by a water surface spreading method, and the ion transmission path is shortened. Finally, in a LiCl / MgCl system, Liion flux has high selectivity, high permeation-high selectivity cooperation is preliminarily realized, the chemical synthesis step can be amplified to a kilogram level, and after a DPAES-g-CE / dichloromethane solution is dropwise added to the water surface, the DPAES-g-CE / dichloromethane solution is rapidly spread to form a film without precise equipment; the raw materials are industrial-grade monomers and have no toxic residues, the membrane can be recycled and reused through dichloromethane, the equipment cost is reduced by about 90%, and industrialization is easy; the main chain of the polyaryl ether sulfone is high in rigidity and resistant to high temperature and chemical corrosion; crown ether grafting avoids molecular chain agglomeration, and the swelling rate is far lower than that of a traditional sulfonated membrane.

The invention relates to the technical field of preparation of high-moisture-absorption warm-keeping anti-wrinkle flexible cloth, in particular to high-moisture-absorption warm-keeping anti-wrinkle flexible cloth and a preparation process thereof.According to the designed moisture-absorption skin-friendly layer, alkali decrement treatment and silane coupling agent grafting treatment are combined, and the natural antibacterial property of coffee grounds is reserved; the shape memory polymer fibers of the anti-wrinkle layer deform when the temperature is larger than or equal to the glass transition temperature, the shape is fixed after cooling, a nanometer adhesive is melted in the hot pressing process to fill gaps of a framework, and the elastic recovery rate after repeated folding is far higher than 85%. The high porosity and low heat conductivity coefficient of aerogel fibers of the warm-keeping layer are combined with the heat storage and temperature regulation functions of phase change microcapsules, so that the air permeability of the warm-keeping layer is remarkably improved; all the layers are chemically bonded through plasmas to form covalent bond combination, so that the phenomenon of layering after multiple times of water washing or bending is effectively avoided.

The invention discloses a high-durability reflective hot-melt road marking coating and a preparation method thereof, and belongs to the technical field of coatings. The coating is prepared from the following raw materials in parts by weight: 15-25 parts of modified petroleum resin, 2-5 parts of a plasticizer, 5-15 parts of glass beads, 5-10 parts of pigment, 45-60 parts of filler, 3-8 parts of a durability enhancer and 0.5-1.5 parts of an antioxidant. The modified petroleum resin is obtained by hydrolyzing silane monomers in a specific molar ratio to prepare an epoxy-terminated organic silicon oligomer and then chemically grafting the epoxy-terminated organic silicon oligomer with petroleum resin. The durability reinforcing agent is prepared by compounding nano silicon dioxide, elastic polymer micro powder and a silane coupling agent according to the mass ratio of (1-2): (1-2): 1. Through the synergistic effect of resin modification and the composite reinforcing agent, the coating has excellent wear resistance, high adhesive force, excellent low-temperature flexibility and lasting light reflection performance, and is controllable in cost, convenient to construct and wide in application prospect.

The invention discloses a catechol side group-containing polylysine derivative as well as a preparation method and application thereof. The preparation method comprises the following steps: (1) dissolving catechol acid in an organic phase, firstly adding NHS, stirring and dissolving until the materials are uniformly mixed, then adding EDC.HCl, and stirring and reacting to obtain a catechol-NHS intermediate solution; (2) dissolving polylysine or a salt thereof in a water phase, and adjusting the pH value to 6.0-7.0 by using an alkaline solution to obtain a solution of polylysine or a salt thereof; and (3) adding the intermediate solution obtained in the step (1) into the polylysine or the salt solution thereof obtained in the step (2), and maintaining the pH value of the reaction system at 5.0-6.0 by using an alkaline solution to obtain the catechol side group-containing polylysine derivative. The preparation method is short in reaction time and mild in reaction condition, and the obtained product is high in grafting rate and high in raw material conversion rate and has a good application prospect in the aspects of tissue adhesives and the like.

The invention discloses a carbon fiber reinforced wear-resistant polyether-ether-ketone composite material and a preparation method thereof, and belongs to the technical field of polymer composite materials. According to the invention, the modified carbon fiber is obtained by one-step synergistic treatment of carbon fiber through oxidizing agent oxidation-silane grafting-nano oxide loading. In the carbon fiber reinforced wear-resistant PEEK composite material, specific modified carbon fibers are used as reinforcing fibers, so that the high-temperature performance of a PEEK matrix can be enhanced, the high-temperature wear resistance can be improved, and meanwhile, high mechanical properties are kept. The material performance synergism is excellent, and through the synergistic effect of the modified carbon fiber (enhanced interface), the nano oxide (enhanced matrix) and the inorganic lubricating material (lubrication barrier), the problem that high-temperature wear resistance and mechanical performance are difficult to consider at the same time in the prior art can be solved. In addition, the invention also has obvious cost and environmental protection advantages.

The invention belongs to the technical field of membranes, and discloses a monovalent / divalent cation selective separation membrane based on an intrinsic microporous polymer, and the preparation route of the membrane is as follows: taking an ether-free polymer synthesized by super acid catalysis as a precursor, introducing an ion exchange site into the polymer by utilizing grafting of a sulfonated monomer, and preparing the monovalent / divalent cation selective separation membrane based on the intrinsic microporous polymer. And improving the separation performance of monovalent ions / divalent ions by using an alkoxy chain graft with specific interaction on the monovalent ions, and greatly improving the mechanical strength of the membrane by using the interaction of hydrogen bonds between main and side chains, thereby finally obtaining the monovalent / divalent cation selective separation membrane. According to the present invention, the industrial production difficulty is significantly reduced by the full solvation reaction membrane synthesis route, the selectivity of the prepared membrane material is superior to the selectivity of the commercial membrane of the same type, the extremely high mechanical strength is maintained, and the large-scale production and application potential is provided.

The invention provides a low-dielectric high-toughness alkali-free spherical glass powder modified copper-clad plate. The low-dielectric high-toughness alkali-free spherical glass powder modified copper-clad plate consists of a composite resin matrix, modified alkali-free spherical glass powder, a synergistic functional filler, an auxiliary agent, a reinforced base material and a conductive layer, the modified alkali-free spherical glass powder is subjected to gradient treatment of plasma activation, silane grafting and organic silicon coating, the particle size of the modified alkali-free spherical glass powder is 0.5-2 microns, the modified alkali-free spherical glass powder accounts for 10-20 parts by weight in the raw materials, and the content of organic functional groups on the surface of the modified alkali-free spherical glass powder is larger than or equal to 1.6 mmol / g.The invention further provides a preparation method of the low-dielectric high-toughness alkali-free spherical glass powder modified copper-clad plate. Compared with the prior art, the preparation method has the following beneficial effects that a double-resin blending and elastomer toughening system is constructed through a modification process of filler activation, silane grafting and organic silicon coating, and the technical bottleneck is solved in combination with an interface compatibility technology.

The present application relates to the technical field of resin coating, and particularly relates to a preparation method of modified acrylic resin and application thereof, which comprises the following steps: firstly, hydrolysis and condensation of multiple organosilicon alkoxyl monomers, then grafting with epoxy resin to obtain organosilicon-epoxy resin containing vinyl; subsequently, under the protection of nitrogen, a premixed solution of styrene, multiple acrylate monomers, initiator and solvent is added dropwise into a reaction kettle containing the resin, and after polymerization by staged heat preservation, parameters are adjusted to obtain the modified acrylic resin. The resin has a ternary hybrid structure of acrylic acid, epoxy and organosilicon through grafting, condensation and copolymerization, and has good film forming property, high adhesion, excellent high temperature resistance and flexibility. The coating prepared by using the resin can realize normal temperature self-drying, and the coating layer is dense and smooth, has strong adhesion, good corrosion resistance and impact resistance, and can withstand high temperature and cold cycle, and is suitable for protection of parts which need long-term high temperature and corrosion resistance.

The invention discloses a preparation process of carboxylated shell-based activated carbon for organic matter adsorption, and particularly relates to the technical field of adsorption materials, and the preparation process comprises the following steps: mixing coconut shell powder and walnut shell powder, crushing, and loading potassium hydroxide in stages in a gradient manner; carrying out two-stage microwave activation in an inert atmosphere, namely low-temperature pre-activation in the first stage and high-temperature activation in the second stage, and introducing carbon dioxide; the activated product, phosphoric acid, a laccase-peroxidase complex enzyme preparation and a buffer solution are subjected to ultrasonic synergistic modification, and then a weak acid reaction is maintained through dynamic pH regulation and control; and finally, performing graded washing and gradient drying to obtain a finished product. According to the method, high-density carboxyl grafting and graded pore construction are synchronously realized under mild conditions through a synergistic effect of directional catalysis of biological enzyme and dynamic regulation of microwave, so that the problems of structural damage caused by strong acid corrosion, pore imbalance caused by fixed parameters and stability reduction caused by insufficient post-treatment in a traditional process are solved; the adsorption performance and the regeneration cycle performance of the material are also obviously improved.

The invention discloses a method for preparing radiation-resistant polystyrene resin and controlling the aperture of the radiation-resistant polystyrene resin. The preparation method of the radiation-resistant polystyrene resin comprises the following steps: fully dissolving polyvinyl alcohol in deionized water, adding an organic phase containing styrene and the like into the deionized water, uniformly stirring and mixing, heating and carrying out a synthetic reaction to prepare non-porous matrix microspheres, and carrying out pore-forming and surface modification treatment on the matrix microspheres. Compared with the prior art, rapid preparation of the radiation-resistant porous mass transfer resin is achieved through two steps, the high grafting rate is kept through accurate control over a cross-linked skeleton, meanwhile, radiation resistance is considered, and the method has the advantages that the process is simple, the cost is low, the particle size is controllable and narrow in distribution, relevant parameters are easy to standardize, and the method is suitable for industrial amplification.

The invention discloses a bamboo shoot pulp enzymolysis and bamboo shoot composite flavor seasoning egg preparation technology, and belongs to the technical field of seasoning egg preparation. The preparation process is used for solving the technical problem that the flavor and taste of the seasoning eggs need to be further improved in the prior art, and comprises the following steps: soaking pretreated eggs in flavor seasoning juice for 10-12 hours, and performing post-treatment to obtain the flavored seasoning eggs. Bamboo cellulose modification and bamboo shoot enzymolysis technologies are combined, the hydrophilicity and flavor carrying performance of cellulose are improved through oxidation reduction and glycerol and malic acid grafting, sauce forms stable colloid, the seepage force is enhanced, enzymolysis bamboo shoot pulp releases small-molecule flavoring substances, natural fresh fragrance is given, and the flavor of the bamboo shoots is improved by being matched with vacuum and long-time impregnation. The seasoned eggs are elastic and moist in taste and rich in flavor, and the overall quality is remarkably improved.

The invention relates to the technical field of composite materials, in particular to a carbon fiber reinforced nylon composite material and a preparation method thereof. The carbon fiber reinforced nylon composite material is prepared from the following raw materials in parts by weight: 60 to 90 parts of nylon matrix resin, 10 to 40 parts of modified carbon fiber, 0.1 to 0.5 part of release agent, 0.1 to 0.5 part of antioxidant and 0.2 to 1.0 part of chain extender, the modified carbon fiber is obtained by performing high-energy electron irradiation on carbon fiber. Through high-energy electron radiation, free radicals are formed on the surfaces of the carbon fibers, react with oxygen in air to form polar groups, and react with polar groups in nylon and a chain extender to form chemical grafting, so that the mechanical conductivity of an interface is enhanced, and the mechanical property of the composite material is improved.

The invention belongs to the technical field of biomedical materials, and particularly relates to a poly-4-methyl-1-pentene (PMP) gas-blood exchange membrane for an extracorporeal membrane oxygenation (ECMO) system, which realizes a long-acting antithrombotic function through a bionic interface construction technology. The invention aims to provide a bionic antithrombotic PMP gas-blood exchange membrane based on zwitter-ion gradient grafting, and through material and process innovation, the following problems existing in a traditional ECMO gas-blood exchange membrane: an antithrombotic coating is easy to fall off, and the long-term effect is insufficient; the risk of blood injury caused by dependence on heparin or anticoagulants; and the surface modification process destroys the membrane pore structure and air permeability.

The invention discloses a modified inorganic solid electrolyte filler as well as a preparation method and application thereof. Belongs to the technical field of solid-state lithium metal batteries. The modified inorganic solid-state electrolyte filler comprises inorganic solid-state electrolyte powder and an organic-inorganic hybrid grafting layer grafted on the surface of the powder, the inorganic solid electrolyte powder is one or more of oxide, sulfide and halide; and the organic-inorganic hybrid grafting layer is formed by bonding maleimide-polyethylene glycol-silane (Mal-PEG-silane) with the surface of the filler and then covalently copolymerizing the bonded maleimide-polyethylene glycol-silane and the surface of the filler with polyethylene glycol diacrylate (PEGDA). According to the modified inorganic solid electrolyte filler disclosed by the invention, a stable organic-inorganic hybrid structure is constructed through surface grafting and copolymerization, so that the dispersity of the filler in a polymer matrix can be remarkably enhanced, and the organic-inorganic interface compatibility and stability are improved; therefore, the ionic conductivity, the mechanical strength and the electrochemical cycle performance of the composite solid electrolyte are improved.

The invention relates to the technical field of immunochromatography, in particular to time-resolved fluorescent microspheres, a preparation method and application of the time-resolved fluorescent microspheres in PSP / CRP / MxA quantitative detection immunochromatography test strip, and the preparation method of the time-resolved fluorescent microspheres comprises the following steps: 1) preparing surface aminated polystyrene microspheres; (2) carrying out glutaraldehyde crosslinking and 1, 10-phenanthroline-5-amino combination; 3) grafting a rare earth fluorescent dye on the surface; and 4) coating a polymer shell layer and modifying carboxyl. According to the invention, through a dual fixation strategy of surface grafting and polymer coating, the time-resolved fluorescent dye is confined to a functional region between the surface of the microsphere and a polymer shell layer, diffusion and leakage of dye molecules to the external environment are blocked, and the problem of dye shedding of traditional fluorescent microspheres is solved; the polymer shell layer can effectively isolate external ultraviolet light, oxygen and other corrosive factors, reduce photooxidative degradation and non-radiative transition loss of fluorescent molecules, and improve the light stability and fluorescent lifetime of the fluorescent molecules.

The invention relates to the technical field of adhesives, and particularly discloses an adhesive for repairing a glass fiber reinforced plastic pipeline and a preparation process. The invention relates to an adhesive for repairing a glass fiber reinforced plastic pipeline. The adhesive is prepared from the following raw materials: modified bisphenol A epoxy resin, a curing agent, a glass fiber reinforced filler, a silane coupling agent, phenyl glycidyl ether, hydroxyl-terminated nitrile rubber and an antioxidant 1076, the modified bisphenol A type epoxy resin is prepared by grafting and modifying bisphenol A type epoxy resin through amino-terminated polyether; the glass fiber reinforced filler is prepared from hydroxylated glass fibers and a graphene-carbon nanotube compound through covalent grafting. The adhesive can be used for emergency repair of glass fiber reinforced plastic pipelines, has the advantages of high low-temperature curing speed, high bonding strength and good durability, can effectively avoid cracking and leakage of repaired parts, and is adaptive to low-temperature and high-pressure complex repair working conditions. The preparation process is simple and convenient to operate and high in controllability, the adhesive with uniform performance can be stably prepared, and the repair efficiency and repair quality are guaranteed.

The invention discloses a stationary phase of a novel zwitterionic monomer containing a multi-charge structure as well as a preparation method and application of the stationary phase, and belongs to the technical field of hydrophilic interaction chromatography (HILIC) stationary phases. According to the method, multi-charge zwitterions are used as hydrophilic monomers, the multi-charge structure of the multi-charge zwitterions endows the monomers with higher hydrophilic performance, and the multi-charge zwitterions are immobilized on the surface of a matrix by utilizing an active free radical polymerization method, so that a series of novel super-hydrophilic HILIC stationary phases are finally prepared. The multi-charge zwitterionic monomer adopted by the invention not only has better hydrophilic performance and higher charge density, but also can efficiently, simply and conveniently realize matrix surface grafting and modification. The developed stationary phase is suitable for HILIC column chromatography separation analysis, and the HILIC chromatographic performance can be greatly improved; the method can also be applied to the fields of biological sample pretreatment, material science, marker clinical diagnosis and the like, and has high economic and social values.

The invention relates to the technical field of papermaking and food packaging materials, in particular to a preparation method of full-degradable plastic-substituted high-strength food packaging paper. Preparing a fiber layer by taking plant fiber as a base material; the preparation method comprises the following steps: grafting a methyl methacrylate-butyl acrylate block copolymer on nano-cellulose through an atom transfer radical polymerization technology to prepare enhanced nano-cellulose; dialdehyde starch rich in aldehyde groups and chitosan are subjected to a Schiff base reaction to form a dynamic cross-linked network, polylactic acid microspheres modified by beta-cyclodextrin are introduced to serve as supramolecular enhancement units, and functional coating liquid is prepared; and finally, coating the functional coating liquid on the fiber layer, and drying, cross-linking and curing to obtain a finished product. Through cooperation of chemical grafting, dynamic covalent bonds and supramolecular action, the packaging paper is endowed with extremely high strength and toughness and excellent oil and moisture resistance and heat sealability, meanwhile, it is ensured that the packaging paper can be completely biodegraded in the natural environment, and functional replacement of traditional plastic packaging is successfully achieved.

The invention relates to the technical field of medical protection materials, and discloses an anti-allergy skin-friendly operating kit and a preparation technology, and the composite material of the operating kit comprises the following components by mass: 40-70 parts of cellulose-based non-woven fabric; 1 to 10 parts of polymethacryloyloxyethyl phosphorylcholine which is covalently grafted to the cellulose-based non-woven fabric; 20 to 50 parts of polylactic acid-quaternary ammonium salt copolymer; 5 to 15 parts of a polyurethane hot melt adhesive; the method comprises the following steps: grafting a PMPC molecular brush on the surface of a cellulose-based non-woven fabric to obtain a skin-friendly layer; carrying out coaxial electrostatic spinning and solvent treatment on the polylactic acid-quaternary ammonium salt copolymer to prepare a hollow nanofiber barrier layer; and finally hot-pressing and compounding the two layers through a polyurethane hot-melt adhesive. According to the invention, allergy is solved through surface grafting; the toxicity is avoided by using an intrinsic antibacterial polymer; the hollow fibers and the net film are compounded, so that the contradiction between water resistance and breathability is overcome, and the biological safety and comfort of the material are improved.

The invention belongs to the technical field of nano materials and environment-friendly functional coatings, and discloses a preparation method and application of a lignin-based super-hydrophobic coating. The method comprises the steps that lignin is pretreated with ethylene carbonate to break steric hindrance and improve the grafting rate, then hexadecyl trimethoxy silane is added for grafting to form a hydrophobic chain, and surface energy is reduced; then adding silicon dioxide and N, N-dimethylformamide, carrying out ultrasonic dispersion to synergistically construct a micro-nano coarse structure, spraying the micro-nano coarse structure on a base material by using a spraying method, and putting the base material into a drying oven for curing, so as to obtain the lignin-based super-hydrophobic coating material. According to the method disclosed by the invention, a high-activity epoxy group is grafted on a lignin skeleton through ethylene carbonate pretreatment, so that steric hindrance in a three-dimensional space is broken, and dense anchor points are provided for a subsequent hydrophobic chain; then cocondensing with hexadecyl trimethoxy silane to form an alkyl-siloxane double network, and cooperating with nano silicon dioxide to construct micro-nano double roughness, so that a stable super-hydrophobic core under a fluorine-free condition is realized, and the technical route is simple and efficient.

The invention belongs to the technical field of cable materials and preparation thereof, and discloses a high-melt-index fire-resistant cable body and a preparation method thereof.The cable body takes modified polyolefin as a matrix, and through in-situ grafting of phosphorus-containing and nitrogen-containing functional monomers, the melt fluidity of a polymer is remarkably improved; and the surface-functionalized nano-micron synergistic composite flame-retardant filler is introduced, so that efficient dispersion and synergistic interaction are realized. During preparation, the modified matrix and the composite filler are integrally extruded and molded in a twin-screw extruder to obtain a cable body with excellent fire-resistant retentivity and mechanical and electrical properties; compared with the prior art, the processing performance and the fire resistance of the material are both considered, the preparation process is simple and convenient, the energy consumption can be greatly reduced, and the fire resistance requirements in building and industrial scenes are met.

The invention belongs to the technical field of petrochemical anticorrosion, and provides a multifunctional water-soluble corrosion inhibitor for an oil refining device and a preparation method of the multifunctional water-soluble corrosion inhibitor, and the corrosion inhibitor is a functionalized grafted copolymer obtained by a ring-opening reaction of a succinimide ring on a polysuccinimide intermediate and a plurality of amino-containing compounds; the amino-containing compound at least comprises gemini imidazoline quaternary ammonium salt with a corrosion inhibition function; a polyaspartic acid chain segment precursor with scale inhibition and dispersion functions; the organic amine compound has targeted chelating and pH buffering functions and contains sulfonic acid groups and carboxyl groups; according to the invention, double-anchored gemini imidazoline quaternary ammonium salt is taken as a corrosion inhibition core, and a polysuccinimide ring-opening grafting process is combined, so that chain segments with corrosion inhibition, scale inhibition, targeted buffering and temperature-sensitive self-repairing functions are covalently integrated into a same polymer main chain, and multi-functional efficient protection of a single agent in an oil refining device water phase system is realized.

The invention discloses a full-biodegradable bag and a preparation method thereof in the technical field of biodegradable materials.According to the full-biodegradable bag, polylactic acid and poly (butylene adipate-co-terephthalate) serve as matrixes, and performance optimization is achieved by adding a specially-made nanofiber interpenetrating network compatibilizer and a star-shaped structure bio-based plasticizer; wherein the nanofiber interpenetrating network compatibilizer is prepared by grafting polylactic acid and poly (butylene adipate-co-terephthalate) chain segments on cellulose nanofibers through an atom transfer radical polymerization technology, and the star-shaped structure bio-based plasticizer is prepared through ring opening polymerization and melt grafting technologies. In addition, the formula also comprises a maleimide modified lignin filler, an ethylene bis stearamide lubricant and an antioxidant. Through the synergistic effect of the two specially-made modified compounds, the compatibility of all the components is remarkably improved, the preparation process is simple and reliable and suitable for industrial production, and the problem of white pollution of traditional plastic products can be effectively solved.

The invention belongs to the field of avocado cultivation, and discloses an efficient cultivation method for reducing avocado root rot, which comprises the following steps: planting 3-5 different varieties of avocado seedlings together according to the plant spacing of 1-1.5 m; a high-quality material is used as a main cultivar, other plants are pollinizers, and trunks can be cut when the plants grow to 60 cm; when lateral branches intersect, high-altitude grafting can be conducted, and binding type cultivation is conducted after healing. According to the method, a multi-tree binding high-position grafting technology is adopted, each tree can be reinforced, typhoon prevention and root rot reduction are achieved, the proportion of varieties in binding is well matched, the pollination and fertilization probability is improved, and the purposes of high yield and stable yield are achieved.