28169results about "Process efficiency improvement" patented technology

Processes for extracting lithium from a clay mineral and compositions thereof are described. The extraction process includes providing a clay mineral comprising lithium, mixing a cation source with the clay mineral, performing a high-energy mill of the clay mineral, and performing a liquid leach to obtain a lithium rich leach solution.

The invention provides lithium and aluminum hydroxyfluoride extraction equipment and a low-grade cathode carbon block recovery process, and relates to the technical field of metal recycling, the lithium and aluminum hydroxyfluoride extraction equipment comprises a bracket, a tank body, a mounting plate, a driving mechanism, a reciprocating mechanism, a water washing liquid discharging mechanism and an acid leaching liquid discharging mechanism; the tank body is installed in the support, a top plate is installed at the top end of the tank body through bolts, and a supporting frame is installed on the upper surface of the top plate through bolts. According to the scheme, a layer of pickle liquor is covered and injected after water washing liquid enters, so that the two extracting solutions can be added in a laminated manner, and the water washing liquid and the pickle liquor are quantitatively added in the laminated adding process, so that layered mixing is realized in the adding process of the device, and the efficiency of the device is improved. According to the device, the subsequent stirring time can be shortened, electric power is saved, meanwhile, it is guaranteed that two kinds of liquid are mixed more sufficiently and stably, and meanwhile the internal alkaline balance can be guaranteed through a stacked adding mode.

The invention relates to a high-strength complex-phase hot-rolled wire rod for a 2100MPa-grade stranded wire and a manufacturing method of the high-strength complex-phase hot-rolled wire rod, after a C-Si-Mn-Cr-Mo high-carbon component system is rolled and spun into a wire rod, the wire rod is subjected to online molten salt strong quenching isothermal treatment, so that the wire rod is firstly subjected to front-section molten salt treatment and is cooled at a cooling speed of greater than or equal to 33 DEG C / s, and enters a bainite phase region from an austenite state; the method comprises the following steps: firstly, carrying out first-stage molten salt treatment to promote transformation of austenite into bainite, then carrying out later-stage molten salt treatment to form a structure mainly comprising bainite, carrying out isothermal tempering on the structure, reserving part of untransformed retained austenite, and finally, carrying out roller way slow cooling to promote transformation of the untransformed retained austenite into martensite, and carrying out tempering, the microstructure of the hot-rolled wire rod comprises a complex-phase structure composed of tempered bainite and tempered martensite, the tensile strength of the hot-rolled wire rod can reach 1435-1485 MPa, the percentage reduction of area of the hot-rolled wire rod is 31%-36%, off-line heat treatment of follow-up machining is avoided, and the risk of wire breakage is reduced.

The invention discloses a method for manufacturing 7072 alloy high-performance air conditioner foil in a low-carbon, efficient and short-process mode, and relates to the technical field of aluminum foil machining. S2, continuous casting and rolling; s3, cold foil rolling; s4, finished product annealing; and S5, checking and packaging. Through component adjustment, iron and silicon alloy elements are controlled at the lower limit of the national standard, generation of coarse aluminum-iron-silicon phases is reduced, and low ductility caused by coarse grains after finished product annealing is avoided; in the cold foil rolling process, indexes of a working roll and rolling oil are adjusted, process parameters are optimized, the blank is directly rolled into a finished product, the direct rolling process is beneficial to improving the mechanical property of the finished product, and punching production of downstream customers is facilitated; and after triple continuous rolling is finished, subsequent cold foil rolling continuous rolling is rapidly arranged, deformation heat generated by triple continuous rolling and rolling of each pass is fully utilized, and large-machining-rate rolling of each pass is achieved.

The invention relates to a hot-rolled wire rod for a 2260MPa-grade stranded wire and a manufacturing method of the hot-rolled wire rod, after the high-carbon component design of C-Si-Mn-Cr-Mo-Nb-Al is adopted for rolling and spinning to form the wire rod, online molten salt isothermal toughening treatment is carried out, so that the wire rod is firstly subjected to front-section molten salt treatment and is rapidly cooled, and enters a sorbite phase region from an austenite state to form a structure taking a sorbite structure as a main structure; and then carrying out rear-section molten salt treatment, reducing the circulation volume of molten salt, promoting the unconverted retained austenite to be continuously converted into sorbite, carrying out isothermal tempering, promoting fusing of a part of sorbite lamellar layers, and finally carrying out slow cooling through a roller way, so as to prepare the hot-rolled wire rod of which the microscopic structure comprises a mixed structure consisting of tempered sorbite, ferrite and fused sorbite, the tensile strength can reach 1534-1584 MPa, the percentage reduction of area can reach 33%-38%, and the alloy can be used in the application fields of manufacturing 2260 MPa grade stranded wires and the like without additional heat treatment procedures.

The invention belongs to the technical field of non-oriented electrical steel manufacturing, and relates to a method for producing non-oriented silicon steel based on thin-strip cast rolling. The low-silicon and aluminum-free component design is adopted, the hot-rolled thin substrate is directly obtained through thin strip cast rolling, casting blank continuous casting and casting blank heating are omitted, the hot rolling reduction is greatly reduced, it is avoided that unfavorable textures of alpha and gamma components in the finished non-oriented silicon steel are remarkably improved, and the high magnetic induction of the finished product is guaranteed; after acid pickling and cold rolling, grain growth is promoted by means of high-temperature cover annealing, and low iron loss of a finished product is guaranteed; the high-magnetic-induction low-iron-loss non-oriented silicon steel with the thickness specification of 0.50 mm is obtained, the grain size of a finished product is 80-100 microns, the iron loss P1.5 / 50 is smaller than or equal to 4.0 W / kg, and the magnetic induction B5000 is larger than or equal to 1.76 T.

The invention belongs to the field of metal materials, and particularly relates to a high-strength hot-rolled pickled steel plate for an automobile chassis and a production method thereof. The steel plate is mainly suitable for manufacturing automobile chassis structural parts. The steel comprises the following chemical components: C, Si, Mn, Al, V, Ni, Cu, Cr, Pt and Y, P is limited to be less than or equal to 0.015%, S is limited to be less than or equal to 0.005%, N is limited to be less than or equal to 0.006%, and the balance is Fe and inevitable impurities. The yield strength of the steel plate ranges from 498 MPa to 552 MPa, the tensile strength ranges from 608 MPa to 643 MPa, the transverse elongation A ranges from 33% to 38%, the steel plate is qualified after transverse cold bending by 180 degrees D = a, the surface quality is good, oxide scale stripes and chromatic aberration defects are avoided, the surface roughness Ra ranges from 1.10 micrometers to 1.35 micrometers, and the steel plate has excellent corrosion resistance.

The invention discloses a high aspect ratio micropore pulse abrupt change current copper filling method and system, and belongs to the technical field of printed circuit board manufacturing, and the method comprises the steps: obtaining micropore structure parameters, and generating a gradient pulse abrupt change current waveform; monitoring a deposition thickness parameter of the orifice of the micropore in real time, and when the deposition thickness parameter exceeds a preset thickness threshold value, activating the reverse peak clipping pulse group; generating a resonant composite sound field in the electroplating bath; detecting the concentration distribution of the additive in the micropores in real time, and generating a dynamic adjusting instruction according to the concentration distribution of the additive; the independent injection rate of the accelerator and the inhibitor is controlled according to the dynamic adjusting instruction; and based on the gradient pulse abrupt change current waveform, the resonant type composite sound field and the dynamic adjusting instruction, the copper filling process is executed till the target deposition parameters are achieved. According to the method, a multi-field coupling mechanism of gradient pulse dynamic peak clipping, composite sound field synergistic mass transfer and additive concentration real-time regulation and control is adopted, and defect-free high-reliability copper filling can be achieved.

The invention relates to the technical field of aluminum foil processing, in particular to a method for producing high-stability 3102 alloy air-conditioning foil in a short process, which comprises the following steps of: smelting, continuously casting and continuously rolling an aluminum alloy raw material to obtain a strip, directly trimming the strip, rolling the strip on a cold rolling unit, preparing a cold-rolled coil with the thickness of 0.15-0.2 mm after three-pass rolling, rolling the cold-rolled coil by an aluminum foil rolling mill, and rolling the cold-rolled coil by an aluminum foil rolling mill to obtain the high-stability 3102 alloy air-conditioning foil. The tensile strength of the aluminum foil finished product is 135-139 Mpa, the ductility is larger than or equal to 19%, and the cupping is larger than or equal to 5.9 mm. The aluminum foil finished product is suitable in tensile strength, small in fluctuation range, higher in ductility and cupping value, capable of better meeting the use requirements of air conditioner foil, capable of guaranteeing the product quality and meanwhile capable of improving the product quality. According to the method, the production process is greatly shortened, the production cost is reduced, and the production efficiency is improved.

The invention discloses a 340MPa grade P-containing hot-dip galvanized iron alloy high-strength IF steel, the chemical composition of which is as follows by weight: C: ≤0.003%, Si: ≤0.03%, Mn: 0.35-0.65%, P: 0.03-0.075%, S≤0.010%, Als: 0.020-0.045%, Nb: 0.008-0.015%, Ti: 0.02-0.03%, B: 0.0004-0.0010%, N≤0.0035%, and the remainder is Fe and unavoidable impurities; The elements also meet the following restrictions: calculated according to the corresponding weight percentage of each element, 10C+3N+2S≤Ti+2Nb≤12C+3N+2S, 60B≤P≤80B; the present invention adds P element to IF steel, and through composition and process optimization control, obtains a P-containing hot-dip galvanized iron alloy high-strength IF steel with a yield strength of 180-320 MPa, a tensile strength of 340-440 MPa, an elongation of 35-46%, a value (average plastic strain ratio) ≥1.8, high surface quality, high formability, and good cold brittleness.

The invention belongs to the technical field of metallurgical continuous casting, and particularly relates to a method for removing tundish inclusions based on cooperation of an external electric field and physics. The invention discloses a method for removing tundish inclusions based on cooperation of an external electric field and physics, and mainly aims at solving the problems that as the inclusions in tundish molten steel enter a subsequent continuous casting link, a submersed nozzle is clogged and blocked, and the quality of a casting blank is deteriorated. The key point is that an external electric field and physics synergistic effect is used; a bottom blowing device is arranged to provide power for floating of inclusions; an original baffle weir structure of the tundish is improved, and the probability of catching inclusions is increased; and an external electric field is cooperatively used, so that the inclusions are promoted to float towards the tundish covering agent and be attached to the blocking weir. By means of the method for cooperatively removing the tundish inclusions based on the external electric field and physics, the tundish molten steel inclusions can be obviously removed, the service performance of a subsequent water gap is optimized, the casting blank quality is improved, and the improvement of the high-quality steel smelting level in China is assisted.

This invention discloses a process for controlling the shape of A514GrQ extra-thick plates for offshore platforms. It uses 800-1000mm thick steel ingots, and after removing and cleaning the ingot risers, ensures uniform thickness of the ingot body, laying the foundation for obtaining steel plates with excellent flatness. The heating process is optimized to ensure uniform heating of the ingot head, middle, and tail, facilitating uniform deformation during rolling. Homogenized rolling is employed to reduce cooling water usage, limit the reduction per pass, and control the final rolling temperature, avoiding uneven internal stress and shape rebound in the steel plate. The final product is a 180-210mm thick steel plate with a maximum flatness ≤8mm and a lateral flatness ≤4mm within a length of 10000mm and a width of 2400mm, significantly reducing subsequent leveling tasks.

The invention relates to a crown ether covalent organic framework material as well as a preparation method and application thereof. The preparation method comprises the following steps: dissolving a crown ether monomer and an amino monomer in an o-dichlorobenzene solvent, adding a catalyst acetic acid aqueous solution, and uniformly dispersing to form a reaction solution; the method comprises the following steps: freezing a reaction solution through a liquid nitrogen bath, vacuumizing, filling nitrogen, carrying out a heating reaction, and carrying out post-treatment operations such as washing and drying on a reaction product, so as to obtain the crown ether covalent organic framework material BADT-DB18C6-COF. The crown ether covalent organic framework material is formed by condensation of a crown ether aldehyde monomer and an amino monomer, the crown ether monomer is 4, 4 ', 4' ', 4 '''-(6, 7, 9, 10, 17, 18, 20, 21-octahydrodibenzo [B, K] [1, 4, 7, 10, 13, 16] hexaoxacyclo octadecene-2, 3, 13, 14-tetrayl) tetrabenzaldehyde, and the crown ether monomer is 4, 4 ', 4' ', 4'''-(6, 7, 9, 10, 17, 18, 20, 21-octahydrodibenzo [B, K] [1, 4, 7, 10, 13, 16] hexaoxacyclo octadecene-2, 3, 13, 14-tetrayl) tetrabenzaldehyde. The amino monomer is 4 ', 5'-bis (4-aminophenyl)-[1, 1 ': 2', 1 ''-terphenyl]-4, 4''-diamine. The crown ether covalent organic framework material BADT-DB18C6-COF prepared by the invention is mainly used as an adsorbent, is used for adsorbing and recovering uranium, thorium and americium ions from a solution, shows good adsorption capacity on radionuclides U-238, Th-232 and Am-243, and is particularly suitable for the field of spent fuel post-treatment in the nuclear industry.

The invention provides a method and system for detecting the content of platinum, palladium and rhodium in an automobile exhaust purification catalyst and application, and relates to the technical field of automobile exhaust purification, the method comprises the following steps: crushing, grinding, sieving, performing microwave acidolysis, neutralizing, washing and drying a catalyst sample to obtain dry filter residues; a trapping agent and a fluxing agent are added into the dry filter residues, constant-temperature heating is conducted in inert gas, then cooling forming is conducted, and an alloy button is obtained; blowing ash on the alloy, then adding mixed acid into the alloy, heating the alloy in a water bath at 95 DEG C for 25-35 minutes to obtain a dissolved solution, then adding a masking agent into the dissolved solution, and oscillating to obtain a solution to be detected; and filtering the liquid to be detected, fixing the volume and detecting. According to the method, precise quantification of trace platinum, palladium and rhodium in the complex matrix catalyst can be realized, and the method has a relatively high recovery rate; meanwhile, pollution elements are prevented from being used, and the method is green and efficient and better conforms to the concept of green chemistry.

The invention belongs to the technical field of tungsten smelting, and particularly discloses a method for recycling tungsten from tungsten smelting soda boiling slag through reselection, tungsten in the slag is recycled through a physical mineral separation method, a large number of acid-base reagents are not introduced, acid-base wastewater is not generated, and high-energy-consumption roasting or high-temperature acid-base leaching is not needed. The process is simple, large-scale treatment can be achieved, reagent consumption is low, energy consumption is low, closed-loop circulation of mineral separation water can be achieved, no wastewater is discharged, the process is environmentally friendly and free of pollution risks, meanwhile, indexes of the soda boiling residues subjected to innocent treatment can reach industrial solid waste, hazardous waste is converted into common solid waste, and the economic benefit is high. The environment-friendly treatment cost is low.

The invention provides a method for detecting the porosity of ores in a dump leaching process, and belongs to the technical field of detection of the porosity of the ores. The method comprises the following steps: taking a dump leaching ore body, screening, uniformly mixing, splitting, putting into a dump leaching column to obtain the volume of a sample subjected to splitting in the dump leaching column, then performing fine grinding, putting into the dump leaching column to obtain the volume of the sample subjected to fine grinding in the dump leaching column, and then performing image analysis on the sample subjected to fine grinding to obtain the pore volume among sample particles subjected to fine grinding. And finally, converting the three volumes to obtain the porosity of the heap-leached ore. Through screening treatment, the sample representativeness is effectively improved; the ore before superfine grinding and after superfine grinding is introduced into a dump leaching column, the sampling uniformity is controlled, and the accuracy and stability of data are improved through the in-pile process under the same test column; an image analysis algorithm is introduced, and meanwhile, a correction coefficient is introduced, so that small pores among particles are precisely measured and calculated. The method is simple in process and convenient to operate, and the ore porosity can be rapidly and accurately measured and calculated.

The invention provides a method for detecting the porosity of in-situ dump-leached ore, and belongs to the technical field of ore porosity detection. The method comprises the following steps: taking an ore body on site, preparing a filling agent, performing vacuum gradient impregnation, curing, dissolving and separating the ore to obtain a pore model; melting and softening the pore model to obtain the pore volume in the ore, and finally obtaining the porosity of the ore; wherein nano SiO2 is added into the filler resin, and permeation of tiny pores is guaranteed based on the size effect and the interface optimization effect of a nano material; and through vacuum gradient impregnation, sufficient permeation of tiny pores is further ensured. According to the detection method, the limitation of a drainage method on ore pores containing water-soluble minerals is avoided; the problems that ore samples need to be collected and taken back to a laboratory to be detected in a mercury injection method, a gas adsorption method and the like, the ore body structure is damaged, and consumed time is long are solved. Detection can be carried out on site, ore permeability parameters are provided for the in-situ dump leaching process, and a real-time basis is provided for flow selection.

The invention provides equipment for extracting lithium from electrolytic aluminum slag and a process for extracting lithium and co-producing cryolite, and relates to the technical field of solid waste treatment, the equipment comprises a bottom plate, a heating tank, an extracting tank, a filtering tank, a top cover, a driving mechanism, a switching mechanism and a mixing mechanism; the heating tank is installed on the upper surface of the bottom plate, the extraction tank is installed inside the heating tank, the filtering tank is installed inside the extraction tank, the top cover is installed on the upper surface of the filtering tank in a sealed mode, and a liquid inlet pipe and a feeding pipe are installed inside the top cover. According to the scheme, the conical mixing barrel and the linkage overturning type material mixing plate are adopted, the material mixing plate can overturn caustic soda flakes into the electrolytic aluminum slag, then the caustic soda flakes and the electrolytic aluminum slag are mixed through the material mixing rod, it can be guaranteed that the caustic soda flakes can be evenly mixed with the electrolytic aluminum slag through the design, and it is guaranteed that the caustic soda flakes can be well attached to the surface of the electrolytic aluminum slag; and rapid overheating can be avoided when the subsequent caustic soda flakes are contacted with water, so that the filter tank works more stably and safely.

The invention provides equipment and a process for extracting lithium from lepidolite frame residues and synthesizing urea gypsum, and relates to the technical field of solid waste resource recycling, the equipment comprises a reaction tank, a sealing plate, a reciprocating motion mechanism and a multi-point detection mechanism; the reciprocating motion mechanism comprises a bidirectional threaded lead screw and a threaded block, the bidirectional threaded lead screw is transversely and rotatably connected to the inner wall of the reaction tank, the threaded block is in threaded connection with the bidirectional threaded lead screw, and the bottom of the threaded block is slidably connected with a guide seat. According to the scheme, when the top of a rotating wheel is in contact with a concave position of a convex plate, a rotating seat can drive a sliding rod and a PH detector to move upwards under the action of a spring, so that the bottom end of the PH detector is separated from filtrate, and a plurality of convex parts are arranged on the convex plate, so that the filtrate is subjected to multi-point real-time detection; lithium ion loss caused by co-precipitation of lithium, iron and aluminum due to over-high local pH value of the filtrate is avoided, and the concentration of the lithium solution is effectively improved.

The invention relates to the technical field of high-performance structural ceramic materials and corrosion resistance optimization thereof, in particular to a preparation method of high-performance silicon nitride ceramic, which realizes performance improvement through dynamic optimization of a composite sintering aid, closed-loop regulation and control of air pressure sintering and multi-process data linkage. In the raw material pretreatment stage, a laser particle size analyzer is adopted for monitoring particle size distribution in real time, surface modification parameters are adjusted in a linkage mode, and a uniform monomolecular coating layer is formed; the proportion of rare earth oxide and aluminum oxide in the composite sintering aid is dynamically adjusted according to the fluctuation of the mixing torque, and agglomeration and segregation of the aid are inhibited. And in the air pressure sintering stage, the argon pressure and the heating rate are dynamically adjusted based on the slope of a shrinkage curve, and directional arrangement of beta-phase grains is promoted by combining low-temperature nitrogen protection and high-temperature argon densification. And multi-dimensional process control synergistically optimizes grain boundary components, structure and density, so that the corrosion resistance and the service life of the silicon nitride ceramic in a sulfur-containing environment are remarkably improved and the service life of the silicon nitride ceramic in the sulfur-containing environment is remarkably prolonged.

The invention relates to a high-strength complex-phase hot-rolled wire rod for a 2230 MPa grade stranded wire and a manufacturing method of the high-strength complex-phase hot-rolled wire rod. After a Nb-containing high-carbon component is used for rolling and spinning at a spinning temperature to form a wire rod, online molten salt mixing quenching isothermal treatment is carried out, so that the wire rod is firstly subjected to front-section molten salt treatment and is cooled at a cooling speed of more than or equal to 35 DEG C / s, and enters a bainite and pearlite mixed phase region from an austenite state; the method comprises the following steps: firstly, carrying out heat treatment on austenite to promote part of austenite to be converted into bainite and sorbite, then carrying out later-section molten salt treatment, increasing the molten salt temperature, promoting unconverted retained austenite to be decomposed and converted into sorbite, carrying out isothermal tempering, and finally, carrying out roller way slow cooling, so as to prepare the hot-rolled wire rod of which the microscopic structure comprises a complex-phase structure consisting of tempered bainite and tempered sorbite, the drawing and hardening capacity can be improved, the production efficiency is considered, the tensile strength is 1522-1572 MPa, and the percentage reduction of area is 29%-34%, so that off-line heat treatment is avoided, and the wire breaking risk and cost of stranded wire manufacturing are reduced.

A method for predicting in-situ leaching effects of sandstone-type uranium mining deposits after blasting is provided, which comprises: based on a finite element analysis platform, establishing an HJC rock-blasting constitutive model, and carrying out a blasting numerical simulation; calibrating a cloud map of blasting crack damage by using a Kriging interpolation algorithm; establishing a COMSOL multiphysics model; establishing a coupling interface between the COMSOL multiphysics model and PHREEQC based on MATLAB, and optimizing a cycle duration and a time step; performing a geochemical reaction calculation and saving results, running COMSOL files, and inputting the results of geochemical reaction calculation into PHREEQC to obtain a dynamic cyclic iterative simulation; dynamically correcting migration coefficients of uranyl complexes by integrating an LSTM neural network, and stopping the cycle to output multi-scale dynamic simulation results of migration of uranium.

The invention belongs to the technical field of aluminum alloy production, and particularly discloses a low-carbon, low-cost and safe method for producing a 4343 alloy blank, raw materials are weighed according to a certain proportion, an aluminum melt obtained through smelting in a smelting furnace is refined and subjected to on-line degassing and filtering, the 4343 alloy blank is produced through a continuous casting and rolling method, a finished product is small in crack edge, segregation of internal components of the material is small, and the production cost is low. The method has the advantages that secondary aluminum can be used as raw materials in a large proportion, low carbon and consumption reduction are achieved, and the method is different from a traditional casting production mode, a matched casting deep well is not needed, the phenomenon that cooling water is accumulated in the deep well or a narrow area is avoided, and the explosion problem possibly occurring after high-temperature aluminum water makes contact with the cooling water is avoided; the production process is simple, the safety degree is high, aluminum-strontium alloy is not needed in the production process, the production cost is reduced, and meanwhile the strontium poisoning phenomenon caused by misoperation of field operators is completely eradicated.

The invention discloses a method for low-carbon preparation of a high-reactivity blast furnace burden from magnetite concentrate and the blast furnace burden, and belongs to the technical field of ferrous metallurgy. According to the method, an iron-containing raw material, an organic-inorganic composite binder, a multifunctional additive and water are sequentially subjected to uniform mixing, high-pressure double-roller forming and consolidation, and the finished product cold pressing block is obtained. According to the method, the strength and reducibility of the cold pressing block can be remarkably improved by optimizing the particle size composition of the raw materials and adding the multifunctional additive, the technological process is simple, a high-temperature process is not needed, and carbon emission is low.

The embodiment of the invention provides a pipeline blockage monitoring method and system for wet metallurgy slurry conveying, and belongs to the technical field of pressure measurement and pipeline blockage monitoring. The method comprises the following steps: collecting multi-point pressure signals along a slurry pipeline, and extracting pressure pulsation amplitudes and phase characteristics in a pump fundamental frequency and frequency multiplication range based on the multi-point pressure signals so as to establish an on-way pulsation transmission sequence; determining equivalent on-way impedance based on comparison between the on-way pulse transmission sequence and a reference working condition, and outputting an initial judgment result for representing a blockage risk; flow temperature and viscosity estimation parameters are introduced based on the initial judgment result to carry out rheological correction on an impedance threshold value, and a high-frequency phase difference is extracted at an elbow section to update a candidate blockage position; and based on the updated candidate blockage position and the corrected impedance threshold, fusing a phase stability index, and generating and outputting a current blockage evaluation result. According to the scheme, early-stage accurate positioning and stable judgment of slurry pipeline blockage can be achieved under complex working conditions.

The invention relates to the technical field of steel pipe hot galvanizing, in particular to steel pipe hot galvanizing automation equipment and a galvanizing technology.The steel pipe hot galvanizing automation equipment comprises a zinc liquid pool, a second horizontal moving part is fixedly arranged on one side of the zinc liquid pool, placing tables are arranged on one side of the second horizontal moving part at intervals, and the upper ends of the placing tables are in threaded connection with blocking strips through bolts; a moving assembly is arranged above the molten zinc pool, a stirring assembly is arranged on the outer surface of the moving assembly, a deslagging assembly is arranged at the upper end of the molten zinc pool, first electric telescopic rods are detachably connected to the two sides of the molten zinc pool through supports, push plates are fixedly arranged at one ends of the first electric telescopic rods, and an air blowing part is arranged on one side of the molten zinc pool in a penetrating mode. Through the arrangement of the moving assembly and the slag removal assembly, automatic hot galvanizing of the special-shaped steel pipe is achieved, automatic removal of zinc slag on the surface of zinc liquid can be achieved, through the arrangement of the moving assembly, the stirring assembly and the first electric telescopic rod, residues of the zinc liquid can be reduced, and the possibility of zinc tumor occurrence is reduced.

The invention relates to a high-strength complex-phase hot-rolled wire rod for a 2200MPa-grade stranded wire and a manufacturing method of the high-strength complex-phase hot-rolled wire rod, and the manufacturing method comprises the following steps: rolling and spinning to form a wire rod by adopting a high-hardenability component design, and then carrying out online molten salt mixed phase region quenching isothermal treatment, so that the wire rod is firstly subjected to front-section molten salt treatment and enters a bainite and pearlite phase region from an austenite state; the method comprises the following steps: carrying out high-temperature treatment on austenite to promote part of austenite to be converted into bainite and sorbite, carrying out later-section molten salt treatment, increasing the molten salt temperature, reducing the molten salt circulation amount, promoting unconverted retained austenite to be decomposed and converted into bainite and sorbite, carrying out isothermal tempering, and finally carrying out slow cooling through a roller way, the hot-rolled wire rod with a microscopic structure comprising a complex phase structure composed of tempered bainite and tempered sorbite is prepared, the material cost can be reduced, the complex phase structure and the structure toughness can be regulated and controlled on line, the tensile strength is 1505-1555 MPa, the percentage reduction of area is 32%-37%, efficiency and energy consumption are both considered, off-line heat treatment is avoided, and high-efficiency production of stranded wires is promoted.

The invention belongs to the technical field of aluminum alloy production, and particularly discloses a low-carbon environment-friendly method for producing a 3104 alloy blank with a high secondary aluminum proportion, which comprises the procedures of smelting, melt purification, online degassing filtration, continuous casting and triple continuous rolling, and is characterized in that alloy components are optimized, secondary aluminum waste is used in a large proportion, the Fe content is increased, and the production cost is reduced. Iron and elements such as manganese in the aluminum alloy form intermetallic compounds, the intermetallic compounds can serve as heterogeneous nucleation, obviously refine alloy grains during casting and increase Fe content, the performance of the 3104 alloy blank is improved, meanwhile, aluminum is replaced with iron, the main material cost can be reduced, in addition, due to the fact that the rolling temperature of an inlet of each rack is high, and meanwhile the finish rolling temperature is also high, the service life of the 3104 alloy blank is prolonged. The self-tempering effect is achieved, internal dislocation of materials is eliminated, the blank edge cracking condition is improved, strip breakage caused by the edge cracking problem in the subsequent rolling process is avoided, safe production is guaranteed, the main material cost is reduced, meanwhile, the blank performance is improved, the 3104 alloy blank is efficiently produced in a high-quality mode, and the purposes of low carbon and environment protection are achieved.

The invention relates to a high-strength complex-phase hot-rolled wire rod for a 2360MPa-grade stranded wire and a manufacturing method of the high-strength complex-phase hot-rolled wire rod. After a Mo-V high-carbon component system is rolled and spun into a wire rod, the wire rod is subjected to on-line molten salt weak quenching toughening treatment, so that the wire rod is subjected to front-section molten salt treatment to be quickly cooled, enters a bainite and sorbite mixed phase region from an austenite state, and is subjected to high-temperature heat treatment to form a high-strength complex-phase hot-rolled wire rod; the method comprises the following steps: firstly, carrying out heat treatment on residual austenite to form a structure mainly comprising bainite and sorbite, then carrying out later-section molten salt treatment, increasing the temperature of molten salt, promoting decomposition and conversion of unconverted residual austenite into sorbite, carrying out isothermal tempering, and finally, carrying out roller way slow cooling to prepare a hot-rolled wire rod of which the microscopic structure comprises a complex-phase structure consisting of tempered bainite and tempered sorbite, the method has the advantages that the structure toughness can be regulated and controlled on line, the tensile strength is 1574-1627 MPa, the percentage reduction of area is 28-33%, the mechanical property fluctuation is reduced, the material cost and the production efficiency are both considered, the ultra-high-strength stranded wire can be produced without off-line heat treatment, and the wire breaking risk is reduced.

The invention belongs to the technical field of rare and precious metal recovery, and particularly relates to a method for recovering metallic silver from waste crystalline silicon battery pieces, which comprises the following steps: (1) putting the waste crystalline silicon battery pieces into an inorganic alkali aqueous solution for soaking reaction to obtain an aluminum-containing solution and dealuminized crystalline silicon pieces; (2) adding the dealuminized crystal silicon wafer into a mixed solution of organic acid and hydrogen peroxide for soaking reaction, filtering and washing to respectively obtain silver-containing filtrate and a silver-removed silicon wafer; (3) carrying out chlorination precipitation reaction on the silver-containing filtrate and a chlorine source, filtering and drying to obtain silver chloride powder; (4) adding silver chloride powder into an ammonia water solution, heating and stirring to completely dissolve silver chloride to obtain a silver-ammonia solution; (5) adding PVP (Polyvinyl Pyrrolidone) into the silver-ammonia solution, heating and stirring until the PVP is completely dissolved, adding ascorbic acid, and carrying out reduction reaction at room temperature to obtain metal silver powder precipitate; and filtering, washing and drying the precipitate to obtain the spherical silver powder. According to the method, the silver recovery efficiency is high, the spherical nanoscale silver powder can be prepared, and the purity is high.