5556 results about "Leachate" patented technology

Particulate compositions are described comprising a carbonaceous material, such as petroleum coke and/or coal, treated or otherwise associated with a gasification catalyst, where the catalyst is at least in part derived from a leachate from a biomass char, for gasification in the presence of steam to yield a plurality of gases including methane and at least one or more of hydrogen, carbon monoxide, and other higher hydrocarbons are formed. Processes are also provided for the preparation of the particulate compositions and converting the particulate composition into a plurality of gaseous products.

An alternative cover for landfill may be formed from a slurry mixture of water, cementitious binder, adhesion enhancing admixture and fiber. These constituents may be mixed and applied to cover landfilled wastes, granular material piles or for soil erosion control. The cover will harden to minimize water infiltration, wind blown dust, odor and affinity to birds, flies and other insects. The water may include tap water, landfill leachate and wastewater. The binder may include Portland cement, blended cement, cement kiln dust, class C fly ash, and/or calcium sulphate hemihydrate. The adhesion enhancing admixture includes water-dispersible polymers. The fibers may comprise shredded paper or wood or plastic fibers.

A process for leaching a value metal from a base metal sulfide ore, comprising the step of leaching the ore with a lixiviant comprising a chloride, an oxidant and hydrochloric acid is disclosed. The leaching is controlled, by use of low concentrations of hydrochloric acid and a redox potential, to effect formation of hydrogen sulfide from the base metal sulfide ore. The hydrogen sulfide is stripped from the leach solution, thereby reducing the amount of sulfate generated in the leach to very low levels. The leaching may also be conducted to limit the co-dissolution of platinum group metals and gold with the base value metals. The leach forms a value metal-rich leachate and a solids residue. The solids residue may be subsequently leached to recover the platinum group metals and gold. The value metal-rich leachate can be is oxidized and neutralized to recover the value base metals. In an embodiment, the chloride is magnesium chloride and lixiviant solution is regenerated.

The invention provides a full-component resource reclamation method for waste positive electrode materials of lithium ion batteries. The method comprises the following steps: 1) separating active substances and aluminum foils in waste positive electrode materials of lithium ion batteries by using an aqueous solution of fluorine-containing organic acid and carrying out liquid-solid-solid separation so as to obtain leachate, the lithium-containing active substances and the aluminum foils; 2) respectively carrying out high temperature roasting and impurity removal with alkali liquor on the lithium-containing active substances; 3) respectively carrying out recovery of the fluorine-containing organic acid through addition of acid and distillation, deposition of impurity ions through addition of alkali and ammonium carbonate coprecipitation on the leachate so as to prepare nickel-cobalt-manganese carbonate ternary precursor; and 4) carrying out component regulation on a mixture of the treated active substances and the nickel-cobalt-manganese carbonate ternary precursor, adding lithium carbonate in a certain proportion and carrying out high temperature solid phase sintering so as to prepare a lithium nickel cobalt manganese oxide ternary positive electrode material. The method provided in the invention has the following advantages: the application scope of the method is wide; separation efficiency of the lithium-containing active substances and the aluminum foils is high; short-flow direct re-preparation of positive electrode materials in waste lithium ion batteries is realized; and the method is applicable to large-scale resource reclamation of waste lithium ion batteries.

A compact portable modular wastewater treatment system which integrates several processing technologies to provide a substantially purified water source. A wastewater stream is sent through an initial filtration step. The filtered wastewater is then subjected to electrocoagulation and then further filtered. The resulting stream containing substantially only organics is then treated in an advanced oxidation process which can include passing an electrical current through the water during the oxidation process. The partially treated water is then passed through ion-exchange columns to polish ammonium and other contaminants. The ion-exchange columns are cycled through regeneration cycles to provide continuous ion-exchange medium. The ammonium rich brine solution used in regeneration is subjected to an ammonium destruct process and then reused in regenerating ion-exchange columns. The water can then be sent through a final disinfection oxidation process to destroy or inactivate pathogens and/or remove any remaining colorants or odor to provide a water source suitable for almost any use.

The invention relates to a method of recycling valuable metals from arsenic-containing soot. The method comprises the following steps: (1) mixing acidic wastewater with white soot, controlling the pH value to 2.5-3.0, performing acid leaching at a temperature of 70-80 DEG C, and filtering to obtain leachate and lead slag; (2) replacing indium for the leachate by using zinc powder, and filtering to obtain indium slag; (3) performing rotational-flow electrodeposition arsenic removal and zinc removal on filtrate in sequence to obtain arsenic slag and zinc slag. The method disclosed by the invention can be used for purifying the acidic wastewater to reach a condition for recycling the acidic wastewater to a smelting acid manufacturing and purifying section, so that the treated acidic wastewater can be directly returned to the acid manufacturing and purifying section, and therefore, the gypsum slag is completely removed to truly achieve the purpose of zero emission. Meanwhile, the method disclosed by the invention can also be used for achieving the treatment of white soot and recycling the valuable metals, so that environmental protection and resource comprehensive utilization are achieved.

The invention discloses a comprehensive recovery method of complex polymetal sulphide ore containing copper, lead and zinc and adopts dressing-metallurgy combination method and hydrometallurgy-pyrometallurgy combination method to recover metals. The recovery method comprises the following steps: first performing bulk flotation to the complex polymetal sulphide ore, fine grinding the obtained concentrate, leaching by using two-step counter flow oxygen pressure leaching process, extracting and separating copper and zinc from the obtained leachate, electrodepositing the strip liquor of copper-loaded organic phase to obtain cathode copper, cleaning the obtained raffinate and electrodepositing to obtain cathode zinc; pressurizing leaching residue to perform flotation separation and obtain sulfur concentrate and lead silver residue, distilling sulfur concentrate to obtain sulfur; performing lead smelting process to lead silver residue to obtain electrolytic lead product and lead anodic slime; and comprehensively recovering noble metals such as gold, silver and the like from lead anodic slime. The method can greatly improve the metal recovery rate, resource utilization and the economic efficiency of mines and generate a lot of sulfur so as to obviously reduce the sulfur dioxide pollution to the atmosphere.

The invention relates to a method for recovering a waste SCR (Selective Catalytic Reduction) denitration catalyst. According to the method, the waste SCR denitration catalyst is subjected to pretreatment firstly so as to remove impurities and catalysis ingredients, such as activated vanadium, tungsten and molybdenum, and then, the waste SCR denitration catalyst is subjected to leaching, so as to obtain titanium-rich leached residue and a tungsten-molybdenum-vanadium-containing leachate; valuable elements in the leachate can be subjected to resource treatment through two methods: the first method comprises the steps of synchronously purifying the valuable elements in the leachate, then, proportionally adjusting the content of each substance so as to prepare a mixture of the catalysis ingredients, and further preparing a new catalyst so as to realize remanufacturing; the second method comprises the steps of separating and purifying each valuable element in the leachate, thereby preparing different products. The method can be used for recovering the valuable elements in the waste SCR denitration catalyst, and the environmental and economic benefits are remarkable.

A method of recovering hydrocarbons from hydrocarbonaceous materials can include forming a stationary permeability control infrastructure. This constructed infrastructure defines a substantially encapsulated volume. A comminuted hydrocarbonaceous material can be introduced into the control infrastructure to form a permeable body of hydrocarbonaceous material. The permeable body can be heated sufficient to remove hydrocarbons therefrom within a temperature range which is sufficient to substantially avoid formation of carbon dioxide or non-hydrocarbon leachates. During heating the hydrocarbonaceous material is substantially stationary as the constructed infrastructure is a fixed structure. Removed hydrocarbons can be collected for further processing, use in the process, and/or use as recovered.

The invention discloses two toadstool natural culturing methods belonging to one general invention conception. The first method comprises the following steps of mixing toadstool cultivated species with toadstool culturing materials and soil evenly, forming the mixture of the toadstool cultivated species, culturing materials and soil, sowing the mixture containing the toadstool cultivated species in a land and covering with soil with the thickness of 0.5cm-2.5cm; the toadstool culturing materials comprise herbaceous plant in grass family, crop straws, bran and KH2PO4, MgSO4, urea and other nutrient substances. The second method is as follows: hole sowing the toadstool cultivated species in the land directly and covering with soil with the thickness of 0.5cm-2.5cm. For the above two methods, at least one time of nutrition supplementation is carried out when mycelial is mature, and the nutrient supplementary solution is prepared by grass ash leachate, KH2PO4, MgSO4 and urea.

The invention discloses a production method for manganese sulfate by using low-grade manganese ores. According to the method, manganese sulfate with high purity can be produced by using waste low-grade manganese ores with manganese content of 10% to 20%, manganese tailing or manganese-containing solid waste residue. The method comprises the steps of preparation of raw materials, a slaking reaction, a leaching reaction, neutralization and purification of leachate, etc. According to the invention, production of manganese sulfate is not restricted by the grade of manganese ores, and low-grade manganese oxide ores with a grade greater than 10%, manganese tailing or manganese-containing solid waste residue can be fully utilized; produced manganese sulfate has high yield and high purity and is a very important industrial fundamental product; almost no external heat supply is needed, low energy consumption is achieved, production cost is low, it does not need to turn over and mix materials in the process of the reactions, the reactions are smooth, no toxic gas is generated, and no environmental pollution is produced; discharge of three wastes (waste gas, waste water and industrial residue) reaches national discharge standards for environmental protection, and there is no dust pollution in a workshop.

The invention relates to a method for recovering valuable metals from electroplating sludge. Electroplating sludge is used as a raw material; advanced theories and scientific means of leaching principle, redox principle, extraction principle, iron filing displacement principle and evaporation crystallization principle in a wet method metallurgy are integrally utilized; and a technology of ''acid decomposition of electroplating sludge-leachate purification to remove ferrochrome-P204 impurity removal-P507 enrichment-condensation crystallization'' is employed. Meanwhile, calcium and magnesium are removed by an extraction method, which substitutes a traditional sodium fluoride method for removing calcium and magnesium. A recovery rate of nickel reaches 95%, and copper content of recovered copper sponge is larger than 80%. Besides, acid dissolved slag and purifying slag can be solidified to reach requirements of environmental protection and will not cause secondary pollution; waste water can be recycled and has a strong technological versatility. The method is suitable for treating various routine electroplating sludge, has easily controllable technical conditions and low operating cost and is easy for realizing large scale production; therefore, the method is a practical novel technology for treating electroplating sludge in a way of quantitative reduction, harmlessness and resource.

The invention relates to a process for separating and recovering selenium from a selenium-containing material. The process comprises the following steps: dissolving the selenium-containing material into a sulfuric acid solution, adding 10% H2O2 into the mixture, filtering and separating to get leachate and residue containing silver, lead, copper and other valuable metals; separating the selenium from tellurium in the oxidation leachate by using sodium hydroxide; and acidifying the selenium leachate with hydrochloric acid, adding sodium sulfite to reduce the settled selenium, washing and drying to get crude selenium with the grade of not lower than 90%. The crude selenium which is separated by the process is higher in purity and can be directly refined, so that the process flow of recovering selenium is shortened, the recovery rate of selenium is improved, the production cost is reduced and the energy is saved; and the sodium sulfite is used for substituting sulfur dioxide to perform reduction, the control is easy and the environmental pollution is further reduced. The process has very important significance in both aspects of recovering resources and protecting an environment.

The invention relates to a silver anode mud treatment process. The process is characterized by leaching silver anode mud with nitric acid, wherein silver, palladium and base metals enter into solution while gold and platinum remain in residue; after roasting the leaching residue and removing impurities, using a cast gold anode plate to electrolyze the leaching residue to obtain gold No. 1 and using electrolyte for recycling platinum; regulating the pH value of leachate and adding mixed precipitator A solution to selectively precipitate palladium to obtain palladium precipitate residues; solution after palladium precipitation mainly being AgNO3 solution and returning the AgNO3 solution to undergo silver electrolysis; dissolving the palladium precipitate residues with aqua regia and filtering the dissolved solution to obtain the filter residue which is mainly AgCl, reducing the filter residue with hydrazine hydrate to obtain crude silver powder and returning the crude silver powder to a cast silver anode plate; and concentrating and carrying out ammonium on the solution after dissolution to obtain (NH4)2PdCl6 precipitate, dissolving the (NH4)2PdCl6 precipitate with ammonia and acidizing the (NH4)2PdCl6 precipitate with hydrochloric acid to obtain Pd(NH3)2Cl2 precipitate, then reducing the Pd(NH3)2Cl2 precipitate with hydrazine hydrate and then drying the reduction product to obtain spongy palladium, wherein the produced filtrate is returned to the concentration process. The invention has the advantages of less precious metal loss, low cost, strong practicability, high comprehensive recoverability and obvious economic benefit.

The invention discloses a garbage leachate treatment technique, comprising: homogenizing the water quality of garbage leachate by an adjusting tank, and then leading the garbage leachate to enter a coagulative precipitation tank; then, alkalifying and deaminizing, and lifting into a UASB+AF tank through pump; after that, removing a great deal of organic matter, and leading the effluent to enter apacked A/O tank together with the sewage processed by the original sewage plant; removing the organic matter and the ammonia nitrogen which are difficult to degrade, and then passing through a secondary sedimentation tank and entering an advanced oxidation system for deep oxidation; leading the effluent to enter a biological aerated filter, processing by a sand filtering system and then entering amembrane processing system; and finally, ensuring the water quality of the effluent to be stable and reach the standard. As the garbage leachate treatment technique adopts the technology of 'biochemistry+ physical chemistry+ membrane separation' to treat the leachate, the effluent can reach the first grade discharge standard (GB16889-1997).

A method for extracting zinc indium and recovering iron from high-iron high indium zinc concentrate comprises the following steps: roasting high-iron high indium zinc concentrate which comprises 13-20% of Fe and 0.05-0.25% of In to produce zinc calcine; performing neutral leaching of zinc calcine; performing hot acid reduction and leaching of the neutral leached residues; performing preneutralization of the hot acid reduced leachate by zinc oxide; performing replacement and indium deposition of the preneutralized solution by zinc powder; performing iron deposition of the solution after indium deposition by oxygen-compressed hematite to produce hematite slag with 55-65% of iron; separating sulfur concentrate and flotation tailings from the hot acid reduced leached residues by a flotation method, returning the sulfur concentrate for boiling and roasting treatment, allowing the tailings to enter a fuming furnace for reduction and volatilization treatment.

The invention relates to an apparatus and a method for nitrogen removal by combining garbage leachate SBR and anaerobic ammoxidation, which belongs to the low carbon nitrogen (CN) ratio high density ammonia nitrogen garbage leachate biological denitrogenation technical field. The apparatus comprises an integrated water tank, a SBR short distance nitrated reactor and an anaerobic ammoxidation reactor; a preposition water tank and a postposition water tank in the integrated water tank are communicated with a peristaltic pump and the SBR short distance nitrated reactor, the postposition water tank is connected with the bottom of the anaerobic ammoxidation reactor through the outlet pipe and the peristaltic pump, an self-circulation pipeline is provided on the anaerobic ammoxidation reactor, and is connected with the SBR preposition water tank through the outlet pipe and the peristaltic pump. The method comprise the following steps starting the SBR short distance nitrated reactor, starting the anaerobic ammoxidation reactor, and an operation is in series of the SBR short distance nitrated reactor and the anaerobic ammoxidation reactor is carried out. The apparatus of the present invention is suitable for organic matter removal and short distance nitrogen removal of the garbage leachate at late period in the garbage landfill, the process is advanced, and the advantages of energy saving and consumption reduction is obvious.

The invention provides a recovery method of a copper indium gallium selenide thin-film solar panel. The method comprises the steps that: the copper indium gallium selenide thin-film solar panel is crushed into pieces; the pieces are soaked by using a H2SO4+H2O2 system, such that a soaking liquid is obtained; the soaking liquid is filtered, such that a first leachate is obtained; with a first phase ratio of 1, the first leachate is extracted by using an extraction agent; separation is carried out, such that a first extraction liquid and a first raffinate are obtained; the extraction agent is composed of 30% of P2O4 and 70% of kerosene by volume percentage, the extraction and balance time is 5-20min; an HCl solution is adopted as a stripping agent, and the first extraction liquid is striped by using a second phase ratio, such that In and stripping residual liquid are obtained; a reducing agent is added into the first raffinate; when a reduction reaction is finished, crude Se and a second leachate are obtained by filtering; alkali is added into the second leachate, and a pH value is regulated such that the pH value is constantly higher than 14; when a reaction is finished, filtering is carried out, such that a filtering slag comprising a hydroxide of Cu and a water solution comprising Ga are obtained; the alkali is NaOH, the pH value adjustment process is to add the NaOH in the reaction process after pH=14 so that the pH is always kept more than 14 during the reaction process, and the reaction time is kept for 0.5-2h; and the water solution is electrolyzed.

The invention discloses a method for separating tombarthite from phosphorus ore and relates to the method for separating the tombarthite from the phosphorus ore containing the tombarthite. The method is characterized in that the process steps are as follows: (1) mixing phosphate concentrate containing the tombarthite with a phosphoric acid solution for performing reaction; (2) filtering for getting a reaction solution and slag containing the tombarthite; (3) adding acid into the slag containing the tombarthite for leaching for getting leachate containing the tombarthite, and further recycling the tombarthite through one or more of an extraction method, an ion exchange adsorption method, a precipitation method and a crystallization method; and (4) performing decalcification on the reaction solution obtained by filtration and then returning to the step (1). By adopting the method, the precipitation rate of the tombarthite in the phosphorus ore is greater than 85%, the slag rate is small, the grade of the tombarthite in the slag is high, the leaching rate of the tombarthite in the slag is high, no additives are added during the process and the product quality of the phosphoric acid is not affected; and furthermore, the phosphoric acid used during the process can be self-produced and can also be circulating dilute phosphoric acid, dilute phosphoric acid and the like generated during the production process of the phosphoric acid, thereby being tightly linked with the production process of the phosphoric acid through the sulfuric acid method.

The invention discloses a method to remove arsenic with high arsenic lead anode mud in noble metal metallurgical technical domain, which comprises the following steps: adding alkali liquor into high arsenic lead anode mud; leaching with alkali under the condition of air-blowing and heating; removing the arsenic; getting lead anode mud; reclaiming god and silver and other valuable metal with known craft; incorporating sodium arsenate in the leachate; depositing arsenic with lime; reclaiming arsenic clean ore; supplementing alkali liquor for the solution after depositing arsenic; backing to alkaline leaching process. This invention can make arsenic of anode mud decrease to below 1% and does not need any alteration for original craft.

The invention relates to a method for preparation of lithium carbonate extracting lithium from lithionite. The invention consists of milling, leaching and filtering after modifying by broasting lithonite ore together with the additive findings such as calcium fluoride, calcium sulfate and sodium sulfate at a certain temperature, adding sodium carbonate into the leachate to deposite lithium ion forming the deposition of lithium carbonate, and washing and drying the solid gained by filtering to get the product of lithium carbonate. The filtered mother liquid returns to the circulation to deposit lithium ion. After secondary circulation, we get the mixed salts of potassium sulfate and sodium sulfate as the educts by washing and drying the aforementioned filtered mother liquid. Some of the mixed salts return as findings roasted with lithonite ore for circulation use, while others can be used as raw material for preparation of potassium sulfate.

The invention discloses a method and a device for treating garbage percolate, wherein the method comprises the steps of pretreatment, anaerobic treatment, membrane biochemical treatment, nanofiltration treatment, sludge treatment and the like; the device comprises a primary sedimentation tank (1) and an adjusting tank (2), the adjusting tank (2) is connected with an anaerobic reactor (3), the anaerobic reactor (3) is connected with a denitrification tank (4), and the denitrification tank (4) is communicated with a nitrification tank (5); and the nitrification tank (5) is connected with an ultrafiltration apparatus (6), and the ultrafiltration apparatus (6) is connected with a nanofiltration device (7). The method and the device achieve COD degradation of high-concentration wastewater so that the COD of high-concentration COD of 50,000 reaches about 50 after treatment and reaches the standard of industrial reuse water, thus the method and the device achieve zero discharge of the percolate, initiate a new attempt to treat high-concentration percolate, and fill up the domestic blank.