177 results about "Leaching rate" patented technology

The invention belongs to the technical field of hydrometallurgy, and particularly relates to a pretreatment method for enhancing peroxide to improve the leaching rate of high-sulfur-arsenic gold ore. Comprising the following steps that the high-sulfur-arsenic gold ore is ground and then prepared into ore pulp; an oxidizing agent is added into the ore pulp, oxidation pretreatment is conducted on the high-sulfur-arsenic gold ore under the catalytic action of ultraviolet light, and ore pulp activation liquid is formed; and the pH of the ore pulp activating solution is adjusted to 9-12, a gold leaching agent is added into the ore pulp complexing solution, and stirring gold leaching treatment is conducted. According to the method, efficient oxidation of sulfide and arsenide is achieved under the mild condition through the synergistic effect of photocatalysis and chemical oxidation, the leaching rate of gold is remarkably increased, compared with a conventional peroxide oxidation method for pretreatment, the leaching rate can be increased by 10%-35%, and meanwhile the agent use amount and environmental pollution are reduced.

The invention provides a method and equipment for leaching and recycling an aluminum electrolysis waste carbon cathode. The method relates to the field of solid waste treatment, and comprises the following steps: S1, crushing the recycled waste aluminum electrolysis waste carbon cathode by using a jaw crusher, further finely grinding to a certain mesh number by using a vibration mill, and drying for later use; s2, the ground waste carbon cathode is weighed, a certain amount of water is added, the mixture is placed in an ultrasonic instrument at the normal temperature to react for a period of time, and washing residues and washing liquid are obtained through filtering; s3, a sodium hydroxide solution with a certain concentration is added into the washing residues to be mixed, and the mixture is placed in an ultrasonic instrument to react for a period of time at a certain temperature. Compared with a traditional leaching method, the method has the advantages of being high in efficiency and good in effect, the leaching rate of valuable substances is greatly increased, and the valuable substances are recycled through a series of steps such as washing, alkaline leaching, acid leaching and recycling. The method realizes efficient recovery of useful components in the waste carbon cathode, does not produce solid waste and wastewater in the process, is environment-friendly, and realizes effective utilization of resources and harmless treatment of dangerous solid wastes.

The invention relates to an efficient copper removal and recycling process for copper-cyanogen complex wastewater, which comprises the following steps: (1) critical acidification-selective crystallization of the copper-cyanogen complex wastewater: directionally recombining a copper-cyanogen complex to generate insoluble CuCN crystals by accurately regulating and controlling the pH value of the wastewater; (2) rotational flow enhanced crystallization: separating CuCN crystals from overflow liquid through a hydrocyclone; (3) gradient activation of a composite vulcanizing agent for deep copper removal: enabling the fine CuCN particles and the dissolved-state low-coordination copper-cyanogen complex to react to generate insoluble CuS crystals by adjusting the pH value and adding the composite vulcanizing agent; and (4) magnetic seed enhanced separation: carrying out magnetic separation by adopting modified magnetic seeds and a low-intensity magnetic separator, separating CuS magnetic flocs from the wastewater, and finally obtaining purified tail liquid. According to the closed-loop process, copper in the copper-cyanogen complex wastewater can be efficiently removed and recovered, the purified tail liquid can be reused for cyanidation leaching operation, the unit consumption of sodium cyanide is remarkably reduced, the leaching rate of gold and silver is increased, and zero discharge of wastewater and full recovery of copper resources are truly achieved.

The invention discloses a method for preparing a NaFeO2 material and leaching copper, zinc and molybdenum from copper slag, and relates to the technical field of metallurgical solid waste resource utilization. The method comprises the following steps: grinding the copper slag, mixing the ground copper slag with a sodium salt, roasting the mixture in a muffle furnace at a proper temperature, and finally carrying out ultrasonic washing and filtering on the roasted product to obtain filter residues and filtrate; and drying filter residues to obtain a high-purity NaFeO2 material, and recovering valuable metals such as copper, zinc and molybdenum from filtrate. In the washing process, valuable metal elements copper, zinc and molybdenum in the copper slag are efficiently leached into the solution, the leaching rate reaches 96% or above, and synchronous recovery of the valuable elements is achieved; according to the method, the industrial waste residue copper slag is successfully converted into the NaFeO2 product with the high additional value, meanwhile, valuable metal is efficiently extracted, the method has the advantages of being simple in process, low in cost, high in recycling degree and environmentally friendly, a new way is opened up for high-value utilization of the copper slag, and the method has good industrial application prospects.

A preparation method of an ionic rare earth leaching agent includes the following steps: (1) domestication microorganisms with rare earth activated mineral powder culture medium to obtain a microbial suspension; (2) amplifying and culturing the microbial suspension and additives to obtain the amplified culture medium; and (3) mixing the modified sesbania gum with the amplified culture medium to obtain the ionic rare earth leaching agent. The activated mineral powder is the active metal-containing mineral powder in nature, which has excellent cation exchange function after activation, and the activated mineral powder and ionic rare earth mineral powder are used as the medium components to domesticate microorganisms, so that microorganisms can survive in the above-mentioned ionic solution and improve the leaching rate of synergistic leaching ionic rare earth.

The invention discloses a method for enhancing biological leaching of copper in a waste circuit board by utilizing magnetite. The method comprises the following steps: adding the pre-crushed waste circuit board and magnetite into a 9K culture medium with the pH value of 1.8-2.0 according to a certain mass ratio, inoculating Acidithiobacillus ferrooxidans as a leaching strain, and carrying out a leaching reaction under a constant-temperature oscillation condition. The magnetite is added, so that the leaching of copper in the circuit board is remarkably enhanced, the leaching rate is remarkably improved, and the leaching period is shortened. And compared with the microbiological leaching result without magnetite, the copper leaching rate is improved by 12-32%. By utilizing the difference between the circuit board and the magnetite in particle size, the magnetite can be recycled from the leaching residues through a physical separation means for a new round of leaching. The method is simple in process, the strain is easy to culture, and the method has good environmental friendliness and is suitable for green and efficient recovery of copper in the waste circuit board.

The invention provides a method for preparing a poly-aluminum and functional silicon material by activating coal gasification slag and waste hydrochloric acid through microwave synergistic mechanical force, and belongs to the technical field of industrial solid waste recycling. The method comprises the following steps that the coal gasification slag is sequentially subjected to microwave radiation treatment and ball milling, activated slag and waste hydrochloric acid are subjected to an acid leaching reaction, and aluminum-iron-containing leachate and silicon-rich slag are obtained; extracting the aluminum-iron-containing leaching solution to obtain an iron-rich organic phase and a purified aluminum chloride solution; performing thermal polymerization reaction on the purified aluminum chloride solution to obtain polyaluminum chloride; the method comprises the following steps: carrying out alkaline leaching reaction on silicon-rich slag and waste alkali liquor, adding a structure-directing agent into a sodium silicate solution, and sequentially carrying out aging, solution pH value adjustment and crystallization precipitation to obtain mesoporous silica. According to the method, the aluminum-silicon leaching rate is remarkably increased through microwave-mechanical force synergistic activation, synergistic and efficient treatment of the three kinds of waste including the coal gasification slag, the waste hydrochloric acid and the waste alkali liquid is achieved, the technological process is closed, the product additional value is high, and the environmental and economic benefits are remarkable.

The invention discloses a method for leaching valuable elements in silicate rare earth ore, and belongs to the technical field of rare earth metallurgy. According to the method, the valuable elements in the rare earth concentrate are efficiently leached by adopting the processes of low-temperature sulfating intensified roasting, clinker hydrometallurgy, leached ore pulp flocculation and filter cake washing. The strengthened low-temperature sulfating roasting process avoids the problems of high energy consumption, serious equipment corrosion, low rare earth leaching rate and complex waste gas treatment (SO2 escape) of a traditional process, meanwhile, silicate rare earth ore decomposition is achieved, the effect of a back-end leaching process is remarkably improved, compared with an acid pickling process, the hydrometallurgy process reduces the acid consumption and the wastewater treatment difficulty, and the production cost is reduced. The leaching ore pulp flocculating settling process is beneficial for improving the industrial production efficiency, the filter cake washing process is beneficial for further improving the leaching rate of valuable elements, the silicate rare earth ore concentrate resources are utilized to the maximum extent on the premise of being environmentally friendly, and a technical path is provided for industrial utilization of silicate type rare earth ore.

The invention discloses a multi-stage oxygen pressure leaching process for coarse-grained zinc sulfide concentrate, and belongs to the technical field of hydrometallurgy. The process comprises the following steps: carrying out first-stage high-temperature oxygen pressure leaching on 80-160-mesh coarse-grained zinc sulfide concentrate; the first-section leaching residues are subjected to flotation separation, and flotation concentrate and flotation tailings are obtained; and the flotation concentrate is finely ground and then subjected to second-stage low-temperature oxygen pressure leaching. Flotation operation is introduced between the first-stage oxygen pressure leaching and the second-stage oxygen pressure leaching, a large amount of gangue minerals and iron are effectively separated and opened, the amount of materials entering the second-stage leaching is remarkably reduced, and therefore the second-stage ore grinding load and leaching energy consumption are greatly reduced while the high leaching rate of zinc, indium, copper and the like is guaranteed, and the leaching efficiency is improved. And efficient, energy-saving and stable treatment of the coarse-grained zinc sulfide concentrate in a zinc hydrometallurgy system is realized.

The invention provides a method for treating clay type lithium ore through multi-composite-field medium-low-temperature roasting and continuous water leaching, and belongs to the technical field of mineral processing. According to the method, multi-field roasting and continuous leaching processes are adopted for treatment, a microwave-suspension composite roasting device is adopted for multi-field roasting, and a plurality of continuous leaching devices are adopted for continuous leaching. The method provided by the invention has the advantages of simple process flow, high roasting efficiency and low energy consumption, and can effectively destroy mineral lattices of the clay type lithium ore; in addition, by means of the continuous leaching technological process, the lithium extraction rate is greatly increased, the lithium leaching rate is increased, the use amount of an acid leaching agent is reduced, sulfuric acid is recycled, the water demand is reduced, the problem of lithium resource shortage is solved, and a theoretical basis is provided for subsequent industrial production.

The application provides an amino acid composite reagent system and a method for treating electronic waste to prepare high-purity glycine copper, and belongs to the technical field of metal hydrometallurgy and resource recycling. The application builds an ammonia catalytic reduction mechanism by designing an amino acid composite reagent system, greatly improves the leaching rate, simultaneously inhibits the dual effects of copper hydroxide precipitation and glycine chelation, and realizes efficient solution of copper ions; through narrow window regulation technology of pH at 9.5±0.2, the stability of ammonia, the activity of glycine anion are maintained, and the selective leaching rate of copper is ensured; a directional crystallization process of leaching solution is constructed, the "self-assembly directional crystallization" process of glycine copper chelate is used, based on the saturation concentration of glycine copper in the leaching solution and the stable chelate structure, through three-stage crystallization precise regulation, the preparation of high-purity crystal is realized. The process realizes the closed-loop crystallization system of "zero addition of crystal seeds and zero wastewater discharge" of the copper-containing complex leaching solution of electronic waste.

The invention discloses a method for efficiently leaching and extracting germanium from germanium-containing zinc oxide smoke dust based on ultrasonic strengthening, and relates to the technical field of metal metallurgy, the method comprises the specific steps of raw material pretreatment, ultrasonic-assisted leaching, solid-liquid separation and zinc powder replacement germanium precipitation, germanium-enriched slag strengthened leaching and germanium enrichment and purification; according to the method, the ultrasonic leaching device is introduced, the leaching efficiency of germanium in the germanium-containing zinc oxide smoke dust is improved, passive films on the surfaces of smoke dust particles are effectively damaged through the action of the ultrasonic leaching device, permeation of a leaching agent into the particles is accelerated, and therefore efficient leaching of germanium is achieved within a short time, and meanwhile the leaching efficiency of germanium in the germanium-containing zinc oxide smoke dust is improved. According to the method, the leaching rate of germanium is increased by optimizing the proportion and leaching conditions of the mixed leaching agent, the germanium slag leaching solution is merged into the initial leaching solution, and a secondary enhanced leaching process of a subsequent zinc powder replacement germanium precipitation procedure is carried out, so that the maximum recovery of germanium resources is ensured, the overall resource utilization rate is increased, and the production cost is reduced.

The invention relates to the technical field of solid waste recycling, and particularly provides a circulating fluidized bed system for gasification fly ash resourceful treatment and an aluminum oxide leaching method. The system comprises a hearth, a gas-solid heat exchange bed and an activation reactor. The gasified fly ash and a water glass binder are agglomerated and thickened through a fine powder agglomerator, incineration is conducted through a hearth, and ammonia gas is injected to fix heavy metal; the ash enters an activation reactor, a mullite structure is destroyed by utilizing residual carbon oxygen-enriched combustion (850-950 DEG C) of fly ash, aluminum ions are extracted through gradient acid leaching, acid leaching liquid is neutralized by ammonia water to precipitate aluminum hydroxide, and high-purity aluminum oxide (greater than 99%) and a byproduct ammonium chloride fertilizer are obtained through calcination; the escape rate of fine particles is lower than 10%, the leaching rate of aluminum oxide exceeds 85%, and the treatment cost is reduced by 50% or above compared with that of a traditional method.

The invention provides a method for roasting-leaching clay type lithium ore by replacing a roasting aid with biomass, and belongs to the technical field of ore dressing processes. According to the method, the plant ash generated after biomass combustion is used for replacing part of alkali-containing salt or alkali in the clay type lithium ore so as to achieve the purpose of alkali roasting-water leaching, the sintering condition of a roasting auxiliary and the clay type ore can be effectively reduced through addition of the plant ash, and bulk consumption of solid waste of the plant ash is achieved. The invention provides a mixed roasting-water leaching method of plant ash generated after biomass combustion and clay type lithium ore, so that the consumption of a roasting auxiliary agent is greatly reduced (the consumption of an alkaline agent is reduced by 50-80%), the phenomenon that the roasting auxiliary agent and the clay type ore are easy to sinter at high temperature is improved, clean and effective utilization of biomass is realized, and the method is suitable for industrial production. The lithium obtained through the method is high in leaching rate and low in cost.

The invention relates to the technical field of solid waste biological treatment, and discloses La and Ce toxicity resistant thiobacillus thiooxidans and application thereof, and the collection number of the thiobacillus thiooxidans is GDMCC No: 63522. The invention provides a novel thiobacillus thiooxidans, and the preservation number of the novel thiobacillus thiooxidans is GDMCC No: 63522. The strain can highly tolerate La and Ce, and can realize biological leaching of solid wastes rich in La or (and) Ce under high ore pulp density, so that more solid wastes can be treated in a single batch, the biological leaching rate is improved, and the strain has a good application prospect.

The invention discloses an in-situ leaching liquid injection system and method for high-altitude ionic rare earth ore, and belongs to the field of rare earth hydrometallurgy. The system is composed of a liquid injection well pattern, a layered liquid injection device, a first liquid supply system, a second liquid supply system and a collection system. Exploring the thickness of an ore body weathering crust and vertical distribution of rare earth / impurities; the liquid injection hole is vertically divided into an upper layer liquid injection area (1 / 3-1 / 2 of the upper part) and a lower layer liquid injection area (1 / 2-2 / 3 of the lower part); a 1.0-1.4 wt% low-concentration diethylenetriamine-ammonium acetate composite leaching agent is injected into the upper layer, and co-leaching of impurities such as aluminum and iron is reduced; 1.5-2.5 wt% of high-concentration diethylenetriamine-ammonium acetate composite leaching agent is injected into the lower layer to ensure efficient leaching of rare earth; and rare earth-rich leaching liquid is collected. Compared with a traditional full-layer high-concentration process, the method has the advantages that the use amount of a leaching agent is reduced by 20-40% while the rare earth leaching rate is kept to be larger than or equal to 90%, the aluminum ion concentration of the leachate is reduced by 30-60%, the agent cost and the follow-up impurity removal load are remarkably reduced, and the method is particularly suitable for the high-altitude, low-temperature, low-air-pressure and thick-weathered crust environment.

The invention provides a roasting conversion method of ionic rare earth acid-soluble slag, which comprises the following steps: (1) mixing the ionic rare earth acid-soluble slag and an alkaline medium to ensure that the water content of the mixed material is 20-30%, and then granulating to obtain a granulated mixture; (2) loading the granulated mixture into a customized sagger, and carrying out a roasting reaction; (3) after the roasting reaction is finished, stripping the customized saggar from the clinker to obtain preparatory slag; and (4) sequentially carrying out water washing, acid leaching and solid-liquid separation on the preparatory slag to obtain rare earth-barium chloride-rich feed liquid and acid-soluble residues. According to the method, the process problem that the roasted clinker and the sagger are difficult to separate is effectively solved, the yield of the roasted clinker is high, the total weight reduction rate of the acid-soluble slag is high, and the barium leaching rate and the rare earth leaching rate are high; the dissipation of radioactive dust is reduced, and the industrial application prospect is good.

The invention discloses a nuclear waste containing material and a preparation method and application thereof, and belongs to the technical field of nuclear waste treatment.The nuclear waste containing material is characterized in that site-specific doping of trivalent or tetravalent nuclides is achieved through trivalent or tetravalent nuclides, namely, A-site doping is conducted on Lu4Hf3O12 through Z < 3 + > or B-site doping is conducted on Lu4Hf3O12 through Z < 4 + >, the solid solubility of the A-site Z < 3 + > is as high as 25 mol%, and the solid solubility of the B-site Z < 4 + > is as high as 40 mol%; compared with a traditional pyrochlore-based material, the nuclide containing capacity is remarkably improved, the relative density of the nuclear waste containing material is larger than or equal to 95%, and the grain size can reach 1-5 microns; the prepared nuclear waste containing material is excellent in leaching resistance, and the leaching rate of the nuclear waste containing material is 2-4 orders of magnitude lower than that of a conventional curing material; the nuclear waste containing material prepared by the invention has better long-term chemical stability, and the mass loss rate of a highly-doped sample after long-term leaching is reduced by 21% compared with that of a low-doped sample.

The invention provides an amino acid composite reagent system and a method for preparing high-purity copper glycinate by treating electronic waste through the amino acid composite reagent system, and belongs to the technical field of metal hydrometallurgy and resource regeneration. According to the method, an amino acid composite agent system is designed, an ammonia catalysis barrier reduction mechanism is constructed, the leaching rate is greatly increased, the double effects of copper hydroxide precipitation and glycine chelation are synchronously inhibited, and efficient dissolution of copper ions is achieved; the ammonia stability and the glycine anion activity are maintained through a narrow window regulation and control technology with the pH value being 9.5 + / -0.2, and the copper selective leaching rate is guaranteed; the method comprises the following steps: constructing a leaching solution directional crystallization process, and preparing a high-purity crystal by utilizing a self-assembly directional crystallization process of a copper glycinate chelate based on the saturation concentration of copper glycinate in the leaching solution and a stable chelation structure through precise regulation and control of three-stage crystallization. According to the process, a closed-loop crystallization system of'zero seed crystal addition and zero wastewater discharge 'of the copper-containing complex leaching solution of the electronic waste is realized.

The present application relates to the field of non-ferrous smelting solid waste resource utilization and pollution control technology, and specifically discloses a zinc oxide fume treatment control system and method. The system comprises a raw material slurry module, a first-stage leaching alkali control module, a second-stage leaching temperature control module and a calcification arsenic precipitation control module. In the first-stage leaching process, the efficient arsenic leaching balance point is dynamically captured according to the arsenic and zinc leaching rate variation curve with pH, and the leaching agent addition amount is accurately controlled; in the second-stage leaching, the heating temperature is real-time regulated according to the dissolved zinc rate; before the calcification arsenic precipitation, oxidation treatment is carried out, the oxidation-reduction potential is controlled based on the trivalent arsenic oxidation efficiency, and the lime milk addition amount is dynamically adjusted according to the arsenic concentration and zinc content in the precipitate during the arsenic precipitation process. The present application realizes efficient selective leaching and stable solidification of arsenic, effectively inhibits the loss of zinc, and has the advantages of high separation efficiency, high resource recovery rate and the like.

The application discloses a high-pressure leaching system and a high-pressure leaching method based on carbon dioxide and oxygen. The high-pressure leaching system comprises a carbon dioxide injection device, a high-pressure oxygen injection device and a high-pressure liquid injection device. The carbon dioxide injection device is connected with a liquid injection pipeline through a carbon dioxide gas conveying pipeline and a liquid carbon dioxide conveying pipeline. One end of the liquid injection pipeline is connected with a water storage tank, and the other end of the liquid injection pipeline is connected with an injection well. The other ends of the carbon dioxide gas conveying pipeline and the liquid carbon dioxide conveying pipeline are connected with a liquid carbon dioxide storage tank. The high-pressure oxygen injection device comprises a high-pressure oxygen conveying pipeline. One end of the high-pressure oxygen conveying pipeline is connected with a liquid oxygen storage tank, and the other end of the high-pressure oxygen conveying pipeline is connected with the injection well. The high-pressure injection of gaseous or liquid carbon dioxide increases the acidity of underground water, accelerates the dissolution of minerals and the complexation of uranium. The high-pressure injection of oxygen can quickly oxidize uranium-containing minerals and reducing substances, and improve the leaching rate of uranium.

The invention belongs to the technical field of waste residue resource utilization, and particularly relates to a method for improving the leaching rate of nickel and cobalt residues and the purity of leachate, and the method comprises the following steps: uniformly mixing the nickel and cobalt residues with concentrated sulfuric acid to obtain a roasting raw material; the nickel-cobalt slag is roasted under the continuous dynamic condition, and a roasted product is obtained; and the roasted product obtained in the previous step is mixed with industrial water and an additive for leaching, the pH value is adjusted, filtering is conducted, leaching residues and leaching liquid are obtained, and the content of iron impurities in the leaching liquid is low. According to the method, through sulfating oxidizing roasting and additive adding leaching, the content of nickel and cobalt elements in the leaching solution can be increased, the iron content in the solution can be reduced, the nickel and cobalt leaching rate and the purity of the leaching solution can be increased, and environmental pollution can be reduced.

A dynamic optimization method for acid-to-ore ratio in high-pressure leaching of laterite nickel ore includes: obtaining a feed ore composition, a pulp concentration, a pulp flow rate, a leaching temperature and a pulp duration time in an autoclave, and setting a target leaching rate of nickel; setting a flow rate of sulfuric acid; obtaining a relationship between a hydrogen ion concentration in a solution and a reaction time; obtaining a theoretical leaching rate of nickel when a leaching time reaches the pulp duration time in the autoclave; comparing the theoretical leaching rate of nickel with the target leaching rate of nickel; adjusting the set flow rate of the sulfuric acid until the theoretical leaching rate of nickel is equal to the target leaching rate of nickel, calculating a corresponding optimal acid-to-ore ratio; and adjusting an opening degree of a sulfuric acid flow regulating valve of the autoclave.

The present application relates to the technical field of metal extraction, and particularly relates to a lithium extraction process for brown salt lake clay containing lithium-adsorbed ash. The lithium extraction process for brown salt lake clay containing lithium-adsorbed ash comprises the following steps: crushing and sieving the brown salt lake clay containing lithium-adsorbed ash, then immersing fine particles in a leaching agent, and filtering to obtain a leaching solution containing lithium elements; wherein the leaching agent is configured by low-mineralization water and concentrated sulfuric acid, the volume of the concentrated sulfuric acid is 5% to 20% of the volume of the leaching agent, and the low-mineralization water is natural water in Mahai Basin. The present application configures a composite leaching system by compounding low-mineralization water in a mining area with sulfuric acid, and through the triple synergistic effect of H + , SO4 2‑ and cations in low-mineralization water dissociated by sulfuric acid, the lithium leaching rate of 86.88% is achieved while the cost of the leaching agent is significantly reduced.

This invention discloses a method for extracting molybdenum from molybdenum oxide raw materials, comprising: mixing the molybdenum oxide raw materials with a certain proportion of leaching agent for leaching to obtain a first leaching solution for later use; removing impurities from the first leaching solution through resin or extractant to obtain a molybdenum-containing purified solution; adding a control agent to the molybdenum-containing purified solution to obtain a precursor solution; and placing the precursor solution in an autoclave for heating and decomposition to obtain the final product. The process of this invention can prepare molybdenum dioxide products in a short time, with simple steps and low economic cost, and avoids the introduction of ammonia nitrogen reagents throughout the process, thus preventing the generation of ammonia nitrogen waste pollutants. The molybdenum leaching rate during the leaching process and the molybdenum precipitation rate during the product preparation process of this invention exceed 99.5%.

The invention discloses a method for preparing an electrolyte by utilizing stone coal vanadium ore. The method comprises the following steps: S1, pretreatment and leaching: carrying out crushing and acid leaching treatment on raw ore; s2, purification and impurity separation: filtering the leachate by adopting a chemical precipitation method to remove precipitates; s3, extraction and back extraction process: adopting a two-stage counter-current extraction process; s4, process optimization and innovation: using digital twin modeling to synchronize actual production data in real time; and S5, finally tempering the electrolyte. In the leaching stage, the ore is heated to 100 DEG C within 10 minutes by virtue of a microwave-assisted acid leaching technology, the reaction time is greatly shortened to 30 minutes from the conventional reaction time, the leaching rate is as high as 95% or above, and meanwhile, the energy consumption is reduced by 45%; and after the leaching aid is added, the vanadium leaching rate is increased from 60% to 90% or above. In the purification step, the molar ratio of calcium to aluminum is accurately controlled to be 1: 0.3, and under the condition that the pH value is 1.5-2.0, the impurity removal rate exceeds 95%, the vanadium loss is lower than 1%, and hydrolysis loss is effectively avoided.

The application relates to a method for leaching gallium from lime residue, which comprises the following steps: adding a composite alkali liquor into lime residue to obtain a slurry; wherein the components of the composite alkali liquor include alkali metal hydroxide and alkali metal carbonate; and heating the slurry to leach gallium and obtain a gallium-containing mixed slurry. The application improves the leaching rate of gallium by using a composite alkali liquor and a combined leaching process, and solves the technical problem of poor economic efficiency of the existing gallium leaching process from lime residue. Compared with the prior art, the method avoids the defects of high equipment requirement of the traditional alkali leaching process, and the shortcomings of large acid consumption of the acid leaching process, high content of impurity elements such as calcium in the leaching solution, and complex solution purification process.

The invention discloses a technology for improving the leaching rate of micro-fine particle wrapped gold based on microwave and oxidizing agent combined pretreatment, and belongs to the technical field of gold extraction metallurgy. The process comprises the steps of ore pulp pretreatment, concentration and pulp mixing, composite oxidizing agent adding, microwave pretreatment, cyanidation leaching and the like. According to the method, the microwaves and the composite oxidizing agent are utilized, a microfine particle gold wrapping carrier is efficiently destroyed, the leaching rate of gold is increased to 85-92% from 45-55% of a traditional method, meanwhile, energy consumption is reduced by 40% or above, sulfur dioxide emission is avoided, and the method has the advantages of being efficient, low in consumption, environmentally friendly and the like and is particularly suitable for extraction of arsenic-containing, sulfur-containing, carbon-containing and other microfine particle wrapping type refractory gold ores.

The invention relates to a utilization method of low-grade easily dissolvable stone type niobium concentrate, and belongs to the field of mineral processing and hydrometallurgy. The method solves at least one of the problems of low recovery rate of Fe and Nb elements, complex process flow, high energy consumption and cost, harsh reaction conditions, high environmental pollution risk and the like in the utilization of the low-grade easily dissolvable stone type niobium concentrate in the prior art. The invention relates to a utilization method of low-grade easily dissolvable stone type niobium concentrate, which comprises the following steps: uniformly mixing niobium concentrate with a reducing agent, pelletizing, and reducing and roasting to obtain roasted ore; the roasted ore is smashed and then subjected to magnetic separation, and iron ore concentrate and tailings are obtained; acidizing and roasting to obtain re-roasted ore; circulating grass leaching to obtain grass leaching liquid and grass leaching residues; the grass extract is subjected to extraction and back extraction through extraction resin, and niobium-containing back extraction liquid is obtained. According to the method, the leaching rate of niobium and the recovery rate of the iron element are increased, the technological process is simplified, the energy consumption and the production cost are reduced, and green and environment-friendly production is achieved.

The invention relates to the technical field of mineral processing, and particularly discloses a method for leaching beryllium from low-grade chrysoberyl type beryllium ore. According to the method for leaching beryllium from the low-grade chrysoberyl type beryllium ore, firstly, the silica-alumina ratio of chrysoberyl type flotation beryllium concentrate is regulated and controlled, then granulation is conducted, then low-temperature alkaline roasting is conducted, the roasting temperature is lower than the chrysoberyl melting temperature, leaching is conducted through a sulfuric acid solution after roasting, and beryllium-rich leaching liquid is obtained through separation. The method has the advantages of low roasting temperature and high beryllium leaching rate.