537 results about "Rare earth ions" patented technology

The invention relates to the technical field of plastic packaging preparation, in particular to an anti-aging plastic packaging material and a preparation method thereof.The anti-aging plastic packaging material is prepared from, by mass, 100-140 parts of polylactic acid, 60-80 parts of PBAT, 2-5 parts of a composite anti-aging agent, 1-2 parts of a lubricant, 2-4 parts of a flame retardant and 3-6 parts of a compatilizer; the composite anti-aging agent comprises a modified anti-aging agent obtained by compounding functionalized montmorillonite and modified silicon dioxide, the functionalized montmorillonite is carnosic acid grafted rare earth ion modified montmorillonite, and the modified silicon dioxide is epoxy methyl oleate grafted silicon dioxide. According to the anti-aging plastic packaging material provided by the invention, a plastic material system with multiple protection mechanisms is constructed through the synergistic effect of all the components, and the prepared plastic packaging material not only keeps good biodegradability, but also has excellent ultraviolet light resistance and oxidation resistance.

A high-brightness and high-power fiber laser adopts an oscillator structure and comprises a pumping module, a high-reflectivity fiber grating, a gain fiber, a low-reflectivity fiber grating and a cladding light filter, the gain fiber is a rare earth ion doped ZBLAN fiber which takes ZBLAN as a matrix material and is of an all-solid-state anti-resonance structure, and the low-reflectivity fiber grating is a rare earth ion doped ZBLAN fiber which is of an all-solid-state anti-resonance structure. The gain optical fiber comprises a fiber core area, a cladding area, an anti-resonance area and a coating layer, the anti-resonance area is composed of at least one capillary tube set, each capillary tube set comprises a plurality of capillary tubes, the capillary tubes in each capillary tube set are annularly arranged on the periphery of the fiber core area with the fiber core area as the center, and the cladding layer is arranged on the cladding layer. The matrix material in each capillary tube and the matrix material in the cladding region are the same and are ZBLAN, and the matrix material ZBLAN in the fiber core region is doped with dysprosium ions. According to the invention, the rare earth doped all-solid-state anti-resonance optical fiber is adopted as the gain optical fiber, so that high-brightness, high-power and high-efficiency output can be realized.

The invention provides a preparation method of rare earth ion heavily-doped luminescent glass and application of a light source. The rare earth ion heavily-doped luminescent glass comprises the following components in percentage by mass: 50-68% of black talcum powder, 10-25% of LiF, 10-25% of NaF, 10-25% of CaF2, an externally-doped rare earth compound accounting for 15-25% of the total mass of other raw materials (black talcum powder + LiF + NaF + CaF2), and an externally-doped clarifying agent accounting for 0.5-2% of the total mass of other raw materials (black talcum powder + LiF + NaF + CaF2). The preparation raw materials of the luminescent glass are easy to obtain and low in price, the process is simple, and industrial production is easy; the emission peak of the obtained rare earth doped luminescent glass under the excitation of purple light / ultraviolet light is 450-750 nm, the internal quantum efficiency is greater than or equal to 85%, and the luminous intensity at 150 DEG C is more than 85% of the luminous intensity at room temperature. A light source packaged by the prepared luminescent glass has the characteristics of warm white light output, low color temperature (CCTlt, 4500K), high color rendering index (CRIGt, 90) and high lumen efficiency (LEgt, 851m / W).

The invention relates to the technical field of organic and inorganic hybrid functional materials, in particular to a doped chiral metal halide material with light-induced circular polarization luminescence and a preparation method and application of the doped chiral metal halide material, the chemical formula of the doped chiral metal halide material is L2BnC1-nX4, and the value of n is 0 lt; n is less than 1. The fluorescence quantum yield of a film sample is remarkably improved by using a transition metal ion or rare earth ion doping method. According to the invention, the plug splitting energy in the chiral metal halide is adjusted, so that the chiral optical property of the film material is remarkably improved. The preparation process of the chiral metal halide thin film is simple, the thin film does not need to be prepared after a single crystal material is obtained through a harsh single crystal preparation method, and the material composition and the doping proportion can be easily adjusted according to the requirements of material properties. The invention provides a feasible way for regulating and controlling the chiral optical property of the chiral metal halide by doping transition metal ions or rare earth ions.

The invention provides a holmium and ytterbium co-doped mid-infrared microsphere Raman laser and a preparation method thereof, and relates to the technical field of laser preparation, the holmium and ytterbium co-doped mid-infrared microsphere Raman laser comprises an infrared transmission optical fiber, a pump light source, holmium and ytterbium co-doped tellurate glass microspheres and passive tellurate glass microspheres, pump light emitted by the pump light source is guided to a conical region through the infrared transmission optical fiber, and the holmium and ytterbium co-doped tellurate glass microspheres and the passive tellurate glass microspheres are arranged in the conical region; sequentially carrying out optical coupling with holmium and ytterbium co-doped tellurate glass microspheres and passive tellurate glass microspheres; in the holmium and ytterbium co-doped tellurate glass microspheres, the doping amount of the holmium element is 0.3%, and the doping amount of the ytterbium element is 0.45% according to the mass percentage. Compared with the prior art, through the cascade structure of the holmium-ytterbium co-doped microspheres and the passive microspheres, three-step wavelength conversion of pump light-rare earth ion lasing-Raman frequency shift is realized in a single system for the first time, and the wavelength limitation that a traditional single microsphere depends on a rare earth ion fixed energy level is broken through.

Heterogeneous photonic circuits comprise a gain section optically coupled to a photonics section. The gain section can include at least one gain waveguide which can be formed from a III-V semiconductor material to provide optical gain. The gain waveguide can be coupled to optical components in the photonics section to form an integrated pump module. The photonics section can include a light-generating photonic circuit, which can comprise at least one waveguide doped with a rare-earth ion or transition-metal ion. Output from the integrated pump module and / or the light-generating photonic circuit can be tunable. Tuning can be implemented with feedback control.

The invention belongs to the field of glass material research, and discloses a method for regulating and controlling rare earth ion clusters in laser glass based on molecular dynamics simulation and application of the method. Based on given glass components, density and atomic number, an initial amorphous structure model M0 is constructed; based on a molecular dynamics theory, performing high-temperature melting quenching simulation on the initial amorphous structure model M0, and constructing a glass structure model M; calculating glass microstructure parameters and designing rare earth ion cluster parameters based on atomic coordinate information of the glass structure model M; establishing a glass component-microstructure mathematical model and a microstructure-rare earth ion cluster mathematical model based on the glass components, the microstructure parameters and the rare earth ion cluster parameters; based on the model, regulation and control on the agglomeration degree of the rare earth ions in the glass are realized. According to the method, the problem that the rare earth ion clusters in the laser glass cannot be quickly and effectively regulated and controlled due to the fact that the rare earth ion clusters in the glass are difficult to quantitatively describe by experimental means is solved.

The invention relates to the technical field of biomass fibers, in particular to a modified biomass fiber for a resin anticorrosive coating as well as a preparation method and application of the modified biomass fiber, and the modified biomass fiber is a biomass fiber with a rare earth complex anchored on the surface; the rare earth complex is formed by combining rare earth metal ions serving as central ions with organic ligands through coordinate bonds; rare earth ions and organic ligands are grafted to the surfaces of the pretreated biomass fibers through chemical reaction, so that the binding capacity of the biomass fibers in resin can be improved, and the biomass fibers are endowed with fluorescence characteristics; and moreover, the biomass fibers subjected to fluorescence modification are doped into the resin coating, so that the integrity of the coating can be self-detected under ultraviolet light, and the effect of monitoring the resin coating in real time can be achieved.

The invention discloses a preparation method of chromium-free fingerprint-resistant liquid for an aluminized zinc plate, and relates to the technical field of metal surface treatment materials.The preparation method comprises the steps that a benzotriazole-cerium molybdate composite corrosion inhibition system is constructed, and multiple layers of adsorption films are formed through intermolecular pi-pi accumulation and rare earth ion coordination; meanwhile, a graphene oxide / nano silicon dioxide synergistic enhancement system is introduced, graphene sheet layers are directionally arranged to form a physical barrier, and micropores are filled with nano particles to improve compactness; and meanwhile, a lanthanide rare earth compound is adopted for modifying the flash-rust inhibitor, the stability of a passivation film on the metal surface is enhanced through the empty orbital characteristic of rare earth elements, the nanometer material gradient dispersion technology is combined with the ultrasonic-mechanical coupling dispersion technology, filler uniform distribution and interface bonding strengthening are achieved, and the fingerprint resistance, corrosion resistance and the like of the film layer are effectively guaranteed.

The invention discloses a preparation method and application of a granzyme B response near-infrared two-region ratiometric fluorescent probe (DCGA). The DCGA combines the NIR-II dual-emission fluorescence characteristic of rare earth ions with a ratio-type signal response mode, the sensitivity and signal stability of in-vivo fluorescence imaging are greatly improved, ultralow or enhanced F1060nm fluorescence signals are respectively shown before and after interaction with granzyme B (GzmB), F1525nm fluorescence signals are almost kept unchanged, and the DCGA can be used for detecting the in-vivo fluorescence imaging of the granzyme B (GzmB). Therefore, the self-calibration ratio fluorescence imaging GzmB activity change is realized. The DCGA is applied to tumor treatment of immunotherapy drugs, and responders and non-responders of immunotherapy can be distinguished in a non-invasive early stage through ratio fluorescence signals of the DCGA. Therefore, the fluorescent probe can be used as an effective GzmB active NIR-II ratio fluorescence imaging tool, and is expected to provide powerful support for immunotherapy research, precision medicine and personalized diagnosis and treatment.

The invention discloses a dual-wavelength microsphere laser based on tri-doped rare earth ions and a preparation method thereof, the dual-wavelength microsphere laser based on tri-doped rare earth ions comprises a silica fiber, the middle part of the silica fiber is provided with a conical region; the pump light source is arranged at one end of the silica fiber; the erbium, holmium and ytterbium tri-doped tellurate glass microspheres are arranged in the conical region; pump light emitted by the pump light source is guided to the conical region through the single-mode optical fiber and is optically coupled with the erbium-holmium-ytterbium tri-doped tellurate glass microsphere; in the erbium-holmium-ytterbium triple-doped tellurate glass microspheres, infrared-transmitting tellurate glass is used as a matrix, and the doping amount of an erbium element is 0.11%, the doping amount of a holmium element is 0.22%, and the doping amount of an ytterbium element is 0.80% in percentage by mass. According to the dual-wavelength microsphere laser based on the three-doped rare earth ions, efficient and stable dual-wavelength laser output is achieved.

The invention relates to the technical field of batteries, in particular to a high-temperature-resistant lithium cobalt oxide positive electrode material and a preparation method and application thereof.The high-temperature-resistant lithium cobalt oxide positive electrode material comprises a lithium cobalt oxide matrix and a coating layer coating the surface of the lithium cobalt oxide matrix, the lithium cobalt oxide matrix is doped with Mg, Ti and La, and the coating layer is a fast ion coating layer of a Li-Gd-Ti-O4 spinel phase. Bulk phase doping is carried out through a high-temperature solid-phase method, Mg, Ti and La are doped in a lithium cobalt oxide matrix, and the lattice structure thermal stability of lithium cobalt oxide under high voltage (4.4 V) is improved; a fast ion coating layer of a Li-Gd-Ti-O4 spinel phase is formed on the surface of a lithium cobalt oxide matrix by adopting a solid phase method, and the comprehensive performance of the lithium cobalt oxide positive electrode material is improved through multiple mechanisms such as the lattice stabilization effect of rare earth ions, the interface barrier effect of composite oxide and lithium ion conductivity regulation and control; particularly, the capacity, the cycling stability, the thermal stability, the high-voltage tolerance and the like are realized.

The invention discloses a preparation process of a rare earth precipitation resistant electrophoretic coating for an automobile body. The preparation process comprises the following steps: S1, preparing a stable solution; s2, preparing a rare earth chelating solution; adding lanthanum lactate into the stable solution for multiple times, and adding ammonium ceric sulfate for multiple times after the lanthanum lactate is completely dissolved; s3, preparing a resin base solution; s4, preparing mixed slurry; s5, adding a solvent and an auxiliary agent; a five-membered ring chelate with thermodynamic stability is formed by carboxyl, hydroxyl and rare earth elements in sodium citrate, rare earth ions can be tightly wrapped through strong coordination bonds, namely, empty orbits of the rare earth ions and lone pair electrons of a chelating agent form coordination bonds, so that the rare earth ions cannot be dissociated in a system, and the rare earth ions are prevented from being dissociated in the system. And a path of generating hydroxide precipitates by free rare earth ions is thoroughly blocked, so that rare earth elements are effectively ensured to be uniformly distributed in the electrophoretic paint, and the surface of a raw material treated by a subsequent electrophoresis process is more uniform.

The invention belongs to the field of rare earth separation, and particularly discloses a heavy rare earth ion separation method based on complexing of a phosphate complexing agent. In the separation method provided by the invention, the phosphate complexing agent can form a heavy rare earth-phosphate complex with significant difference and good reversibility with each heavy rare earth, and then the water phase containing the heavy rare earth-phosphate complex and the organic phase are subjected to extraction separation to purify the heavy rare earth ions, so that the purpose of efficiently separating each heavy rare earth ion is achieved; the invention provides a key technical means for solving the problem of green separation of heavy rare earth.

The invention discloses a large-mode-field active optical fiber convenient to prepare. The optical fiber comprises an active fiber core region and a cladding region, luminescent rare earth ions are doped in the active fiber core area; the cladding area comprises an inner cladding area and an outer cladding area, and the inner cladding area is composed of a passive background material area and double-layer nested capillary tubes which are distributed around the active fiber core area and meet the thickness of the anti-resonance condition; the double-layer nested capillary tube comprises an inner-layer capillary tube and an outer-layer capillary tube, and the distance between the outer wall of the inner-layer capillary tube and the inner wall of the outer-layer capillary tube meets the resonance condition of an LP11 mode in an active fiber core area; the outer cladding area surrounds the inner cladding area, and pump light is limited to be transmitted in the inner cladding area and the fiber core area. The refractive index difference value between the fiber core area and the background area is increased, optical fiber preparation is facilitated, and laser mode characteristic degradation caused by active fiber core area thermally-induced refractive index change under the high-power condition is effectively restrained.

The invention belongs to the technical field of high polymer materials and electric power engineering protection, and particularly relates to an MPP power cable protection pipe containing a rare earth anti-aging system and a preparation method of the MPP power cable protection pipe. The protection tube is composed of rare earth coordination modified polypropylene, N, N '-bis (2-hydroxyethyl) adipamide, an antioxidant 1010, a light stabilizer 622, a hindered amine light stabilizer 944, a lubricant and an anti-ultraviolet absorbent. Rare earth ions and polypropylene grafted maleic anhydride form a stable coordination structure, small organic molecules enhance interface bonding through hydroxyl and acylamino hydrogen bonds, and multi-point stability of molecular chains is achieved. The thermal oxidation resistance, ultraviolet aging resistance and thermal deformation resistance of the material are remarkably improved, and the prepared cable protection tube has excellent mechanical strength, heat resistance and long-term weather resistance.

The application belongs to the field of polymer materials and power engineering protection technology, and particularly relates to a MPP power cable protection pipe containing a rare earth anti-aging system and a preparation method thereof. The protection pipe is composed of rare earth coordination modified polypropylene, N,N'-bis(2-hydroxyethyl)adipamide, antioxidant 1010, light stabilizer 622, hindered amine light stabilizer 944, lubricant and ultraviolet absorption agent. Rare earth ions and polypropylene grafted maleic anhydride form a stable coordination structure, and organic small molecules enhance the interface combination through hydrogen bonds of hydroxyl and amide groups, so that the molecular chain is stably connected at multiple points. The application significantly improves the thermal oxidation resistance, ultraviolet aging resistance and thermal deformation performance of the material, and the prepared cable protection pipe has excellent mechanical strength, heat resistance and long-term weather resistance.

The present application belongs to the field of rare earth separation, and particularly discloses a method for separating heavy rare earth ions. In the method, a vinyl complexing agent including at least one of vinyl phosphonic acid, vinyl sulfonic acid, vinyl acetic acid or 4-vinyl benzyl chloride is used to selectively complex heavy rare earth ions in an aqueous phase, so as to obviously increase the distribution coefficient between different heavy rare earth ions. Then, the aqueous phase containing the complex of heavy rare earth ions is subjected to extraction separation of different heavy rare earth ions with an organic phase containing an extractant, so as to achieve the purpose of improving the separation efficiency.

The invention relates to the field of road building materials, and discloses an anti-ultraviolet aging environment-friendly asphalt regenerant suitable for a plateau environment and a preparation method of the anti-ultraviolet aging environment-friendly asphalt regenerant. Comprising the following components in parts by weight: 60-70 parts of plant-based light oil, 5-10 parts of an anti-ultraviolet aging agent, 5-10 parts of an epoxy plasticizer, 5-10 parts of an elastic restorer, 5-10 parts of a reducing agent, 5-10 parts of an inorganic rare earth ion complexing agent, 1-5 parts of a penetrant, 1-5 parts of a non-amine anti-stripping agent and 1-5 parts of a stabilizer. The asphalt regenerant provided by the invention not only can effectively recover the performance of aged asphalt, but also shows excellent ultraviolet aging resistance especially for a strong ultraviolet radiation environment in a plateau high-altitude area, so that the service life of an asphalt pavement is prolonged.

The invention provides an optical gain and electro-optical modulation integrated device and a preparation method thereof, and relates to the field of photoelectron, the optical gain and electro-optical modulation integrated device comprises a chip platform, and an electro-optical modulator and a gain waveguide which are integrated on the chip platform, and the chip platform is doped with rare earth ions in a region corresponding to the gain waveguide; the electro-optical modulator is used for modulating an input optical signal to obtain a modulated optical signal; and the gain waveguide is used for amplifying the modulated optical signal under the action of the pump light and the rare earth ions to obtain a target optical signal. The electro-optical modulator and the gain waveguide are integrated on the chip platform, cooperative work between the electro-optical modulator and the gain waveguide is achieved through rare earth ions, integrated design is achieved, the defects of discrete devices are overcome, and the design target of an on-chip photonic system can be met.

The invention discloses a prospecting exploration method for ion adsorption type heavy rare earth ore in middle and low mountainous areas, and belongs to the technical field of geological mineral exploration. According to Y, Dy and Nb abnormity and Y-Nb combination abnormity areas such as water chemical exploration and soil chemical exploration of a working area, high-silicon, potassium-rich, alkali-rich and sphene-rich heavy rare earth secondary mineral mineralization mother rocks are preferably selected, and a favorable mineralization area of the ion adsorption type heavy rare earth ore is delineated by combining characteristic parameters that Y / Ce is greater than 0.9 and Dy / Ce is greater than 0.2; screening south and east-south-east abrupt slope (gradient of about 30 degrees) areas by utilizing a GIS spatial analysis technology, overlapping favorable mineralization areas of the ion adsorption type heavy rare earth ore, and comparing and determining an ion adsorption type heavy rare earth ore prospecting target area in a working area; whether mineralization abnormity exists in the heavy rare earth ore prospecting target area or not is verified by using a manual impact sampling drill and a rare earth ion leaching-titration qualitative analysis method; chemical samples are preliminarily collected, 15 components of ion phases are analyzed, whether heavy rare earth ore bodies exist or not is judged and evaluated, the prospecting exploration range of the ion adsorption type heavy rare earth ore is determined, and the prospecting efficiency of the ion adsorption type heavy rare earth ore is improved. According to the method, the mineralization prospective area of the ion adsorption type heavy rare earth ore can be rapidly delineated in a large range, the prospecting target area is narrowed, and the prospecting efficiency of the ion adsorption type heavy rare earth ore is improved.

A process for ultrasensitive in vitro detection and / or quantification of a substance of interest in a sample is performed by detecting the luminescence emission by photoluminescent inorganic nanoparticles. The process includes (i) use of photoluminescent particles comprising a photoluminescent inorganic nanoparticle consisting of a crystalline matrix having at least 103 rare-earth ions, and coupled to a targeting agent for the substance to be analyzed, under conditions conducive to their association with the sample substance to be analyzed; (ii) exciting the rare-earth ions of the particles by an illumination device having a power of at least 50 mW and an excitation intensity of at least 1 W / cm2; (iii) detecting the luminescence emission by the particles after single-photon absorption; and (iv) determining the presence and / or concentration of the substance by interpreting said luminescence measurement. This process can be used for in vitro diagnostic purposes and as an in vitro diagnostic kit.

The invention discloses a method capable of reducing the refrigeration interval of rare earth fluoride, and belongs to the field of magnetic functional materials. According to the method, diamagnetic ions K < + > are added into rare earth fluoride to reduce magnetic interaction among rare earth ions, so that a magnetic phase transformation point moves to a lower-temperature region, and a lower magnetic ordered temperature and a lower refrigeration interval are obtained while large magnetic entropy change is ensured. The series of materials are LnF3 (Ln = Tb, Dy, Ho, Er, Tm) powder samples and KLn1. 4F5.2 powder samples obtained after K < + > ions are introduced. In order to explore the influence of the addition of K < + > on the magnetic ordered temperature, a 100Oe variable magnetic field is respectively applied to the series of materials. The introduction of K < + > enables the Curivus temperature of the material to be obviously reduced to 3K or below. By comparing the effects of K < + > with different contents on the overall performance of the material, the optimal ratio of K / Gd is found, and under the optimal ratio of LnF3 series samples, before and after the K < + > is introduced, the changes of theta CW values are 4.34 to 2.04 K, 5.31 to 1.76 K, 8.31 to 2.54 K, 14.74 to 1.73 K and 3.59 to 1.75 K in sequence.

The invention provides an electrolysis method for a solution containing rare earth ions, and relates to the technical field of hydrometallurgy, the electrolysis method comprises the following steps: taking the solution containing rare earth ions as a catholyte, carrying out electrolysis to increase the pH value of the catholyte, obtaining a turbid solution in a cathode chamber, carrying out solid-liquid separation to obtain a solid-phase substance which is a precipitate rich in rare earth or a precipitate rich in impurities, according to the method, the solid-phase substance is separated from the rare earth, so that selective separation and enrichment are realized, that is, when the solid-phase substance is a precipitate containing rare earth, the purpose of preparing a high-grade rare earth enriched substance can be achieved through electrolysis, and when the solid-phase substance is a precipitate containing impurity ions, the purpose of separating the impurity ions can be achieved through electrolysis; according to the electrolysis method, chemical reagents do not need to be added, new ions are not introduced, salt-containing wastewater is not generated, operation is easy, and the process is clean and free of pollution.

The invention relates to the technical field of rare earth oxide preparation, in particular to a high-purity rare earth metal oxide efficient preparation method which comprises the steps that rare earth metal raw materials are dissolved in ethyl alcohol, and a first solution is obtained; reacting organic acid with the first solution to generate mixed complex salt; adding oxygen aerosol into the mixed complex salt, and reacting the mixed complex salt in combination with UV light treatment to form a rare earth oxide precursor; according to the method, organic acid H2C2O4 is introduced to serve as a complex salt ligand, rare earth ions are stabilized, reaction uniformity and stability are achieved, oxygen aerosol and UV light are used for treatment, the reaction speed and product structure control are improved, a microcosmic control technology is combined, and the high-purity rare earth metal oxide is obtained. Reaction parameters and structural design are optimized, the morphology and lattice structure of the rare earth oxide are regulated and controlled, the preparation efficiency of the rare earth metal oxide is improved, and relatively high purity is obtained.

The invention is applicable to the technical field of photoelectricity, and provides a single-matrix white-light rare earth lead-free perovskite nanocrystal, a preparation method and application, and the single-matrix white-light rare earth lead-free perovskite nanocrystal is Eu < 3 + > ion doped Cs3TbCl6 nanocrystal. The rare earth ion Eu < 3 + > is doped into the Cs3TbCl6 nanocrystal, full-spectrum white light emission of blue light (matrix self-limiting state exciton emission), green light (Tb < 3 + > ion emission) and red light (Eu < 3 + > ion emission) is obtained, excellent thermal stability and environmental stability are achieved, and the nanocrystal material also shows excitation light dependent color adjustable emission (blue light, green light, red light and white light) and has good application prospects. The nanocrystal prepared based on a solution method can be applied to large-area flexible photoelectric devices; the fluorescent conversion layer can be used as a fluorescent conversion layer of a white light emitting diode with a high color rendering index, and can also be applied to anti-counterfeiting and information encryption.

The invention discloses a device and a method for extracting and separating rare earth. The device comprises high-shear emulsification equipment, an extraction kettle connected with the high-shear emulsification equipment, an organic phase recovery barrel connected to the extraction kettle and a rare earth-rich internal phase solution barrel connected to the extraction kettle, the method comprises the following steps: firstly, preparing a liquid membrane, mixing a matrix, a flow carrier and a surfactant in proportion, forming a stable emulsion liquid membrane through high-shear emulsification equipment, then injecting the emulsion liquid membrane and rare earth feed liquid into an extraction kettle, and forming a complex on the outer surface of the membrane by rare earth ions and the flow carrier; selective migration of target rare earth, reaction of a rare earth complex and an acid solution and desorption of rare earth elements into an internal-phase aqueous solution are realized by utilizing the complexing ability difference of different rare earth and a carrier, and a rare earth enriched solution with the internal-phase rare earth concentration of 50 g / L or above is formed in the process.

The invention relates to the technical field of functional composite color-changing materials, in particular to a dynamic color-changing flexible composite material and a preparation method and application thereof. The flexible composite material is prepared from the following raw materials: photochromic powder, a flexible film matrix, low-viscosity silicone oil and a curing agent, the chemical general formula of the photochromic powder is (Li < 0.1 > Na < 0.4 > Bi < 0.5 >) < 0.95-x > Bi < 2 > Pr < x > Y < 0.05 > Nb < 2 > O < 9 >, wherein x ranges from 0.001 to 0.05. According to the flexible composite material provided by the invention, inorganic photochromic powder doped with rare earth elements is introduced into a PDMS / low-viscosity silicone oil elastomer matrix, and the composite ratio of the photochromic powder to the flexible film matrix and the doping content of rare earth ions praseodymium in the photochromic powder are regulated and controlled; the real-time, accurate and reversible regulation and control of the optical characteristic color of the material are realized by virtue of photostimulation, and a brand new thought is provided for preparing an optical stealth material.

Hybrid integrated photonic integrated circuit laser comprising a photonic integrated circuit including an elongated optical waveguide comprising an elongated gain medium waveguide, at least a first and second optical reflector, the gain medium waveguide being located or extending between the first and second optical reflectors and being located inside an optical cavity to provide optical feedback. Further comprising a pump laser diode to provide electromagnetic radiation to the gain medium waveguide. The elongated optical waveguide, and the first and second optical reflectors are monolithically integrated inside the photonic integrated circuit. The gain medium waveguide comprises a rare-earth ion implanted silicon nitride waveguide core. The pump laser diode is positioned adjacent to the at least one photonic integrated circuit and is edge coupled or facet coupled to a lateral edge or a facet of the photonic integrated circuit to provide pump radiation to the rare-earth ion implanted silicon nitride waveguide core.

The invention discloses white dry granules with a multi-layer three-dimensional effect and a preparation method thereof, and relates to the technical field of building ceramic materials. The white dry granules with the multi-layer three-dimensional effect are prepared from a frit base material and a rare earth calcium phosphate additive, rare earth and calcium phosphate are added into a frit base material to serve as an additive, the high refractive index of oxides of La < 3 + > and Ce < 3 + > is utilized, refractive index difference is formed between the oxides of La < 3 + > and Ce < 3 + > and the frit base material, and light rays are subjected to multiple scattering and refraction at an interface; and meanwhile, the refractive index gradient is formed through particle size grading synergism, the reflection and refraction paths of light rays among particles with different particle sizes are different, and the visual'depth sense 'is generated. The additive is uniformly dispersed to ensure the consistent optical effect and avoid local over-brightness or over-darkness; due to the high refractive index of rare earth ions, light scattering is enhanced, and whiteness is improved; grain size distribution and light scattering are cooperated to form a multi-layer stereoscopic visual effect of bottom-layer framework support, middle-layer transition connection and top-layer fineness and brightness, and the decoration is enhanced.