43 results about "Phosphate glass" patented technology

The present invention relates to ternary lithium nickel phosphate glasses and a process for their production. The invention also relates to the preparation and use of said glasses as active materials for positive electrodes, particularly in metal-ion batteries, as well as to said active materials and electrodes per se. (no figure)

Disclosed in the present invention are an antimicrobial glass composition comprising a mixture of two types of glass, an antimicrobial glass powder thereof, and a method for producing same. The dual-type antimicrobial glass composition is prepared by mixing an Ag-containing borate glass and a Zn-containing phosphate glass to appropriately utilize two antimicrobial active substances. The dual-type antimicrobial glass composition is designed such that the Ag-containing borate glass and the Zn-containing phosphate glass have different elution rates when exposed to moisture or the like, thereby forming a crystalline phase in which an elution of Ag does not manifest as discoloration and thus suppressing discoloration caused by reduction of Ag.

This invention belongs to the field of optical glass technology and discloses a method for preparing low-hydroxyl NdFeB-doped fluorinated phosphate glass by discharge plasma sintering. Using Sr(PO3)2, Ba(PO3)2, MgF2, AlF3, NdF3, or NdI3 as raw materials, a batch is prepared by mixing in a specific ratio. The batch is then sintered by discharge plasma and cooled to obtain NdFeB-doped fluorinated phosphate glass. The sintering pressure is 250-300 kg, the sintering temperature is 1000-1200℃, and the holding time is 15-40 min. This invention successfully prepares NdFeB-doped fluorinated phosphate glass using discharge plasma sintering technology. Compared with the high-temperature melting method with the same formula, the melting temperature of this invention is reduced by 200℃, and the hydroxyl absorption coefficient is reduced from 4.77 cm⁻¹. ‑1 It dropped to 0.075cm ‑1 The lifetime increased from 339.1 μs to 388.4 μs, providing a new approach for preparing high-efficiency luminescent fluorine-phosphorus optical glass with low hydroxyl absorption coefficient.

The application discloses a mineralization treatment method of organic waste liquid, and belongs to the technical field of radioactive waste treatment. The organic waste liquid contains uranium, tributyl phosphate and diluent. The mineralization treatment method comprises the following steps: the organic waste liquid is separated through short-path molecular rectification to obtain a diluent fraction and a tributyl phosphate fraction; the tributyl phosphate fraction is reacted with alkali liquor to generate an alkaline hydrolysis product containing dibutyl phosphate salt, n-butanol, water and uranium; the n-butanol is collected through condensation reflux; and the remaining alkaline hydrolysis product is treated through two-stage oxygen-controlled incineration, so that phosphate glass and qualified flue gas are finally obtained. The mineralization treatment method has the advantages of no corrosion, short process, high-efficiency mineralization and stabilization of the waste liquid, direct disposal of the product, consideration of resource recovery and radioactive safety, and easy industrialization.

An insulator-coated soft magnetic powder includes:a soft magnetic powder formed of an Fe—Si—B—C-based amorphous alloy soft magnetic material; andan insulating coating that coats a surface of the soft magnetic powder and contains a phosphate-based glass;wherein the average particle diameter is 15.0 μm or more and 40.0 μm or less;the phosphate-based glass is a glass containing phosphorus oxide as a main component and containing Li; andthe ratio Li / P of the content of Li to the content of P quantified by an elemental analysis method is 0.01 or more and 0.20 or less.

This invention relates to a fluorophosphate glass containing P, F, and O as essential components, with Cu as a cation percentage. 2+ It is 5-14%, (Ca 2+ Ba content 2+ (content) / ΣR 2+ (ΣR 2+ It refers to Ba 2+ 、Sr 2+ Ca 2+ Mg 2+ The total amount (total) is 0.75–1.0, Li + Content / ΣR' + (ΣR' + It refers to Li + Na + The total amount of the substance is 0.75 to 1.0 (excluding 1.0), and its Young's modulus is above 70 GPa.

This invention provides a radiation-resistant fluorophosphate glass and its preparation method, relating to the field of glass preparation technology. The fluorophosphate glass, by weight, comprises the following raw materials: Ba(PO3)2 30-48 parts, Sr(PO3)2 6-12 parts, Al(PO3)3 10-16 parts, AlF3 4-8 parts, MgF2 4-8 parts, BaF2 4-10 parts, SrF2 6-10 parts, LiF1-4 parts, and Ce-Gd@LaF3 nanocomposite 0.5-2.0 parts. The Ce-Gd@LaF3 nanocomposite is prepared by the following method: a Ce-Gd co-doped nanocomposite is synthesized using Ce(NO3)3·6H2O and Gd(NO3)3·6H2O, and then LaF3 is coated onto the surface of the Ce-Gd co-doped nanocomposite to obtain the Ce-Gd@LaF3 nanocomposite. A method for preparing a radiation-resistant fluorophosphate glass includes Ce-Gd co-doped nanocomposite synthesis, LaF3 coating, and melting of the co-doped fluorophosphate glass. This invention provides a radiation-resistant fluorophosphate glass with excellent radiation resistance, mechanical properties, and optical properties.

The invention discloses high-conductivity high-temperature sintered copper paste, a preparation method and application, and solves the technical problems of insufficient densification of a conductive network and high resistivity caused by thermal decomposition of an organic carrier in the high-temperature sintering process of the existing copper-based conductive paste. The copper paste comprises the following raw material components in parts by weight: 50-80 parts of copper powder, 15-45 parts of an acrylic resin organic carrier, 10-36.5 parts of a solvent, 0.5-5 parts of a dispersing agent, 0.5-5 parts of a flatting agent and 3-15 parts of low-melting-point phosphate glass powder. The conductive performance of the sintered copper film is improved to be close to the performance level of a high-conductivity copper material, meanwhile, good film adhesive force is achieved, and a reliable slurry solution is provided for low-cost manufacturing of high-performance electronic elements.

The application discloses a glass antibacterial agent and a preparation method and application thereof, and antibacterial glass slurry. The glass antibacterial agent comprises a glass base and an antibacterial metal oxide; the antibacterial metal oxide is ZnO and / or CuO; the content of the antibacterial metal oxide is 12wt%-35wt%; the glass base is one or more of silicate glass, borate glass, borosilicate glass and phosphate glass; wherein, the glass base comprises an alkaline earth metal oxide; the content of the alkaline earth metal oxide is 4wt%-20wt%. The glass antibacterial agent in the application has good stability, can be stored at room temperature for 3-6 months without sedimentation and agglomeration, has good dispersing performance in paint, and can make the paint have excellent antibacterial performance; meanwhile, the preparation method of the glass antibacterial agent in the application is simple and safe, is suitable for large-scale production, and has wide application prospect in the fields of paint and fiber.

comprising an optoelectronic component (100): a semiconductor chip (1); a conversion element (2) comprising a wavelength-converting phosphor dispersed in a matrix material (5); where - the matrix material (5) is a phosphate glass and is water-resistant; - the phosphate glass includes P2O5, Al2O3, B2O3, Na2O, K2O and F, - the optoelectronic component (100) is configured to emit warm white light during operation, - the warm white light has a correlated color temperature in the range of 1500 K to 3500 K, and - the light is emitted from the semiconductor chip (1) through the conversion element (2).

We provide phosphate glass with a high refractive index and low density. [Solution] The glass composition contains phosphorus oxide (P2O5), niobia (Nb2O5), barium oxide (BaO), and potassium oxide (K2O) as essential components, and may optionally contain titania (TiO2), calcium oxide (CaO), sodium oxide (Na2O), lithium oxide (Li2O), bismuth oxide (Bi2O3), strontium oxide (SrO), tungsten oxide (WO3), and other components, with the total of TiO2 + Nb2O5 being 1.0 mol% or more and 55.0 mol% or less. The glass can be characterized by a high refractive index at 587.56 nm at relatively low density at room temperature.

The glass composition includes phosphorus oxide (P2O5), niobium oxide (Nb2O5), barium oxide (BaO), and potassium oxide (K2O) as essential components, and can optionally include titanium oxide (TiO2), calcium oxide (CaO), sodium oxide (Na2O), lithium oxide (Li2O), bismuth oxide (Bi2O3), strontium oxide (SrO), tungsten oxide (WO3), and other components. The glass can be characterized as having a high refractive index at 587.56 nm with a comparable room temperature low density.

The application discloses an inductive heating starting method for nuclear waste cold crucible glass solidification, which comprises a bubble tube arranged in a stepped mode, starting glass filled with two particle sizes, a high-conductivity consumable light starting medium with proper volume density, thickness and weight, and a high-frequency power source power setting program. The application is applicable to the starting heating of phosphate glass and borosilicate glass, improves the melting efficiency of the glass, shortens the consumption time of the light starting medium after floating, realizes rapid and efficient starting, and has the advantages of simple operation, controllable process, no pollution and high safety.

The invention relates to an optical filter. The optical filter is provided with phosphate glass, a dielectric multilayer film (1) and a dielectric multilayer film (2) provided on both surfaces of the phosphate glass, a barrier film (1) provided between the phosphate glass and the dielectric multilayer film (1), a barrier film (2) provided between the phosphate glass and the dielectric multilayer film (2), and a light absorption layer provided on the dielectric multilayer film (2), the barrier film (1) and the barrier film (2) each independently contain one or more elements selected from the group consisting of TiO2, Nb2O5, Ta2O5, and HfO2, and the optical filter satisfies specific spectral characteristics (i-1) to (i-5).

Glass compositions include one or more of phosphorus oxide (P2O5), niobia (Nb2O5), titania (TiO2), potassium oxide (K2O) and lithium oxide (Li2O) as essential components and may optionally include barium oxide (BaO), zinc oxide (ZnO), V2O5 (vanadia), FeO (iron oxide) and other components.

A device for supporting surgical procedures and method of its manufacture include preparing a glass melt in a silica crucible, injecting a gas bubble into the glass melt, shaping the glass melt containing the gas bubble into a phosphate glass structure having a tubular shape, cooling the phosphate glass structure, wherein the phosphate glass structure includes a network-forming component and a modifier, and truncating the phosphate glass structure into a desired length to form the device, wherein the device has a dissolution rate of at least 50 mg cm−2 hr−1.

The present application relates to calcium-containing high refractive phosphate glasses. The glass composition contains phosphorous oxide (P2O5), niobium oxide (Nb2O5), titanium oxide (TiO2), potassium oxide (K2O), and calcium oxide (CaO) as essential components, and can optionally contain barium oxide (BaO), sodium oxide (Na2O), lithium oxide (Li2O), tungsten oxide (WO3), bismuth oxide (Bi2O3), tantalum oxide (Ta2O5), silicon oxide (SiO2), and other components. The glass can be characterized as having a high refractive index at 587.56 nm with a comparable room temperature low density.

An optical filter includes: a phosphate glass; a dielectric multilayer film 1 and a dielectric multilayer film 2 provided on both surface sides of the phosphate glass; a barrier film 1 provided between the phosphate glass and the dielectric multilayer film 1; a barrier film 2 provided between the phosphate glass and the dielectric multilayer film 2; and a light-absorbing layer provided on or above the dielectric multilayer film 2, in which the phosphate glass has near-infrared ray absorbing properties, is substantially free from fluorine atoms, and has a thickness of 0.3 mm or less, the light-absorbing layer includes a near-infrared ray absorbing dye, the barrier film 1 and the barrier film 2 each independently include one or more selected from TiO2, Nb2O5, Ta2O5, and HfO2, and the optical filter satisfies all of spectral characteristics (i-1) to (i-5).

The glass composition includes niobium oxide (Nb2O5), phosphorous oxide (P2O5), and titanium oxide (TiO2) as essential components, and can optionally include calcium oxide (CaO), potassium oxide (K2O), barium oxide (BaO), sodium oxide (Na2O), lithium oxide (Li2O), magnesium oxide (MgO), zinc oxide (ZnO), and other components. The glass can be characterized as having a high refractive index at 587.56 nm with a comparable room temperature low density.

The glass composition includes phosphorus oxide (P2O5), niobium oxide (Nb2O5), titanium oxide (TiO2), potassium oxide (K2O), and calcium oxide (CaO) as essential components, and can optionally include barium oxide (BaO), sodium oxide (Na2O), lithium oxide (Li2O), tungsten oxide (WO3), bismuth oxide (Bi2O3), tantalum oxide (Ta2O5), silicon oxide (SiO2), and other components. The glass can be characterized as having a high refractive index at 587.56 nm with a comparable room temperature low density.

An optical filter includes a glass substrate in which a first barrier layer, a resin layer, and a first multilayer film are disposed on a first main surface of the glass substrate in order from near to far from the glass substrate, and a second barrier layer, a resin layer, and a second multilayer film are disposed on a second main surface of the glass substrate in order from near to far from the glass substrate. A second barrier layer and a second multilayer film are arranged in this order from near to far from the glass substrate, and the glass substrate is phosphate glass containing an infrared absorbent; the first barrier layer and the second barrier layer each independently contain an oxide of at least one metal selected from the group consisting of titanium (Ti), niobium (Nb), tantalum (Ta), and hafnium (Hf) at a ratio of 80 mol% or more, and the first multilayer film and the second multilayer film each independently contain a plurality of dielectric layers.

This invention claims protection for the core glass of an optical fiber used for long-distance solar-blind detection and its preparation method. The core glass is composed of a matrix glass doped with rare earth ions, wherein the matrix glass is a silicate, germanate, or phosphate glass, and the rare earth ions are selected from Tb. 3+ Eu 3+ Ce 3+ One or more of the following. Its preparation method includes batching, high-temperature melting, casting, and annealing steps. This fiber-core glass can efficiently convert solar-blind ultraviolet light into visible light and transmit it over long distances with low loss using optical fibers made from it, solving the problem that existing bulk fluorescent materials cannot be used for long-distance detection. This invention provides a novel material solution and integrated technology approach for long-distance, high-sensitivity detection of solar-blind ultraviolet signals.

A fluorophosphate glass which essentially contains P, Al, K, Cu, F, and R (R is one or more elements selected from among Li, Na, Rb, and Cs), has an Al < 3 + > content of 2-20% by mass, and has an expected value of an ion radius of an alkali metal component containing K and R of 80 picometers or more and less than 133 picometers.

The invention relates to an optical filter. The optical filter is provided with: a phosphate glass having near-infrared absorbency and a thickness of 0.3 mm or less; a dielectric multilayer film (1) and a dielectric multilayer film (2) provided on both surfaces of the phosphate glass; a barrier film (1) provided between the phosphate glass and the dielectric multilayer film (1); and a barrier film (2) provided between the phosphate glass and the dielectric multilayer film (2). And a light absorbing layer that is provided on the dielectric multilayer film (2) and contains a near-infrared ray absorbing dye, in which the barrier film (1) and the barrier film (2) each independently contain one or more elements selected from the group consisting of TiO2, Nb2O5, Ta2O5, and HfO2, and all specific spectral characteristics (i-1) to (i-5) are satisfied.

This invention belongs to the field of radiation detection and discloses a rare-earth-doped phosphate microcrystalline glass for high-energy radiation detection, its preparation method, and its application. The rare-earth-doped phosphate microcrystalline glass comprises 0.01~2 mol% rare-earth ions, wherein the rare-earth ions are Eu. 2+ The crystalline phase precipitated in the glass-ceramic is LiSrPO4. The preparation method includes the following steps: weighing the raw materials by molar percentage, thoroughly grinding them, melting them to obtain a glass melt, cooling and shaping them into a transparent glass block, annealing to obtain a precursor glass, and then heating, holding, and cooling to obtain the glass-ceramic. The preparation method of this invention is simple, can prepare large-size samples, is low-cost, and is easy to mass-produce industrially. The obtained rare-earth-doped phosphate glass-ceramic possesses excellent optical properties and high-energy ray and high-energy particle detection performance, superior to commercially available lithium-ion scintillator glass. It can be used in radiation detection, energy exploration, environmental monitoring, and other related fields, and has broad application prospects.

The present invention provides a ceramizable silicone rubber, a manufacturing process, and a use thereof, and belongs to the field of functional materials. The ceramizable silicone rubber according to the invention is produced from the following starting materials in the following mass proportions: 90 to 105 parts methyl vinyl silicone rubber; 35 to 45 parts fumed silica; 3 to 10 parts hydroxy silicone oil; 0.1 to 8 parts silane coupling agent; 1 to 75 parts inorganic filler, wherein the inorganic filler comprises mica powder, montmorillonite, and wollastonite; 10 to 30 parts low-melting-point glass powder, wherein the low-melting-point glass powder has a melting point of 400 to 600 °C and is borate glass and / or phosphate glass powder; 0.1 to 0.3 parts platinum-containing flame retardant; 0.5 to 1.5 parts vulcanizing agent. and 0.1 to 0.5 parts internal release agent.The ceramicizable silicone rubber according to the invention enables not only good ceramicizability but also high tensile strength and elongation at break.

The present invention relates to an optical filter provided with glass, a barrier film (1) provided between the glass and a dielectric multilayer film (1), a barrier film (2) provided between the glass and a dielectric multilayer film (2), and a light absorption layer provided on the dielectric multilayer film (2), in which the glass is phosphate glass or fluorophosphate glass. The light absorbing layer contains a near-infrared ray absorbing dye, and the optical filter satisfies specific spectral characteristics (i-1)-(i-3) and (i-6).

The invention relates to a luminescent phosphate fluorescent glass ceramic capable of rapidly responding to radiation dose detection and a preparation method and application thereof.The luminescent phosphate fluorescent glass ceramic is prepared from Na2CO3, BaCO3, NH4H2PO4 and H3BO3 through mixed grinding, calcination, melting quenching, grinding, compression molding, heat treatment and cooling, Dy < 3 + > is doped in a glass ceramic matrix in the form of a compound, and the Dy < 3 + > ion doped NaBaPO4 glass ceramic is obtained. Cold white light is emitted under the excitation of a specific excitation wavelength, through experiments and calculation, the sample contains three shallow trap energy levels with different depths, the characteristic endows the sample with remarkable rapid response performance, and charge carriers can be rapidly released in the optical excitation reading process, so that shorter signal reading time and rapid bleaching capability are realized, and the sensitivity of the sample is improved. And good linear dose response to high-energy rays in a range of 0.1-200 Gy is realized. The fluorescent material has good white light luminescence characteristic, rapid response characteristic, wide radiation dose response performance and good reusability, and can be applied to the field of luminescence and radiation dose detection as a novel fluorescent material.

An object of the present invention is to provide a three-dimensional network structure which has high hydrolysis resistance and thus degradation of resin due to moisture in the air is prevented in long-term use. The three-dimensional network structure includes a three-dimensional random loop shaped and bonded structure including a linear continuous fiber, wherein the linear continuous fiber includes a resin composition, and the resin composition includes a polyester-based thermoplastic elastomer and a phosphate glass. The phosphate glass preferably contains P2O5, SiO2, ZnO, and at least one selected from the group consisting of an alkali metal oxide and an alkaline earth metal.