714 results about "Arsenic" patented technology

The invention discloses a smelting wastewater trace arsenic real-time monitoring method based on an electrochemical sensing array, and relates to the technical field of electrochemical detection.The method comprises the steps that bypass sample flow is established through a peristaltic pump and pre-filtered, and stable sample flow is obtained; the sample flow is divided into a first passage and a second passage, and a form distinguishing sample flow is obtained after oxidation setting and medium equalization; performing short-time adsorption equilibrium to obtain an interface state parameter set, executing multi-segment coded deposition control based on the parameter set, and collecting a dissolution current curve; a dissolution signal set is obtained by applying single-frequency perturbation signals, characteristic peak parameters are extracted and subjected to correlation calculation with a multi-section response matrix, the total arsenic concentration and the pentavalent arsenic concentration are calculated through a weighted inversion algorithm, and a confidence interval is obtained; and calculating the concentration of the trivalent arsenic and determining an uncertainty range according to the two. According to the method, the quality judgment result is linked with the dynamic adjustment of the sampling flow, the potential amplitude and the deposition duration, so that the self-adaptive optimization control of the detection process is realized.

The invention relates to the technical field of acidic wastewater titrimetric analysis, and discloses an automatic sampling titrimetric analysis method based on a copper smelting acidic wastewater treatment link, which comprises the following steps: collecting waste acid to obtain a waste acid sample; carrying out titration treatment on the waste acid sample to obtain a waste acid sample image after the titration reaction is finished, and carrying out sediment outline extraction on the waste acid sample image to generate sediment coagulation complexity; according to the method, automatic sampling titration is combined with image analysis, precipitation coagulation complexity and arsenic specific hue separation degree are extracted, a precipitation effectiveness index and an arsenic residue risk coefficient are generated through dynamic fusion, arsenic precipitates and other precipitates in similar forms are accurately distinguished by utilizing precipitate contour features and arsenic specific hue in an HSV color space, and the arsenic content is accurately determined. The method has the advantages that spectral signal superposition interference is avoided, and the arsenic residual state can be accurately reflected, so that whether arsenic removal is qualified or not is reliably judged, the accuracy and safety of waste acid treatment are improved, and the quality of water reuse is guaranteed.

The present application belongs to the technical field of gaseous arsenic adsorption, and particularly relates to a sulfur-tolerant gaseous arsenic adsorption material, a preparation method and application thereof. Manganese oxide and an iron source are mixed and placed in a ball mill jar, then the ball mill jar is sealed, argon is filled into the jar, and the iron-modified manganese oxide adsorption material is obtained by ball milling. The addition of iron improves the sulfur tolerance of manganese oxide, so that the adsorbent still has high gaseous arsenic adsorption capacity under high-concentration SO2 conditions, and is suitable for the removal of gaseous arsenic in typical high-SO2 flue gas, i.e. non-ferrous smelting flue gas. The preparation method is simple, the cost is low, the gaseous arsenic adsorption capacity is large, and the present application has a wide application prospect.

The invention belongs to the technical field of heavy metal treatment, and particularly relates to a synthesis method and application of a sludge biochar Schwertmannite composite material capable of synchronously mineralizing cadmium and arsenic. Municipal or industrial sludge is used as a raw material, sludge biochar rich in Ca, Fe and alkaline functional groups is prepared through pyrolysis, then the sludge biochar is deeply compounded with Schwertmannite through a high-energy ball milling technology, a core-shell-like nested structure is formed through induction, and a large number of reaction sites are exposed. Under the condition that As / Cd coexists, the surface of the composite material can be induced to generate stable minerals, a synchronous precipitation mechanism is formed, and As and Cd have an adsorption synergistic enhancement effect. The process is wide in raw material source, clean and efficient in preparation process and free of high-temperature hydrothermal or organic reagents, has cation exchangeability, alkali energy storage and carbon immobilization value, provides a new theory and material support for long-term environment immobilization of multi-metal pollutants, and has large-scale application potential.

The invention discloses a pretreatment method and system for sulfur-containing and arsenic-containing ore. The method comprises the steps of crushing, alkaline wet ore grinding, strong alkaline pre-oxidation, cyanidation leaching, cyanogen removal treatment and high alkaline flotation. In the pretreatment process, liquid caustic soda is added into an ore grinding system, and oxygen is introduced into a cyanidation serial stirring tank for pre-oxidation treatment, so that the oxidation activation effect of the arsenic-sulfur minerals is remarkably enhanced, and the gold release efficiency and the cyanidation leaching rate are improved. The same group of serially connected stirring tanks is adopted for pre-oxidation and cyanidation leaching, and the first three stirring tanks are used for pre-oxidation and subsequently communicated with the stirring tanks for cyanidation reaction, so that process integration and equipment reuse are realized. Experimental results show that the comprehensive recovery rate of gold can be remarkably increased, the agent consumption can be reduced, and the method has good industrial application value.

The invention discloses an iron-based layered silicate material for efficiently removing variable-valence heavy metals and water treatment application of the iron-based layered silicate material, and belongs to the technical field of water treatment.The preparation method of iron-containing layered silicate minerals comprises the following steps that ferrous sulfate heptahydrate is dissolved in water, sodium dithionite and sodium orthosilicate are sequentially added, stirring is conducted, and a mixture is obtained; stirring, homogenizing and aging for two hours; the hydrothermal reaction kettle is used for reacting in a high-temperature and high-pressure environment; according to the iron-containing layered silicate mineral material, a unique layered structure similar to natural iron-containing layered silicate minerals and high adsorption performance are reserved, variable-valence heavy metal arsenic in a wastewater solution is synergistically and efficiently removed by means of the oxidation-reduction activity of the iron-containing layered silicate mineral material and induction of generation of Fenton-like reaction, and the iron-containing layered silicate mineral material is obtained. The method disclosed by the invention shows high treatment efficiency, environmental friendliness and remarkable economic benefits, and is expected to exert remarkable environmental benefits in the field of water treatment.

The invention belongs to the technical field of hydrometallurgy, and particularly relates to a pretreatment method for enhancing peroxide to improve the leaching rate of high-sulfur-arsenic gold ore. Comprising the following steps that the high-sulfur-arsenic gold ore is ground and then prepared into ore pulp; an oxidizing agent is added into the ore pulp, oxidation pretreatment is conducted on the high-sulfur-arsenic gold ore under the catalytic action of ultraviolet light, and ore pulp activation liquid is formed; and the pH of the ore pulp activating solution is adjusted to 9-12, a gold leaching agent is added into the ore pulp complexing solution, and stirring gold leaching treatment is conducted. According to the method, efficient oxidation of sulfide and arsenide is achieved under the mild condition through the synergistic effect of photocatalysis and chemical oxidation, the leaching rate of gold is remarkably increased, compared with a conventional peroxide oxidation method for pretreatment, the leaching rate can be increased by 10%-35%, and meanwhile the agent use amount and environmental pollution are reduced.

The present invention relates to the field of sludge treatment technology, and more specifically, to a method for solidifying arsenic in high-arsenic sludge using clay and copper slag. The method involves drying the high-arsenic sludge at 105°C for 12 hours and grinding it to a particle size of less than 0.5 mm to obtain a dry material. The dry material is then mixed evenly with clay powder, copper slag, and coal powder. Water is then added, stirred at room temperature for a pre-reaction of 6 hours, and poured into a crucible to obtain a paste-like mixture A. The dry mixture A is then calcined at 850-900°C for 20-40 minutes under a protective atmosphere. The reaction product, after natural cooling, is then used as a roadbed material, for example. This method utilizes clay and copper slag calcination to treat high-arsenic sludge, resulting in low arsenic and other heavy metal leaching toxicity and excellent stability, while also fully utilizing metallurgical solid waste.

The invention belongs to the technical field of gold smelting wastewater treatment and resource utilization, and relates to a method for recycling gold by cooperatively treating tailings with acid wastewater, which comprises the following steps of: (1) concentrating the acid wastewater; (2) controlling the fineness of the roasting cyanidation gold extraction tailings; (3) removing impurities by acid; (4) adsorbing and recovering gold and silver by using thiourea leaching carbon; and (5) vulcanizing the acidolysis solution to recover copper and arsenic in a targeted manner. According to the method, efficient treatment is carried out through a five-stage treatment process, so that sulfuric acid in the acid wastewater is efficiently recycled, the roasting and cyaniding gold extraction tailings are comprehensively and efficiently utilized, resource high-value utilization and clean production of the acid wastewater and the roasting and cyaniding gold extraction tailings are achieved, and harm of the acid wastewater and the roasting and cyaniding gold extraction tailings to the environment is eliminated; the technological process is smooth, operability is high, the environment is excellent, and remarkable economic benefits, social benefits and environmental benefits are achieved.

The invention provides a method for comprehensively recovering valuable metals from liquid purified by an antimony-based adsorbent, and belongs to the field of hydrometallurgy. The method comprises the following steps: (1) primary electrodeposition copper removal; (2) primary purification and impurity removal; (3) secondary electrodeposition copper removal; (4) secondary purification and impurity removal; (5) diffusion dialysis; (6) neutralizing to remove iron; (7) nickel precipitation by oxalic acid; and (8) roasting to obtain the high-purity nickel oxide powder. The treated object is the copper electrolyte subjected to purification and impurity removal through the antimony-based adsorbent, and the content of arsenic, antimony and bismuth impurities is remarkably reduced. By means of the method, it can be guaranteed that the quality of electric copper reaches the A-level copper standard, meanwhile, generation of highly toxic H3As gas is avoided, the comprehensive utilization efficiency of valuable metal resources in purified liquid is high, and the method is suitable for industrial application of copper electrolyte purification.

The invention discloses a preparation method and application of an iron-manganese modified biochar material for remediation of cadmium and arsenic contaminated soil, and relates to the field of new materials.According to the material, rice hull biochar serves as a carrier, and the specific surface area and surface active sites are increased through programmed intermittent ball milling; and the Fe-O / Mn-O bonding modification complex is formed through gradient loading of iron and manganese oxides. The maximum adsorption capacity of the material to Cd < 2 + > and As (V) reaches 71.54 mg.g <-1 > and 49.30 mg.g <-1 > and is 1.65 / 2.53 times that of original biochar, the content of available Cd and As in soil is reduced by 8.98% and 25.2% under the condition that the addition amount is 0.4%, and the passivation efficiency is improved by 1.05 times (Cd) and 9.08 times (As) compared with that of non-ball-milled iron-manganese modified biochar; the material prepared by the method is applied to cadmium and arsenic polluted soil, pollution can be controlled by waste, and the soil can be effectively repaired.

The present application belongs to the technical field of rare metal metallurgy, and particularly relates to a method and device for removing arsenic in germanium tetrachloride by hydrogen peroxide oxidation. The arsenic removal device comprises GeCl4, H2O2 and HCl storage containers, the storage containers are connected with a first reactor and a second reactor through pipelines, fourth, fifth, sixth, seventh and eighth valves are arranged on the pipelines, a first constant temperature heater is arranged at the lower part of the first reactor, a first mechanical stirrer is arranged at the top of the first reactor, a first residual liquid collector is connected with the bottom of the first reactor through a pipeline, and ninth and eleventh valves are arranged between the first reactor and the first residual liquid collector. Compared with the traditional chlorine arsenic removal method, the present application uses hydrogen peroxide to remove arsenic in germanium tetrachloride, is more environmentally friendly, safe, low-cost and does not bring new impurity elements, and the arsenic removal effect is very significant.

The invention relates to the technical field of geological exploration, in particular to an X-ray fluorescence spectrometer and geological radar combined gold vein rapid positioning method, which comprises the following steps: S1, arranging an exploration survey line in a pre-selected exploration area; s2, along the same measuring line, measuring the content of the gold mineralization indication element in the earth surface or the shallow medium by using an X-ray fluorescence spectrometer, synchronously recording the position information of a measuring point, and generating element content spatial distribution data; the gold mineralization indicating element comprises at least one of arsenic As, antimony Sb and mercury Hg; s3, carrying out detection by using a geological radar along the same measuring line, obtaining a reflected wave signal of an underground medium, synchronously recording position information of a detection point, identifying fault zone and joint zone geological structure anomalous bodies through data processing, and generating geological radar space distribution data; through XRF and GPR data fusion, a CAI quantitative model is established to precisely delineate an ore prospecting target area, a hidden ore body is effectively identified, the exploration precision and efficiency are greatly improved, and the exploration cost is reduced.

The invention discloses a method for predicting spatial distribution of heavy metal arsenic in soil based on Bayesian maximum entropy, and relates to a method for predicting spatial distribution of heavy metal arsenic in soil based on multi-source environment variables and a Bayesian maximum entropy-geographically weighted regression-common Kriging model. According to the method, multi-source environment variables such as terrains, natural conditions and remote sensing images are combined, uncertainty of soft and hard data is integrated by using a BME model, and prediction precision is improved; processing a spatial heterogeneity relationship between variables through a GWR model; and optimizing local interpolation by using an OK model. According to the method, the precision of heavy metal arsenic distribution prediction is remarkably improved, meanwhile, the regional soil heavy metal pollution spatial distribution diagram can be drawn, and a scientific basis is provided for soil environment risk assessment and pollution abatement.

A light emitting device comprising a germanium first layer; a nucleation layer; a buffer layer comprising a III-V composition; and an active layer. The sum product of As concentration and layer thickness in each of the layers is less than 20%. This enables the devices to be fabricated in an environment which must be free, or substantially free, of arsenic.

The invention provides a method for preferentially extracting gold and silver from lead anode slime, and relates to the technical field of precious metal recovery, firstly, silver, antimony and other valuable metals in the lead anode slime are leached into a solution through catalytic oxidation leaching in the presence of a protective agent, and gold is enriched in residues; then, silver is selectively precipitated from the leachate, and silver precipitation residues and a valuable metal solution are obtained; and finally, valuable metals in the solution are recovered by adding a neutralizer and a precipitator, the obtained leaching mother liquor can be returned for leaching after being supplemented with hydrochloric acid, and the valuable metal precipitates are used for recovering antimony and bismuth. The method changes the traditional lead anode slime treatment thinking of first impurity removal and second refining, has the characteristics of high gold and silver direct recovery rate (greater than 99.5%), high reaction speed (total consumed time is less than 1 h), low cost and no generation of waste residue and wastewater, and is expected to solve the problems of long gold and silver recovery process, low direct recovery rate, capital overstock and difficult treatment of arsenic and antimony-containing smoke in the existing lead anode slime treatment method. The method has remarkable economic and environmental benefits and a good application prospect.

The invention relates to the technical field of environmental protection, in particular to an arsenic and selenium online removal system and method for a waste incineration power plant. In the working process, the system obtains fly ash on line from a dust remover of a waste incineration power plant, the fly ash is modified through the on-site chemical and ball-milling integrated modification device to prepare an efficient arsenic-selenium adsorbent, and then the efficient arsenic-selenium adsorbent is conveyed and sprayed into a flue to adsorb pollutants such as arsenic and selenium in flue gas. The adsorbent raw materials are obtained on site in the waste incineration power plant, online modification and further injection adsorption can reduce emission of pollutants such as arsenic and selenium to the atmosphere, the situation that the adsorbent raw materials are obtained from the outside of the waste incineration power plant is avoided, the pollutant control cost is reduced, and the automatic operation level is improved. Namely, the system can realize integrated operation of on-site feeding, modification, injection and adsorption, and can meet the requirement of adsorbing and removing discharged pollutants such as arsenic and selenium in flue gas of coal-fired power plants of units with different capacities.

The invention discloses a method for removing arsenic and recovering copper and zinc from scrap copper smelting smoke dust, which comprises the following steps: carrying out first-stage acid leaching on the scrap copper smelting smoke dust to obtain first-stage leaching liquid and first-stage leaching slag; second-stage acid leaching is conducted on the first-stage leaching residues, second-stage leaching liquid and second-stage leaching residues are obtained, and the second-stage leaching liquid is returned to the first-stage acid leaching; zinc oxide is added into the first-section leaching solution to adjust the first-section leaching solution to a preset pH value, then iron powder is added to replace copper in the mixed leaching solution, and copper sponge and a replaced solution are obtained; zinc oxide is added into the replaced liquid to adjust the replaced liquid to a preset pH value, then ferrous sulfate heptahydrate is added, oxygen is introduced for oxidation arsenic precipitation, and arsenic precipitation residues and arsenic precipitation liquid are obtained; and adding zinc oxide into the arsenic-precipitated liquid to adjust the arsenic-precipitated liquid to a preset pH value for neutralization and purification to obtain neutralized and purified residues and a zinc sulfate solution, and returning the neutralized and purified residues to the second-stage acid leaching. According to the method, the valuable elements of arsenic, copper and zinc can be thoroughly separated, and arsenic precipitation caused in the zinc stannate decomposition process can be avoided.

The invention relates to the field of metallurgy and chemical engineering, in particular to a heap leaching gold extraction method for low-grade gold sulfide ore. Comprising the following steps that an anti-seepage bottom mat is laid on a dump leaching site; pre-treating the sulfide gold ore by using quick lime; ore crushing; ore is poured and piled on the upper portion of the bottom pad; spraying is conducted on the top of the ore heap and a side slope frame pipe, the gold-containing pregnant solution is collected, and the spraying solution is a sodium cyanide solution; and recovering gold from the gold-containing pregnant solution. According to the heap leaching gold extraction method provided by the invention, the quicklime is adopted to carry out pretreatment (iron removal, desulfurization and arsenic removal) on the sulfide gold ore, and then processes of subsequent ore crushing, heap building, spraying, adsorption and the like are carried out, so that the difficult problems of heap leaching utilization and popularization of low-grade sulfide ore resources are solved.

The invention belongs to the technical field of metallurgy, and relates to a complex gold concentrate multi-element comprehensive recovery method which comprises the following steps: S1, complex gold concentrate and auxiliary materials are subjected to bottom blowing smelting in an oxygen-enriched air atmosphere to obtain matte, bottom slag and flue gas; s2, copper matte and auxiliary materials are subjected to top-blowing converting in the air atmosphere, and crude copper, flue gas and converting slag are obtained; and S3, the crude copper and carbonate are refined in the air atmosphere, after refining is finished, sulfur hexafluoride gas is introduced for a reaction in the air atmosphere, methane gas is introduced for reduction in the inert atmosphere after the reaction is finished, and the copper anode plate is obtained. According to the method, arsenic, antimony and bismuth in the crude copper are removed through two-step oxidation and impurity removal, and the phenomenon that arsenic, antimony and bismuth elements in the complex gold concentrate are enriched in the copper anode plate along with smelting and refining, and consequently the copper anode plate is passivated in the subsequent electrolysis process is avoided; and the recovery method is simple in process and high in recovery rate.

The application belongs to the technical field of metallurgy, and relates to a method for efficiently purifying and directionally removing oxygen and impurities from a precious antimony alloy, which comprises the following steps: S1, after the precious antimony alloy is melted, an arsenic-tellurium removal agent is added, and smelting is performed at 600-610 DEG C to obtain a pre-impurity removal alloy melt and an arsenic-tellurium residue; the arsenic-tellurium removal agent is a mixture of sodium hydroxide and sodium nitrate; S2, the pre-impurity removal alloy melt obtained in step S1 is heated to 620-640 DEG C, a reducing agent is added, and smelting is performed to obtain an arsenic alkali residue and a refined antimony alloy; the reducing agent is a mixture of antimony sulfide and sodium hydroxide; S3, the arsenic-tellurium residue obtained in step S1 and the arsenic alkali residue obtained in step S2 are ball milled, leaching and filtration are performed to obtain a filtrate and a filter residue; S4, the filtrate obtained in step S3 is mixed with sulfuric acid, and after reaction, a neutralization residue and a neutralization liquid are obtained. By introducing the efficient arsenic-tellurium removal agent and the reducing agent, the content of antimony in the arsenic alkali residue is significantly reduced, and the direct recovery rate of antimony and the recovery rate of tellurium are effectively improved.

The invention discloses an arsenic-containing copper-zinc polymetallic ore beneficiation method and an arsenic-containing mineral inhibitor, and belongs to the field of beneficiation. The arsenic-containing mineral inhibitor comprises the following components by mass percent: 40-60% of lime; 30%-40% of ferrous cyanide salt; and 10%-20% of a sulfomethylation modified tannin extract. The sulfomethylation modified tannin extract is prepared from the following raw materials in percentage by mass: 40-60% of tannin extract; 10-20% of sodium hydroxide; 15 to 25% of formaldehyde; and 5-15% of sulfuric acid. According to the method, the lime, the ferrocyanide and the sulfomethylation modified tannin extract are innovatively compounded according to a specific proportion and are in mutual synergistic interaction, the selectivity of arsenic mineral inhibition can be effectively improved, the agent dosage is reduced, the long-term effect of inhibition is enhanced, deep arsenic reduction can be achieved in the mineral separation process, and the concentrate quality and the recovery rate are improved.

The invention provides a composite flocculant, and relates to the technical field of wastewater treatment. The composite flocculant is prepared from chitosan and humate, heavy metal cadmium and arsenic are removed, the sludge volume is reduced, a method for synchronously removing cadmium and arsenic in acid mine wastewater is provided, thorough removal of cadmium and arsenic is achieved through the synergistic effect of calcium peroxide, the diatomite adsorbent and the composite flocculant, and the service life of the composite flocculant is prolonged. The mass and volume of the sludge are reduced, the wastewater treatment cost is reduced, and the method is a rapid, economic and efficient environment-friendly treatment scheme for the acid mine wastewater.

The invention discloses a process for recovering zinc, nickel, cadmium, copper and chlorine in high-chlorine zinc slag. The process comprises the following steps: S1, four-stage reverse water washing; s2, removing impurities from water washing liquid; s3, concentrating and crystallizing the impurity-removed liquid; s4, leaching the washed mixed slag; s5, neutralizing the leachate to remove arsenic and iron; s6, replacing to remove copper, cadmium and nickel; and S7, concentrating and crystallizing the copper-cadmium-nickel-removed solution. According to the method, the technical bottleneck problem that the high-chlorine zinc slag is used for recovering zinc and discarding chlorine resources by applying a traditional zinc hydrometallurgy process technology is solved, and the environment-friendly process technology for recovering zinc and chlorine at low cost, producing ammonium chloride and zinc sulfate products and realizing zero emission of three wastes is realized. And meanwhile, valuable metals such as lead, cadmium and copper in the high-chlorine zinc slag are enriched and recycled.

The invention relates to the technical field of nanometer detection, in particular to a preparation method and application of nitrogen-sulfur-doped fluorescent carbon dots for detecting arsenic elements. Comprising the following steps: dissolving thiourea and o-phenylenediamine in formamide, transferring the solution into a polytetrafluoroethylene reaction kettle for reaction, cooling the product to room temperature, centrifuging, collecting supernate, filtering by using an organic filter membrane, dialyzing by using a dialysis bag, filtering by using a water-phase filter membrane, putting into a rotary evaporator for rotary evaporation concentration, and freeze-drying the product to obtain the o-phenylenediamine. The nitrogen and sulfur doped fluorescent carbon dot powder capable of being used for detecting the arsenic element is obtained; the fluorescent carbon dots are simple to synthesize, quick in response and high in sensitivity, arsenic can be qualitatively and quantitatively detected without chemically modifying the detection probe, and the fluorescent carbon dots have a good application prospect.

The invention discloses a tellurium copper slag comprehensive treatment technology and a multi-element collaborative recovery method, and relates to the technical field of non-ferrous metal metallurgy and solid waste recycling, and the tellurium copper slag comprehensive treatment technology comprises the following steps: pretreatment and arsenic volatilization removal, selective acid leaching copper extraction, tellurium enrichment through alkaline oxidation, tellurium reduction and arsenic recycling. According to the method, by combining the advantages of a wet process and a pyrogenic process, the defects that in the prior art, arsenic cannot be effectively recycled in the tellurium-copper slag treatment process and the process is complex are overcome, efficient copper and tellurium separation is achieved through coordinated regulation and control of an acid / alkali medium and an oxidizing agent, arsenic is recycled in an industrial raw material form, and the limitation that only tellurium and copper are concerned in a traditional process is broken through.

The invention provides a ferrihydrite-spent grain solid powder material as well as a preparation method and application thereof, and relates to the technical field of removal of arsenic and antimony in a water body. The preparation method comprises the following steps: respectively providing spent grain powder leachate and an iron nitrate nonahydrate solution; dropwise adding the spent grain powder leachate into the iron nitrate nonahydrate solution until the pH value of the obtained mixed solution is 7.2-7.5; wherein the dropwise adding speed is 50mL / h; and carrying out centrifugal treatment, cooling treatment and freeze drying treatment on the mixed solution. The preparation method is simple and easy to operate, the material can be prepared in quantity, and quantitative production is realized. The material can be used for reducing the content of arsenic and antimony in a water body by constructing a barrier zone at the upstream of the water body. According to the barrier belt, the concentration of arsenic and antimony in the water body is remarkably reduced, and water resources and the ecological environment are protected. Complex equipment and operation procedures are not needed, and when the material reaches adsorption saturation, the material is easy to replace, convenient to maintain and manage and wide in application range.

A non-oriented electrical steel sheet having a composition of the following elements, expressed in percentage by weight 0.0001%≤Carbon≤0.007%, 0.15%≤Manganese≤0.25%, 2.9%≤Silicon≤3.4%, 0.8%≤Aluminum≤1.1%, Phosphorus≤0.15%, Sulfur≤0.006%, Nitrogen≤0.09%, with 3.85%≤Si+Al+Mn≤5.5%, and the following optional elements 0%≤Niobium≤0.1%, 0%≤Titanium≤0.1%, 0%≤Vanadium≤0.1%, 0%≤Chromium≤1%, 0%≤Molybdenum≤0.5%, 0%≤Tungsten≤0.1%, 0%≤Cobalt≤1%, 0%≤Arsenic≤0.05%, 0.001%≤Calcium≤0.01%, 0%≤Copper≤1%, 0%≤Nickel≤1%, 0%≤Boron≤0.05%, 0%≤Lead≤0.2%, 0%≤Tin≤0.2%, 0%≤Antimony≤0.2%, the remainder composition being composed of iron and unavoidable impurities caused by processing. The microstructure is made of ferrite and including in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and having a percentage of eddy current losses in total iron losses less than 25% and simultaneously having a magnetic polarization at 5000 A / m from 1.625 T to 1.690 T.

To provide a heavy metal insolubilizing material for insolubilizing heavy metal contained in a heavy metal contaminant (for example, incineration ash, soil, and drainage water), which can exhibit an excellent insolubilization effect to a plurality of kinds of heave metal (for example, arsenic and hexavalent chromium), in a short time (for example, 2 to 3 hours).SOLUTION: A heavy metal insolubilizing material contains an iron compound composed of either or both of ferrous sulfate monohydrate and ferrous chloride tetrahydrate, and a magnesium compound composed of one or more selected from the group consisting of magnesium sulfate heptahydrate, magnesium sulfate nonhydrate, and magnesium sulfite hexahydrate. A ratio of the iron compound in the total amount of the iron compound and the magnesium compound is 5 to 80 mass%. The heavy metal insolubilizing material can be prepared in a powdery form.SELECTED DRAWING: None

The application discloses a kind of arsenic-containing waste residue processing device, including sealed pipe, the sealed pipe includes heating reduction section and condensing section, the heating reduction section is located above the condensing section, reaction load part is equipped in the heating reduction section, and the heating reduction section and condensing section are respectively equipped with reduction temperature control part and condensing temperature control part for controlling the temperature of heating reduction section and condensing section.The application also provides a kind of method for processing arsenic-containing waste residue using the above-mentioned arsenic-containing waste residue processing device.The arsenic-containing waste residue processing device of the application includes integrated heating reduction section and condensing section, arsenic vapor generated by heating reduction section directly enters condensing section for condensation, and the temperature of heating reduction section and condensing section is controlled by reduction temperature control part and condensing temperature control part respectively, which can realize the condensation of arsenic vapor within a certain temperature range to obtain α-single-element arsenic, and the purity of single-element arsenic is higher.