The invention relates to the technical field of solar cells, and particularly discloses a
crystalline silicon thermal electron solar cell and a photovoltaic module, which comprise a
silicon substrate, and the
silicon substrate comprises a P-type region and an n-type region positioned on one side of an illumination surface of the P-type region; the illumination surface of the
silicon substrate is provided with a silver collection gate
electrode, and the back side of the silicon substrate is provided with a silver extraction
electrode; an Ag-Si
semiconductor alloy junction is arranged at the position, corresponding to the silver collection gate
electrode, in the silicon substrate, an n-type ultra-shallow
diffusion layer is formed on the outer side of the Ag-Si
semiconductor alloy junction, an n-P junction is formed between the n-type ultra-shallow
diffusion layer and the P-type region, and the n-P junction and the n-P junction form a three-dimensional PN junction
quantum well; the silver collection gate electrode and the Ag-Si
semiconductor alloy structure form a
contact electrode. Thermo-
electron transmission is accelerated, thermo-
electron extraction and utilization are realized, and the
photoelectric conversion efficiency is further improved.