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376 results about "In situ doping" patented technology

Composite material of nitrogen-doped porous carbon-wrapped carbon nano tube as well as preparation method and application of material

The invention relates to a composite material of a nitrogen-doped porous carbon-wrapped carbon nano tube as well as a preparation method and an application of the composite material. The preparation method comprises the following steps: dispersing the carbon nano tube in water, adding a carbon source to obtain a reaction system, subsequently performing hydrothermal reaction, performing thermal treatment on the carbon nano tube wrapped with a carbon layer on the surface, and a nitrogen source at the high temperature so as to obtain the composite material of the nitrogen-doped porous carbon-wrapped carbon nano tube. According to the preparation method, the carbon source is polymerized under a hydrothermal reaction condition so as to obtain the carbon layer, the outer surface of the carbon nano tube is wrapped with the carbon layer, subsequently the carbon layer is carbonized and decomposed to generate a porous structure under high temperature treatment, and at the same time, the gasified nitrogen source is diffused to the carbon layer through ducts to be subjected to in-situ doping. The composite material provided by the invention can be used as a cathode oxidation reduction catalyst of a fuel battery, is excellent in catalysis, and is high in oxidation activity when being compared with other nitrogen-doped materials reported in documents. The preparation method provided by the invention is simple and economic in process, convenient to operate and easy to achieve the large-scale production.
Owner:INST OF CHEM CHINESE ACAD OF SCI

Lithium sulfur battery anode material and lithium sulfur battery utilizing same

The invention discloses a lithium sulfur battery anode material and a lithium sulfur battery utilizing same. By adopting an in-situ doping method, iron and nitrogen are jointly added, and an iron-nitrogen exotic atom dual-doped porous carbon material is prepared by adopting a hard template method. The method comprises the following steps: preparing a precursor, a catalyst and a previous polymer ofa hard template; calcining the previous polymer to obtain solids; and etching, cleaning and drying the solids to obtain the carbon material of the invention. The prepared carbon material is uniformlymixed with sulfur powder to be heated in an argon atmosphere to form a carbon sulfur composite material which is applied to the lithium sulfur battery. The obtained carbon material is relatively highin content of nitrogen and iron, relatively high in specific surface area and yield, simple in preparation step and easy in operation. When the lithium sulfur battery anode material is applied to thelithium sulfur battery, the electrochemical performance is relatively good, compared with the iron-free carbon material, the performance is apparently improved, the sulfur can be well fixed by addingthe iron catalyst, the shuttle of the poly-sulfide can be inhibited, and the reaction dynamics can be accelerated, so that the cycling stability of the lithium sulfur battery can be improved.
Owner:BEIJING INSTITUTE OF TECHNOLOGYGY

Non-carbon heteroatom-modified porous graphene framework and preparation method thereof

ActiveCN105836738AOptimal three-dimensional structureOptimizing Surface ChemistryGraphenePorous grapheneHigh heat
The invention discloses a non-carbon heteroatom-modified porous graphene framework and a preparation method thereof, and belongs to the technical field of novel material preparation. The framework is of a three-dimensional structure formed by assembling graphene slices, a supporting cavity with the size of 50-5000 nm is presented, and 80%-99% of non-carbon heteroatoms are modified on the edges of the graphene slices and holes. The non-carbon heteroatom-modified porous graphene framework is prepared by calcining a ternary solid mixture of a carbon source, a non-carbon heteroatom source and a catalytic graphitization template at high temperature, and in-situ doping is achieved. The framework enriches the varieties of carbon nanomaterials, supplies a hole structure and non-carbon heteroatom-modified graphene material which is controllable in adjustment and has the wide application prospect in the fields of electrochemical energy storage, heterogeneous catalysis, adsorptive separation and the like. Meanwhile, the efficient low-cost graphene preparation method is achieved, the technology is simple and safe, the raw materials are rich and cheap, research and industrialization of the graphene material are effectively promoted, and the high additional value of the cheap raw materials, production of graphene-related energy materials and development of energy industry are promoted.
Owner:TSINGHUA UNIV

UTB-SOI tunneling field-effect transistor with abrupt junction and preparation method thereof

The invention relates to an ultra-thin-body-silicon-on-insulator (UTB-SOI) tunneling field-effect transistor with an abrupt junction and a preparation method thereof. The preparation method comprises: selecting a UTB-SOI substrate; forming a shallow trench isolation unit; carrying out etching to form a P type/N type trench; carrying out silicon material deposition in the P type/N type trench and carrying out in-situ doping to form a P type/N type highly-doped source region; carrying out etching to form an N type/P type trench; carrying out silicon material deposition in the N type/P type trench and carrying out in-situ doping to form a low doped N type/P type drain region; forming a gate dielectric layer and a front gate layer on the top layer silicon surface of the substrate and carrying out etching to form a front gate; and carrying out lead window photoetching, metal deposition, and lead photoetching to form source region, drain region, and front gate metal leads. According to the invention, with the technique and preparation of trench etching and selective epitaxy deposition and filling at the source and drain regions, the tunnel junction area can be limited precisely; and on the basis of in-situ doping, the tunnel junction with the steep doping concentration gradient and the source and drain regions with uniform doping can be formed well and the driving current of the device can be effectively improved and the sub-threshold slope can be reduced.
Owner:XIAN UNIV OF SCI & TECH
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