The invention provides a preparation method of a silicon/carbon multi-component composite negative electrode material. The preparation method comprises the following steps: (1) preparing a carboxyl carbon nano-tube by using acid and a carbon nano-tube, or preparing an aminated carbon nano-tube by using the carboxyl carbon nano-tube; (2) oxidizing the surface of nanometer silicon so as to generate a layer of silicon oxide, or aminating slightly oxidized nanometer silicon by using ammonia-containing organosilane under the condition of heating reflux; (3) adding the carboxyl carbon nano-tube and the aminated nanometer silicon, or the carboxyl carbon nano-tube and the slightly oxidized nanometer silicon to an organic carbon source-containing solvent, dispersing and carrying out spray drying-pyrolysis; (4) mixing a material obtained in the step (3) with asphalt, and sequentially carrying out low-temperature, constant temperature and high-temperature heat treatments, thus obtaining a secondary silicon-carbon nano-tube/amorphous carbon composite negative electrode material; and (5) carrying out airflow crushing, grading, adding to the organic carbon source-containing solvent, carrying out spray drying-pyrolysis or spray pyrolysis, and carrying out high-temperature treatment, thus obtaining the silicon/carbon multi-component composite negative electrode material. The silicon/carbon multi-component composite negative electrode material prepared by the method has the advantages of large reversible capacity, designable capacity, good cycle performance, high tap density and the like.