1405 results about "Nitrogen source" patented technology

The invention discloses a Burkholderia sp. Strain and an application thereof in prevention and treatment of eucalyptus blight. The Burkholderia sp. AS-SF-1 disclosed by the invention has the preservation number of GDMCC (Graphical December Microorganism Center) No. 66223; the culture and volatile matter of the strain can inhibit growth of various forest pathogenic bacteria, the eucalyptus has a remarkable control effect on branch blight, siderophore can be generated, absorption and utilization of iron can be promoted, various types of carbon sources or nitrogen sources can be utilized, and the strain can grow within the pH range of 4-9. The burkholderia sp. AS-SF-1 disclosed by the invention has an important application value on planting of eucalyptus and prevention of diseases.

The invention belongs to the technical field of lithium batteries, and particularly relates to a lithium-rich manganese-based positive electrode material and a preparation method and application thereof. The preparation method comprises the following steps: mixing a metal salt solution, a precipitator and a complexing agent, and carrying out coprecipitation reaction on an obtained coprecipitation reaction precursor solution to obtain a lithium-rich manganese-based precursor; the metal salt solution comprises a manganese element, a cobalt element and a nickel element; and mixing the lithium-rich manganese-based precursor, a lithium source, an auxiliary agent and a dispersing agent, and calcining to obtain the lithium-rich manganese-based positive electrode material, the auxiliary agent comprises a nitrogen source or a nitrogen source and a carbon source. The first discharge specific capacity, the rate capability and the cycling stability of the lithium-rich manganese-based positive electrode material can be improved, and the problems of capacity fading, discharge voltage drop and dynamic delay in an electrochemical reaction process are solved.

The present invention relates to increasing and / or maintaining nitrogen content in soil by administration of nitrogen sources particles coated with urease inhibitors. In one embodiment, urease inhibitors are dispersed in an improved organo liquid delivery system at concentration levels of 60-95%. In another embodiment, urease inhibitors were applied in a non-aqueous, organo liquid delivery system coating nitrogen sources particles utilizing simple blending equipment at temperatures of 20°-70° C. Another embodiment discloses dry, flowable nitrogen sources coated with a urease inhibitor which can be administered directly to the soil, to a dry natural and / or a manmade fertilizer or to a liquid fertilizer which provides for the reduction of nitrogen loss from the soil. In another embodiment, a composition of urea and <0.2% dimethyl sulfoxide improves the crush resistance of the urea particles.

The present disclosure provides agronomically stable liquid agricultural compositions, methods of formulation thereof, and methods of application thereof. The agricultural compositions comprise nitrogen-fixing microorganisms and one or more of a buffering agent, a microbial stabilizer, and a physical stabilizer. The disclosed liquid agricultural compositions have a longer shelf life and greater ease of application than other existing dry and liquid formulations. The disclosed liquid agricultural compositions are stable for a period of thirty days or longer with low toxin accumulation and high microbial stability. The compositions are suitable for use on agricultural plant tissues or the environs thereof for providing a source of fixed atmospheric nitrogen to the agricultural plant. The compositions are used to increase crop yield and decrease yield variance.

The invention discloses a superconducting carbon black co-production method based on directional refining of catalytic slurry oil and a product thereof, and belongs to the technical field of carbon black preparation, and the method comprises the following steps: mixing the catalytic slurry oil and catalytic circulating oil to obtain mixed slurry oil, and adding a deliming agent for settling separation to obtain purified slurry oil; carrying out continuous solvent extraction on the obtained purified oil slurry to respectively obtain an aromatic component and a heavy component; carrying out thermal polycondensation reaction on the obtained aromatic component in a magnetic field environment in the presence of a catalyst and a cross-linking agent, and then carrying out supercritical fluid extraction to obtain spinnable mesophase pitch; carrying out slurry reactor hydrogenation deconstruction on the obtained heavy component to obtain stable micromolecular carbon black raw oil, mixing the carbon black raw oil with a nitrogen source and a template precursor, carbonizing, and carrying out acid pickling to obtain the superconducting carbon black; through a heavy oil slurry reactor hydrogenation deconstruction'doping-template 'synergistic carbonization strategy, the superconductive carbon black with nitrogen / phosphorus co-doped and developed hierarchical porous structure is constructed in situ by a one-step method.

The invention discloses a cobalt-copper bimetallic nitrogen-doped carbon catalyst, which is characterized in that CoCu-coated LNC, Co and Cu nanoparticles are anchored on a nitrogen-doped carbon carrier derived from lignin. Accordingly, the inventor also establishes a corresponding preparation method, and the catalyst is prepared by taking lignin as a carrier, cobalt-copper bimetal as an active component and dicyandiamide as a nitrogen source through one-pot pyrolysis. The method has the characteristics of simple and efficient process, high catalyst stability and activity, economy, high efficiency, environmental friendliness and the like. The method is used for preparing 2, 5-furandicarboxylic acid through thermal catalytic oxidation of 5-hydroxymethylfurfural, the yield of the target product FDCA almost reaches 100%, and the application prospect is wide.

The invention provides a preparation method of a plate-shaped glassy carbon electrode, which comprises the following steps: curing a resin raw material into a plate-shaped resin block, carbonizing in an inert atmosphere, and respectively introducing a nitrogen source and a boron source for doping operation to obtain a co-doped plate-shaped resin block precursor; placing the co-doped plate-shaped resin block between two porous graphite plates, and carrying out high-temperature treatment to obtain a glassy carbon matrix; and immersing the glassy carbon substrate into the adhesion layer solution to form an adhesion layer, transferring the adhesion layer into a deposition solution which comprises a bismuth-containing solution and a gold-containing solution, forming bismuth-gold nano-dots on the adhesion layer, and washing and drying the bismuth-gold nano-dots to obtain the plate-shaped glassy carbon electrode. Through directional arrangement of crystal orientations, the tantalum carbide coating achieves higher electrical conductivity and thermal conductivity. And the sensitivity and the service life of the plate-shaped glassy carbon electrode are obviously improved and prolonged.

The invention discloses keratinase Phyto-Keratinase and application of the keratinase Phyto-Keratinase. The keratinase Phyto-Keratinase comprises the following components: (1) protease which is coded by a nucleotide sequence as shown in SEQ ID NO.1; and / or (2) protease which is derived from bacillus subtilis, is coded by a nucleic acid sequence with more than 98% of identity with the SEQ ID NO.1 nucleotide sequence and has the characteristic of hydrolyzing keratin. According to the plant keratinase Phyto-Keratinase disclosed by the invention, the Phyto-Keratinase (plant keratinase) produced by utilizing microbial fermentation is a serine proteolytic enzyme, is also a biocompatible cutinase, and is obtained by fermenting saccharomyces cerevisiae. Phyto-Keratinase provides a nitrogen source for the growth of plants (beans), and contains various amino acids (functional peptides) and special proteolytic enzymes derived from the plants at the same time. The Phyto-keratinase can provide the effects of resisting inflammation, removing cutin and providing nutrition for skin regeneration at the same time, can relieve various inflammations by inhibiting PAR-2 receptors, and has potential value in the fields of cosmetics, beauty medicine and environment.

The invention provides a culture medium for tylosin fermentation. Specifically, the culture medium comprises a carbon source, a nitrogen source, inorganic salt and trace elements. The applicant optimizes the types and contents of a carbon source, a nitrogen source, inorganic salts and trace elements, so that the culture medium for improving the yield of tylosin is obtained. The culture medium disclosed by the invention is low in cost, and the yield of tylosin can be remarkably increased. Compared with the prior art, the method has the advantage that the yield of tylosin is increased by 27.95%.

The invention discloses biomass porous carbon material loaded iodine as well as a preparation method and application thereof. The preparation method comprises the following steps: pretreating a biomass material: firstly pickling and then washing to be neutral; the method comprises the following steps: uniformly mixing a biomass material, a pore forming agent, a nitrogen source and water, and pre-carbonizing in a nitrogen or inert gas atmosphere to obtain yellow powder, with the pore forming agent being potassium oxalate and the nitrogen source being melamine; carbonizing the yellow powder at 600-900 DEG C in a nitrogen or inert gas atmosphere, cooling to room temperature to obtain black powder, washing and drying to obtain a biomass porous carbon material; the method comprises the following steps: mixing the biomass porous carbon material and iodine elementary substance, heating in a closed environment to sublimate the iodine elementary substance and absorb iodine by the biomass porous carbon material, cooling to room temperature, preserving heat at 50-65 DEG C in an open environment for at least 12 hours, and cooling to room temperature to obtain the biomass porous carbon material loaded iodine. The battery obtained by loading iodine on the biomass porous carbon material still has good cycle life and relatively high capacity retention rate under high rate.

This invention discloses a Chinese saprophytic bolete ( Buchwaldoboletus xylophilus This invention relates to the mother culture medium, its preparation method, and its application, belonging to the field of microbial culture technology. The strain JSJ-Bx1 of the *Boletus spp.* mother culture, with accession number CGMCC No. 42007, is deposited at the China General Microbiological Culture Collection Center. The culture medium composition is: 10–30 g carbon source, 2–6 g nitrogen source, 1–3 g inorganic salts, 0.1–0.3 g suitable growth factors, 20 g agar, and 1 L water, with a pH of 4–6. Using the culture medium of this invention, the mycelium of the *Boletus spp.* mother culture exhibits rapid, vigorous, and dense growth, with neat colony edges, and does not produce pigments or exhibit mycelial degeneration such as exudation, significantly shortening the mother culture growth cycle.

The invention provides a method for constructing an axial halogen coordination iron-based catalyst and application of the axial halogen coordination iron-based catalyst, and belongs to the technical field of catalytic materials and environmental pollution control. The preparation method comprises the following steps: introducing amino to the surface of a multi-walled carbon nanotube to obtain a modified multi-walled carbon nanotube; iron tetracarboxyl phthalocyanine and the modified multi-walled carbon nanotubes are subjected to covalent grafting through an amidation reaction, and a precursor is obtained; mixing the precursor with a halogen-containing solid source and a nitrogen source, and carrying out temperature programming and segmented pyrolysis in an inert gas atmosphere to obtain a pyrolysis product; and carrying out acid pickling on the pyrolysis product. The core of the preparation method disclosed by the invention lies in a multi-step collaborative strategy of molecular isolation, interface bridging, gas phase migration, fixed-point capture and coordination regulation, so that ultrahigh monatomic dispersity is realized, and unification of high density and high dispersity is ensured; meanwhile, the electronic structure of the iron center is effectively optimized, and excellent intrinsic activity is shown.

The invention discloses a Pseudomonas putida high-yield rhamnolipid fermentation medium based on a step-by-step optimization strategy, an optimization method and application thereof, through the step-by-step strategy of component screening-single-factor optimization-multi-factor interactive optimization, a mixed carbon source and a mixed nitrogen source are taken as cores, and a Plackett-Burman test, a steepest climbing test and Box-Behnken response surface design are combined, so that the high-yield rhamnolipid fermentation medium for the pseudomonas putida high-yield rhamnolipid is obtained. Optimizing to obtain a special fermentation culture medium; two genetic engineering strains estA-2 and estA-3 are constructed by heterologous expression of key genes, and the supply and extracellular transport efficiency of a rhamnolipid synthesis precursor is enhanced; the recombinant strain is applied to the optimized culture medium, and efficient production of a shake flask and a 5L fermentation tank is achieved. The rhamnolipid yield of the estA-3 strain in a 5L fermentation tank reaches 35.59 + / -2.18 g / L, the conversion rate is 0.282 g / g, the productivity is 0.404 g / L / h, the rhamnolipid yield, the conversion rate and the productivity are obviously superior to those in the prior art, and a key technical support is provided for industrial production of rhamnolipid.

The invention belongs to the technical field of denitration catalysts, and discloses a CO-SCR denitration catalyst and a preparation method and application thereof. The preparation method comprises the following steps: (1) putting honeycomb cordierite into a muffle furnace for preliminary calcination to obtain a carrier; (2) immersing the carrier into a mixed solution containing an aluminum source and an alkaline nitrogen source for hydro-thermal treatment, taking out the carrier after hydro-thermal treatment, and washing and drying to obtain a surface modified carrier; (3) preparing a bottom layer coating solution containing catalyst powder and a first pore-forming agent; preparing a surface layer coating solution containing catalyst powder and a second pore forming agent; wherein the average particle size of the first pore-forming agent is larger than that of the second pore-forming agent; (4) immersing the surface modified carrier into the bottom layer coating liquid for coating, carrying out primary drying, then immersing the surface modified carrier into the surface layer coating liquid for coating, and carrying out drying treatment to obtain a catalyst precursor; and (5) calcining the catalyst precursor to obtain the CO-SCR denitration catalyst.

The invention provides a nitrogen and fluorine co-doped three-dimensional carbon material as well as a preparation method and application thereof. The preparation method comprises the following steps: in a protective atmosphere, heating a uniform mixture containing an organic carbon source, a fluorine source and a nitrogen source at 400-1000 DEG C to obtain the nitrogen-fluorine co-doped three-dimensional carbon material. When the nitrogen and fluorine co-doped three-dimensional carbon material is used for preparing a sodium ion battery without a negative electrode active layer, the sodium ion deposition process can be well homogenized, sodium dendrite growth and negative electrode volume expansion are inhibited, and the sodium ion battery has relatively low polarization and longer cycle life.

The invention relates to the technical field of microbial treatment of antibiotic pollution, and discloses an antibiotic degrading bacterium with salt tolerance and capable of degrading sulfamethoxazole at low temperature and application, the strain degrades SMX in a wide temperature range of 10-40 DEG C, the degradation rate of 20mg / L SMX at 10-35 DEG C within 64 hours is greater than 70%, and the degradation rate of 20mg / L SMX at 20-30 DEG C reaches 100%; at the low temperature of 10 DEG C, low-concentration SMX is obviously degraded, and the SMX with the concentration of 5 mg / L can be completely degraded within 16 hours; the MJ2 can still effectively degrade SMX under the harsh conditions that the temperature is low and SMX serves as the unique carbon and nitrogen source, the degradation rate reaches 100% after 66h at the concentration of 5 mg / L, and it is proved that the MJ2 has the unique oligotrophic adaptability. Salinity tests show that the degradation rate of MJ2 to 20 mg / L SMX within 48 hours under the 0.1-2% NaCl concentration is 100%, the degradation rate is still kept at 50% even under the stress of 3% high salt, and remarkable salt tolerance is also shown. In conclusion, the strain MJ2 integrates wide temperature range adaptability, low-temperature high efficiency, oligotrophic tolerance and high salt stability, and has great application value in sulfonamide antibiotic pollution remediation in a complex environment.

The invention relates to the technical field of waste gas recovery, and discloses a waste gas recovery treatment device and a printing waste gas treatment technology.The waste gas recovery treatment device comprises a main shell, an auxiliary shell and a strip-shaped shell which are integrally arranged, the auxiliary shell is located on one side of the main shell, and the strip-shaped shell extends to the top of the auxiliary shell from the top of the main shell; two groups of main adsorbers and a plurality of groups of auxiliary adsorbers are arranged in an inner cavity of the main shell. By arranging the heat exchanger, the auxiliary shell, the two sets of main adsorbers and the driving assembly, the two main adsorbers connected in series can be switched for use, rapid saturation of a single main adsorber is avoided, the saturated adsorbers can be subjected to desorption regeneration in the auxiliary shell, recycling is achieved, the overall adsorption efficiency of harmful substances is improved, and in addition, the adsorption efficiency of the harmful substances is improved. By arranging the heat exchange assembly, the rapidly saturated main adsorber can be cooled, then the safety risk is reduced, overheating ignition is prevented, the high temperature of the main adsorber can also heat a nitrogen source for desorption, energy loss is reduced, and more energy is saved.

The invention discloses a compound fertilizer for improving the utilization rate of nutrient elements and a preparation method thereof, and belongs to the technical field of organic fertilizer and microbial fertilizer manufacturing. The compound fertilizer comprises the following components in parts by mass: 10-30 parts of a nitrogen source, 5-20 parts of a phosphorus source, 10-25 parts of a potassium source, 3-15 parts of a synergist, 1-5 parts of medium trace elements, 2-8 parts of a coating material and 8-15 parts of a plant growth promoter. The plant growth promoter is a specific deuterated benzene ring derivative and has the structural characteristics as shown in formula 1. The preparation method comprises the processes of raw material mixing and crushing, microbial pre-fermentation, coating liquid granulation, fluidized bed coating and the like. Through chelation of humic acid, activation of a microbial agent and synergism of a deuterated molecular structure, the utilization rate of nitrogen, phosphorus and potassium is increased to 1.5 times or more of that of a conventional fertilizer, field tests show that the yield of purple cabbage can reach 4083 kg / mu, the yield is increased by 31.4% compared with that of a traditional compound fertilizer, meanwhile, the soil microbial environment is improved, and intelligent slow release of nutrients is achieved.

The present disclosure provides agronomically stable liquid agricultural compositions, methods of formulation thereof, and methods of application thereof. The agricultural compositions comprise nitrogen-fixing microorganisms and one or more of a buffering agent, a microbial stabilizer, and a physical stabilizer. The disclosed liquid agricultural compositions have a longer shelf life and greater ease of application than other existing dry and liquid formulations. The disclosed liquid agricultural compositions are stable for a period of thirty days or longer with low toxin accumulation and high microbial stability. The compositions are suitable for use on agricultural plant tissues or the environs thereof for providing a source of fixed atmospheric nitrogen to the agricultural plant. The compositions are used to increase crop yield and decrease yield variance.

The invention discloses a biomass nitrogen-doped derivative porous carbon material and a preparation method and application thereof, and belongs to the technical field of photo-thermal atmospheric water catching.The preparation method comprises the following steps that a carbon source and a nitrogen source are put into water to be subjected to an ultrasonic reaction, a reactant is subjected to hydrothermal treatment, and a solid product is obtained; carrying out steam etching and high-temperature annealing treatment on the solid product and metal salt in an inert atmosphere, and then sequentially carrying out acidizing treatment, grinding and drying to prepare the biomass nitrogen-doped derived porous carbon material. The biomass nitrogen-doped derivative porous carbon material prepared by the method has a rich pore structure and efficient adsorption-desorption performance, can replace an expensive MOFs material, optimizes the preparation path, improves the nitrogen doping efficiency and the material stability, remarkably reduces the cost and the environmental burden while ensuring the excellent atmospheric water collection performance, and has a wide application prospect. And the method shows more excellent industrialization prospects and sustainable development values.

The invention discloses kluyveromyces marxianus and application of the kluyveromyces marxianus in production of single-cell protein by taking straw as a raw material. The Kluyveromyces marxianus is a ZH-2 bacterial strain which is CGMCC (China General Microbiological Culture Collection Center) No.32295 The strain is obtained from a wild strain in a laboratory adaptive evolution mode, wheat straw and an inorganic nitrogen source can be used as raw materials for efficiently producing single-cell protein, compared with a parent strain, the utilization speed and the utilization rate of biomass, glucose and xylose are remarkably increased, the yield of ZH-2 SCP can reach 0.047 g.g <-1 >, and the yield of ZH-2 SCP can reach 0.045 g.g <-1 >. And the essential amino acid mode basically accords with adult and infant amino acid modes, and can be used as high-quality protein nutrition supply. The Kluyveromyces marxianus ZH-2 strain capable of obtaining single-cell protein by fermenting wheat straw as a raw material is provided from the perspective of utilizing cheap waste resources, so that the production cost of SCP is greatly reduced, and the problem of protein resource shortage is effectively solved.

The invention discloses a production process of activated carbon with efficient adsorption performance, and belongs to the technical field of porous carbon material preparation. The preparation method comprises the following steps: by taking biomass as a raw material, compounding the biomass with a eutectic salt system consisting of zinc chloride and potassium chloride, a nitrogen source precursor and a sacrificial cation source to obtain a homogeneous reaction precursor; the key point is that the precursor is subjected to programmed variable-pressure pyrolysis treatment under the condition that the temperature is far lower than the traditional activation temperature. According to the process, deep infiltration of molten salt is achieved through initial pressurization operation, and then reaction gas is guided to escape orderly through a later programmed pressure reduction process. Through collaborative innovation of the composition and the process, multiple steps of carbonization, activation, pore forming, in-situ functionalization and the like are integrated in a single low-temperature reaction unit, and the technical problems that a traditional method is high in energy consumption and long in flow, and the physical structure and surface chemistry of a material are difficult to synchronously regulate and control are solved.

The invention discloses a porous carbon particle adsorption material capable of preparing ultra-pure helium through one-step purification as well as a preparation method and application of the porous carbon particle adsorption material. The method comprises the following steps: (1) carbonizing biomass particles; (2) dipping the carbonized biomass particles in a nitrogen source-containing aqueous solution; (3) carrying out CO2 activation pore-forming and nitrogen functional group doping on the nitrogen source impregnated carbonized biomass particles obtained in the step (2) at high temperature; and (4) fully activating the nitrogen source impregnated carbonized biomass particles, performing programmed cooling, and introducing water vapor to perform secondary pore forming and oxygen functional group doping to obtain the porous carbon material. According to the method, the porous carbon particle adsorbent is prepared from natural biomass, the pore size distribution is concentrated, nitrogen and oxygen containing functional groups are rich, the adsorbent has ultrahigh adsorption and capture capacity on various impurities in the crude helium under the low-temperature condition, the impurities in the crude helium can be removed in one step, the helium is purified to reach the 6N standard, and the method is suitable for industrial production. And the application requirement of high-efficiency removal of impurities in the production process of ultra-pure helium is met.

The invention discloses a preparation method of modified salicornia biochar, and belongs to the technical field of environmental protection. The preparation method comprises the following steps: washing, drying and crushing salicornia europaea serving as a raw material, mixing the salicornia europaea with a nitrogen source modifier according to a certain mass ratio, adding water, uniformly stirring, dipping and drying; the nitrogen source modifier is one or more of urea, melamine or thiourea; then carrying out pyrolysis and carbonization, grinding, washing and drying the obtained carbon material, and finally preparing the modified salicornia biochar. The prepared modified salicornia biochar is used for adsorbing organic matters in sewage or wastewater, can effectively remove dissolved organic carbon (DOC, 86.34%), UV254 (89.33%) and chromaticity (CN, 94.74%) in an adsorption experiment of livestock and poultry biogas slurry, and shows excellent adsorption performance. The method follows the principle of treating waste with waste, the salicornia europaea waste is effectively treated, the obtained biochar has good application potential in the aspect of sewage and wastewater treatment, and high-value utilization of the waste is achieved.

The invention discloses a preparation method and application of nickel-cobalt bimetallic phosphide for in-situ growth of nitrogen-doped carbon nanotubes. The preparation method comprises the following steps: preparing a graphene oxide dispersion liquid; sequentially adding a cobalt source, a nickel source, a segmented copolymer, a phosphorus source and a nitrogen source into the graphene oxide dispersion liquid, and uniformly mixing to obtain a mixed solution; drying the mixed solution to obtain a precursor; and annealing the precursor in an inert atmosphere to obtain the product. According to the nitrogen-doped carbon material coated phosphide nano-particle composite material and the preparation method thereof, by regulating and controlling the ratio of Ni to Co, a carbon source grows on graphene in situ to form a carbon nano-tube, nickel-cobalt bimetal phosphide nano-particles are uniformly distributed on a nitrogen-doped carbon material to form the nitrogen-doped carbon material coated phosphide nano-particle composite material, and the nitrogen-doped carbon material coated phosphide nano-particle composite material is used as a modified diaphragm material of a lithium-sulfur battery. The preparation method disclosed by the invention has the advantages of mild reaction conditions and easiness in amplification and regulation, and the prepared composite material has a relatively high specific surface area and can be applied to the field of energy sources, especially the field of lithium-sulfur batteries.

The invention discloses a method for synthesizing a platinum-based nitrogen-doped graphdiyne catalyst based on an atomic layer deposition technology and application of the platinum-based nitrogen-doped graphdiyne catalyst. Firstly, hexabromobenzene and calcium carbide are subjected to vacuum ball milling, calcination and purification to obtain a graphdiyne carrier, then the graphdiyne carrier and melamine are mixed and calcined to achieve nitrogen doping of the carrier, and then loading of platinum nanoparticles is accurately controlled through an atomic layer deposition technology. According to the method, the characteristics of an atomic layer deposition technology are utilized, deposition parameters and the number of cycles are controlled, uniform distribution and size control of Pt nano-particles on porous graphdiyne are achieved, and a nitrogen-doped graphdiyne carrier and the platinum nano-particles have a synergistic effect. The platinum-based nitrogen-doped graphdiyne catalyst prepared by the invention has the specific surface area of 734.8 m < 2 > g < 1 > and the average pore size of 8.68 nm, and shows excellent electrocatalytic activity and dynamic performance in reaction.

The invention provides a preparation method of lithium iron phosphate, lithium iron phosphate and a lithium ion battery, and belongs to the technical field of new energy batteries. The preparation method comprises the following steps: providing ternary composite iron phosphate; mixing the ternary composite iron phosphate with a lithium source and a ligand in a solvent to form a precursor solution, and spraying a nitrogen source solution into the precursor solution in a spraying form to obtain slurry; drying the slurry to obtain a solid precursor; and carrying out heat treatment on the solid precursor in an atmosphere containing red phosphorus steam, and cooling to obtain the lithium iron phosphate. The ternary composite iron phosphate with a specific proportion is adopted as the raw material, so that the electrochemical performance of the lithium iron phosphate is effectively improved; the preparation method is simple in process, easy to control and capable of realizing large-scale industrial production. The prepared lithium iron phosphate has high specific capacity, long cycle life and good rate capability, and the overall performance of the lithium ion battery is remarkably improved.

The invention discloses a method for improving the fermentation performance of clostridium aerovorans and application of the clostridium aerovorans, and according to the method, an effective amount of methionine or a derivative thereof is added into a fermentation culture medium of the clostridium aerovorans to completely replace expensive complex organic nitrogen sources such as yeast extracts. The method successfully solves the three technical bottlenecks of slow biomass accumulation, low ethanol yield and dependence on expensive nitrogen sources in the fermentation process of the clostridium aerovorans by utilizing synthesis gas or CO2 / H2 mixed gas. Experiments prove that methionine or a derivative thereof can synergistically promote growth metabolism of thalli and a synthesis path of a product, so that the gas conversion efficiency of a carbon source is remarkably improved and metabolism is guided to flow to ethanol synthesis while the growth rate and the final biomass of the thalli are improved, and thus the production capacity of alcohols is synchronously enhanced. The method is simple in process and remarkable in effect, and an efficient and economical new strategy is provided for reducing the production cost of biofuel and promoting industrial application of a synthesis gas biorefinery technology.

The invention relates to the technical field of acid tail gas treatment, and discloses a boron-nitrogen-doped aluminum oxide catalyst as well as a preparation method and application thereof. The method comprises the following steps: (1) mixing an aluminum source, a nitrogen source, a boron source and water to obtain a mixed solution, then adding a peptizing agent to adjust the pH of the mixed solution to be acidic, and then standing and aging; (2) drying the material subjected to standing and aging in the step (1), then roasting under protective gas, and then sequentially carrying out high-temperature nitriding and cooling; and (3) carrying out plasma treatment on the material cooled in the step (2). The catalyst prepared by the method has large specific surface area and catalytic activity, can well capture water and carbonyl sulfide, converts carbonyl sulfide into hydrogen sulfide and improves the purity and yield of enriched hydrogen sulfide, and the preparation method of the catalyst is simple and efficient.

The invention discloses a photo-thermal carbon dioxide adsorbent as well as a preparation method and application thereof. The photo-thermal carbon dioxide adsorbent is green in production process and wide in raw material source, chitosan which is high in natural abundance and low in price is directly used as a raw material, and the energy consumption in the preparation process is effectively reduced through a composite pore-forming strategy that an activating agent, a pore-forming agent and a nitrogen source are introduced through a one-pot method. The photo-thermal carbon dioxide adsorbent provided by the invention can realize direct carbon capture in normal-temperature air or adsorption separation of CO2 in flue gas, and then realizes zero-carbon desorption under sunlight irradiation, thereby providing a new idea for capture, utilization and storage of carbon dioxide.