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2710 results about "Nitrogen doped" patented technology

Preparation method of nitrogen-doped porous-structure carbon material

The invention discloses a preparation method of a nitrogen-doped porous-structure carbon material and belongs to the technical field of inorganic material preparation. The preparation method utilizes a micromolecular carbon-containing compound as a raw material and comprises the following steps of based on the weight of the raw material, adding 0-400wt% of an inorganic base, 0-400wt% of an organic nitrogen-containing compound and 0-50wt% of a metal or metal oxide or inorganic metal salt into the raw material, carrying out uniform dispersion, and carrying out a reaction process in an inert gas protective atmosphere at a temperature of 400-900 DEG C for 0.5-12h so that the nitrogen-doped porous-structure carbon material having micropores, mesopores and macropores is obtained. The preparation method has simple processes, can be controlled easily, and realizes one-step combination of porous structure, functionalization nitrogen doping and metal particle modification. The nitrogen-doped porous-structure carbon material having high nitrogen content has a large capacitance value and good cycle performances, can be used as an oxygen reduction reaction catalyst having high activity, high selectivity and high stability and has a very large application prospect.
Owner:BEIJING UNIV OF CHEM TECH

Preparation of nitrogen doped carbon-encapsulated core-shell structure ferro-nickel nano-catalyst and application thereof in catalyzing o-chloronitrobenzene hydrogenation reaction

The invention provides a preparation method of a nitrogen doped carbon-encapsulated core-shell structure ferro-nickel nano-catalyst and the application of the nitrogen doped carbon-encapsulated core-shell structure ferro-nickel nano-catalyst in catalyzing an o-chloronitrobenzene hydrogenation reaction. According to the method, the novel nitrogen doped carbon-encapsulated core-shell structure ferro-nickel nano-catalyst is prepared by synthesizing a ferronickel layered doubled hydroxide precursor with small grain size and high surface energy through a nucleation crystallization isolation method, evenly mixing the ferronickel layered doubled hydroxide precursor with a melamine and dicyandiamide mixed carbon material precursor, and finally self-reducing at high temperature. The nitrogen doped carbon-encapsulated core-shell structure ferro-nickel nano-catalyst is efficiently applied to the reaction where halogenated aniline is generated through catalytic hydrogenation of a nitro-halogen compound, and the conversion rate of o-chloronitrobenzene and the selectivity of o-chloroaniline are respectively up to 95-100% and 98-100%. The structure of the novel nitrogen doped carbon-encapsulated core-shell structure ferro-nickel nano-catalyst is unique and novel, the process is green and energy-saving, the structure of the catalyst is stable, and the catalyst has a broad application prospect.
Owner:BEIJING UNIV OF CHEM TECH

Nitrogen-doped porous carbon and preparation method thereof

The invention relates to a preparation method of nitrogen-doped porous carbon, and in particular relates to a method for preparing doped porous carbon by taking a heavy organism as a carbon source, belonging to the technical field of carbon material preparation. The method comprises the following steps of: firstly, conducting a reaction between a nitrogen source and formaldehyde to generate a prepolymer; then, mixing the prepolymer with a template and the carbon source, and reacting at certain temperature; and finally, curing and carbonizing a crosslinking product to obtain nitrogen-doped porous carbon. The method provided by the invention can obtain nitrogen-doped porous carbon with different pore structures and nitrogen contents through multiple ways such as control on the nitrogen source type, temperature control, control on the mass ratio of a carbon source to a nitrogen source, control on the dosage of a template agent and the like. By adopting a chemical polymerization blending carbonization method, the method effectively controls the loss of nitrogen in a thermal treatment process and improves the utilization rate of the nitrogen source; the selection range of the raw material is wide; and the method is easy to operate and easily realizes large-scale preparation while providing a new way for efficiently utilizing heavy organic matters.
Owner:DALIAN UNIV OF TECH

Composite material of nitrogen-doped porous carbon-wrapped carbon nano tube as well as preparation method and application of material

The invention relates to a composite material of a nitrogen-doped porous carbon-wrapped carbon nano tube as well as a preparation method and an application of the composite material. The preparation method comprises the following steps: dispersing the carbon nano tube in water, adding a carbon source to obtain a reaction system, subsequently performing hydrothermal reaction, performing thermal treatment on the carbon nano tube wrapped with a carbon layer on the surface, and a nitrogen source at the high temperature so as to obtain the composite material of the nitrogen-doped porous carbon-wrapped carbon nano tube. According to the preparation method, the carbon source is polymerized under a hydrothermal reaction condition so as to obtain the carbon layer, the outer surface of the carbon nano tube is wrapped with the carbon layer, subsequently the carbon layer is carbonized and decomposed to generate a porous structure under high temperature treatment, and at the same time, the gasified nitrogen source is diffused to the carbon layer through ducts to be subjected to in-situ doping. The composite material provided by the invention can be used as a cathode oxidation reduction catalyst of a fuel battery, is excellent in catalysis, and is high in oxidation activity when being compared with other nitrogen-doped materials reported in documents. The preparation method provided by the invention is simple and economic in process, convenient to operate and easy to achieve the large-scale production.
Owner:INST OF CHEM CHINESE ACAD OF SCI

Nitrogen-doped high-luminescent carbon quantum dot and preparation method thereof

The invention provides a nitrogen-doped high-luminescent carbon quantum dot and a preparation method thereof. The preparation method comprises the following steps: reacting by using a sodium citrate solution as a carbon source and ethanediamine as a source of N under a sealing condition, cooling an obtained product, then separating, and drying a solution obtained after separation so as to obtain the nitrogen-doped high-luminescent carbon quantum dot. The preparation method is simple in process, short in preparation period, low in manufacturing cost and good in repeatability; obtained raw materials are simple and easily available. The nitrogen-doped high-luminescent carbon quantum dot prepared by using the method is uniform in size distribution and high in luminescent density; the luminescent density of the nitrogen-doped high-luminescent carbon quantum dot is about 20 times of that of a general quantum dot, so that the application of the nitrogen-doped high-luminescent carbon quantum dot in the field of cell marking can be expanded. As the improvement of the luminescent density is caused by nitrogen doping, the nitrogen-doped high-luminescent carbon quantum dot prepared by the method has unique application when being used for detecting whether N exists in environments.
Owner:CHINA UNIV OF PETROLEUM (BEIJING)

Nitrogen-doped chitosan-based activated carbon and preparation method thereof

The invention provides nitrogen-doped activated carbon synthesized by using biomass derivative and particularly provides nitrogen-doped chitosan-based activated carbon. Chitosan is used as raw materials. The content of nitrogen in the activated carbon is 2-8wt%. The specific surface area of the activated carbon is 600-1100m<2>/g. The aperture of the activated carbon is 0.46-1.5nm. The nitrogen-doped chitosan-based activated carbon is prepared by using the chitosan as raw materials through dissolution, freeze-drying and high-temperature carbonization. By dissolving the chitosan to reduce acting force among molecules, by conducting freeze-drying to control the overall structure of chitosan dry gel and by increasing the porosity and the specific surface area of chitosan carbonization products, the nitrogen-doped chitosan-based activated carbon with large specific surface area is obtained. An environmental-friendly process of preparing high-performance activated carbon without consuming strong acid and strong alkali is realized. The traditional activated carbon preparation process which is not environmental-friendly and is high in cost because activating agents, water and the like are greatly used is avoided. The invention additionally provides a preparation method of the nitrogen-doped chitosan-based activated carbon, which has the advantages that the preparation process is simple, the equipment is simple and easy to obtain and the like.
Owner:DALIAN UNIV OF TECH

ZIF-67 template method for preparing cobalt-platinum core-shell particle/porous carbon composite material and catalytic application of composite material in cathode of fuel cell

The invention discloses application of a nitrogen-doped porous carbon fixed Co@Pt nano-particle composite material, prepared by taking ZIF-67 as a template, as an efficient catalyst for oxygen reduction catalytic reaction of a cathode of a fuel cell. The application has the superiorities that (1) a synthetic method of the catalyst is simple and feasible, the shape of the catalyst is controllable, batch preparation can be realized, and the catalytic performance is very stable; (2) the oxygen reduction catalytic reaction of nitrogen-doped porous carbon fixed cobalt-platinum core-shell nano-particles in the cathode of the fuel cell shows that the nano-particles have good catalytic activity and excellent methanol poisoning resistance stability, and compared with traditional commercial Pt/C, the nano-particles have relatively high take-off potentials and half-wave-peak potentials (nano-particles: 0.99V and 0.87V, and Pt/C: 0.98V and 0.83V); and (3) metal organic frameworks (MOFs) for preparing the catalyst have sequential microcellular structures and relatively large specific surface areas and can be widely applied to the storage and conversion of energy sources. Therefore, a method for simply and directly preparing cheap and efficient cathode oxygen reduction electro-catalyst is provided for the fuel cell and has a wide application prospect.
Owner:SOUTH CHINA UNIV OF TECH

Nitrogen-doped carbon-clad manganese oxide lithium ion battery composite cathode material, and preparation method and application of composite cathode material

The invention discloses a nitrogen-doped carbon-clad manganese oxide lithium ion battery composite cathode material, and a preparation method and an application of the composite cathode material. The composite material is composited by nanoscale manganese oxide and dopamine, wherein manganese oxide is spherical. The method comprises the steps of mixing a prepared spherical manganese oxide nano particle and dopamine hydrochloride, performing filtering, washing and drying to obtain a manganese oxide and polydopamine composite, and then converting a polymerization layer into a nitrogen-doped carbon layer by high-temperature carbonization. The prepared nitrogen-doped carbon-clad manganese oxide (MnO@NC) lithium ion battery composite cathode material is stable in structure and good in conductivity, and has excellent rate capability and cycling stability as a lithium ion battery cathode material; and polymerization of the dopamine is only completed at a room temperature and under a slightly alkaline condition, so that the composite cathode material is low in cost, low in energy consumption, convenient to control and environment-friendly, is suitable for a practical application of a lithium ion battery, and can realize industrial mass production.
Owner:SOUTH CHINA UNIV OF TECH

Preparation method of nitrogen-doped zinc oxide film

The invention relates to the technical field of zinc oxide preparation, and in particular relates to a preparation method of a nitrogen-doped zinc oxide film. The preparation method comprises: placing a silicon substrate in the reaction cavity of atomic layer deposition (ALD) equipment; introducing gas containing a zinc source into the reaction cavity of the ALD equipment, wherein the zinc atoms in the gas containing the zinc source are adsorbed to the silicon substrate; conveying hydrogen to the reaction cavity of the ALD equipment based on nitrogen as a carrier gas, and simultaneously carrying out plasma discharge; introducing an oxygen-containing source to the reaction cavity of the ALD equipment, wherein the zinc atoms which do not react with nitrogen atoms form zinc-oxygen bonds withthe oxygen atoms in the oxygen-containing source; and repeating the steps, so as to grow the zinc oxide film containing the nitrogen atoms layer by layer. In the preparation method provided by the invention, nitrogen doping is carried out on the zinc oxide film by utilizing the ALD equipment; the method is simple and practicable; by utilizing the characteristic of atomic layer deposition and single-layer cycle growth, the uniform nitrogen doping in the whole film structure can be achieved in the process of zinc oxide film growth so that the doped film is complete in structure and excellent inproperty.
Owner:INST OF MICROELECTRONICS CHINESE ACAD OF SCI
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