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126 results about "Silicon oxycarbide" patented technology

Silicon/silicon oxycarbide/graphite composite negative electrode material

The invention relates to a silicon / silicon oxycarbide / graphite composite negative electrode material which is a silicon-containing material which has the size being lower than 3 microns uniformly and is firmly distributed on the surface of a negative electrode of graphite. The invention further provides a preparation method of the composite negative electrode material. The preparation method comprises the steps of dispersing a silicon-containing material in a liquid organo-siloxane monomer, sequentially adding an acid liquid of alcohol and water, a curing agent and a graphite negative electrode material, then carrying out ball milling or mechanical stirring, pinching and mixing to obtain a paste-type mixture; calcining the paste-type mixture at high temperature under a protective atmosphere, crushing and sieving to obtain different-particle-size silicon / silicon oxycarbide / graphite lithium-ion battery negative electrode material. The silicon-containing materials of the silicon / silicon-oxygen carbon / graphite composite negative electrode material are firmly and uniformly distributed on the surface of a graphite material; due to the structure, the silicon-containing materials can be effectively adsorbed on the surface of the graphite, the self agglomeration of the silicon-containing material can be avoided and the silicon-containing material is prevented from peeling off from the graphite; the silicon / silicon oxycarbide / graphite composite negative electrode material has the characteristics that the charge and discharge specific capacities are adjustable, and the electrochemical cycle stability is high.
Owner:CHINA AUTOMOTIVE BATTERY RES INST CO LTD

Silicon/silicon oxycarbide/carbon anode material and preparation method and application thereof

The invention discloses a silicon/silicon oxycarbide/carbon anode material and a preparation method and an application thereof. In the silicon/silicon oxycarbide/carbon anode material, ultra-small silicon-oxygen-carbon nanoparticles are evenly dispersed into a carbon substrate to be used as a buffer substrate while silicon nanoparticles are evenly inlaid into the carbon/silicon-oxygen-carbon buffer substrate. The method comprises the following steps: with a thermosetting resin monomer as a solvent system instead of a traditional solvent, dispersing silicon nano powder into the solvent evenly; obtaining a solid block of a silicon/polysiloxane/carbon precursor composite material by solidifying vinylite and a silane coupling agent containing double bonds; and carrying out high-temperature calcination after crushing, and carrying out ball-milling to obtain the silicon/silicon oxycarbide/carbon anode material. According to the method, a traditional organic solvent is not used; solvent post-treatment is avoided; the silane coupling agent is directly polymerized with resin; and carbon and silicon-oxygen-carbon are formed in situ through calcination polymer pyrolysis. With ceramic (silicon-oxygen-carbon) and carbon as the buffer substrates, the stress caused by silicon volume expansion is absorbed; and bad consequences caused by silicon volume expansion are eliminated and reduced.
Owner:NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI

Interface-phase-including alumina fibrous fabric reinforced SiOC (silicon oxycarbide) ceramic and preparation method thereof

The invention discloses an interface-phase-including alumina fibrous fabric reinforced SiOC (silicon oxycarbide) ceramic. The interface-phase-including alumina fibrous fabric reinforced SiOC ceramic uses a SiOC ceramic as a matrix and three-dimensional alumina fibrous fabric as a reinforcement, and a sacrificial carbon interface phase is formed between the matrix and the reinforcement. A preparation method of the interface-phase-including alumina fibrous fabric reinforced SiOC ceramic comprises the following steps of first, putting the alumina fibrous fabric into a muffle furnace for carrying out high-temperature oxidation to remove impurities; afterwards, preparing a cracking carbon coating on the surface of the alumina fibrous fabric by utilizing a chemical vapor deposition technique; preparing a precursor solution, carrying out vacuum impregnation on the alumina fibrous fabric coated with the cracking carbon coating with the precursor solution, taking out the vacuum-impregnated alumina fibrous fabric out for air-drying, carrying out low-temperature crosslinking on the air-dried alumina fibrous fabric, and then completing a one-time compaction process through high-temperature ceramization; repeatedly carrying out compaction for at least five times to prepare a SiOC ceramic intermediate product; finally, carrying out subsequent oxidation to sacrifice cracking carbon, so as to prepare a final product. The product provided by the invention is excellent in room-temperature and high-temperature mechanical properties, high in inoxidizability and low in cost, and can be molded in a near-net-size manner.
Owner:NAT UNIV OF DEFENSE TECH
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