The invention discloses a positive
film structure for improving UV attenuation of a TOPCon battery and a preparation method, and relates to the technical field of TOPCon batteries, the positive
film structure comprises a
silicon oxycarbide
passivation anti-reflection film deposited on the front surface of a
silicon wafer, a SiOC low-folding layer, a SiOC
silicon-carbon-rich layer, a SiOC
transition layer and a SiOC
oxygen-rich layer are sequentially arranged from the surface of the silicon
wafer to the outside, the film thickness, the atomic percentage and the
refractive index of each layer are in specific ranges, and the thickness of the
silicon oxycarbide passivation anti-reflection film is larger than that of the
silicon oxycarbide passivation anti-reflection film. The SiOC low-folding layer is used for playing a role in stress buffering, the SiOC silicon-carbon-rich layer is used for resisting UV
decomposition and playing a role in passivation, the SiOC
transition layer is used for playing roles in stress buffering and optical optimization, and the SiOC
oxygen-rich layer is used for resisting environmental
corrosion and playing a role in optical optimization. According to the positive
film structure,
silicon oxycarbide is introduced into the positive film layer of the battery piece, through the synergistic effect of the four
layers of SiOC films,
ultraviolet dissociation can be resisted, dangling bonds can be reduced, the four-layer gradient
refractive index structure can achieve wide spectrum matching and improve the light
absorption efficiency,
oxygen atoms and carbon atoms are matched to reduce the interface
state density, and the UV attenuation resistance is improved on the basis that the
electrical performance is kept.