The invention discloses a preparation and purification process of quartz sand and quartz powder and products thereof. The preparation and purification process of quartz sand comprises raw quartz ore, rough separation, fragmentation, water separation, roasting, water fragmentation, soaking in oxalic acid or citric acid, dry grinding or wet grinding, high-gradient magnetic separation, classification, combined process washing, floatation, deionized water washing, special drying. The preparation and purification process of quartz powder comprises quartz sand flotation, ultra fine grinding (dry grinding or wet grinding ), combined process washing, high-gradient magnetic separation, electrostatic separation, deionized water washing, classification, special drying, and vacuum packing. The quartz sand and quartz powder produced with the process of the invention can not foam in the production of glass and chips, an optical fibre and an optical cable can not be broken, the glass does not have water streaks, and the application area is widened. The quartz sand and the quartz powder is suitable for being applied in the fields of monocrystal line silicon, chips, optical fibre and optical cables, war industry, fine chemistry industry and micro-electronics.