The invention discloses processes for preparing and purifying quartz sand and quartz powder and products thereof. The process for preparing and purifying quartz sand comprises the following steps: carrying out rough concentration on vein quartz green ores, crushing, roasting, quenching with water, grinding and grading, carrying out high-gradient magnetic separation, carrying out a complex reaction by using drugs, carrying out floatation, carrying out electrostatic separation, washing with deionized water, and drying to obtain the product. The process for preparing and purifying quartz powder comprises the following steps: carrying out rough concentration on vein quartz green ores, crushing, roasting, quenching with water, grinding and grading, carrying out high-gradient magnetic separation, carrying out a complex reaction by using drugs, treating with microwaves, carrying out electrostatic separation, washing with deionized water, and drying to obtain the product. The quartz sand and the quartz powder produced by using the processes provided by the invention do not bubble in the production process of glass and chips, optical fibers and cables can not break, and the glass does not have water grains. The quartz sand and the quartz powder have widened the application fields, and are applicable to the fields of monocrystalline silicon, polycrystalline silicon, optical fibers and cables, war industry, fine chemical industry and micro-electronics.