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21621results about How to "High recovery rate" patented technology

Upgrading and recovery of heavy crude oils and natural bitumens by in situ hydrovisbreaking

A process is disclosed for the in situ conversion and recovery of heavy crude oils and natural bitumens from subsurface formations using either a continuous operation with one or more vertical injection boreholes and one or more vertical production boreholes in which multiple, uncased, horizontal boreholes may extend from the vertical boreholes, or a cyclic operation whereby both injection and production occur in the same vertical boreholes in which multiple, uncased, horizontal boreholes may extend from the vertical boreholes. A mixture of reducing gases, oxidizing gases, and steam are fed to downhole combustion devices located in the injection boreholes. Combustion of the reducing gas-oxidizing gas mixture is carried out to produce superheated steam and hot reducing gases for injection into the formation to convert and upgrade the heavy crude or bitumen into lighter hydrocarbons. Communication between the injection and production boreholes in the continuous operation and fluid mobility within the formation in the cyclic operation is induced by fracturing, multiple horizontal boreholes extending from vertical boreholes, or other related methods. In the continuous mode, the injected steam and reducing gases drive upgraded hydrocarbons and virgin hydrocarbons to the production boreholes for recovery. In the cyclic operation, wellhead pressure is reduced after a period of injection causing injected fluids, upgraded hydrocarbons, and virgin hydrocarbons in the vicinity of the boreholes to be produced. Injection and production are then repeated for additional cycles. In both operations, the hydrocarbons produced are collected at the surface for further processing.
Owner:WORLD ENERGY SYST

Sublevel shrinkage caving stage open stope afterwards filling mining method

The invention discloses a sublevel shrinkage caving stage open afterwards filling mining method. In the earlier stage of stoping, caved ores are utilized to support surrounding rocks on a top tray, and in the later stage of stoping, a goaf area is filled with fillers to control ground pressure so as to achieve safe and efficient mining. Ore blocks are mined in two steps, mining blocks in step two are stoped after the mining blocks in step one are stoped and filled. After the ores are completely let out, the goaf area is filled with the fillers to control the ground pressure. Because the stoping modes of sublevel ore caving, sublevel shrinkage, final ore drawing and empty area afterwards filling are adopted, the mining method has large one-time filling amount and low cost; the method adopts middle-deep hole drilling and blasting and carry scraper ore removal, and the device has high level and large production capacity; the method has the advantages of large production capacity of the sublevel caving method and the stage open stope method, high recovery rate of the filling method, and earth surface protection; the safety is good, and drilling, ore removal and other operations are all carried out in a sublevel drilling and ore removal approach roadway; and the ores can be removed in advance, and the ores can be removed partially after the first sublevel is ready.
Owner:NORTHEASTERN UNIV +1

Method for comprehensively recycling valuable metals from spent lithium ion battery

The invention discloses a method for comprehensively recycling valuable metals from a spent lithium ion battery. The method comprises the following steps: carrying out electric discharge treatment on a spent battery, crushing, pre-roasting at 300-400 DEG C, adding a reducing agent, and carrying out reduction roasting at 450-700 DEG C; carrying out water extraction and evaporative crystallization on fine aggregates obtained through the reduction roasting, so as to obtain a high-purity lithium product, leaching copper, nickel and cobalt from leached slag and roasted lump materials by virtue of ammonia oxide, carrying out magnetic separation and sieving on ammonia leaching slag so as to obtain iron and aluminum enriched products, and carrying out reduction acid leaching, purification and edulcoration on sieved products, so as to obtain a high-purity manganese sulfate solution; and carrying out extraction and selective reverse extraction on ammonia leaching liquid, so as to obtain a high-purity nickel sulfate solution and a high-purity copper sulfate solution, and carrying out vulcanization cobalt precipitation, oxidation acid leaching and extraction purification on raffinate, so as to obtain a high-purity cobalt sulfate solution. The method is high in extraction rate of valuable metals and applicable to the treatment of multiple waste lithium ion battery raw materials and efficient utilization of multiple elements, and sorting is not required.
Owner:GUANGDONG GUANGHUA SCI TECH

Skeletal iron catalyst having improved attrition resistance and product selectivity in slurry-phase synthesis processes

Particulate skeletal iron catalyst is provided which contain at least about 50 wt. % iron with the remainder being a minor portion of a suitable non-ferrous metal and having characteristics of 0.062-1.0 mm particle size, 20-100 m2/g surface area, and 10-40 nm average pore diameter. Such skeletal iron catalysts are prepared and utilized for producing synthetic hydrocarbon products from CO and H2 feeds by Fischer-Tropsch synthesis process. Iron powder is mixed with non-ferrous powder selected from aluminum, antimony, silicon, tin or zinc powder to provide 20-80 wt. % iron content and melted together to form an iron alloy, then cooled to room temperature and pulverized to provide 0.1-10 mm iron alloy catalyst precursor particles. The iron alloy pulverized particles are treated with NaOH or KOH caustic solution at 30-95° C. temperature to extract and/or leach out most of the non-ferrous metal portion, and then screened and treated by drying and reducing with hydrogen and to provide the smaller size skeletal iron catalyst material. Such skeletal iron catalyst is utilized with CO+H2 feedstream for Fischer-Tropsch reactions in either a fixed bed or slurry bed type reactor at 180-350° C. temperature, 0.5-3.0 mPa pressure and gas hourly space velocity of 0.5-3.0 L/g Fe/hr to produce desired hydrocarbon products.
Owner:INST OF COAL CHEM ICCCHINESE ACADEMY OF SCI +1

Full-temperature-range pressure swing adsorption gas separation, refinement and purification method

ActiveCN105749699AReduce energy consumptionBroaden the scope of adsorption separation applicationsSolidificationLiquefactionEnergy gradientPurification methods
The invention discloses a full-temperature-range pressure swing adsorption gas separation, refinement and purification method.By means of the difference of the temperatures and pressures of different raw material gases and the difference of the adsorption separation coefficients and physical chemistry properties of all components in the raw material gases in the temperature range of 80-200 DEG C and the pressure range of 0.03-4.0 MPa, the adsorption or desorption regeneration operation of the pressure swing adsorption circulation process is adjusted by coupling all separation methods, the adsorption theory that the pressure or temperature swing adsorption separation process is only limited to the adsorption and desorption regeneration circulation operation through pressure or temperature changes is expanded, and therefore all raw material gases are separated, refined and purified by achieving the energy gradient utilization in the gas separation, refinement and purification process and achieving the circulation operation, where adsorption, desorption and regeneration are easily matched and balanced, in the moderate to low cold and moderate to high temperature pressure swing adsorption separation process, and it is changed that a traditional adsorption method is only limited to the auxiliary effect of refinement and purification, and adsorption becomes the basic separation unit operation just as important as refinement, absorption and extraction separation.
Owner:SICHUAN TECHAIRS

Medium thick heavy-pitch crushed ore body frame type artificial top downward segmenting cemented filling method

The invention discloses a medium thick heavy-pitch crushed ore body frame type artificial top downward segmenting cemented filling method which comprises the following steps: dividing chamber jambs along the trend of an ore body; adopting a rail-less mining aligning system; pre-constructing a high-strength reinforced concrete artificial top in a segmented drilling lane; adopting a stoping sequence from up to down; performing drilling and blasting ore removal on the ore body through the segmented drilling lane at bottom; adopting medium-length hole drilling and remotely controlling a scraper to discharge ore; after finishing the mining of the chamber, utilizing concrete tailings to perform cemented filling; after finishing the mining of the jambs, utilizing concrete tailings or pure tailings to perform cemented filling; after completely stoping the mine chamber in the frame under the protection of the concrete artificial top, starting to stope the jamb adjacent to the segment, and meanwhile stoping the corresponding mine chamber in the frame of the next segment, and then stoping the corresponding jamb of the next segment; and after completely mining the chamber jamb in the middle segment, immediately turning towards the lower middle segment for stoping. The method provided by the invention has the advantages that the safety for mining the heavy-pitch medium thick crushed or ultra-crushed ore body is high, the resource depletion loss rate is low, the mechanical degree is high, the production capacity is high, and the like.
Owner:CENT SOUTH UNIV +1

Method for recovering waste/used lithium iron phosphate positive-pole material by acid leaching method

The invention belongs to the technical field of recovery of lithium-ion batteries and particularly relates to a method for recovering a waste/used lithium iron phosphate positive-pole material by an acid leaching method. The method provided by the invention comprises the following steps: (a) carrying out acid leaching: adding acid into the lithium iron phosphate positive-pole material for acid leaching so as to obtain a suspension, and carrying out filtration, so as to obtain filtrate; (b) carrying out oxidation: adjusting the pH value of the filtrate obtained in the step (a) to be smaller than 1, and adding an oxidant into the filtrate to oxidate ferrous ions in the filtrate into ferric ions, so as to obtain a mixed solution; (c) carrying out separation: adjusting the pH value of the mixed solution obtained in the step (b) to be 1.5 to 4, carrying out a reaction for 1 to 3 hours at the temperature of 60 DEG C to 95 DEG C so as to produce ferric phosphate precipitates, and carrying out filtrating and washing, thereby obtaining lithium-containing filtrate and ferric phosphate. The method provided by the invention is simple in process, continuous in cycle, low in cost and easy to industrialize and is environmentally friendly; the recovery rate of Li, Fe and P reaches 95% or more, subsequent prepared FePO4 is low in impurity content, the particle size is 1 to 6 microns, is uniform and is narrow in distribution, and the morphology is controllable, so that the FePO4 is battery-grade ferric phosphate.
Owner:TIANQI LITHIUM CORP

Technological process for producing high concentration nitric-phosphate fertilizer

The invention discloses a technique method for producing high-concentration nitric phosphate, which comprises the following steps of: adding nitric acid into phosphorus ore for acidolysis, depositing and separating acid non-soluble substance, freezing and crystallizing calcium nitrate, filtering the calcium nitrate, neutralizing the mother liquid, vaporization, pelleting and drying. The invention is characterized in that: a step of thoroughly removing the calcium of the mother liquid is arranged between the steps of filtering the calcium nitrate, and neutralizing the mother liquid. The steps comprise the following steps of: I) thoroughly removing the calcium of the mother liquid and adding sulfuric acid or ammonium sulfate; the calcium ions and the sulfate ions in the mother liquid generate dihydrate calcium sulfate crystal; II) the grading processing of reaction slurry: employing a grading device to carry out grading processing to the reaction slurry; returning the reaction slurry provided with small grain calcium sulfate to the mother liquid for thoroughly removing the calcium, and feeding the reaction slurry provided with large grain calcium sulfate to the calcium sulfate for filtering; and III) filtering and washing the filtering reaction slurry of calcium sulfate by a filter, feeding the primary filtrate and the primary lavage fluid into the working procedure of neutralizing, and returning the secondary lavage fluid to the filter. The invention has the advantage of using middle-low quality phosphorite to prepare the high-concentration nitric phosphate.
Owner:TIANJI COAL CHEM IND GROUP +1

Method for recovering lithium from waste lithium ion battery and waste pole piece

ActiveCN101942569AHigh recovery rateEffectively realize comprehensive recyclingProcess efficiency improvementPhysical chemistryLithium-ion battery
The invention discloses a method for recovering lithium from a waste lithium ion battery and a waste pole piece. The method comprises the following steps of: (1) crushing the waste lithium ion battery or the waste pole piece by using a crusher, placing the crushed material in a high-temperature furnace and removing an adhesive from the crushed material by thermal processing to obtain powder; (2) removing aluminum from the powder by dissolving the aluminum in sodium hydroxide solution and filtering the solution to obtain low-aluminum filter mud; (3) leaching the low-aluminum filter mud with acid and a reducing agent to obtain lixivium; (4) removing impurities such as iron, copper, aluminum and the like from the lixivium by a chemical method; (5) precipitating lithium in the lixivium with fluorine salt to obtain a lithium fluoride rough product; (6) washing the lithium fluoride rough product, filtering and drying to obtain a lithium fluoride product; and (7) returning filtrate obtained after the lithium fluoride rough product is washed to the step (3) for processing. By the method of the invention, the lithium fluoride product has purity of over 98.0 percent and the primary recoveryrate of lithium is between 75 and 92 percent; and the method of the invention has the advantages of simple process, low cost, easy industrial production and high economic benefit.
Owner:HUNAN BRUNP RECYCLING TECH
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