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984 results about "Mole fraction" patented technology

In chemistry, the mole fraction or molar fraction (xᵢ) is defined as the amount of a constituent (expressed in moles), nᵢ divided by the total amount of all constituents in a mixture (also expressed in moles), nₜₒₜ: xᵢ=nᵢ/nₜₒₜ The sum of all the mole fractions is equal to 1: ∑ᵢ₌₁ᴺnᵢ=nₜₒₜ; ∑ᵢ₌₁ᴺxᵢ=1 The same concept expressed with a denominator of 100 is the mole percent or molar percentage or molar proportion (mol%).

High-melting polyolefin copolymer elastomers, catalysts and methods of synthesis

This invention relates to high melting polyolefin copolymers suitable as thermoplastic elastomers and catalysts and methods for their synthesis. These elastomeric olefin copolymers are characterized by a mole fraction of crystallizable component Xc from about 30 to about 99%; low glass transition temperatures, below -20° C., and typically below -50° C.; melting points above about 90° C.; high molecular weights; a molecular weight distribution MW / Mn< / =10; and a narrow composition distribution between chains of < / =15%. The novel copolymers of the invention range from reactor blends to multiblock copolymers that can be sequentially fractionated into fractions of differing crystallinities, which fractions nevertheless show compositions of comonomers which differ by less than 15% from the parent polymer (reactor product). The invention also relates to a process for producing such copolymers by utilizing an unbridged, substituted or unsubstituted cyclopentadienyl metallocene catalyst that is capable of interconverting between states with different copolymerization characteristics, which interconversion is controlled by selecting the substituents of the cyclopentadienyl ligands so that the rate of interconversion of the two states is within several orders of magnitude of the rate of formation of a single polymer chain. Where ri>rf the polymer can be characterized as multiblock; where ri<rf, the result is a polymer blend and where ri / rf is close to 1, the resulting polymer is a mixture of blend and multiblock. The metallocene catalysts of the invention are able to interconvert between more than two states, with embodiments of four states being shown in FIG. 2.
Owner:THE BOARD OF TRUSTEES OF THE LELAND STANFORD JUNIOR UNIV

High-melting polyolefin copolymer elastomers, catalysts and methods of synthesis

This invention relates to high melting polyolefin copolymers suitable as thermoplastic elastomers and catalysts and methods for their synthesis. These elastomeric olefin copolymers are characterized by a mole fraction of crystallizable component Xc from about 30 to about 99%; low glass transition temperatures, below -20° C., and typically below -50° C.; melting points above about 90° C.; high molecular weights; a molecular weight distribution MW / Mn< / =10; and a narrow composition distribution between chains of < / =15%. The novel copolymers of the invention range from reactor blends to multiblock copolymers that can be sequentially fractionated into fractions of differing crystallinities, which fractions nevertheless show compositions of comonomers which differ by less than 15% from the parent polymer (reactor product). The invention also relates to a process for producing such copolymers by utilizing an unbridged, substituted or unsubstituted cyclopentadienyl metallocene catalyst that is capable of interconverting between states with different copolymerization characteristics, which interconversion is controlled by selecting the substituents of the cyclopentadienyl ligands so that the rate of interconversion of the two states is within several orders of magnitude of the rate of formation of a single polymer chain. Where ri>rf the polymer can be characterized as multiblock; where ri<rf, the result is a polymer blend and where ri / rf is close to 1, the resulting polymer is a mixture of blend and multiblock. The metallocene catalysts of the invention are able to interconvert between more than two states, with embodiments of four states being shown in FIG. 2.
Owner:BP AMOCO CORP +1

AEI/CHA eutectic molecular sieve containing triethylamine and synthetic method thereof

The invention discloses an AEI/CHA eutectic molecule sieve containing triethylamine. An anhydrous chemical composition of the AEI/CHA eutectic molecule sieve is expressed as mR.(Six.Aly.Pz)O2, wherein x, y and z are molar fractions of Si, Al and P respectively; the x is between 0.001 and 0.98; the y is between 0.01 and 0.6; the z is between 0.01 and 0.6, x+y+z is equal to 1; the R is a template agent, and the m is a mole number of the R; and the value of the m is between 0.02 and 0.6. A preparation method for the AEI/CHA eutectic molecule sieve comprises the following steps: a) according to the mol ratio of oxides of various components, stirring and mixing evenly a silicon source, an aluminum resource, a phosphorus source, the template agent, and water are to obtain an initial gel mixture; and b) transferring the initial gel mixture into a stainless steel synthesis kettle to be sealed, then heating the kettle to a crystallization temperature of between 160 and 250 DEG C, and performing crystallization at constant temperature for 1 to 120 hours under the self-generated pressure, and separating a solid product, washing the solid product to be neutral, and drying the solid product to obtain the AEI/CHA eutectic molecule sieve. The molecule sieve can be used as a catalyst for an acid catalytic reaction after the template agent is removed through the baking.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Method for preparing nano-scale ZSM-5 molecular sieve by using coal ash

The invention relates to a method for preparing a nano-scale ZSM-5 molecular sieve by using coal ash. The method comprises the following steps: pre-treating coal ash; using the coal ash subjected to pretreatment to prepare aluminum hydroxide and sodium silicate; uniformly mixing the aluminum hydroxide and the sodium silicate which are obtained after the coal ash is processed with water and the template agent tetrapropyl-ammonium hydroxide, wherein molar fraction of the water, the tetrapropyl-ammonium hydroxide, the aluminum hydroxide and the sodium silicate are respectively 90-98 percent, 0.25-1.0 percent, 0.025-0.01 percent and 1-2 percent; performing microwave auxiliary synthesis for 24-72 hours at the temperature of 150-250 DEG C; taking out a product in a reaction kettle, washing for 2-5 times with water at the temperature of 60-80 DEG C, and drying at the temperature of 120 DEG C for 12-24 hours; after drying, roasting the product at the temperature of 600-800 DEG C for 4-8 hours to obtain a nano-scale ZSM-5 molecular sieve finished product, wherein the particle size of the ZSM-5 molecular sieve is 200-500 nm. According to the method, the synthesis cost of the ZSM-5 molecular sieve is reduced, the problem of environment pollution caused by coal ash is reduced, and high-value use of the coal ash is realized.
Owner:NORTHEAST GASOLINEEUM UNIV
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