725results about How to "Wide pH range" patented technology

The present invention relates to no-phosphate corrosion and scale inhibitor and its application. The no-phosphate corrosion and scale inhibitor consists of polyaspartic acid and/or polyepoxy succinic acid 10-20 wt%, polymaleic anhydride 20-30 wt%, copolymer of acrylic acid and 2-acrylamido-2-methyl propenyl sulfonic acid 15-20 wt%, zinc salt 3-5 wt%, natural organic high molecular compound 5-12 wt%, molybdate 5-8 wt%, and other components 5-20 wt%. It has excellent corrosion retarding performance, high scale inhibiting performance and environment friendship.

A complex metal oxide used as an adsorbent for removing fluorine from water is prepared from the transition metal chosen from Ti, V, Cr, Mn, Fe, Co, Ni, Cu and Zn, aluminum and RE metal chosen from Ce and La in the mole ratio of (0.5-1.5): (2-6): (0.5-1.5) through dissolving them in water to become aqueous solution, dropping alkali solution to make its pH=9.0-9.5, laying aside, centrifugal washing and separating by deionized water, drying, and grinding.

The invention discloses a preparing method of a manganese oxide-charcoal composite adsorbent, which comprises following steps: (1) air-drying or drying a biomass raw material, pulverizing into powder and uniformly mixing for standby; (2) taking potassium permanganate or sodium permanganate as a pre-treating agent, and performing pretreatment on the biomass raw material by adopting an equivalent-volume impregnation method; (3) drying, pyrolyzing and carbonizing the pretreated material to prepare the composite adsorbent material; (4) soaking the obtained composite adsorbent material with inorganic acid, and washing and drying to obtain the manganese oxide-charcoal composite adsorbent finished product. The method is simple, the prepared composite adsorbent is suitable for an adsorption method as an adsorbent for treating heavy metal ion-containing waste water, and has an advantage in the aspect of treating the acid heavy metal ion waste water particularly. The adsorbent can also serve as a conditioner for soil polluted by heavy metal ions, and achieves an action of controlling the absorption of plants to heavy metal ions by adsorbing the heavy ion ions after being applied into the soil.

The invention discloses a magnetic Co ₃ o ₄ The ‑C nanometer material and its preparation method and the application of activated persulfate as a catalyst in wastewater treatment belong to the technical field of water pollution control. In this method, cobalt metal-organic framework compounds are used as precursors, which are calcined at high temperature in a certain atmosphere, and finally magnetic Co ₃ o ₄ ‑C nanomaterials. The porous carbon component in this material not only acts as a carrier of metal oxides to evenly distribute the catalytic sites, but also effectively enriches pollutants in water to improve the degradation efficiency of the system; the magnetic Co in this material ₃ o ₄ The components can be used as heterogeneous catalysts to efficiently activate monopersulfate to generate free radicals to degrade pollutants in water bodies. The method has the characteristics of high efficiency and convenience, wide application range of pH, catalyst recovery by external magnetic field, good recyclability, and environmental friendliness, and has great potential in the actual treatment and application of organic wastewater.

The invention relates to a method for preparing an active coal ash phosphoric adsorbent, which comprises the following steps: a) mixing the coal ash and the basic activating agent evenly in the high-speed batch mixer, b) roasting and activating them in the calcining furnace, c) putting them into the acidproof retort after cooling and adding acidic modifier into the retort, d) heating them to react, then drying and grinding the materials and getting the powdered phosphoric adsorbent with high active. Said invention uses the industrial waste coal ash as the raw material, and by means of the low-cost activating agent and modifier it can dissolve out the material with high absorptive in the coal ash, and the prepared absorbent has high dephosphorize effect.

The invention relates to an immobilized enzyme biocatalyst and the manufacturing method and application. The immobilized enzyme biocatalyst regards tubular hollow silica dioxide dielectric hole material as a carrier external surface, inner surface and micropore in the wall of which are fixed biological enzyme molecule. The method includes physical adsorption cast investment or chemical coupling/ crosslinking method; the biocatalyst is provided with good enzyme dispersibility and high carrying quantity, high recovery ratio of enzymatic activity, low enzyme flow rate. The invention can fix penicillin acylating enzyme, glucose oxidase, peroxidase, cytase and so on, which also can be used for removing sugar in protein, removing sugar in total egg, removing oxygen in food , microbiological sensing device, antibiosis and disinfection reaction, wherein immobilized penicillin acylating enzyme biocatalyst can be used to hydrolyze penicillin potassium and manufacture 6-APA.

The invention discloses a wastewater treatment device and method for in-situ electric generation of H2O2 cooperating with O3 oxidation. The device comprises a reaction container, wherein a magnetic stirrer is arranged at the bottom of the reaction container; a stirring magneton is arranged in the reaction container; a stainless steel microporous aeration head, an inert anode and a gas dispersing cathode are arranged in the reaction container; the inert anode and the gas dispersing cathode are vertically opposite to each other; the reaction container is also provided with a pipeline for introducing O3; and the inert anode and the gas dispersing cathode adopt a DC (direct current) power supply. The method comprises the following steps of: firstly inserting the inert anode and the gas dispersing cathode into the treated wastewater solution, and connecting with the DC power supply; then connecting pure oxygen with an ozone generator by a polytetrafluoroethylene tube; connecting the stainless steel microporous aeration head at a gas outlet of the ozone generator, and inserting into the bottom of the wastewater solution; and finally, switching on the DC power supply to treat the wastewater solution. Through the invention, H2O2 is continuously and efficiently generated and can quickly react with O3 to generate.OH so as to efficiently remove persistent organic pollutants in the water body.

A substituted porphyrin-metal coordination compound is prepared by simulating the biologic enzyme catalyst, and can be used as the cathode catalyst of methanol fuel battery.

The invention discloses a preparation method and application of activated carbon for recycling gold and belongs to the field of wet metallurgy and precious-metal recovery. The method disclosed by the invention comprises the following steps: weighing a certain amount of activated carbon, washing to remove ash in the activated carbon by using deionized water, filtering and drying; stirring and dipping the activated carbon at normal temperature by using a transition metal salt solution, washing, filtering and drying; stirring and dipping at normal temperature by using ferrous cyanate ([Fe(CN)6]4-) salt solution in a certain concentration range, generating a Prussian blue analogue compound on the surface of the activated carbon, washing and filtering; and drying the filtered activated carbon for later use. According to the activated carbon prepared by the method, gold ([Au(S2O3)2]3-) in thiosulfate solution can be recycled, the highest recovery rate can be 100 percent, and the maximum capacity of the activated carbon can be 1.27kg/t.

A composite disinfectant for culturing aquatic products contains potassium (or sodium) perferrite, excipient, and/or pH regulator, stabilizer, adhesive, talc powder and magnesium stearate. Its advantages are high effect on disinfecting, enriching oxygen in water, and removing heavy metals, organic substances and harmful suspended substances, and no poison.

The invention relates to an organic metal framework derived cobalt/nitrogen carbon nano material as well as a preparation method and application thereof. The preparation method comprises the followingspecific steps: (1) stirring and dissolving Co(NO3)<2>.6H2O in methanol to prepare a Co(NO3)2 solution; stirring and dissolving 2-methylimidazole in methanol to prepare a 2-methylimidazole solution;pouring the 2-methylimidazole solution into the Co(NO3)2 solution, standing and aging the mixture at room temperature, centrifuging the mixture, and washing and drying a product to obtain ZIF-67; and(2) carrying out annealing treatment on the ZIF-67 obtained in the step (1), and carrying out acid pickling, water washing and drying to obtain the cobalt/nitrogen carbon nano material. Compared withthe prior art, the cobalt/nitrogen carbon material prepared by the method has the advantages of low metal dissolution, good reusability, a simple and convenient operation process, a wide pH application range and the like when being used for activating peroxydisulfate, and has wide application prospects in the field of treatment of degradation-resistant organic matter wastewater.

The invention provides a method for preparing a core-shell ferroferric oxide/graphene oxide composite nano-catalyst. The method comprises the following steps of preparing nanometer ferroferric oxide by utilization of a hydrothermal method, preparing graphene oxide by utilization of a modified Hummers method, preparing the core-shell ferroferric oxide/graphene oxide composite nano-catalyst by utilization of an electrostatic self-assembly method. The catalyst prepared according to the method provided by the invention has the advantages that the adsorptive property is excellent, the stability is good, the catalyst can be cyclically utilized, and an excellent adsorption effect can be achieved during the process of degrading simulated dye rhodamine B.

The invention relates to a pharmaceutical chemical wastewater treatment device and a treatment method thereof. The treatment device comprises a vertical flow type coagulative precipitation tank, a catalysis zero valence bimetallic packing tower, a Fenton-like reactor, an anaerobic MBBR (Moving Bed Biofilm Reactor) pool, an aerobiotic MBBR pool and a solid-liquid seperation system which are sequentially connected. The treatment method is a catalysis zero valence bimetallic- Fenton-like-MBBR coupling treatment method. The treatment device has the advantages of being capable of simultaneously treating multiple organic pollutants, occupying a small area and being simple in structure and easy for finalization and industrialization. The catalysis zero valence bimetallic packing tower enables the performance of reducing and treating degradation-resistant organic matters to be stronger, does not harden after running for long-term and is suitable for a wide pH value range and low in operating cost, and the consumption of metallic iron is little. The Fenton-like reactor is faster in oxidation reaction rate and suitable for the wide pH value range. The pharmaceutical chemical wastewater treated by the wastewater treatment method provided by the invention can reach the new emission standard of wastewater in a pharmaceutical chemical industry.

An application of waste brick in treating sewage is dislcosed, which features that the leftover of brick is mechanically broken to become the granular adsorbent of harmful element (P, etc) in sewage. Its advantages are high adsorptive ability and low cost.

The invention relates to an anion chromatographic column a preparation method thereof, particularly relates to a preparation method of a surface-grafting anion chromatography stationary phase. The method disclosed herein is characterized by: preparing monodispersed linear polystyrene microspheres seeds by dispersion polymerization, activating the seeds, then synthesizing polystyrene-divinyl benzene-glycidyl methacrylate microballoons by one-step seed swelling method, and extracting to remove the pore forming agent; adopting multi-step grafting synthetic method, taking methylamine and 1,4-butanediol diglycidyl ether as raw materials, and introducing a large amount of positively charged quaternary ammonium groups as the anion exchange functional group to the surface of the prepared polystyrene-divinyl benzene-glycidyl methacrylate microballoons; and packing by homogenate method. According to the invention, the method disclosed herein has the advantages of low cost and simple process, the prepared filling material has uniform granularity and has no need to be screened, and the particle size distribution is narrow.

The invention belongs to the field of biological engineering and relates to chitosan modification. The chitosan modification comprises the following steps of: adding protein or polypeptide; adding transglutaminase; adjusting the pH value; removing precipitates after full reaction; and desalting and drying for modification. The modified chitosan produced by the technical scheme disclosed by the invention is good in water solubility, does not generate precipitate at the pH value of 3-10, and is small in viscosity. Moreover, the functions including strong adsorption, antibacterial property and the like of the chitosan are kept, and the application prospect is extensive.

The invention discloses a process using an inorganic polymer flocculating agent polymerizing aluminum chloride and iron chloride, which is characterized in that, add alkaline matter in acidated waste liquor which is produced in the process that concavo-convex rod stone and clay produce floridin, stir the solution, adjust pH of solution, heat and polymerize solution, then fully stir solution to make reaction, thereby generating an inorganic polymer flocculating agent polymerizing aluminum chloride and iron chloride. The applicable pH range is wider, and the treatment effect is better than other flocculating agent in common usage.

A preparation method for a magnetic MOFs solid-phase extractant comprises the following steps: 1, employing a coprecipitation process to prepare a magnetic Fe3O4 nanosphere with the particle size of 10-20 nm; 2, employing Stober silica gel coupling process to prepare Fe3O4@SiO2 with a shell-core structure; 3, employing an in-situ precipitation process to prepare Fe3O4@SiO2@Cu(OH)2; 4, employing an in-situ conversion manner to synthesize Fe3O4@SiO2@HKUST-1; and 5, performing post-functionalization on Fe3O4@SiO2@HKUST-1 synthesized in the step 4 to synthesize the Bi-I modified magnetic MOFs solid-phase extractant. The advantages comprise that the provided method is simple, convenient, low in cost and friendly to environment. The prepared magnetic MOFs solid-phase extractant has the advantages of rapid adsorption speed, large adsorption capacity, high removal efficiency and the like, and efficient removal of low-concentration Hg<2+> can be realized.

The invention discloses a preparation method of a phosphotungstic acid @MIL(Fe) photocatalyst. The method comprises the following steps: firstly, dispersing phosphotungstic acid in a solvent; secondly, preparing MIL(Fe) through a solvothermal method so as to obtain the phosphotungstic acid @MIL(Fe) photocatalyst, wherein the phosphotungstic acid exists in a pore channel of the MIL(Fe) in a molecular state. The photocatalyst is high in catalytic activity, environmentally-friendly, easy to recover and recyclable; moreover, the method is simple in equipment requirement and convenient to operate, and has a great application prospect, and organic pollutants in water can be efficiently decomposed in a wider pH value range.