1049 results about "Phosphorous acid" patented technology

The invention discloses a method for deeply removing readily oxidizable substances in high-purity electronic-grade phosphoric acid, which deeply removes the readily oxidizable substances in the high-purity electronic-grade phosphoric acid in a mode of combining ozone oxidation and resin adsorption to obtain a high-purity electronic-grade phosphoric acid finished product with extremely low readily oxidizable substance concentration. The specific process mainly comprises the following three steps: S1, introducing ozone gas at a certain temperature to oxidize readily oxidizable substances such as phosphorous acid and hypophosphorous acid in phosphoric acid into phosphoric acid so as to reduce the concentration of the readily oxidizable substances; s2, feeding the phosphoric acid subjected to ozone oxidation into an adsorption reactor to be in contact with an adsorbent, and further removing residual readily oxidizable substances in the phosphoric acid; and S3, filtering the phosphoric acid subjected to adsorption treatment through a filter element for separation, and removing residual small particles and impurities to obtain the electronic-grade phosphoric acid with readily oxidizable substances removed. The method is simple in process, controllable in condition, convenient to operate, safe and environment-friendly, does not need to add an additional solvent, avoids introduction of new impurities, reduces secondary pollution, and is suitable for preparing high-purity electronic-grade phosphoric acid.

The invention discloses an anti-scale cross-linked polymer fracturing fluid and a preparation method thereof, and relates to the technical field of petroleum fracturing fluids. When the anti-scale cross-linked polymer fracturing fluid is prepared, allylamine hydrochloride and epoxy chloropropane react to prepare a double-bond chlorinated intermediate; reacting the double-bond chlorinated intermediate with lauramidopropyl dimethylamine to prepare a cationic monomer; copolymerizing a cationic monomer and acrylamide to prepare a cationic polymer; the preparation method comprises the following steps: reacting L-lysine with formaldehyde and phosphorous acid to prepare phosphoric acid modified lysine; reacting the phosphoric acid modified lysine with allyl glycidyl ether to prepare a phosphoric acid modified monomer; acrylamide and an anionic monomer are copolymerized to prepare an anionic polymer; the anionic polymer and the cationic polymer are dissolved in water to prepare the anti-scale cross-linked polymer fracturing fluid. The anti-scale cross-linked polymer fracturing fluid prepared by the invention has the advantages of scale prevention, good temperature resistance, good shear resistance and self-crosslinking.

The invention relates to the field of wear-resistant fabrics, and discloses a high-strength wear-resistant fabric and a preparation method thereof.The high-strength wear-resistant fabric comprises a surface coating and a base cloth layer, the surface coating and the base cloth layer are formed by coating and drying modified waterborne polyurethane emulsion, and the modified waterborne polyurethane emulsion comprises isophorone diisocyanate, ethylene glycol terephthalate, 2, 3, 4-trimethyl-1, 3-pentanediol monoisobutyrate, polyisobutylene glycol monoisobutyrate, according to the present invention, 2, 2-dimethylolpropionic acid, a modified additive, a flame retardant modifier, 1, 4-butanediol, trimethylolpropane and the like are adopted to prepare the modified additive, dopamine is subjected to in-situ auto-polymerization on the surface of a titanium dioxide nanotube, nano-silica is grown on the surface in situ, and modification is performed through a polysiloxane solution to prepare the modified titanium dioxide nanotube flame retardant; the polysiloxane solution is prepared by carrying out a reaction on methyl triethoxysilane and dihydroxyl-terminated polydimethylsiloxane; the flame-retardant modifier is prepared by reacting 2-chloro-4, 6-diamino-1, 3, 5-triazine, 5-hydroxymethylfurfural and phosphorous acid, so that the fabric is endowed with good mechanical properties and wear resistance, and the fabric has a hydrophobic surface and is excellent in flame retardance and durability.

The invention provides a method for detecting the concentration of phosphite ions in a natural water medium, which comprises the following steps: detecting a to-be-detected sample solution containing phosphite ions and impurity ions by using an ion chromatograph to obtain a chromatogram of the to-be-detected sample; determining a peak area value of phosphite ions from the chromatogram of the sample to be detected; obtaining the concentration of the phosphite ions in the sample to be detected according to a linear regression equation of the peak area value of the phosphite ions and the concentration of the phosphite ions; wherein the test conditions of the ion chromatograph are as follows: an anion exchange column is selected as a chromatographic column, and the column temperature is 43-56 DEG C; the leacheate is a potassium hydroxide solution, the flow rate is 1.0-2.0 mL / min, gradient leaching is adopted, and the concentration of the leacheate is 15-18 mM within the time period of 0-14 min; the concentration of the leacheate is 33-36 mM within the time period of 16-30 min; the concentration of the leacheate is 17 to 20 mM within the time period of 32 to 36 minutes.

The invention relates to the field of textile processing, and discloses a production process of an antistatic chinlon fabric, which comprises the following specific steps: performing blade coating on chinlon base cloth by using a modified waterborne polyurethane emulsion, and performing pre-drying and baking to obtain the antistatic chinlon fabric, the modified waterborne polyurethane emulsion comprises a waterborne polyurethane emulsion, a hybrid composite filler, a functional additive and the like; the hybrid composite filler is prepared by using a double-bond silane coupling agent to modify nano titanium dioxide and then reacting with modified graphene, and the modified graphene is prepared by using phenyl tri (dimethyl siloxane) silane, a flame-retardant additive and the double-bond silane coupling agent to react and then modifying hydrazine hydrate to reduce graphene oxide; the flame-retardant additive is prepared from phenylphosphoryl dichloride, eugenol, a flame-retardant primary product and sodium as raw materials, the flame-retardant primary product is prepared by reacting formaldehyde with p-hydroxyphenylethylamine and then further reacting with phosphorous acid, and the chinlon fabric prepared by the method not only has a conductive function, but also keeps the mechanical properties of the fabric and is excellent in flame retardance.

The invention discloses a coating type high-molecular flame-retardant material. The composite material is prepared from the following components: organic silicon modified epoxy resin, a bio-based castor oil derivative, hydroxyapatite, carbon nanofibers, expanded graphite, ammonium polyphosphate, zinc borate, nano silicon dioxide, molybdenum oxide, microencapsulated red phosphorus, magnesium hydroxide, melamine cyanurate, aluminum diethylphosphinate, pentaerythritol, trihydroxymethyl phosphine oxide and a silane coupling agent. The coating is prepared from a titanate coupling agent, stearic acid, polyethylene glycol, 2, 6-butylated hydroxytoluene, triphenyl phosphite, 2, 4-dihydroxybenzophenone, sebacic diester, polytetrafluoroethylene micro powder, a modified polydimethylsiloxane flatting agent, organic montmorillonite, a polyether modified silicon defoaming agent and a solvent. The invention has the beneficial effects of high flame retardant efficiency, environmental friendliness, excellent comprehensive performance and excellent processability.

The invention discloses a wear-resistant vehicle body film and a preparation method thereof, and relates to the technical field of films. The wear-resistant automobile body film prepared by the invention is prepared from polytetrahydrofuran ether glycol, isophorone diisocyanate, a catalyst, dihydric alcohol quaternary ammonium salt, a functional aid, modified silicon dioxide and a chain extender. The dihydric alcohol quaternary ammonium salt is obtained by reacting N, N '-dihexyl-N, N'-dimethyl propane-1, 3-diamine with monochloroacetone and then condensing with glycerol; the functional additive is obtained by reacting 2-boric acid thiophene-4-methyl acetate with 2, 7-dibromofluorene and then carrying out bromination hydrolysis; the modified silicon dioxide is obtained by reacting pretreated silicon dioxide with melamine and then reacting with sodium hypophosphite. The wear-resistant vehicle body film prepared by the invention has good anti-aging, wear-resistant, antibacterial and flame-retardant properties.

The invention discloses an organic wastewater treatment agent and a preparation method thereof, and relates to the field of water treatment materials. When the organic wastewater treatment agent is prepared, nano silicon dioxide sequentially reacts with a silane coupling agent 4140, sodium periodate, p-phenylenediamine and dimethyl phosphite, and modified nano silicon dioxide is prepared; the preparation method comprises the following steps: reacting modified nano silicon dioxide with 2, 4, 6-triformyl phloroglucinol and 2, 4-diamino-6-methoxypyrimidine, so as to prepare functionalized nano silicon dioxide; the preparation method comprises the following steps: reacting microcrystalline cellulose with thionyl chloride, N-(glycidyl)-N-phenyl-ethylene oxide methylamine and thiourea in sequence to prepare modified cellulose; and reacting the modified cellulose with the functionalized nano silicon dioxide to prepare the organic wastewater treatment agent. The organic wastewater treatment agent prepared by the invention has the capabilities of resisting bacteria, adsorbing anionic pollutants, adsorbing cationic pollutants and photocatalytically degrading organic pollutants.

The invention discloses electrolyte for a long-service-life sodium-ion battery as well as a preparation method and application of the electrolyte, and relates to the technical field of sodium-ion battery electrolyte. According to the invention, the piperidinyl and phosphorous acid tetrafluoroborate ionic liquid is added, so that the performance of the sodium ion electrolyte is remarkably improved. Firstly, the additives improve the thermal stability and chemical stability of the electrolyte, which are particularly important in the long-term operation process of the battery, and can effectively prevent the electrolyte from being decomposed under high-temperature or extreme operating conditions. And secondly, because the ionic liquid has excellent electrochemical stability, the electrochemical window of the electrolyte is enhanced due to the existence of the ionic liquid, that is, the electrolyte can bear a wider voltage range without electrochemical reaction. This is very advantageous for improving the energy density and power output of the battery. And finally, the introduction of the ionic liquid can also increase the ionic conductivity of the electrolyte and reduce the internal impedance of the battery, so that the charge-discharge efficiency and the cycle life of the battery are improved.

The present invention provides a polyester heat-shrinkable film containing recycled materials and a preparation method thereof, belonging to the technical field of polymer synthetic films. The raw materials of the polyester heat-shrinkable film include recycled PET polyester particles, PET polyester chips, and a modified masterbatch; the modified masterbatch is prepared from polyethylene terephthalate-1,4-cyclohexanedimethanol ester, triphenyl phosphite, polyethylene glycol block copolymer, nano-silica, and hyperbranched polyester amine; the polyethylene glycol block copolymer is prepared from polyethylene glycol and γ-valerolactone under the action of a catalyst; the hyperbranched polyester amine is prepared from trimethylolpropane, methyl crotonate, and diethylenetriamine. The product of the present invention has excellent properties such as excellent unidirectional anti-shrinkage performance and low haze.

Provided is a lubricating oil composition containing a base oil (A), a phosphorous acid ester (B) having at least one sulfur atom-containing group having 2 to 20 carbon atoms, the sulfur atom-containing group having at least one -(S)x- group (x is an integer of 1 or more) between two adjacent carbon atoms in a structure of an alkyl group, a thiadiazole-based compound (C), and a benzotriazole-based compound (D), wherein a content of the component (C) is 0.01 mass% or more and less than 0.60 mass% based on the total amount of the lubricating oil composition, and a content of the component (D) is 0.02 mass% or more and less than 0.20 mass% based on the total amount of the lubricating oil composition.

The present invention relates to the technical field of preparation of adsorbent materials for removing heavy metals from acidic wastewater, specifically a method for preparing a resin-based magnetic composite adsorbent material, comprising the following steps: using waste expanded resin as a base carrier, ferric chloride as an added magnetic auxiliary substance, mixing magnesium sulfate and aluminum sulfate evenly, stirring at high speed and ultrasonic dispersion, then adding sodium phosphite and sodium hypophosphite and placing them in a microwave reactor, adjusting the pH of the sodium phosphite and sodium hypophosphite in the reactor to precipitate, while the phosphite intercalates into the precipitate, finally filtering the precipitate and washing and drying to obtain a novel adsorbent material for excellent adsorption of heavy metals in acidic mine wastewater. The material prepared by the present invention can effectively adsorb various heavy metal ions such as cadmium, chromium, zinc, lead, manganese, copper, etc. in acidic mine wastewater, has a large adsorption capacity, and the adsorbent material has magnetism and can be regenerated by solid-liquid separation through magnetism.

The invention relates to the technical field of chemical synthesis, and particularly discloses an alpha methyl beta phosphonate compound and a synthesis method thereof.The alpha methyl beta phosphonate compound is obtained by directly oxidizing the alpha position of aryl ketone into carbon positive and combining the carbon positive with diethyl phosphite anions under the alkaline condition by using hydrogen peroxide and iodine as oxidizing agents. The alpha methyl substituted beta phosphate ester compound can be generated by a one-step method. The method is suitable for synthesizing compounds of phosphoric acid (methyl, ethyl, propyl and the like) with different alkyl substitutes (methyl, ethyl, propyl and the like) at carbonyl alpha positions. According to the method, the alpha-methyl substituted beta phosphate compound can be synthesized only by using commercial cheap and easily available aryl ketone as a raw material, using hydrogen peroxide and iodine as oxidants and using diethyl hypophosphite as a phosphine source, and reacting in the DMSO solvent at 100 DEG C for 12 hours, so that the target product can be obtained, and the yield is excellent. Compared with previously reported methods, the method does not need low-temperature operation, is simple to operate, adopts a one-pot method, does not need a metal catalyst, and all raw materials are common bulk chemicals.

The invention discloses a preparation method and application of a powder coating for a super-weather-resistant high-flexibility coiled material, and relates to the technical field of powder coatings. The invention discloses a preparation method of a powder coating for a super-weather-resistant high-flexibility coiled material, which comprises the following steps: mixing filler modified polyester resin, a curing agent, a defoaming agent, a flatting agent, an adhesion promoter and polytetrafluoroethylene wax according to the weight percentage of the raw materials to obtain the powder coating; the filler modified polyester resin disclosed by the invention is obtained by reacting aminated hydroxyl-terminated polyester, phosphorous acid and epoxy modified graphene oxide and then carboxylating by butanedioic anhydride; the filler modified polyester resin prepared by the invention is added into a coating as a base material of a powder coating, so that the coating is endowed with the characteristics of high weather resistance and high flexibility.

The invention relates to the technical field of polymerization inhibitors, and particularly discloses a polymerization inhibitor ZJ5575 and a preparation method thereof. A preparation method of a polymerization inhibitor ZJ5575 comprises the following steps: mixing phosphite ester, a polymerization inhibitor 701 and a catalyst, carrying out a reaction at 115-125 DEG C for 10-12 h, then adding toluene and water, carrying out stirring at 35-45 DEG C for 2-2.5 h, carrying out standing layering to obtain an upper organic phase, then adding water into the organic phase again, carrying out negative pressure distillation at 55-65 DEG C, and carrying out filtration, washing and drying to obtain the polymerization inhibitor ZJ5575. And cooling to 22-28 DEG C after the toluene is completely removed, centrifuging to obtain a solid, and drying to obtain the polymerization inhibitor ZJ5575, the phosphite being one of triethyl phosphite or trimethyl phosphite. According to the preparation method disclosed by the invention, the yield of the product polymerization inhibitor ZJ5575 can be increased to 98.58%, and meanwhile, the discharge amount of wastewater is remarkably reduced.

The invention relates to the technical field of water treatment, and discloses a water treatment agent for oilfield reinjection water and a preparation method thereof. The water treatment agent for oilfield reinjection water is obtained by copolymerization of sulfonic imidazoline quaternary ammonium salt modified quinoline, Mannich base modified chitosan, acrylic acid and sodium hypophosphite. The water solubility and corrosion inhibition of imidazoline are improved through quaternization modification of imidazoline, quaternary ammonium salt imidazoline can be adsorbed on the metal surface, the corrosion rate is reduced, the quaternary ammonium salt imidazoline serves as a surface active agent, the infiltration and dispersion effects are achieved, and the descaling rate is increased; the sulfonic acid group improves the temperature resistance and prevents the generation of gel, and the strong hydrophilicity of the sulfonic acid group enables a molecular chain to fully stretch in water, so that the scale inhibition performance is improved; mannich base is introduced into chitosan, the acid solubility and temperature resistance of chitosan are improved, the coordination chelation effect of chitosan is enhanced through the conjugation effect of aromatic rings, and the corrosion inhibition effect is improved; various functional groups play a synergistic effect, so that the corrosion and scale inhibition effect is further enhanced.

The invention discloses a manufacturing method of a new energy power battery cooling liquid capable of improving storage stability, and belongs to the technical field of battery anti-freezing solutions, and the new energy power battery cooling liquid comprises the following auxiliary agent components and components: a) ethylene glycol which is used as a basic solvent and accounts for 40-50% of the total mass; b) deionized water accounting for 50%-60% of the total mass; c) an organic corrosion inhibitor which is selected from benzotriazole, mercaptobenzothiazole or a mixture of benzotriazole and mercaptobenzothiazole and accounts for 0.3-0.5% of the total mass; d) an antioxidant which is selected from di-tert-butyl-p-cresol, triphenyl phosphite or a mixture thereof and accounts for 0.1-0.2% of the total mass; the anti-foaming agent is selected from polydimethylsiloxane, silicone oil or a mixture of the polydimethylsiloxane and the silicone oil and accounts for 0.01%-0.05% of the total mass; and f) a pH regulator which is selected from sodium hydroxide, potassium hydroxide or a mixture thereof, is used for regulating the pH value of the cooling liquid to a suitable range of 7-9, and accounts for 0.05-0.15% of the total mass. The cooling liquid disclosed by the invention can keep the stability of key indexes such as conductivity, pH value, corrosion inhibition performance and oxidation resistance in a long-term storage process, so that the storage stability of the cooling liquid is remarkably improved.

The invention relates to the technical field of catalysts, and particularly discloses a phosphorus-containing porous organic polymer supported nickel catalyst which is prepared from a Ni precursor and a phosphorus-containing porous organic polymer, the loading amount mass fraction of Ni in the catalyst is 0.1-10%, and the phosphorus-containing porous organic polymer is a random copolymer and has a structural general formula I; the invention also provides a preparation method and application thereof. After the porous organic polymer containing the phosphorus ligand provided by the invention and transition metal salt form a catalyst, the phosphorous acid diester compound can be efficiently catalyzed and synthesized, the phosphorous acid diester compound can be recycled after the reaction, and the performance cannot be obviously reduced in the cyclic catalysis process.

The invention relates to a surface treatment method of anti-aging nano calcium carbonate for a photovoltaic sealant. Surface treatment is carried out on nano calcium carbonate by using glyceryl monostearate, 2, 4, 6-tri (4-carboxyphenyl)-1, 3, 5-triazine and sodium phosphite, and the nano carbonate treated by the method has relatively high activity and good dispersity, has good resistance to damp-heat aging and ultraviolet aging when being applied to photovoltaic glue, and has good application prospects. Therefore, the problems of aging and yellowing of the existing photovoltaic adhesive are solved.

The invention discloses a washable anti-wrinkle fabric and a preparation method thereof, and relates to the technical field of fabrics. When the washable anti-wrinkle fabric is prepared, a pretreated cotton fabric, triethyl phosphite and 4-amino-3-nitrobenzyl alcohol react to prepare a modified cotton fabric; enabling the nano titanium dioxide wrapped by the chitosan to react with p-hydroxybenzaldehyde to prepare modified nano titanium dioxide; reacting the modified cotton fabric with the modified nano titanium dioxide to obtain a modified cotton gray fabric; and finally, carrying out after-finishing by using 1-chloromethyl-3-trifluoromethyl benzene to obtain the washable anti-wrinkle fabric. The washing-resistant and crease-resistant fabric prepared by the invention has excellent washing resistance, crease resistance, flame retardance and ultraviolet resistance.

The invention relates to the technical field of lithium ion batteries, in particular to an electrolyte, a preparation method thereof, an injection method and a lithium ion battery, the electrolyte comprises a first electrolyte for first injection and a second electrolyte for second injection, the first electrolyte comprises a first solvent, a first lithium salt and a first additive, the second electrolyte comprises a second solvent, a second lithium salt and a second additive, the first electrolyte comprises a first solvent, a first lithium salt and a first additive, the second electrolyte comprises a second solvent, a second lithium salt and a second additive, the mass percentage of the second electrolyte in the electrolyte is 5-20%, the first additive comprises dimethyl sulfide and vinylene carbonate, and the second additive comprises triphenyl phosphate and vinylene carbonate. According to the electrolyte, the first additive comprises dimethyl sulfide, and the second additive comprises triphenyl phosphite, so that the bad problems of high-temperature gas production and negative electrode interface black spots in the use process of a lithium-rich material lithium supplementing agent are solved.

The invention relates to the technical field of pesticides and herbicides, in particular to a preparation method of L-refined glufosinate ammonium, which comprises the following steps: firstly, preparing an intermediate from diethylamine, diethyl methylphosphite, a compound # imgabs0 # as shown in a formula III and a second solvent in the presence of an iridium-containing Lewis base catalyst by adopting a one-pot method; and carrying out rearrangement and hydrolysis reaction to obtain the L-refined glufosinate-ammonium. The preparation method of the L-refined glufosinate-ammonium has the advantages of simple process steps, mild reaction conditions, high yield and high ee value.

The invention discloses a preparation method of a lignite resin drilling fluid filtrate reducer, and relates to the technical field of petroleum and natural gas drilling engineering. The method comprises the following steps: carrying out superfine grinding on lignite, carrying out alkaline hydrolysis pretreatment on waste nylon PA66, alkalizing lignite powder, carrying out sulfonation reaction on the alkalized lignite powder and phosphorous acid to introduce phosphonic acid groups, carrying out cross-linking with tetrabutyl titanate to form a three-dimensional network structure, and adding a nano-montmorillonite suspension to realize physical enhancement. A reaction product is subjected to freeze-drying, a porous structure is reserved, and then the product and polyethylene glycol 400 are mixed and granulated. By utilizing humic acid functional group grafting, inorganic-organic composite cross-linking and waste raw material recycling technologies, the product still keeps excellent filtration loss control capability at the high temperature of 200 DEG C and in a saturated salt solution, the high-temperature and high-pressure filtration loss is less than or equal to 6.50 mL, the viscosity retention rate is greater than or equal to 92.8%, the lubricating coefficient reduction rate is greater than or equal to 48.5%, and the product has the advantages of temperature resistance, salt resistance, environmental protection and low cost, and is suitable for industrial production. And the method is suitable for deep oil-gas drilling engineering.

The invention provides a chemical plating solution, a preparation method of the chemical plating solution, a Ni-P-Gr chemical plating layer and a preparation method and application of the Ni-P-Gr chemical plating layer, and relates to the technical field of chemical plating. The preparation method comprises the following steps: adjusting the pH value of nickel sulfate, sodium citrate, sodium acetate, sodium hypophosphite and graphene oxide to 4-4.5, mixing with sodium dodecyl benzene sulfonate, homogenizing, and ultrasonically dispersing to obtain the chemical plating solution. Homogenization treatment and ultrasonic dispersion are used in the process of preparing the chemical plating solution, the addition amount of the graphene oxide is controlled to be 0.1-0.4 g / L, and the ultrasonic dispersion conditions are 100-180 W and 35-55 min, so that the graphene oxide in the prepared chemical plating solution is good in dispersion uniformity, and the chemical plating solution is uniform in dispersion. The graphene oxide in a Ni-P-Gr chemical plating layer formed by adopting the chemical plating solution prepared by the invention is good in dispersity, and the Ni-P-Gr chemical plating layer is high in hardness, good in wear resistance and strong in binding force with a matrix.

The invention discloses hydrolysis-resistant liquid phosphite ester and a preparation method and application thereof.The hydrolysis-resistant liquid phosphite ester is prepared by the steps that 2, 2, 4-trimethyl-1, 3-pentanediol and phosphorus trichloride or phosphite triester serve as raw materials, a cyclization reaction is conducted firstly, and then the hydrolysis-resistant liquid phosphite ester is obtained; and then carrying out nucleophilic substitution on Cl or aryl and alkyl on the cyclized intermediate by using higher saturated monohydric alcohol with more than C8, wherein the molecular structure is as shown in formula I in the specification. The liquid phosphite ester is novel liquid phosphite ester, the main body of the liquid phosphite ester is of a six-membered ring structure, the basic structure of the phosphite ester is reserved to the maximum extent, and the anti-oxidation effect of the phosphite ester is guaranteed; hydrophobic aliphatic chain structures on phosphorus atoms and branched chains of the phosphorus atoms prevent water molecules from approaching P-O bonds, so that the phosphorus atoms and the branched chains are prevented from being attacked by the water molecules, and the hydrolysis resistance is improved under the conditions that any additional amine hydrolysis-resistant agent is not used and any steric hindrance group is not introduced; good practical value, economic value and market prospect are realized.

The invention discloses a salt-spray-corrosion-resistant stainless steel rod and a preparation method thereof, and belongs to the technical field of salt-spray-corrosion-resistant stainless steel. The salt-spray-corrosion-resistant stainless steel rod comprises a stainless steel rod body and a corrosion-resistant layer attached to the outer surface of the stainless steel rod body. The method comprises the following steps: sequentially polishing, deoiling, activating and cleaning a stainless steel rod, then putting the stainless steel rod into a chemical composite plating solution for chemical composite plating, then putting the stainless steel rod into a nitric acid solution for chemical etching, introducing hydrogen and hydrocarbon gas in a high-temperature atmosphere, and then continuously heating and introducing composite hydrogen to obtain the salt-spray-corrosion-resistant stainless steel rod, wherein the chemical composite plating solution comprises the following components: 30-40 g / L of nickel sulfate, 15-35 g / L of sodium hypophosphite, 4-6 g / L of citric acid, 32-36 g / L of boric acid, 16-20 g / L of sodium acetate, 0.03-0.05 g / L of carbon black and 20-35 g / L of tungsten carbide particles; the salt-spray-corrosion-resistant stainless steel rod prepared by the invention is relatively good in corrosion resistance, wear resistance and toughness.

The invention discloses a synthesis method of allyl phosphonic acid diester. According to the method, phosphorous acid diester and an allyl chloride compound are used as raw materials and react in the presence of a specific transition metal catalyst and alkali under the conditions of normal pressure and 45-60 DEG C to obtain the allyl phosphonic acid diester. The method has the advantages of mild reaction conditions, simple operation, high product yield (90-99%), no by-product, no generation of halogenated alkane gas and easy industrial production, and is suitable for the fields of polymer flame retardants, electronic materials, pesticide and medicine intermediates and the like.

The invention discloses a CAD detection method for phosphoric acid and phosphorous acid in an alendronate sodium oral solution, and belongs to the technical field of pharmaceutical analysis. The method comprises the following steps: preparing a reference stock solution and a test solution; then setting high performance liquid chromatography detection conditions; a Shodex VN-504D chromatographic column is adopted, a CAD detector is adopted as a detector, a mixed solution of a mobile phase A and a mobile phase B is adopted as a mobile phase, the mobile phase A is ammonium formate, the mobile phase B is an acetonitrile solution, and gradient elution is performed by adopting the mobile phase; and respectively measuring the reference stock solution and the test solution, injecting into a liquid chromatograph, and recording a chromatogram. A CAD detector is adopted, the detection sensitivity is obviously improved, the quantitative concentration can reach 0.24 mu g / mL, and the detection concentration can reach 0.10 mu g / mL. The method is high in specificity, high in sensitivity, good in durability, rapid, simple, effective and reliable.

The present invention provides a flame retardant mixture, aluminum diethylphosphinate and a preparation method therefor. The preparation method includes: heating a sodium hypophosphite solution to a first temperature, dropwise adding an initiator, introducing ethylene, maintaining a pressure at 0.30-0.75 MPa, and carrying out an initiation reaction until the reaction is completed; and adjusting the solution to a second temperature, dropwise adding an aluminum sulfate solution for a reaction under heat preservation at normal pressure, performing filtration, and collecting a precipitate to obtain aluminum diethylphosphinate containing a telomer. According to the present invention, an initiator with strong oxidability is not used, such that oxidation of a hypophosphite in a reaction system and subsequent products brought thereby are reduced, for example, aluminum phosphate, aluminum phosphite, aluminum ethylphosphonate and the like are not generated as a result of the reaction. The present invention can be implemented at a relatively low temperature and a relatively low pressure, realizing high-efficiency conversion. The present invention is easy to operate and uses water as a solvent, hazardous materials requiring disposal are not generated or contained after completion of a chemical reaction, raw materials are readily available, and industrial production can be achieved without the need for special devices.

The invention discloses a flame-retardant composite wood board and a preparation method thereof.The preparation method of the composite wood board comprises the following steps that single-layer wood boards are soaked in an aqueous solution containing a first flame retardant and dicyandiamide, after drying, the multiple single-layer wood boards are bonded and pressed through an adhesive, and the flame-retardant composite wood board is prepared; the preparation method of the first flame retardant comprises the following steps: S1: 1, reacting 2-bis (chlorodimethylsilyl) ethane with syringaldehyde in a first organic solvent to prepare an intermediate A; s2, reacting the intermediate A with tyrosine in a second organic solvent to prepare an intermediate B; s3, the intermediate B and phosphorous acid are mixed for a reaction, and the first flame retardant is prepared. The first flame retardant can form covalent bond combination with the wood board, so that the flame retardant property of the treated wood is remarkably improved; and meanwhile, the second flame retardant in the adhesive and the first flame retardant impregnated on the wood board can achieve a synergistic promotion effect, so that the limit oxygen index of the prepared composite wood board is up to 60% or above.