336results about "Halogenated hydrocarbon separation/purification" patented technology

A process for producing propylene and hydrogen from propane, the process comprising the steps of: a) reacting a mixture comprising propane and bromine to produce a first reaction mixture comprising bromopropane and hydrogen bromide, b) subjecting the first reaction mixture obtained in step a) to at least one separation step to obtain a bromopropane-rich composition and to obtain a hydrogen bromide-rich composition, c) subjecting the bromopropane-rich composition obtained in step b) to a catalytic reaction to produce a second reaction mixture containing propylene and hydrogen bromide, d) subjecting the second reaction mixture obtained in step c) to at least one separation step to obtain a hydrogen bromide-rich composition and to obtain propylene, and e) subjecting the hydrogen bromide-rich composition obtained in step b) and / or the hydrogen bromide-rich composition obtained in step d) to electrolysis to obtain hydrogen and a bromine-containing composition, wherein preferably at least a portion of the bromine-containing composition is recycled back to step a).

The invention discloses a high-purity fluorobenzene recovery process in 1, 4-bis (4-fluorobenzoyl) benzene production, and belongs to the technical field of organic waste liquid recovery, the process comprises the following steps: 1, enabling fluorobenzene waste liquid to pass through a tubular reactor filled with anhydrous aluminum chloride particles to react to obtain dewatered fluorobenzene waste liquid, the reaction temperature is 5-40 DEG C, the retention time is 60-200min, and the flow velocity of the fluorobenzene waste liquid is 0.1-0.4 m / min; 2, the water-removed fluorobenzene waste liquid is filtered through a micron filter and then enters a fluorobenzene rectifying tower to be rectified, organic steam on the tower top is compressed through a compressor, subjected to heat exchange through an MVR heat exchanger and condensed and then enters a reflux tank to be refluxed, high-purity fluorobenzene is extracted from the fluorobenzene rectifying tower, the purity of the fluorobenzene is larger than 99.99 wt%, and the mass content of water is smaller than 10 ppm. The fluorobenzene waste liquid in the production process of 1, 4-bis (4-fluorobenzoyl) benzene is used as a raw material, continuous batch production of high-purity fluorobenzene is achieved through reaction dehydration, crystalline aluminum chloride filtration and rectification, the process is simple, and energy consumption is low.

The invention provides a method for preparing p-chloromethyl styrene, which comprises the following steps: (1) in the presence of a catalyst and an assistant, carrying out reaction on paraformaldehyde and hydrogen chloride to obtain a chloromethylation reagent; (2) reacting beta-halogenated ethyl benzene with the chloromethylation reagent obtained in the step (1) to obtain chloromethyl halogenated ethyl benzene; (3) adding an extracting agent into the chloromethyl halogenated ethylbenzene reaction liquid obtained in the step (2) for extraction to obtain an oil layer containing chloromethyl halogenated ethylbenzene and a water-containing acid layer, and crystallizing the oil layer to obtain purified p-chloromethyl halogenated ethylbenzene; and (4) in the presence of a solvent, carrying out elimination reaction on the purified p-chloromethyl halogenated ethyl benzene and alkali to obtain p-chloromethyl styrene.

Disclosed in the present invention is a method for producing 2,3,3,3-tetrafluoropropene from 1,1,2,3,3,3-hexafluoropropene, comprising: (a) introducing 1,1,2,3,3,3-hexafluoropropene and hydrogen into a first reactor for a catalytic reaction to obtain a first reaction product; (b) separating the first reaction product to obtain 1,1,1,2,3,3-hexafluoropropane; (c) introducing 1,1,1,2,3,3-hexafluoropropane into a second reactor for a catalytic reaction to obtain a second reaction product; (d) separating the second reaction product to obtain 1,2,3,3,3-pentafluoropropene; (e) introducing 1,2,3,3,3-pentafluoropropene and hydrogen into a third reactor for a catalytic reaction to obtain a third reaction product; (f) separating the third reaction product to obtain 1,1,1,2,3-pentafluoropropane; (g) introducing 1,1,1,2,3-pentafluoropropane into a fourth reactor for a catalytic reaction to obtain a fourth reaction product; and (h) separating the fourth reaction product to obtain a final product of 2,3,3,3-tetrafluoropropene. The present invention has the advantages of being simple in process, low in cost, high in efficiency, green, and environmentally friendly.

The invention belongs to the technical field of brominated flame retardant synthesis, and particularly provides a decabromodiphenyl ethane bromine distillation process chlorination bromine removal process, which comprises the following steps: S1, adding bromine into a reaction kettle, adding a catalyst, and mixing; cooling and dropwise adding molten diphenylethane; then heating, carrying out a heat preservation reaction, and cooling to obtain a brominated crude product; s2, S201, adding the brominated crude product obtained in S1 into a bromine steaming kettle, and heating; s202, chlorine is introduced, and the total amount of bromine and chlorine is detected; carrying out segmented control on the introduced chlorine according to the total amount of bromine and chlorine; s203, when the total amount of bromine and chlorine is reduced to a threshold value, stopping introducing chlorine, standing, cooling, and introducing nitrogen; s3, filtering the feed liquid in the bromine steaming kettle, washing and purifying for three times, and finally, centrifugally dewatering to obtain a faint yellow solid; and S4, adding the faint yellow solid into a high-temperature jet mill, performing high-temperature aging to obtain white powder, and then performing jet milling on the white powder to obtain a finished product. Physical distillation is replaced by chemical replacement, so that bromine is highly separated.

The invention belongs to the field of chemical production, and particularly relates to a chloromethane cooling recovery system and a chloromethane cooling recovery method. The chloromethane cooling recovery system provided by the invention comprises a first condenser, a second condenser, a third condenser and a recovered chloromethane storage tank, a shell pass inlet of the second condenser is connected with a tube pass outlet of the third condenser, and a tube pass inlet of the third condenser is used for introducing liquid chloromethane. Chloromethane is cooled and recovered by using a liquid chloromethane vaporization heat absorption principle, so that the economical efficiency is good; in addition, due to the fact that the to-be-cooled object and the refrigerant are both methyl chloride, even if mutual leakage occurs in the heat exchange process, the quality of recycled methyl chloride cannot be affected, and raw material losses cannot be caused.

Belonging to the technical field of fine chemical product separation and purification, the invention discloses a beta-bromophenylethane rectification purification process, which comprises the steps of system negative pressure pretreatment, falling film evaporation directional separation, structured packing layer gas-liquid mass transfer, precise reflux ratio regulation and control, segmented collection (front fraction-qualified product), and residual liquid treatment and system circulation. According to the process, the negative pressure of a system is stabilized at 800-1200 Pa, the material temperature of a falling film evaporation discharging end is controlled at 125-135 DEG C, the feeding flow is stabilized at 1.8-2.2 m / h, the reflux ratio is regulated and controlled at 0.8: 1-1.2: 1, and the process realizes efficient purification of beta-bromopheny ethane through precise negative pressure control, synergistic linkage of falling film evaporation and a rectifying tower, segmented material collection and a circular treatment mechanism, so that the process is suitable for industrial production of beta-bromopheny ethane. According to the method, the purity of beta-bromopheny ethane can stably reach 99.5% or above, the material recovery rate is increased to 92% or above, energy consumption is reduced by 15-20% compared with that of a traditional process, material thermal decomposition loss is avoided, and the method is suitable for industrial large-scale production.

The invention provides a process for co-production of HFC-236ea, Z-HFO-1225ye, E-HFO-1225ye and HFO-1234yf, and the process comprises the following steps: reacting hydrogen with HFO-1225ye in the presence of a first catalyst to obtain a first reaction product flow; mixing the first reaction product flow with HFP, and reacting in the presence of a second catalyst to obtain a flow containing HFC-245eb and HFC-236ea; then, a material flow containing HFC-245eb and a material flow containing HFC-236ea are obtained through separation; carrying out a reaction on the material flow containing HFC-236ea in the presence of a third catalyst, washing with water, and extracting to obtain a Z-HFO-1225ye material flow and an E-HFO-1225ye material flow; and reacting the material flow containing HFC-245eb in the presence of a fourth catalyst, and washing and separating to obtain the material flow of HFO-1234yf.

The invention relates to the technical field of refrigerant raw material preparation, and discloses a novel energy-saving environment-friendly refrigerant raw material preparation system which comprises a raw material preparation and supply unit, a reaction and separation unit and a refining unit which are connected in sequence, the reaction and separation unit comprises a mixer, a reflux device, a reactor, a cooling separation device, a membrane type absorption device and a tail gas tower which are connected in sequence; the refining unit comprises an azeotropic tower, a rectifying tower I and a rectifying tower II which are connected in sequence, and is used for performing dehydration, deacidification and rectifying purification on the separated crude chlorinated liquid to obtain a high-purity carbon tetrachloride product; by optimizing the technological process of the raw material preparation and supply unit, the reaction and separation unit and the refining unit, efficient, environment-friendly and energy-saving production of carbon tetrachloride is realized; the problem that the production raw material carbon tetrachloride of the fourth-generation refrigerant is insufficient is solved, the production cost is reduced, and the production efficiency is improved.

The invention provides a reactor comprising a reaction chamber having a catalytic surface in contact with reactants in said chamber; and a source for passing electrical current through said catalytic surface. The reactor can be used for dehydrohalogentation reactions, such as dehydrochlorination of HCFC-244bb to HFO-1234yf, and for reactions where zero valent metals are employed for catalysis. The invention further provides a process to prepare HFO-1234yf from HCFC-244bb using an electrically heated reaction chamber.

This invention provides a method for storing fluoro-2-butene that minimizes the progression of isomerization reactions during storage. [Solution] General formula C4H x F y Fluoro-2-butene, represented by the general formula where x is between 0 and 7, y is between 1 and 8, and x+y is 8, may or may not contain at least one of chromium, molybdenum, iron, zinc, and aluminum as a metal impurity. This fluoro-2-butene is stored in a container with the sum of the concentrations of chromium, molybdenum, iron, zinc, and aluminum (in the case where it contains these impurities) being 1000 ppb by mass or less.

The utility model discloses green low-carbon water alkaline washing equipment for preparing monochlorodifluoromethane. The green low-carbon water alkaline washing equipment comprises a water washing tower and an alkaline washing tower, the upper end of the water washing tower is communicated with a series pipe, and the other end of the series pipe is communicated with the lower end of the alkaline washing tower; a plurality of grating plates are arranged in the water washing tower and the alkaline washing tower; fillers are arranged on the grating plates; observation windows are arranged on the water washing tower and the alkaline washing tower and are higher than the filler; a heat utilization structure is arranged between the water washing tower and the alkaline washing tower; a waste liquid utilization structure is arranged. According to the utility model, gas led out from the alkaline washing tower enters the heat exchanger to be condensed into liquid, heat release occurs in the process, water in the water storage tank circulates in the heat exchanger, the heat can be utilized and absorbed, the temperature of the water is changed, and the washing effect can be improved when the water enters the water washing and alkaline washing procedure subsequently; and waste liquid flowing out of the water washing tower can be recycled.

The invention relates to a post-treatment method and system for chloromethane synthesis, and the post-treatment method comprises the following steps: cooling a chloromethane crude product prepared in a reaction stage through an economizer, and then carrying out gas-liquid separation in a gas-liquid separator, a connecting pipeline between the economizer and the gas-liquid separator is filled with a water flow which flows in a direction opposite to that of the material, so that the temperature of a gas-phase discharge hole in the top of the gas-liquid separator is controlled to be 90-120 DEG C; the separated liquid phase enters a hydrochloric acid buffer tank with a partition plate, and an oil phase and a water phase are separated out; and washing the separated gas phase with water by a water washing tower, and then drying to obtain a chloromethane product. The economizer, the gas-liquid separator with specific temperature control and the hydrochloric acid buffer tank with the partition plate are arranged between the reaction system and the water scrubber, so that three-phase separation of'oil phase silicide-water phase-gas phase 'is efficiently realized, and the oil phase silicide is separated from the chloromethane crude product and does not enter the water scrubber and other subsequent systems; therefore, the problem of pipeline blockage in a post-treatment system is solved.

The invention discloses a device and a method for treating hexafluoropropylene coarse pyrolysis gas in a hexafluoropropylene preparation process, a quench cooler (1) is sequentially communicated with a carbon powder filter (2) and an external shell I (6), a spiral guide plate I (7) in the external shell I (6) is communicated with the external shell I (6), the spiral guide plate I (7) is communicated with a deacidification treatment unit (28), and the deacidification treatment unit (28) is communicated with a deacidification treatment unit (28). The deacidification treatment unit (28) is communicated with the gas outlet I (9) through a drainage pipe I (10), the dry-type deacidification device (3) is communicated with the external shell II (11), the spiral guide plate II (13) is communicated with the external shell II (11), the spiral guide plate II (13) is communicated with the dehydration treatment unit (29), the dehydration treatment unit (29) is communicated with the gas outlet II (24) through a drainage pipe II (14), and the dry-type deacidification device (3) is communicated with the gas outlet II (24) through a drainage pipe II (14). And the outer shell II (11) is communicated with the film coating powder remover (5). According to the invention, the hexafluoropropylene crude pyrolysis gas is effectively treated and collected.

The invention relates to a method for removing cyclohexane in a low-molecular brominated polystyrene recovery solvent, which comprises the following steps: adding the recovery solvent containing cyclohexane and dichloromethane into a reaction bottle, and then adding a certain amount of fuming sulfuric acid; stirring and reacting for a period of time at a certain reaction temperature; adding water for quenching, standing for layering, washing an organic layer to be neutral, and standing for layering; and rectifying the organic layer, and collecting corresponding fractions. The used fuming sulfuric acid contains excessive sulfur trioxide, the sulfonation capacity is higher, cyclohexane is sulfonated to generate sulfonic acid group cyclohexane, then the sulfonic acid group cyclohexane is removed through water washing, the removal rate is high, the operation is convenient and fast, the cost is low, and the method is suitable for industrial production.

The invention discloses a method for preparing a fluorine-containing compound and its application, and relates to the technical field of perovskite material additives. The preparation method is as follows: naphthaleneboric acid, potassium carbonate and bis(triphenylphosphine)palladium chloride are added to a drying container, the container is evacuated to a vacuum state and then filled with nitrogen, phenylacetylene and nine fluoro-4-iodobutane are added to the container, dichloromethane and distilled water are then added to the container, and heated for reaction; the obtained reaction mixture is subjected to extraction and drying, separation and purification, and a fluorine-containing compound is obtained. The fluorine-containing compound prepared by the present invention has good compatibility with the perovskite material, and there will be no heterogeneous phase generation; it is applied as an additive in the perovskite material to suppress the migration and loss of ions, reduce the defect state density at the perovskite grain boundary, extend the carrier lifetime, and improve the charge transfer efficiency; it can also promote the nucleation and growth of perovskite, and improve the quality and morphology of the perovskite film.

The present application belongs to the field of chemical production, and particularly relates to a chloromethane cooling and recycling system and a chloromethane cooling and recycling method. The chloromethane cooling and recycling system comprises a first condenser, a second condenser, a third condenser and a chloromethane recycling tank. The shell side inlet of the second condenser is connected with the tube side outlet of the third condenser, and the tube side inlet of the third condenser is used for passing in liquid chloromethane. The present application uses the vaporization endothermic principle of liquid chloromethane to cool and recycle chloromethane, and is good in economy. Moreover, since the to-be-cooled substance and the refrigerant are both chloromethane, even if mutual leakage occurs in the heat exchange process, the quality of the recycled chloromethane will not be affected and the loss of raw materials will not be caused.

A method for reducing 1,1,1,2,2-pentafiuoropropane (HFC-245cb) in a trans-1,3,3,3-tetrafluoropropene (HFO-1234ze(E)) manufacturing process including catalyst conditioning, temperature reduction, and contact time reduction. The method includes dehydrofluorinating 1,1,1,3,3-pentafluoropropane (HFC-245fa) with a catalyst mixture to produce a product mixture with HFO-1234ze(E) and HFC-245cb, and either incorporating a conditioned catalyst, using a lower temperature for the dehydrofluorination, or reducing the contact time for the dehydrofluorination to reduce the formation of HFC-245cb.

The present application relates to the technical field of fine chemical product synthesis, and in particular to a synthesis method of 3-chloropropynyl co-production of p-chlorobenzaldehyde, which comprises the following steps: mixing propargyl alcohol, a solvent, an ionic liquid catalyst, a cocatalyst DMF and a polymerization inhibitor p-tert-butyl catechol, heating and slowly adding p-chlorobenzylidene dichloride dropwise into the mixture, collecting the generated 3-chloropropynyl crude product at the tail gas outlet, cooling after the reaction is completed, and sequentially reducing pressure rectification of 3-chloropropynyl, the remaining propargyl alcohol and the solvent, and p-chlorobenzaldehyde product through a rectification tower. The present application solves the problems of using toxic and hazardous chemicals chlorinating agent in the production of existing 3-chloropropynyl, and generating a large amount of toxic waste acid gas or low-value byproducts, and the problem of low utilization rate of chlorine atom in the existing direct hydrolysis method of p-chlorobenzaldehyde, and reduces environmental pollution.

There is provided a halon purification method capable of simply, safely, and efficiently removing mixed bromine molecules to obtain high purity halon. The halon purification method is a method for removing bromine molecules from crude halon containing halon and the bromine molecules, and the method includes: a contact step of bringing the crude halon into contact with an absorbing liquid containing an aqueous solution containing metal iodide to obtain a mixed liquid containing the crude halon and the absorbing liquid; and a separation step of separating the halon from the mixed liquid to obtain the halon and the absorbing liquid having absorbed the bromine molecules.

The invention provides a system and method for recycling methane chloride from methyl chlorosilane synthesis tail gas. According to the method, 85%-90% of methane chloride in the methyl chlorosilane synthesis tail gas is recycled in a three-stage sectional type condensation mode. 90-95% of residual methane chloride is recovered through directional absorption of dichloromethane; and finally, residual methane chloride is recovered in a decompression analysis and reflux impurity removal mode, the total recovery rate of methane chloride is larger than or equal to 99%, the purity of methane chloride is larger than or equal to 99.5%, waste of methane chloride is greatly reduced, high recovery of methane chloride is achieved, and methane chloride can be directly reused in a methyl chlorosilane synthesis reaction.

The invention discloses an o-methylbenzyl chloride production process and a production system thereof, and relates to the technical field of o-methylbenzyl chloride production, and the process comprises the steps of reaction raw material pretreatment, staged chlorination reaction, in-situ separation and real-time purification, o-methylbenzyl chloride crude product pretreatment, o-methylbenzyl chloride refining treatment, catalyst recovery and environmental protection treatment. The preparation method has the advantages that by improving the uniformity of free radical generation and the good dispersity of the initiator, the free radical generation sites and concentration in the reaction system are more uniform, and the occurrence of local over-reaction areas and incomplete reaction areas is reduced, so that the problems of excessive chlorination and raw material waste are reduced; the temperature, chlorine flow and illumination conditions are accurately controlled in the staged chlorination reaction, so that hydrogen atoms on benzyl carbon atoms are prevented from being continuously substituted, generation of byproducts such as o-methylbenzyl chloride is reduced, the purity of the target product o-methylbenzyl chloride is improved, and the requirement for subsequent multiple distillation or crystallization purification is reduced.

Provided is a halogenated alkane refining method that can easily, safely, and efficiently remove mixed bromine molecules to obtain a high-purity halogenated alkane. The halogenated alkane refining method is a method for removing bromine molecules from a crude halogenated alkane containing a halogenated alkane and bromine molecules, and includes: a contact step of bringing the crude halogenated alkane into contact with an absorbent solution prepared from an aqueous solution containing a metal iodide to obtain a mixed solution containing the crude halogenated alkane and the absorbent solution; and a separation step of separating the halogenated alkane from the mixed solution to obtain the absorbent solution having absorbed the bromine molecules and the halogenated alkane.

The invention relates to a method for purifying a photoacid generator containing metal ion impurities based on a crystallization method. The light purification method comprises the following steps: (a) dissolving a photoacid generator crude product in a first solvent to form a supersaturated solution; (b) crystallizing the photoacid generator; (c) separating the photoacid generator crystals; and optionally (d) washing the separated photoacid generator crystal with a second solvent. The invention also relates to the high-purity photoacid generator prepared by the method and a photoresist containing the high-purity photoacid generator. According to the method, the photoacid generator containing metal ion impurities can be efficiently purified at low cost.

The present application relates to a composite stabilizer of 2-bromo-3,3,3-trifluoropropene and its use method, the composite stabilizer comprises: a phenolic compound, a phosphite or thioester compound, an acid binding agent, the molar ratio of the amount of the three substances is 1:0.1~6:0.1~6, and the mass ratio of the amount and 2-bromo-3,3,3-trifluoropropene is 0.001~1.0:100. Through the interaction between the above stabilizer components, the rectification process of the product can effectively inhibit the deterioration problems such as the increase of acid value, the color change to yellow and the decrease of purity of 2-bromo-3,3,3-trifluoropropene, provide excellent long-term stability, facilitate its production, transportation and storage, and ensure its smooth application in the field of new fire extinguishing agent, organic synthesis and the like.

The purpose of the present disclosure is to provide a novel separation method for separating refrigerant gas.　This gas separation method comprises: a first step in which a raw material gas containing at least a refrigerant gas A and a refrigerant gas B is supplied to a first module to obtain a first separation gas and a first holding gas that differ in composition from the raw material gas; and a second step in which the first separation gas is supplied to a second module to obtain a second separation gas and a second holding gas that differ in composition from the first separation gas. The first module and / or the second module includes a molecular sieve membrane.

The present invention relates to air stable, binary Ni(0)-olefin complexes and their use in organic synthesis.

The invention relates to the technical field of refrigerants, and particularly provides an environment-friendly refrigerant and a preparation method and a recovery system thereof. In order to solve the problems that a traditional refrigerant is high in global warming potential (GWP), large in degradation energy consumption and not matched with a novel catalyst, the refrigerant is hydrofluoroolefin containing beta-position C = C double bonds, the molecular general formula is CF3CF = CHR (R is H or F), the molecular size is smaller than or equal to 0.8 nm, and the refrigerant is specially designed for being matched with a mesoporous structure of a TNT-120 titanium dioxide nanotube, and adsorption-mass transfer optimization and photo-thermal synergistic degradation synergism are achieved. And a closed-loop solution from production to scrapping is provided for the novel refrigerant. The recycling system adopts a catalytic reactor of which the inner wall is loaded with a titanium dioxide nano coating, and the refrigerant is efficiently degraded under the conditions of low temperature (25-240 DEG C) and low light intensity (0.5-3W / cm < 2 >). The refrigerant has a GWPlt (GWPlt); the refrigerant has the advantages of being good in heat stability, low in degradation energy consumption, environmentally friendly in the whole life cycle and the like, is suitable for replacing a high-GWP refrigerant and meets the requirement for green refrigeration.