880 results about "Water chlorination" patented technology

The invention relates to the technical field of hafnium tetrachloride preparation, in particular to a process method for preparing low-niobium-content hafnium tetrachloride based on a hydrogen reduction method, which comprises the following steps: S1, raw material processing, S2, chlorination and impurity removal, S3, purification, S4, refining and S5, material receiving. According to the method, metal impurities in the hafnium-containing raw stone are removed step by step through the working procedures of raw material processing, chlorination and impurity removal, purification, refining and material receiving, high-purity hafnium tetrachloride with the low niobium content is obtained, in the refining working procedure, under the assistance of the supported catalyst, the metal niobium impurities are removed through a hydrogen reduction method, the removal rate is effectively increased, and the production cost is reduced. And moreover, the process flow is simplified, the energy consumption is reduced, and the method meets the environmental protection requirement.

The invention provides a titanium tetrachloride boiling chlorination process optimization method based on a causal model and electronic equipment, and the method comprises the steps: constructing a generation mechanism between structural equation model expression variables based on the causal relationship between boiling chlorination key process parameters and result variables; the effect of external intervention on the TiCl4 yield and unit cost is simulated through causal inference, and a multi-target optimization model with the minimization of the unit product manufacturing cost and the maximization of the TiCl4 yield as targets is constructed in combination with the structural model and Monte Carlo sampling estimation expectation; and iteratively solving the optimization model by adopting a causal-based non-dominated sorting genetic algorithm, and obtaining a Pareto optimal solution set meeting variable constraint conditions through operations such as causal variable classification, dynamic penalty weighting, non-dominated sorting and sensitive driving disturbance. According to the method, a causal modeling and optimization integrated framework suitable for the boiling chlorination process is constructed, personalized process strategy generation and production operation decision making are supported, and the raw material utilization rate and the process operation economy are improved.

The invention relates to the technical field of organic synthesis, and discloses a preparation process of (S)-3-aminobutyronitrile hydrochloride, which comprises the following steps: by taking a compound S1 as an initial raw material, sequentially implementing chlorination, amino protection, cyano substitution and deprotection reaction through four-step continuous reaction (M01 preparation, M02 preparation, M03 preparation and M04 preparation), and finally obtaining the high-purity (S)-3-aminobutyronitrile hydrochloride. The preparation process disclosed by the invention is simple and convenient to operate, mild in reaction condition, stable in yield of each step, high in safety and suitable for industrial large-scale production, and can be used for carrying out standard treatment on the cyanide-containing wastewater, and has a relatively good application prospect.

The invention relates to the field of fine chemical engineering, and discloses a green process for preparing chloramine T by a continuous flow reactor. The method comprises the following steps: respectively pumping p-toluenesulfonamide, a sodium hydroxide solution and a sodium hypochlorite solution into a micro-channel mixer for instantaneous mixing, and carrying out chlorination reaction in a multi-stage temperature control tubular reaction unit; the concentration of free chlorine is detected on line at an outlet, and the flow rate of a chlorine source is dynamically adjusted through a PID algorithm, so that closed-loop control is realized; the reaction liquid is directly crystallized and separated to obtain the product without alkali wash. The system comprises a base solution and chlorine source conveying subsystem, a micro-channel mixer, a multi-stage reaction unit, an online monitoring module, a central controller and a crystallization unit. The side reaction is inhibited from the source, so that the free chlorine is less than or equal to 0.5 mg / L, the alkali washing step is omitted, the COD (Chemical Oxygen Demand) of the wastewater is reduced by more than 80%, the product purity is more than or equal to 99.5%, and the productivity is improved by 3 times.

The invention provides a method for recovering Si, C and TiO2 based on chlorinated waste salt water quenching slag, which comprises the following steps: sequentially carrying out water quenching dissolution, precipitation separation and filter pressing dehydration treatment on chlorinated waste salt to obtain water quenching slag and supernate; adding a dilute acid solution into the water-quenched slag, dissolving, and adding a reducing agent for reaction to obtain slurry; carrying out solid-liquid separation on the slurry to obtain a solid material and filtrate; the filtrate is pumped into a boiling bed separator, the petroleum coke and TiO2 are intercepted by a medium material layer, clear liquid is discharged, then the medium material layer is subjected to backwashing regeneration, and the desorbed petroleum coke and TiO2 are subjected to graded enrichment by a hydrocyclone, so that petroleum coke slurry and TiO2 slurry are obtained. According to the method, TiO2, C and other resources in the water-quenched slag obtained after molten salt chlorination waste salt water quenching are recycled, and the technical problem that in the existing chlorination waste salt resourceful treatment process, Si, C, TiO2 and other resources in the water-quenched slag are wasted is solved.

The invention discloses a method for reducing the content of rare earth carbonate oil, which comprises the following steps: adding rare earth carbonate seed crystals and pure water into a precipitation tank, feeding a rare earth chloride solution after extraction separation into the precipitation tank, adding an ammonium bicarbonate solution, and carrying out precipitation reaction to obtain rare earth carbonate; the method comprises the following steps: treating rare earth carbonate with hydrochloric acid, converting into a rare earth chloride solution, and filtering the rare earth chloride solution to remove oil to obtain a refined rare earth chloride solution; adding rare earth carbonate into a precipitation tank as a seed crystal, adding the refined rare earth chloride solution and the prepared ammonium bicarbonate solution into the precipitation tank, and carrying out precipitation reaction to produce oil-free rare earth carbonate. According to the invention, oil entrained in the extraction feed liquid and oil dissolved in the feed liquid can be removed, and the quality of the rare earth carbonate product is improved.

The invention discloses a process for separating and recycling scandium, manganese and iron in iron-manganese slag, and belongs to the technical field of metallurgical engineering and comprehensive utilization of secondary resources. The method comprises the following steps: crushing the iron and manganese slag, mixing the crushed iron and manganese slag with a chlorinating agent and a molten salt medium, and carrying out chlorination reaction at 600-850 DEG C, so that iron and manganese are converted into chlorides to volatilize, and scandium is enriched in the slag; the volatile gas is subjected to multi-stage gradient condensation, and manganese and iron concentrates are respectively recovered in different temperature intervals; and leaching-extracting the chlorination residues to obtain a scandium-rich substance. According to the method, source separation and collaborative recovery of iron, manganese and scandium are achieved through pyrogenic process chlorination-condensation, the problems that in a traditional wet process, metal interferes with one another, the process is long, and pollution is heavy are solved, and the method has the advantages of being short in process, small in pollution and high in recycling degree.

The invention relates to the technical field of organic synthesis, and particularly discloses a synthesis process of 2-chloronicotinic acid. The synthesis process of the 2-chloronicotinic acid comprises the following steps: S1, mixing water, concentrated sulfuric acid, 3-cyanopyridine and a composite catalyst, performing pre-reaction, adding hydrogen peroxide, performing oxidation reaction, adjusting pH, performing solid-liquid separation, and washing to obtain an oxide intermediate; s2, in an inert atmosphere, adding phosphorus oxychloride into a reactor, adding the oxide intermediate and triethylamine for a chlorination reaction, recovering phosphorus oxychloride after the reaction is finished, hydrolyzing remaining materials, and performing solid-liquid separation and washing to obtain chloride; and S3, carrying out alkali dissolution, neutralization, decoloration and acidification on the chloride, carrying out solid-liquid separation, washing, carrying out secondary alkali dissolution, neutralization and secondary decoloration, adding a complexing agent, carrying out secondary acidification, carrying out solid-liquid separation, washing, drying and crushing to obtain the 2-chloronicotinic acid. The 2-chloronicotinic acid prepared by the method disclosed by the invention has relatively high purity and yield.

The invention provides a preparation method of chlorinated paraffin 70 with a high softening point, and belongs to the technical field of chlorinated paraffins.The preparation method comprises the steps that S1, mixed wax is provided, and raw materials of the mixed wax are Fischer-Tropsch wax and petrochemical wax; s2, feeding the mixed wax into a reactor, then turning on an ultraviolet lamp in the reactor for irradiation, after liquid chlorine is gasified to form chlorine, feeding chlorine into the reactor, heating and carrying out segmented control reaction; s3, after the reaction is finished, blowing air into the reactor, then washing a reaction product with water, and then adding a compound stabilizer into a crude product obtained by washing with water, so as to obtain chlorinated paraffin 70; the chlorine content of the chlorinated paraffin 70 is not less than 69.5%, the softening point is not less than 98 DEG C, and the acid value is not more than 0.1 mgKOH / g. According to the method, hot chlorination and photo-initiation are combined, so that the chlorine content and the softening point of the product are controllable, the production efficiency is high, the reaction speed is high, the reaction temperature is reduced, the production period is shortened, and the product quality is stable.

The invention relates to a method and a system for preparing chloroethylene carbonate through continuous photochlorination. The system aims at solving the three technical problems that the mass transfer efficiency of chlorine is low under the high gas-liquid ratio, reaction balance is inhibited by accumulation of hydrogen chloride by-products, and selectivity is reduced due to excessive chlorination. The method provided by the invention comprises the following steps: dispersing chlorine into bubbles of 50 microns or below by adopting a metal sintering microbubble generator; a light source and a hollow fiber membrane separation assembly are arranged in the reactor, chlorine and ethylene carbonate are subjected to a reaction through photo-initiation to generate chloroethylene carbonate, and meanwhile generated hydrogen chloride is removed through membrane in-situ displacement by means of purging gas; the system adopts a two-section series structure, and the reaction depth is cooperatively controlled through sectional chlorine gas introduction and gradient illumination intensity. The method provided by the invention realizes efficient utilization of chlorine, real-time breaking of reaction balance and high-selectivity synthesis of monochlorinated products, and is suitable for continuous, safe and efficient industrial production of chloroethylene carbonate.

The invention belongs to the technical field of brominated flame retardant synthesis, and particularly provides a decabromodiphenyl ethane bromine distillation process chlorination bromine removal process, which comprises the following steps: S1, adding bromine into a reaction kettle, adding a catalyst, and mixing; cooling and dropwise adding molten diphenylethane; then heating, carrying out a heat preservation reaction, and cooling to obtain a brominated crude product; s2, S201, adding the brominated crude product obtained in S1 into a bromine steaming kettle, and heating; s202, chlorine is introduced, and the total amount of bromine and chlorine is detected; carrying out segmented control on the introduced chlorine according to the total amount of bromine and chlorine; s203, when the total amount of bromine and chlorine is reduced to a threshold value, stopping introducing chlorine, standing, cooling, and introducing nitrogen; s3, filtering the feed liquid in the bromine steaming kettle, washing and purifying for three times, and finally, centrifugally dewatering to obtain a faint yellow solid; and S4, adding the faint yellow solid into a high-temperature jet mill, performing high-temperature aging to obtain white powder, and then performing jet milling on the white powder to obtain a finished product. Physical distillation is replaced by chemical replacement, so that bromine is highly separated.

The invention discloses an o-chlorotoluene continuous chlorination reaction device and method, and relates to the technical field of chemical engineering, the o-chlorotoluene continuous chlorination reaction device comprises a reaction kettle, the top of the reaction kettle is fixedly provided with a power assembly, the o-chlorotoluene continuous chlorination reaction device further comprises a mixing assembly, the mixing assembly is arranged in the reaction kettle, and the mixing assembly comprises a fixed partition plate fixedly connected to the middle section in the reaction kettle; a methylbenzene input pipe and a chlorine input pipe are fixedly inserted into the top end of the reaction kettle, a rotating rod is fixedly connected to the power output end of the power assembly, a rotating sleeve is rotatably inserted into the top end of the reaction kettle, and a movable partition plate is fixedly connected to the bottom end of the rotating sleeve; a plurality of lowering holes are formed in the surfaces of the movable partition plate and the fixed partition plate, the rotating rod is inserted into the rotating sleeve, and the top end of the rotating sleeve is fixedly sleeved with an outer gear ring, so that the problems that in the period of time when prepared finished products are discharged, the production is stopped, the production interval is large, and the production efficiency is high are solved. And continuous chlorination reaction cannot be carried out.

A hydrometallurgical process for recovering a plurality of metals from a complex rare and precious material, comprising the following steps: step 1: adding a complex rare and precious material to a hydrochloric acid solution, adding an oxidant for reaction, and then performing filtration to obtain a chlorination liquid and a chlorination residue; step 2: using two-stage counter-current gold loading to obtain a gold-loaded liquid and a post-loading liquid, reducing the gold-loaded liquid, performing clarification to obtain an organic phase, and filtering a precipitate to separate a post-reduction liquid and sponge gold; performing evaporation and concentration on the post-reduction liquid to produce a concentrate 1 and a condensate; and cooling and crystallizing the concentrate, performing filtration to obtain residual oxalic acid, and returning the residual oxalic acid to the reduction process and a post-crystallization liquid to gold loading; step 3: performing low-temperature distillation on the post-loading liquid to obtain a concentrate 2; step 4: performing high-temperature distillation on the concentrate 2 to obtain a concentrate 3; step 5: performing directional crystallization and centrifugal filtration on the concentrate 3 to obtain a crystallization residue and selenous acid; and step 6: washing the crystallization residue by using cold water or a low-acid-level condensate produced in step 3, and performing filtration to obtain a tellurium residue and a palladium-platinum-rhodium-rich liquid.

The invention discloses a chlorphenesin coupling crystallization-adsorption purification method based on a deep eutectic solvent, and belongs to the technical field of chemical purification. According to the technical scheme, the method comprises the following steps: S1, mixing crude chlorphenesin with supercritical CO2, and extracting to obtain pretreated chlorphenesin; s2, dissolving the pretreated chlorphenesin in a choline chloride-glycerol DES system, adding an adsorbent after sufficient dissolution, cooling, and separating out chlorphenesin. The technical problems that an organic solvent is used in an existing chlorphenesin purification method, and the solvent is inflammable, toxic, large in dosage, long in purification time and high in energy consumption are solved, and the chlorphenesin coupling crystallization-adsorption purification method based on the eutectic solvent is safe, environmentally friendly, capable of improving production efficiency and high in product purity and yield.

The utility model discloses a kind of silicon chloride slag slurry processing devices in the production process of polysilicon, it is related to polysilicon production technical field, including settling tank, drying machine, hydrolysis kettle, purification kettle and cleavage reaction kettle, settling tank upper portion outlet is connected with purification kettle import, settling tank bottom outlet is connected with drying machine, purification kettle is connected with cleavage reaction kettle feed port, cleavage reaction kettle is connected with rectification process, the drying machine is connected with rectification process, the liquid phase outlet of the purification kettle, cleavage reaction kettle liquid phase outlet and hydrolysis kettle solid phase outlet are connected with hydrolysis kettle feed port respectively, by solid-liquid separation after sedimentation to slag slurry, clear liquid after precipitation is sent into rectification process for recycling in turn after purification, cleavage, sediment after precipitation is sent into rectification process for recycling after liquid after drying machine steam heating drying, drying solid slag of drying machine, purification residual liquid and cleavage residual liquid are sent to three waste treatments after hydrolysis.

The invention belongs to the technical field of zirconium oxychloride preparation, and particularly relates to a preparation method of zirconium oxychloride. The preparation method of the zirconium oxychloride comprises the following steps: (1) carrying out acid leaching on waste fused zirconia corundum brick powder; (2) alkali fusion roasting of filter residues; (3) leaching with hot water and refluxing with hydrochloric acid; (4) purification treatment; and (5) post-treatment. According to the preparation method of the zirconium oxychloride, the waste fused zirconia corundum brick powder is used as a raw material, the problem of solid waste disposal of retired waste fused zirconia corundum bricks of a glass kiln is solved, efficient recycling of resources is achieved, a non-renewable resource zircon sand raw material is partially replaced, and the production cost is reduced; the high-purity zirconium oxychloride is prepared through acid leaching, alkali fusion, hot water leaching, hydrochloric acid reflux conversion, purification and aftertreatment.

The utility model discloses a water circulation system of a chlorinated polyethylene device, and belongs to the technical field of fine chemical engineering. The system comprises a hot water pool and a cold water pool, the output end of the cold water pool is respectively connected with a jacket of a chlorination kettle, a jacket of a material waiting kettle, a drying system and a belt filter, the output end of heating steam is connected with the jacket of the chlorination kettle and the drying system, and the jacket of the chlorination kettle and the output end of the drying system are connected with the hot water pool. According to the utility model, the water resource at the jacket outlet of the chlorination reaction kettle is fully utilized.

The invention relates to the technical field of chemical equipment, in particular to a special online density precision detector for a full-automatic chlorination process. The device comprises an instrument desk assembly installed on a reaction kettle, a compressed air inlet pipe used for air inlet is connected to the side of the instrument desk assembly, an air inlet main valve and a pressure reducing valve are arranged on the compressed air inlet pipe, a rotor flow meter is arranged in the instrument desk assembly, the bottom end of the instrument desk assembly is connected with an H air blowing pipe and an L air blowing pipe, and the two air blowing pipes are both connected into the reaction kettle. The bottom end of the L-shaped air blowing pipe is higher than the bottom end of the H-shaped air blowing pipe, a pressure difference transmitter is arranged on the top of the instrument desk assembly, and the L-shaped air blowing pipe and the H-shaped air blowing pipe are sleeved with sampling pipes. Through the arrangement of the sampling pipe, it is ensured that the measurement environment is stable, and the measurement precision is ensured; the direct contact between an instrument and reaction liquid is directly avoided, indirect measurement is carried out by adopting pressure difference, the service life of equipment is greatly prolonged, and the device is suitable for production of various highly corrosive materials.

The invention relates to the technical field of p-fluorobenzaldehyde production, and particularly discloses a production process of high-purity p-fluorobenzaldehyde. The invention relates to a production process of high-purity p-fluorobenzaldehyde. The production process comprises the following steps: S1, carrying out a chlorination reaction by taking p-fluorotoluene and chlorine as raw materials to prepare a mixed chlorination solution of p-fluoromethyl benzyl monochloride, p-fluoromethyl benzyl dichloride and p-fluoromethyl benzyl trichloride; s2, adding an organic complexing agent, which is a water-soluble aprotic solvent, into the mixed chlorinated liquid prepared in the step S1, and then performing vacuum rectification to obtain distillate and residual liquid; rectifying by taking the residual liquid as a raw material to obtain kettle liquid and rectified liquid; and S3, carrying out hydrolysis reaction by taking the rectification liquid and water as raw materials, separating, and drying to obtain the product. The production process of the high-purity p-fluorobenzaldehyde has the advantages of high raw material conversion rate, high product purity and few three-waste products.

At least one embodiment of the invention provides a preparation method of sponge titanium, which comprises the following steps: pretreating bauxite tailings to obtain a first mixture; carrying out acid treatment on the first mixture, and filtering to obtain a second mixture; putting the second mixture into a reaction kettle containing an alkaline substance to react so as to convert the ferric titanate into titanate and ferric oxide or ferrous hydroxide to obtain a third mixture; carrying out suction filtration treatment on the third mixture to obtain a first solid phase and a first liquid phase, and drying and grinding the first solid phase; roasting the dried and ground first solid phase to form an iron elementary substance, and carrying out magnetic separation to remove the iron elementary substance; adding an acidic material into the first liquid phase for reaction to obtain metatitanic acid colloid, and washing the metatitanic acid colloid; the metatitanic acid colloid is subjected to calcination, chlorination reaction and replacement reaction in sequence to obtain the sponge titanium. The sponge titanium obtained through the preparation method is high in purity.

A high-entropy nano-array for electrocatalytic nitrate reduction coupling waste plastic conversion is prepared by the following method: (1) immerse the nickel foam into a hydrochloric acid solution to remove the surface oxide layer and oil stains, rinse with deionized water / ethanol three times, and dry for subsequent use; (2) solid powders of sodium chloropalladate, platinum acetylacetate, nickel chloride hexahydrate, copper chloride dihydrate, silver trifluoroacetate and tungsten hexacarbonyl are poured into an N-N dimethylformamide solution, ultrasonic is used to dissolve the solid powders, then glacial acetic acid and the treated nickel foam are added to the above solution, and after ultrasonic, heating in an oven is carried out, after the reaction is completed, water and ethanol solution are used for alternate washing, and drying is carried out, and the high-entropy nano-array catalyst is obtained. A preparation method of a high-entropy nano-array for electrocatalytic nitrate reduction coupling waste plastic conversion is provided. The high-entropy nano-array has excellent electrocatalytic activity and stability.

The present application belongs to the technical field of waste incineration fly ash treatment, and particularly relates to a low-carbon treatment process for waste incineration fly ash water washing wastewater, which comprises the following steps: A1: water washing of waste incineration fly ash to wash and remove heavy metals in the fly ash; A2: water washing wastewater is removed of heavy metals by ferrous chloride and sulfide; A3: water washing wastewater after removal of heavy metals is mixed with sodium sulfate to remove calcium ions; A4: residual calcium ions are removed by sodium carbonate, and sodium carbonate removal liquid is subjected to plate and frame pressure filtration and then enters an ultrafiltration and nanofiltration membrane system, and concentrated liquid of the membrane system is returned to configure a sodium sulfate solution; A5: fresh water from the membrane system enters an evaporation system, and mother liquor of the evaporation system is first subjected to diatomite reaction and then enters a raw ash pre-slurry reaction tank for raw ash slurry, so that the above low-carbon process is used to reduce the amount of sodium carbonate and the amount of mother liquor treatment, and efficient and low-carbon treatment of waste incineration fly ash water washing wastewater can be realized.

The utility model discloses a tetrachlorophthalic anhydride production chlorination kettle iodine adding device, which comprises an upper iodine adding valve, a lower iodine adding valve and an iodine solution transfer tank, the iodine solution transfer tank is arranged between the upper iodine adding valve and the lower iodine adding valve, the outer side of the iodine solution transfer tank is communicated with two communicating pipes, one ends of the two communicating pipes far away from the iodine solution transfer tank are communicated with a communicating box, and the communicating box is communicated with the upper iodine adding valve and the lower iodine adding valve. The end, away from the communicating pipe, of the communicating box communicates with a pressure-regulating external pipe. The effective volume between the upper iodine adding valve and the lower iodine adding valve can be increased through the arranged iodine solution transfer tank, and the pressure difference among the upper iodine adding valve, the iodine solution transfer tank and the lower iodine adding valve is adjusted in a matched manner, so that two kilograms of iodine can be added at one time, the upper iodine adding valve and the lower iodine adding valve do not need to be repeatedly opened and closed, the operation becomes simple, the labor intensity is reduced, and the production efficiency is improved. And the iodine is added in a pressure difference manner, so that the unorganized emission of harmful gas in the kettle is avoided, the risk that the iodine is suddenly flushed out is greatly reduced, and the personal safety is guaranteed.

The present application relates to the technical field of extracting rare earth, and particularly relates to an extraction rare earth separation process method. Fluorine-carbon cerium ore crude ore is treated to obtain activated ore powder. The activated ore powder is subjected to alkali pressure boiling oxidation, roasting transformation and optimal dissolution leaching to obtain a purified liquid. The purified liquid is then subjected to barium chloride sulfuric acid removal, lead removal by sulfurized lead, pH adjustment and the like to obtain a low-impurity chlorinated rare earth liquid. The chlorinated rare earth liquid is subjected to multi-stage extraction to obtain a neodymium chloride solution, a praseodymium-neodymium chloride solution and a lanthanum-cerium chloride solution. The solutions are subjected to oxalic acid precipitation and calcination to obtain a rare earth oxide product. The present application adopts fine pretreatment, multi-stage differential extraction and purification processes to achieve efficient separation of lanthanum-cerium, praseodymium-neodymium and neodymium in fluorine-carbon cerium ore and improve product purity.

The invention provides a preparation method of clindamycin hydrochloride alcoholate. The preparation method comprises the following steps: firstly, preparing a chlorination reagent from an oily solvent, DMF (Dimethyl Formamide), a chlorination solvent and an antioxidant; carrying out temperature-controlled chlorination reaction with lincomycin hydrochloride to obtain a chlorination reaction solution; adjusting the pH value of the reaction solution to 10-11, controlling the temperature to react, taking an oil phase after the reaction is finished, concentrating under reduced pressure, diluting with water, and adjusting the pH value to 3-5 to obtain a column loading solution; the preparation method comprises the following steps: dissolving clindamycin hydrochloride in water, adsorbing by using resin, eluting impurities by using dilute alkaline water, analyzing by using ethanol and deionized water in sequence, collecting an analysis solution, concentrating under reduced pressure, adding ethanol, heating for dissolving, adjusting the pH value to 1-1.5, cooling for crystallizing, and drying to obtain the clindamycin hydrochloride alcoholate. According to the preparation method disclosed by the invention, the clindamycin alcoholate with high yield and high purity is prepared by pertinently designing processes such as reaction conditions, a specific oily reagent, temperature control conditions, column adsorption, dilute alkaline water impurity elution, ethanol desorption and the like, only one-time crystallization is needed, repeated refining is not needed, the HPLC (High Performance Liquid Chromatography) purity is up to 99.5% or above, and the clindamycin alcoholate is suitable for industrial production. And 0.14% or less of 2, 7-epiclindamycin.

The present application belongs to the field of hydrochloric acid concentration equipment, and particularly relates to a chlorinated polyethylene production process by-product hydrochloric acid concentration system, which comprises a resolving tower and a condensing section dilute hydrochloric acid input tank, the condensing section dilute hydrochloric acid input tank is connected with an absorption tank and a dilute hydrochloric acid buffer tank, the output end of the dilute hydrochloric acid buffer tank is connected with the liquid input end of the resolving tower, the gas input end of the resolving tower is connected with a reboiler, the gas output end of the resolving tower is connected with the absorption tank, and the output end of the absorption tank is connected with a concentrated hydrochloric acid storage tank. The present application divides the condensed dilute hydrochloric acid generated in the condensing section of the chlorinated polyethylene production process into three parts, reduces the types of system raw materials, reduces the difficulty of material preparation, increases the concentration of dilute hydrochloric acid through the resolving formed hydrogen chloride, improves the concentration of hydrochloric acid, and improves the economic value of the product.

The present disclosure relates to a polyethylene, which is reacted with chlorine to prepare a chlorinated polyethylene having excellent chlorination productivity and thermal stability by enabling an increase in chlorination temperature, and facilitating deoxidation, dehydration and drying processes during chlorination processing, by implementing an enlarged area of the middle and high molecular weight regions in the molecular structure of the polyethylene.

The present application relates to the technical field of acid waste gas treatment, and provides a treatment process for acid waste gas, comprising the following steps: S1, absorbing the acid waste gas by a treatment agent; S2, spraying and absorbing the waste gas after S1 by a ferrous chloride solution; and S3, absorbing the waste gas after S2 by a sodium hydroxide absorption solution. Through the above technical scheme, the problems of low acid waste gas treatment rate and insufficient waste gas treatment in the prior art are solved.

The application relates to a preparation method of a TiO2 / Sb2O3 / PSAC heterojunction sterilization composite material, which comprises the following steps: 1) adding a cationic surfactant, tetrabutyl titanate, antimony trichloride or antimony pentachloride into deionized water in sequence and stirring until the solution is white; 2) placing a FOSS crucible with coal-tar pitch-based spherical activated carbon into a high-pressure reaction kettle with concentrated nitric acid, heating, washing with deionized water until neutral, and naturally air-drying; 3) placing the dried coal-tar pitch-based spherical activated carbon into the white solution, stirring, finally adding sodium hydroxide, stirring, and then placing into a high-pressure reaction kettle, heating and keeping for a period of time; and naturally cooling, centrifugalizing, washing and drying. The application effectively combines the adsorption performance and the photocatalytic performance of the activated carbon through a hydrothermal one-step in-situ method, increases the mechanical performance, and can have high sterilization efficiency under the excitation of sunlight.

The invention discloses a device and method for ultra-clean emission of tail gas of a large fused salt chlorination furnace, the device comprises a water washing device, an alkali washing device and a tail gas white removal device, an inlet of the water washing device is communicated with a smoke outlet of the chlorination furnace, and an outlet of the water washing device is communicated with an inlet of the alkali washing device; in addition, the tail gas white removal device comprises a heat exchanger, and the heat exchanger enables the temperature of the circulating liquid in the alkali washing device to be lower than 40 DEG C. A trace amount of TiCl4 flue gas in the tail gas is absorbed by utilizing a water washing principle, chlorine, CO2 and HCl in the tail gas are absorbed by utilizing an alkali washing principle, and the temperature of circulating liquid in an alkali washing device is controlled by adopting a heat exchanger, so that an alkali washing byproduct, namely sodium chloride, is prevented from being decomposed, and further, the increase of flue gas particulate matters generated by the decomposition is avoided; therefore, most harmful impurities in the tail gas are removed.