2041 results about "Water chlorination" patented technology

The invention discloses a high-purity quartz sand reinforced chlorination purification method, and belongs to the technical field of inorganic non-metallic material processing. The method comprises the following steps: putting a quartz sand raw material containing crystal structure impurities into a roasting furnace, and synchronously introducing a gas chlorinating agent and a gas reducing agent into the roasting furnace for roasting to obtain purified quartz sand. According to the method, on the basis of conventional chloridizing roasting purification, a gas reducing agent is introduced to regulate and control the reaction atmosphere, efficient dissociation and chlorination of crystal structure impurities difficult to remove are promoted, and deep efficient purification of quartz sand is achieved. The method has the advantages of simple process equipment, high raw material applicability, high impurity removal efficiency and the like, and can be widely applied to production of 4N5-grade and above high-purity quartz sand.

The invention discloses an external field reinforced molybdenum concentrate impurity removal method, and belongs to the technical field of molybdenum concentrate impurity removal. The method comprises the following steps: (1) microwave enhanced chloridizing roasting: uniformly mixing the molybdenum concentrate and calcium chloride, and carrying out microwave heating roasting in an inert atmosphere protection environment to obtain a roasted product; (2) ultrasonic enhanced acid leaching: adding the roasted material obtained in the step (1) into a hydrochloric acid solution, leaching under an ultrasonic condition, and then sequentially carrying out suction filtration, washing and drying to obtain an acid leached material; and (3) ultrasonic enhanced alkaline leaching is conducted, specifically, the acid leaching material obtained in the step (2) is added into a sodium hydroxide solution, leaching is conducted under the ultrasonic condition, then suction filtration, washing and drying are conducted in sequence, and iron and silicon removal of the molybdenum concentrate is completed. By means of the method, the iron and silicon removal effect of the molybdenum concentrate can be effectively improved, and the iron and silicon removal rate can reach 97% or above.

The invention belongs to the technical field of sewage treatment, and particularly relates to a demulsifier for eliminating an oil-water interface emulsion layer in oilfield produced liquid treatment and a preparation method of the demulsifier. The preparation method comprises the following steps: adding acrylamide, 1-allyl-3-methylimidazolium bis (trifluoromethanesulfonyl) imine salt, allyl tributyl phosphonium chloride and deionized water into a first reactor, and heating and dissolving the acrylamide, the 1-allyl-3-methylimidazolium bis (trifluoromethanesulfonyl) imine salt, the allyl tributyl phosphonium chloride and the deionized water; adding allyl (diisopropylamino) dimethylsilane, butyl acrylate, deionized water, octylphenol polyoxyethylene ether-10, lauryl sodium sulfate and monopotassium phosphate into the second reactor, and stirring to obtain an emulsion; adding an initiator and sodium hydrogen sulfite into a second reactor, carrying out heating and heat preservation reaction, pouring the mixed solution in the first reactor, and continuously carrying out reaction, heating and heat preservation to obtain a viscous liquid; and drying and granulating the viscous liquid to obtain the demulsifier. The demulsifier provided by the invention has the characteristics of simple synthesis process and high demulsification rate.

The invention relates to the technical field of hafnium tetrachloride preparation, in particular to a process method for preparing low-niobium-content hafnium tetrachloride based on a hydrogen reduction method, which comprises the following steps: S1, raw material processing, S2, chlorination and impurity removal, S3, purification, S4, refining and S5, material receiving. According to the method, metal impurities in the hafnium-containing raw stone are removed step by step through the working procedures of raw material processing, chlorination and impurity removal, purification, refining and material receiving, high-purity hafnium tetrachloride with the low niobium content is obtained, in the refining working procedure, under the assistance of the supported catalyst, the metal niobium impurities are removed through a hydrogen reduction method, the removal rate is effectively increased, and the production cost is reduced. And moreover, the process flow is simplified, the energy consumption is reduced, and the method meets the environmental protection requirement.

The invention belongs to the technical field of rare and precious metal recovery, and particularly relates to a method for recovering metallic silver from waste crystalline silicon battery pieces, which comprises the following steps: (1) putting the waste crystalline silicon battery pieces into an inorganic alkali aqueous solution for soaking reaction to obtain an aluminum-containing solution and dealuminized crystalline silicon pieces; (2) adding the dealuminized crystal silicon wafer into a mixed solution of organic acid and hydrogen peroxide for soaking reaction, filtering and washing to respectively obtain silver-containing filtrate and a silver-removed silicon wafer; (3) carrying out chlorination precipitation reaction on the silver-containing filtrate and a chlorine source, filtering and drying to obtain silver chloride powder; (4) adding silver chloride powder into an ammonia water solution, heating and stirring to completely dissolve silver chloride to obtain a silver-ammonia solution; (5) adding PVP (Polyvinyl Pyrrolidone) into the silver-ammonia solution, heating and stirring until the PVP is completely dissolved, adding ascorbic acid, and carrying out reduction reaction at room temperature to obtain metal silver powder precipitate; and filtering, washing and drying the precipitate to obtain the spherical silver powder. According to the method, the silver recovery efficiency is high, the spherical nanoscale silver powder can be prepared, and the purity is high.

The utility model provides a chlorination device for producing 3, 4-dichlorobenzotrifluoride, which belongs to the field of chemical industry production and comprises a barrel body, a support is fixedly mounted at the bottom of the barrel body, and a stirring component is arranged in the barrel body; the grinding assembly comprises a grinding hopper, a conical grinding plate, a guide hopper, a fixing plate, a lifting plate and a reciprocating screw rod, the grinding hopper is fixedly arranged on the inner wall of the barrel body, the conical grinding plate is matched with the grinding hopper, the guide hopper is fixedly arranged at the top of the conical grinding plate, the fixing plate is fixedly arranged at the top of the guide hopper, and the lifting plate is arranged on the lifting plate. And the reciprocating screw rod is fixedly arranged at the inner top of the barrel body. According to the chlorination reaction device, the stirring assembly is arranged, a solution can be fully stirred and mixed, the chlorination reaction efficiency is guaranteed, the grinding assembly is further arranged, a large catalyst can be ground, and therefore the catalyst is pulverized, and the chlorination reaction efficiency is further improved.

The invention provides a method for synergistically recovering all elements of crystal silicon cells of a decommissioned photovoltaic module, which comprises the following steps of: collecting large-particle waste crystal silicon cells and grinding the large-particle waste crystal silicon cells to obtain powder; the powder is leached with nitric acid, and leach liquor and impurity-removed silicon powder are obtained; leaching the silicon powder subjected to impurity removal by using an HF solution to remove a silicon nitride layer, and filtering, washing and drying to obtain the silicon powder meeting the industrial standard; the leaching solution is subjected to chlorination precipitation to obtain silver chloride and a leaching solution with silver removed, and after the silver chloride is filtered, the silver chloride is subjected to acid pickling and water washing to obtain silver chloride; sodium sulfide is added into the leaching solution after silver removal, metal in the leaching solution is precipitated, and a solution containing Al < 3 + > can be obtained after filtering; the method comprises the following steps: adding an alkaline substance into a solution containing Al < 3 + >, filtering to obtain an aluminum hydroxide precipitate, and washing the aluminum hydroxide precipitate to remove foreign ions adsorbed on the surface; one technical effect of the invention is that collaborative recovery and treatment of each element in the waste crystal silicon battery piece are realized.

The invention discloses a sheath material for a saline-alkaline-resistant dragging cable, a preparation method of the sheath material, the cable and the sheath material. The sheath material is prepared from the following raw materials in parts by weight: 40 to 45 parts of chlorinated polyethylene, 1.5 to 2.0 parts of dicumyl peroxide vulcanizing agent, 2 to 2.5 parts of triisocyanate vulcanizing agent, 0.1 to 0.3 part of ethylene thiourea accelerant, 0.05 to 0.15 part of anti-aging agent RD, 4 to 5 parts of metal oxide, 1 to 1.5 parts of paraffin, 8 to 10 parts of calcium carbonate, 15 to 21 parts of reinforcing agent, 1 to 1.5 parts of lead stearate, 0.5 to 1 part of lead sulfate tribasic, 1 to 1.5 parts of ultraviolet light absorber, 3 to 5 parts of epoxidized soybean oil and 8 to 8 parts of chlorinated paraffin. 9 parts of antimony trioxide and 3-4 parts of antimony trioxide. The cable has the advantages of ultraviolet resistance, no salt deposition, water resistance, tensile resistance, cold resistance and the like, can be used for a long time in a special operating environment, has the service life of at least more than 3 years, and avoids frequent replacement of the cable by a user.

According to the preparation method of the low-temperature humified coal gangue-agriculture and forestry solid waste porous slow-release humic acid water-soluble fertilizer, the coal gangue is subjected to magnetic separation and flotation to remove impurities, then the composite chlorinating agent is used for low-temperature chlorination, heavy metal is effectively removed, and meanwhile energy consumption and environmental risks are reduced. Then, under a controlled low-temperature condition, through microwave assistance and specific atmosphere adjustment, a humification reaction is triggered, meanwhile, formation of a porous structure of the material is triggered, and the water solubility and the slow release effect of the fertilizer are enhanced. According to the method, the resource utilization rate of the coal gangue is increased, the high-efficiency soil conditioner is effectively generated through an innovative low-temperature treatment process, and good environmental protection benefits and economic values are achieved. Through the structural design of the obtained fertilizer, the fertilizer can respond to environmental factors, the nutrient release rate is automatically adjusted, and plant absorption and soil health are optimized.

The invention relates to a sludge biochar modified layered bimetallic oxide, and a preparation method and application thereof. The modified layered bimetallic oxide is prepared from the following main raw materials: domestic sewage aeration tank sludge, NaOH, Na2CO3, FeCl3. 6H2O and MnCl2. 4H2O. The domestic sewage aeration tank sludge is used for preparing dry sludge, the ferric chloride solution and the manganese chloride solution are used for preparing sludge composite layered double hydroxides, and the final layered bimetallic oxide composite sludge biochar catalyst can be prepared by calcining the sludge composite layered double hydroxides. The modified layered bimetallic oxide prepared by the scheme of the invention can effectively degrade bisphenol A, has relatively strong reusability, and still keeps good degradation ability in a relatively wide pH environment.

The invention relates to the technical field of chemical tail gas treatment, and discloses a multi-stage series chlorinated tail gas efficient absorption system and method.The multi-stage series chlorinated tail gas efficient absorption system comprises a multi-stage series absorption unit, a circulation control system, a tail gas collection device, an emission monitoring device, a safety protection system, a tail gas purification device and an automatic control system; the multi-stage series absorption unit comprises a first-stage turbulence absorption tower, a second-stage membrane contact tower and a third-stage deep washing tower, and the multi-stage series absorption unit, a circulation control system, a tail gas collection device, an emission monitoring device, a safety protection system, a tail gas purification device and an automatic control system are integrated; according to the invention, high-efficiency, automatic and intelligent treatment of chlorinated tail gas is realized, the tail gas can be subjected to multi-stage treatment through the design of the multi-stage series absorption unit, and different pollutants can be efficiently removed in each stage, so that the treatment efficiency of the tail gas is greatly improved.

The invention relates to the technical field of cutting fluids, and discloses a high-temperature alloy cutting fluid and a preparation method thereof, the high-temperature alloy cutting fluid comprises the following components: 30%-50% of base oil, 5%-10% of organic alkali, 5%-10% of an antirust agent, 4%-10% of synthetic ester, 15%-20% of an anti-wear reagent at extreme pressure, 0.5%-1.5% of a corrosion inhibitor, 7%-15% of an emulsifier, 2%-4% of a bactericide, 0.05%-0.1% of a defoaming agent, and the balance of water; the extreme pressure anti-wear agent is composed of a chlorination extreme pressure anti-wear agent and a vulcanization extreme pressure anti-wear agent. According to the invention, the ester-based base oil, the organic alkali, the synthetic ester and the extreme pressure anti-wear agent composed of the chlorination extreme pressure anti-wear agent and the vulcanization extreme pressure anti-wear agent are combined to form a continuous high-strength lubricating film, and the continuous high-strength lubricating film is compounded with additives such as the organic acid antirust agent, the corrosion inhibitor and the bactericide; therefore, the antirust corrosion inhibition performance of the cutting fluid on workpieces and machine tools and the long-term use safety and environmental protection performance are improved during processing.

The invention relates to the technical field of quartz sand purification, in particular to a high-purity quartz sand purification method and equipment. 2, a magnetic separation stage; 3, an acid leaching stage; 4, an ultrasonic-assisted cleaning stage; 5, a high-temperature chlorination treatment stage; according to the quartz sand purification method, various impurities such as magnetic impurities, non-magnetic metal impurities and silicate impurities in the quartz sand can be deeply removed through the synergistic effect of multiple steps such as pretreatment, magnetic separation, acid leaching, ultrasonic-assisted cleaning and high-temperature chlorination treatment, the purity of the quartz sand reaches 99.999% or above, the strict requirements of high-end fields such as semiconductors and photovoltaics are met, and the method is suitable for industrial production. The purification steps are closely linked to form a modular purification process, and meanwhile, advanced technologies such as ultrasonic-assisted cleaning and high-temperature chlorination treatment are adopted, so that the impurity removal efficiency is remarkably improved, the purification time is shortened, and the energy consumption and the use amount of chemical reagents are reduced by optimizing the process and equipment.

The invention belongs to the technical field of resource regeneration, and particularly relates to a method for recycling hydrochloric acid and germanium through direct two-stage distillation after germanium chlorination distillation, which comprises germanium chlorination distillation, first-stage positive pressure acid steaming, second-stage negative pressure acid steaming and kettle stopping and slag liquid discharging. According to the invention, two-stage acid distillation is directly carried out in the original production equipment system after germanium chlorination distillation, so that the innovation of integrated continuous production of germanium chlorination distillation and acid distillation in the same equipment system is realized, the process is more energy-saving and economic, the operation is simpler and more convenient, the equipment utilization rate is higher, and the environment is more friendly; the recycling rate of hydrochloric acid is up to 60% or above; a one-stage positive-pressure acid steaming process is adopted, high-concentration hydrochloric acid with the HCl molar concentration larger than or equal to 9.5 mol / L is regenerated and can be directly returned to germanium chlorination distillation for use, and synchronous limit recovery of residual germanium in germanium chlorination distillation residues is achieved; therefore, full recycling of hydrochloric acid and germanium in germanium chlorination distillation waste acid and waste residues is realized.

The invention relates to a rotary distributed quartz sand high-temperature chlorination furnace which comprises a chlorination furnace body, a gas conveying pipe, a rotating device, a heating body, a furnace shell and a bracket, the upper end of the chlorination furnace body is externally connected with a temperature measuring galvanic couple, a gas pressure sensor and a feed port, the lower end of the chlorination furnace body is externally connected with an exhaust port and a discharge port, the inner wall of the chlorination furnace body is provided with a baffle, and the periphery of the chlorination furnace body is provided with a heating body, a furnace shell and a bracket; the gas conveying pipe enters the chlorination furnace body from the lower end of the chlorination furnace body and is close to the upper end; two gas outlets are formed in the top end of the gas conveying pipe. The chlorination furnace body is installed in the furnace shell in an inclined mode and can be driven by the rotating device to rotate slowly so as to drive quartz sand to slide from top to bottom in the furnace, and continuous high-temperature chlorination treatment on the quartz sand is achieved; the baffles on the inner wall of the furnace body can effectively disperse the quartz sand, increase the contact area and reaction time of the quartz sand and the chlorinating agent, fully remove the content of alkali metal impurities and improve the purity of the quartz sand. And the structure is sealed, so that the requirement of the quartz sand chlorination reaction on the pressure in a specific range can be met.

The invention provides a titanium tetrachloride boiling chlorination process optimization method based on a causal model and electronic equipment, and the method comprises the steps: constructing a generation mechanism between structural equation model expression variables based on the causal relationship between boiling chlorination key process parameters and result variables; the effect of external intervention on the TiCl4 yield and unit cost is simulated through causal inference, and a multi-target optimization model with the minimization of the unit product manufacturing cost and the maximization of the TiCl4 yield as targets is constructed in combination with the structural model and Monte Carlo sampling estimation expectation; and iteratively solving the optimization model by adopting a causal-based non-dominated sorting genetic algorithm, and obtaining a Pareto optimal solution set meeting variable constraint conditions through operations such as causal variable classification, dynamic penalty weighting, non-dominated sorting and sensitive driving disturbance. According to the method, a causal modeling and optimization integrated framework suitable for the boiling chlorination process is constructed, personalized process strategy generation and production operation decision making are supported, and the raw material utilization rate and the process operation economy are improved.

The invention relates to a deep sewage defluorination method based on NH4F.LaF3 chemical precipitation, which comprises the following specific steps: adding a solution containing NH4 < + > and La < 3 + > into fluorine-containing water, adjusting the pH value of the sewage to 6-8, and carrying out NH4F.LaF3 chemical precipitation reaction; sediment is discharged, crystal particles in supernate are removed, deep defluorination of the sewage is achieved, and the concentration of fluorine ions in the water after defluorination can be stably lower than 1 mg / L. According to the method disclosed by the invention, by utilizing the characteristic that the solubility of double salt NH4F.LaF3 is very low, NH4 < + > ions (ammonium chloride or ammonia water and hydrochloric acid) and La < 3 + > ions (lanthanum chloride or lanthanum oxide and hydrochloric acid) are added into the fluorine-containing wastewater, so that equivalent reaction of fluorine, lanthanum ions, ammonium ions, fluorine ions and the like in the water is removed, and the addition of a medicament does not need to be excessive. The method has the characteristics of high efficiency and low cost, and has the advantages of small dosage of chemicals, high reaction speed, thorough reaction and low concentration of fluorine in effluent.

The invention relates to the technical field of chemical metallurgy, and discloses a preparation and purification method of high-purity sponge vanadium, which comprises the following steps: preparing a vertical vacuum reduction furnace, adding a reducing agent, discharging air in the furnace, and introducing shielding gas; heating, adding vanadium chloride for smelting, taking out, putting into a distillation furnace, and carrying out heating and heat preservation treatment; and finally, putting the product into a crucible in an electron beam furnace, vacuumizing, heating and smelting, introducing protective gas into the electron beam furnace after smelting, and cooling to room temperature to obtain a sponge vanadium product. The high-purity sponge vanadium is prepared by adopting a novel vanadium chloride metal thermal reduction-distillation method, and the sponge vanadium is further purified through vacuum electron beam refining, so that the common technical problems of long flow, low product purity and the like of a traditional method for preparing the high-purity metal vanadium are solved.

The invention relates to the technical field of organic synthesis, and discloses a preparation process of (S)-3-aminobutyronitrile hydrochloride, which comprises the following steps: by taking a compound S1 as an initial raw material, sequentially implementing chlorination, amino protection, cyano substitution and deprotection reaction through four-step continuous reaction (M01 preparation, M02 preparation, M03 preparation and M04 preparation), and finally obtaining the high-purity (S)-3-aminobutyronitrile hydrochloride. The preparation process disclosed by the invention is simple and convenient to operate, mild in reaction condition, stable in yield of each step, high in safety and suitable for industrial large-scale production, and can be used for carrying out standard treatment on the cyanide-containing wastewater, and has a relatively good application prospect.

Metal recovery and separation systems and methods, more particularly electrothermal chlorination (ETC) and electrothermal carbochlorination (ETCC) methods and systems for selective metal extraction, such as extraction of key metals from waste streams. Alternatively, other oxidizing agents, such as fluorine, bromine or iodine, may be used in place of or in combination with chlorine. Further, or other reducing agents, such as a metal (0), such as tin (0), and H2 (H2 included in argon, such as 1% to 5% by volume of H2 in argon, may be used in place of or in combination with carbon. Embodiments of the invention may utilize ETC to selectively recover In from ITO-containing waste, and utilize ETC in combination with ETCC to recover Ta from capacitor waste.

The invention discloses a method for preparing superfine high-purity germanium dioxide from germanium tetrachloride. The method comprises the following steps: step 1, preparing a reactor; step 2, preparing hydrolysis mother liquor; step 3, hydrolysis; step 4, suction filtration and washing; step 5, drying; and step 6, screening. According to the method for preparing the superfine high-purity germanium dioxide, the production efficiency of the superfine high-purity germanium dioxide can be effectively improved, and the superfine high-purity germanium dioxide is efficiently prepared by controlling the hydrolysis ratio, the acidity of hydrolysate, the germanium content, the temperature of the whole hydrolysis process, the hydrolysis rate and the stirring power.

The utility model relates to the technical field of chlorination reaction kettles, in particular to a chlorination kettle observation auxiliary device which comprises a kettle body, the interior of the kettle body is fixedly communicated with a sampling pipe, the inner wall of the sampling pipe is slidably connected with a piston head, and the interior of the piston head is rotatably connected with a threaded rod. The end, away from the piston head, of the threaded rod is fixedly connected with a fixing column. By arranging the sampling pipe, the threaded rod, the piston head, the fixing plate and other components, when the device is used, the threaded rod is controlled to rotate, so that the threaded rod moves downwards in the fixing plate, and meanwhile, the piston head is driven to move downwards together, when the piston head moves downwards, materials in the kettle body can flow into the sampling pipe, and at the moment, checking can be conducted; after checking is completed, the threaded rod is reversely rotated to enable the piston head to ascend, the piston head can push materials inside and on the inner wall of the sampling pipe to return to the kettle body, and the effects that the reaction effect of the materials can be observed according to needs and the materials are prevented from staying inside the sampling pipe are achieved.

The invention relates to the field of fine chemical engineering, and discloses a green process for preparing chloramine T by a continuous flow reactor. The method comprises the following steps: respectively pumping p-toluenesulfonamide, a sodium hydroxide solution and a sodium hypochlorite solution into a micro-channel mixer for instantaneous mixing, and carrying out chlorination reaction in a multi-stage temperature control tubular reaction unit; the concentration of free chlorine is detected on line at an outlet, and the flow rate of a chlorine source is dynamically adjusted through a PID algorithm, so that closed-loop control is realized; the reaction liquid is directly crystallized and separated to obtain the product without alkali wash. The system comprises a base solution and chlorine source conveying subsystem, a micro-channel mixer, a multi-stage reaction unit, an online monitoring module, a central controller and a crystallization unit. The side reaction is inhibited from the source, so that the free chlorine is less than or equal to 0.5 mg / L, the alkali washing step is omitted, the COD (Chemical Oxygen Demand) of the wastewater is reduced by more than 80%, the product purity is more than or equal to 99.5%, and the productivity is improved by 3 times.

The invention provides a method for recovering Si, C and TiO2 based on chlorinated waste salt water quenching slag, which comprises the following steps: sequentially carrying out water quenching dissolution, precipitation separation and filter pressing dehydration treatment on chlorinated waste salt to obtain water quenching slag and supernate; adding a dilute acid solution into the water-quenched slag, dissolving, and adding a reducing agent for reaction to obtain slurry; carrying out solid-liquid separation on the slurry to obtain a solid material and filtrate; the filtrate is pumped into a boiling bed separator, the petroleum coke and TiO2 are intercepted by a medium material layer, clear liquid is discharged, then the medium material layer is subjected to backwashing regeneration, and the desorbed petroleum coke and TiO2 are subjected to graded enrichment by a hydrocyclone, so that petroleum coke slurry and TiO2 slurry are obtained. According to the method, TiO2, C and other resources in the water-quenched slag obtained after molten salt chlorination waste salt water quenching are recycled, and the technical problem that in the existing chlorination waste salt resourceful treatment process, Si, C, TiO2 and other resources in the water-quenched slag are wasted is solved.

The present invention relates to a process for producing molybdenum dioxide dichloride, which is a very efficient process that does not use hazardous chlorine gas and high reaction temperatures and enables the production of molybdenum dioxide dichloride in high yield without solvent.

The invention discloses a cyanide-free cadmium plating bath solution, a preparation method of the cyanide-free cadmium plating bath solution and application of the cyanide-free cadmium plating bath solution in cadmium plating. The cyanide-free cadmium plating bath solution comprises the following components according to the concentration: 50-70 g / L of cadmium chloride, 180-250 mL / L of an etidronic acid aqueous solution, 16-33 g / L of potassium sodium tartrate, 0.01-0.2 g / L of polyethylene glycol, 0.01-0.2 g / L of a brightener and 0.01-0.1 g / L of an additive HY. The method has the advantages that the bath solution is environment-friendly and non-toxic, wastewater treatment is simple, a plating layer is high in deposition speed, fine in crystallization and good in binding force, the problems that cyanide cadmium plating pollutes the environment, EDTA cadmium plating is poor in stability and the like are effectively solved, and the method has good application value and economic and social benefits.

The invention specifically discloses a lithium iron phosphate battery black powder recovery method. The method comprises the following steps: S100, carrying out defluorination pretreatment on lithium iron phosphate battery black powder; s200, introducing excessive chlorine into the defluorinated lithium iron phosphate battery black powder, and performing chloridizing roasting at a first preset temperature to obtain a low-temperature roasting product; s300, the low-temperature roasting product is subjected to water immersion dissolution, and filtrate containing lithium chloride and filter residues are obtained after filtering; s400, introducing excessive chlorine gas into the filter residues, performing chloridizing roasting at a second preset temperature, cooling after roasting is completed, and collecting condensate and residues; and S500, mixing the residues with hydrochloric acid or phosphoric acid, carrying out acid leaching washing, and filtering to obtain graphite. According to the lithium iron phosphate battery black powder recovery method, lithium and carbon in the battery black powder raw material can be effectively recovered, high-purity lithium chloride and graphite products are obtained, and the method has the advantages of being simple in process, few in product impurity and good in economic benefit.

The invention discloses an o-methylbenzyl chloride production process which comprises the following steps: S1, a chlorination section: pumping o-xylene into an evaporation kettle, heating, vaporizing the o-xylene in the kettle, enabling the vaporized o-xylene to enter a chlorination tower, introducing chlorine gas into the chlorination tower, and carrying out a chlorination reaction on the chlorine gas and rising o-xylene gas under the catalysis of visible light, the generated o-methylbenzyl chloride and o-dichlorobenzyl are in a liquid state and flow back into the evaporation kettle, the material crude benzyl in the kettle is transferred into a rectifying kettle, and hydrogen chloride gas generated by the reaction enters a hydrogen chloride absorption section. The supporting table, the feeding conveying belt, the discharging conveying belt and the rotatable transfer plate in the product tank conveying mechanism are matched with one another to form an efficient conveying system, after being placed on the feeding conveying belt, a finished product tank to be filled can be rapidly conveyed to the positions of the supporting table and the transfer plate, and through rotation of the transfer plate, the finished product tank to be filled can be rapidly conveyed to the supporting table and the transfer plate. And the finished product tanks can be accurately transferred to all stations, so that the conveying efficiency is greatly improved, and the manual carrying time and labor intensity are reduced.

Disclosed herein are methods and systems for the recovery of uranium from used fuel salts using nonaqueous chemistry without electrometallurgy techniques. The used fuel salts are maintained in a molten state in a chlorination chamber, and are then chlorinated for a period of time sufficient to convert at least some UCl3 into a different uranium chloride, thereby generating a uranium-containing gas phase. The uranium-containing gas phase is separated from the resulting residue, and is condensed for collection.

The invention relates to the technical field of supervision and control, in particular to a polyethylene chlorination reaction control system which comprises a hot-pressing time difference extraction module, a viscosity variable-speed recognition module, a chlorine pressure collaborative trend division module, a response centralized recombination module and a stirring amplitude management and control module. According to the method, a multi-source variable data structure is unified through period numbers, cooperative sections with consistent trend directions are constructed, response feature fragments in a continuous period are recognized by combining fluctuation frequency and adjustment amplitude feature extraction, the behavior boundary of each variable in the time dimension is unified, and the recognition precision of multi-variable abnormal evolution is improved; a regulation and control reference is established through trend classification and strength grading, structured expression and controllability analysis of periodic behaviors are realized, the matching between the regulation rhythm and the variable trend is enhanced, and a regulation and control strategy is enabled to have clear boundary recognition, period tracking and behavior intervention capabilities.