The invention relates to a method for rapidly dissolving a high-temperature
alloy, synchronously and efficiently separating
hafnium and recovering
nickel and
cobalt by using an electrolytic method, in particular to a method for promoting
electrochemical dissolution of the high-temperature
alloy, and a method for recovering
nickel and
cobalt products and
hafnium-containing enrichment by controlling an
ion competitive reduction sequence according to
reduction potential differences of different metals. The invention provides a method for rapidly dissolving high-temperature
alloy waste to recover
nickel and
cobalt resources and synchronously and efficiently separating
hafnium-containing enriched substances, and mainly aims at solving the problems that valuable
metal resources are difficult to recover due to the fact that high-temperature alloy is difficult to dissolve in an acid solution, and the process for treating the high-temperature alloy waste is complex and causes secondary
pollution to the environment. According to the method, a traditional long-process
recovery method is broken through, a unique alkaline region of a
cathode / solution interface in the acid solution is regulated and controlled by utilizing
metal reduction potential difference, the nickel-cobalt product is generated, meanwhile, the hafnium-containing enrichment is recovered, and the process flow is shortened. The method comprises the following steps: 1, respectively taking a high-temperature alloy and a
titanium sheet as an
anode and a
cathode of
electrolysis equipment, adjusting the pH value of an
electrolyte to a certain value, turning on a direct-current power supply, and regulating and controlling
electrolysis parameters to carry out
electrochemical dissolution; 2, performing
solid-liquid separation on a product in the electrolytic bath, and filtering to obtain a hafnium-containing enriched product; 3, separating the
cathode product from the cathode to obtain a nickel-cobalt product; and 4, washing the hafnium-containing enriched product and a cathode nickel-cobalt product.