606results about "Acid electrolytes" patented technology

A lead-acid battery comprising: at least one lead-based negative electrode; at least one lead dioxide-based positive electrode; at least one capacitor electrode; and electrolyte in contact with the electrodes; wherein a battery part is formed by the lead based negative electrode and the lead dioxide-based positive electrode; and an asymmetric capacitor part is formed by the capacitor electrode and one electrode selected from the lead based negative electrode and the lead-dioxide based positive electrode; and wherein all negative electrodes are connected to a negative busbar, and all positive electrodes are connected to a positive busbar. The capacitor electrode may be a capacitor negative electrode comprising carbon and an additive mixture selected from oxides, hydroxides or sulfates of lead, zinc, cadmium, silver and bismuth, or a capacitor negative electrode comprising carbon, red lead, antimony in oxide, hydroxide or sulfate form, and optionally other additives. The capacitor electrode may be used in asymmetric capacitors and batteries of other types.

In a solid polymer fuel cell series, various circumstances can result in the fuel cell being driven into voltage reversal. For instance, cell voltage reversal can occur if that cell receives an inadequate supply of fuel (for example, fuel starvation). In order to pass current during fuel starvation, reactions other than fuel oxidation may take place at the fuel cell anode, including water electrolysis and oxidation of anode components. The latter may result in significant degradation of the anode. Such fuel cells can be made more tolerant to cell reversal by promoting water electrolysis over anode component oxidation at the anode. This can be accomplished by incorporating a catalyst composition at the anode to promote the water electrolysis reaction, in addition to the typical anode electrocatalyst for promoting fuel oxidation.

A laminate includes an active material layer and a solid electrolyte layer bonded to the active material layer by sintering. The active material layer includes a crystalline first substance capable of absorbing and desorbing lithium ions, and the solid electrolyte layer includes a crystalline second substance with lithium ion conductivity. An X-ray diffraction analysis of the laminate shows that there is no component other than constituent components of the active material layer and constituent components of the solid electrolyte layer. Also, an all solid lithium secondary battery includes such a laminate and a negative electrode active material layer.

A battery comprises an acid electrolyte in which a compound provides acidity to the electrolyte and further increases solubility of at least one metal in the redox pair. Especially preferred compounds include alkyl sulfonic acids, amine sulfonic acids, and alkyl phosphonic acids, and particularly preferred redox coupled include Co3+ / Zn0, Mn3+ / Zn0, Ce4+ / V2+, Ce4+ / Ti3+, Ce4+ / Zn0, and Pb4+ / Pb0.

Systems and methods drawn to an electrochemical cell comprising a low temperature ionic liquid comprising positive ions and negative ions and a performance enhancing additive added to the low temperature ionic liquid. The additive dissolves in the ionic liquid to form cations, which are coordinated with one or more negative ions forming ion complexes. The electrochemical cell also includes an air electrode configured to absorb and reduce oxygen. The ion complexes improve oxygen reduction thermodynamics and / or kinetics relative to the ionic liquid without the additive.

The invention discloses a preparation method for commercial vanadium battery electrolyte. According to the preparation method, vanadium electrolyte is prepared by one step through a chemical method; the preparation method comprises the following steps: dissolving raw materials containing vanadium by using an alkali; adjusting a pH (Potential of Hydrogen) value by acid-alkali regulation; repeatedly precipitating the vanadium to remove impurity elements; then roasting to obtain an oxide of the vanadium; finally, dissolving the oxide of the vanadium by using concentrated sulfuric acid to obtain the vanadium electrolyte. With the adoption of the method, impurities including iron, chrome, silicon, manganese and the like can be removed effectively and a process flow is shortened; the vanadium yield is improved, the impurity content is reduced and the process flow is shortened; the product purity can also be improved. The preparation method for the commercial vanadium battery electrolyte has important meanings on production technology levels and market competitiveness of the vanadium electrolyte; the method has good economic benefits and social benefits.

A redox cell rebalance system is provided. In some embodiments, the rebalance system includes electrochemical cell and a photochemical cell. In some embodiments, the photochemical cell contains a source of ultraviolet radiation for producing HCl from H2 and Cl2 generated by the system. The HCl product may be collected or circulated back through the system for the rebalancing of electrolytes. A rebalance cell for use in a rebalance system is also provided. In some embodiments, the rebalance cell is the combination of an electrochemical cell and a photochemical cell. In some embodiments, a source of ultraviolet radiation is housed in the cathode compartment of the rebalance cell. In some embodiments, the source of ultraviolet radiation is used to effect the formation of HCl from H2 and Cl2 present in the rebalance cell. The HCl is dissolved in aqueous electrolytes contained in the rebalance cell, which can subsequently be circulated through a rebalance system for the rebalancing of redox cells.

The invention relates to an article comprising: a) one or more stacks of battery plates comprising one or more bipolar plates; b) located between each plate is a separator and a liquid electrolyte; further comprising one of more of the features: 1) c) the one or more stacks of battery plates having a plurality of channels passing transversely though the portion of the plates having the cathode and / or the anode deposited thereon; and d) i) one or more seals about the periphery of the channels which prevent the leakage of the liquid electrolyte into the channels, and / or posts located in one or more of the channels having on each end an overlapping portion that covers the channel and sealing surface on the outside of the monopolar plates adjacent to the holes for the transverse channels and applies pressure on the sealing surface of the monopolar plates wherein the pressure is sufficient to withstand pressures created during assembly and operation of electrochemical cells created by the stacks of battery plates; 2) c) a membrane comprising a thermoplastic polymer is disposed about the entire periphery of the edges of the stack of plates; 3) wherein the separator is in the form of a sheet having adhered to its periphery a frame; and 4) c) an integrated valve and integrated channel communicating with the valve.

The invention discloses a chargeable zinc ion battery, which comprises an anode, a cathode, isolating membrane arranged between the anode and the cathode, and electrolyte which contains the anion and the cation and has ionicconductivity, wherein the cathode adopts active materials which are mainly zinc elements, the active materials of the anode are oxide materials of manganese which can occlude and release zinc ions, the electrolyte is liquid or gel materials with ionicconductivity which adopts the soluble salt of zinc as solute and water as solvent, and the pH value of the electrolyte lies between 3 and 7. The battery has the characteristics of high capacity, chargeable property, long cycle life and the like. Proven by experiments, the chargeable zinc ion battery has excellent rate performance, reversible performance and cycle performance.

A metal-air semi-fuel cell is provided, preferably based on lithium anode and a fuel cell type air / oxygen electrode immersed in an aqueous neutral, alkali or acid solution. The lithium anode is comprised of the active metal and one or more separators protecting the anode from reacting with an aqueous solution. The outermost layer on the lithium electrode is a solid-state lithium-ion conducting glass-ceramic which is impervious to and stable towards aqueous solutions. The cathode is comprised of an air or oxygen fuel cell type electrode in contact with the aqueous solution. The lithium anode of this invention also can be replaced by other electroactive metals which react with water and acids, bases and neutral solutions, such as metals from Groups 1 and 2 of the Periodic Table of Elements in addition to Zn, Mg, and Al.

The present invention relates to fuel cells and components used within a fuel cell. Heat transfer appendages are described that improve fuel cell thermal management. Each heat transfer appendage is arranged on an external portion of a bi-polar plate and permits conductive heat transfer between inner portions of the bi-polar plate and outer portions of the bi-polar plate proximate to the appendage. The heat transfer appendage may be used for heating or cooling inner portions of a fuel cell stack. Improved thermal management provided by cooling the heat transfer appendages also permits new channel field designs that distribute the reactant gases to a membrane electrode assembly. Flow buffers are described that improve delivery of reactant gases and removal of reaction products. Single plate bi-polar plates may also include staggered channel designs that reduce the thickness of the single plate.

The present invention relates to fuel cells and components used within a fuel cell. Heat transfer appendages are described that improve fuel cell thermal management. Each heat transfer appendage is arranged on an external portion of a bi-polar plate and permits conductive heat transfer between inner portions of the bi-polar plate and outer portions of the bi-polar plate proximate to the appendage. The heat transfer appendage may be used for heating or cooling inner portions of a fuel cell stack. Improved thermal management provided by cooling the heat transfer appendages also permits new channel field designs that distribute the reactant gases to a membrane electrode assembly. Flow buffers are described that improve delivery of reactant gases and removal of reaction products. Single plate bi-polar plates may also include staggered channel designs that reduce the thickness of the single plate.

A power cell (100A) has an electrolyte that includes a reodox pair comprising cerium. The electrolyte in preferred cells is an acid electrolyte that comprises a element ion complexed by an organic acid or a chelating agent, and contemplated electrolytes may further include a compound that reduces the hydrogen overpotential. Where the power cell comprises a plurality of cells (100B), preferred configurations may include glassy carbon as bipolar electrolytes.

A battery (100) comprises a cell having a cathode compartment (120) that includes an element that is oxidized during charging of the battery (100), wherein the oxidized element forms a salt with an acid and thereby increases the H+ concentration in the cathode compartment (120) sufficient to promote an H+ flux into the anode compartment (110) across the separator (130), wherein the H+ flux across the separator (130) is sufficient to disintegrate a zinc dendrite proximal to the separator (130).

A non-liquid electrolyte containing electrochemical cell which operates efficiently at room temperature. The cell includes (a) a non-liquid electrolyte in which protons are mobile, (b) an anode active material based on an organic compound which is a source of protons during cell discharge, or an anode active material including a metal whose cation can assume at least two different non-zero oxidation numbers and (c) a solid cathode including a compound which forms an electrochemical couple with the anode. Anode and cathode active materials can be chosen so that the cell has the feature that the electrochemical reactions at the anode and cathode are at least partially reversible. An important feature of the cell is that no thermal activation is required for its operation, therefore, the cell efficiently operates under ambient temperatures.

A load leveling battery (122) comprising an electrolyte that includes a cerium zinc redox pair wherein preferred electrolytes are acid electrolytes, and most preferably comprise methane sulfonic acid. Contemplated load leveling batteries (122) have an open circuit voltage of at least 2.4 Volt per cell. Such batteries are useful at power grid substations (120) and commercial and industrial applications were large amounts of power are used. Preferred capacity is at least 100,000 kWh, more preferably 250,000 kWh.

The disclosure describes compositions and methods for producing a change in the voltage at which hydrogen gas is produced in a lead acid battery. The compositions and methods relate to producing a concentration of one or more metal ions in the lead acid battery electrolyte.

The present invention relates generally to the production of a vanadium electrolyte, including a mixture of trivalent and tetravalent vanadium ions in a sulphuric acid solution, by the reactive dissolution of vanadium trioxide and vanadium pentoxide powders, the surface area and particle size characteristics being controlled for complete reaction to produce the desired ratio of V(III) to V(IV) ions in the solution. The solution may be suitable for direct use in the vanadium redox battery, or the solution can provide an electrolyte concentrate or slurry which can be reconstituted by the addition of water or sulphuric acid prior to use in the vanadium redox battery.

A lead-acid battery comprising:at least one lead-based negative electrode;at least one lead dioxide-based positive electrode;at least one capacitor electrode; andelectrolyte in contact with the electrodes;wherein a battery part is formed by the lead based negative electrode and the lead dioxide-based positive electrode; and an asymmetric capacitor part is formed by the capacitor electrode and one electrode selected from the lead based negative electrode and the lead-dioxide based positive electrode; and wherein all negative electrodes are connected to a negative busbar, and all positive electrodes are connected to a positive busbar.The capacitor electrode may be a capacitor negative electrode comprising carbon and an additive mixture selected from oxides, hydroxides or sulfates of lead, zinc, cadmium, silver and bismuth, or a capacitor negative electrode comprising carbon, red lead, antimony in oxide, hydroxide or sulfate form, and optionally other additives. The capacitor electrode may be used in asymmetric capacitors and batteries of other types.

A battery (100B) comprises an electrolyte in which a first element forms a redox pair with a second element, wherein the battery (100B) is charged at a voltage sufficient to plate the first element at the anode (122B) and wherein the voltage is insufficient to plate the second element on the anode (122B). Preferred batteries include secondary batteries comprising a mixed electrolyte that includes a redox pair formed by a first element and a second element.

A battery includes a cathode, an anode, and an aqueous electrolyte disposed between the cathode and the anode and including a cation A. At least one of the cathode and the anode includes an electrode material having an open framework crystal structure into which the cation A is reversibly inserted during operation of the battery. The battery has a reference specific capacity when cycled at a reference rate, and at least 75% of the reference specific capacity is retained when the battery is cycled at 10 times the reference rate.

The present invention provides electrolyte that can suppress reduction of battery efficiencies and capacities with increased cycles of charge / discharge of the battery, a method for producing the same, and a redox flow battery using the same electrolyte. The redox flow battery uses the electrolyte having a NH4 content of not more than 20 ppm and a relation of Si concentration (ppm)×electrolyte quantity (m3) / electrode area (m2) of less than 5 ppm·m3 / m2. By limiting a quantity of contaminants in the electrolyte, a clogging of carbon electrodes to cause reduction of the battery performances with increased charge / discharge operations can be suppressed.

Carbon materials having low gassing properties and electrodes and electrical energy storage devices, especially lead-acid batteries, comprising the same are provided.

The invention relates to an article comprising; a) one or more stacks of battery plates comprising one or more bipolar plates; b) located between each plate is a separator and a liquid electrolyte; further comprising one of more of the features: 1) c) the one or more stacks of battery plates having a plurality of channels passing transversely though the portion of the plates having the cathode and / or the anode deposited thereon; and d) i) one or more seals about the periphery of the channels which prevent the leakage of the liquid electrolyte into the channels, and / or posts located in one or more of the channels having on each end an overlapping portion that covers the channel and sealing surface on the outside of the monopolar plates adjacent to the holes for the transverse channels and applies pressure on the sealing surface of the monopolar plates.

The present invention provides electrolyte that can suppress reduction of battery efficiencies and capacities with increased cycles of charge / discharge of the battery, a method for producing the same, and a redox flow battery using the same electrolyte. The redox flow battery uses the electrolyte having a NH4 content of not more than 20 ppm and a relation of Si concentration (ppm)xelectrolyte quantity (m<3>) / electrode area (m<2>) of less than 5 ppm.m<3> / m<2>. By limiting a quantity of contaminants in the electrolyte, a clogging of carbon electrodes to cause reduction of the battery performances with increased charge / discharge operations can be suppressed.

A method for preparing a redox flow battery electrolyte is provided. In some embodiments, the method includes the processing of raw materials that include sources of chromium ions and / or iron ions. The method further comprises the removal of impurities such as metal ions from those raw materials. In some embodiments, an ammonium salt may be used to remove metal impurities from an aqueous mixture of chromium ions and / or iron ions. Further provided is a redox flow battery comprising at least one electrolyte prepared from the above-identified methods.

A composition comprising a lead species (e.g., leady oxide, porous metallic lead, metallic lead, lead sulfate) a carbon material and an expander are described herein. Also disclosed are electrodes, devices (e.g., batteries) including the same. Methods for making and using the disclosed novel composition are also detailed herein.

The present invitation discloses a rechargeable zinc ion battery, in which anodic zinc will be electrochemically dissolved as Zn2+ions, diffuses to the cathodic electrode / electrolyte interface through the electrolyte, and zinc ions are subsequently intercalated into manganese dioxide during discharging. In charging, above-mentioned process will be reverse. The rechargeable zinc ion battery comprises a cathode formed from a compressed mixture of alpha manganese dioxide particles, electrically conductive particles and a binder; a zinc anode separated from cathode; an aqueous electrolyte contains zinc ions in which the pH value may be controlled between 4 and 7.

Highly anion resistant electrocatalysts suitable for catalyzing an oxygen reduction reaction (ORR) and methods of synthesizing the same are provided. The catalysts contain a transition metal, a heteroatom, and carbon. Preferred catalysts include N as the heteroatom and Fe as the transition metal, with active sites having Fe—N4 stoichiometry (FexNyCz) as part of a metal organic framework (MOF) or sequestered within a MOF. Electrocatalysts further including Fe nanoparticles (FeNPs) are also provided. The catalysts described herein are applicable in the preparation of oxygen decoupled cathodes (ODC) for chlorine evolution processes such as in chlor-alkali cells or HCl electrolyzers. The catalysts are also useful in preparing ODC for use in fuel cells, including phosphoric acid fuel cells.

Disclosed is a solution for an electrochemical process, the solution containing a sulfonic acid and having a low concentration of sulfur compounds, either low or high valence, that are susceptible to reduction and which is intended for use in electrodeposition, batteries, conductive polymers and descaling processes.