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384 results about "Glassy carbon" patented technology

Glass-like carbon, often called glassy carbon or vitreous carbon, is a non-graphitizing, or nongraphitizable, carbon which combines glassy and ceramic properties with those of graphite. The most important properties are high temperature resistance, hardness (7 Mohs), low density, low electrical resistance, low friction, low thermal resistance, extreme resistance to chemical attack and impermeability to gases and liquids. Glassy carbon is widely used as an electrode material in electrochemistry, as well as for high temperature crucibles and as a component of some prosthetic devices, and can be fabricated as different shapes, sizes and sections.

Method for quickly detecting lead and cadmium by adopting scanning anodic stripping voltammetry

The invention discloses a method for quickly detecting lead and cadmium by adopting scanning anodic stripping voltammetry. The method comprises the following steps: a sample to be tested is prepared; lead or cadmium standard liquid is prepared; a three-electrode system consisting of glassy carbon electrodes plated with mercury films, platinum wire counter electrodes and Ag/AgCl reference electrodes is assembled; parameters are set and the scanning anodic stripping voltammetry is adopted to respectively implement parallel determination for current values between working electrodes and reference electrodes of each standard liquid solution until the relative standard deviation of readings is not more than 5%; lead and cadmium heavy metals of the sample are measured through detecting the current values between the working electrodes and the reference electrodes; a working station automatically calculates to obtain detecting results through automatically searching peaks to determine each curve peak area. The detecting method has the advantages of high sensitivity, good accuracy, reduction of mercury pollution, high electrode stability and good reproducibility, and can be applied to the detection of the heavy metals of lead and cadmium with conventional trace and ultratrace.
Owner:TIANJIN UNIVERSITY OF TECHNOLOGY

Protein molecular imprinting polyion liquid membrane electrochemical transducer

The invention relates to the technical field of electro-analytical chemistry and protein identification transducers, and discloses a synthesizing method of functionalized ionic liquid and a preparation method and application of a molecular imprinting electrochemical transducer composed of the functionalized ionic liquid, carboxylation multiwalled carbon nanotubes and glassy carbon electrodes. The preparation method of the molecular imprinting electrochemical transducer comprises the steps that the polymerizable amino-functionalized ionic liquid is used as a functional monomer, BSA is used as template protein, N, N'-methylene bisacrylamide is used as a cross-linking agent, an oxidation-reduction system composed of ammonium persulfate and TEMED is used as an initiator, after polymerization, a molecularly imprinted polymer film is formed on the surfaces of the glassy carbon electrodes decorating the carboxylation multiwalled carbon nanotubes, and then the template protein is eluted to obtain the molecular imprinting electrochemical transducer which can identify template protein in a specific mode. The molecular imprinting electrochemical transducer has the advantages of being simple in preparation, low in material cost, high in selectivity, good in biocompatibility, and capable of being used for identifying and detecting protein in aqueous solution.
Owner:SOUTH CENTRAL UNIVERSITY FOR NATIONALITIES

Core-shell type ultra-micro electrode prepared through coaxial electrostatic spinning and preparation method thereof

The invention relates to a preparation method and application of a core-shell type ultra-micro electrode. The core-shell structure ultra-micro electrode is obtained by preparing ultra-micro electrode fibers of a coaxial structure in a one-step mode through a coaxial electrostatic spinning method and then performing packaging. The coaxial structure comprises a core electrode base layer and one or two surface sensing layers. By the adoption of the one-step forming technology, the complex surface modification process of traditional ultra-micro electrodes (such as glassy carbon electrodes obtained after ablation treatment) is omitted, and the ultra-micro electrode with the diameter ranging from 40 nm to 6 micrometers can be prepared; due to the subsequent treatment temperature ranging from 70 DEG C to 150 DEG C, the structures and functions of organic functional components (such as biological protein and enzymes) in a modification layer of the ultra-micro electrode can be easily maintained, which is of great significance for the pluralistic design of the ultra-micro electrode. The ultra-micro electrode is used for detecting adenosine triphosphate (ATP), dopamine and adrenal hormones and is high in response speed and sensitivity, strong in anti-jamming capability and especially suitable for on-line rapid determination, particularly, real-time non-destructive determination of living cells.
Owner:JIANGXI SCI & TECH NORMAL UNIV

Process for producing fiber-reinforced silicon carbide composites

A process produces a fiber-reinforced silicon carbide composite. The resulting composite has a high toughness where bundles of a reinforcing fiber are densely covered with glassy carbon derived from a resin to avoid deterioration of the strength, and it can easily be produced even in complicated shapes. Specifically, a fiber-reinforced silicon carbide composite is produced by preparing a fiber prepreg containing a powdered silicon and a resin and molding the prepreg to yield a green body having a desired shape, or laminating a fiber prepreg containing a resin and a woven fabric prepreg containing a powdered silicon and a resin in alternate order, and molding the laminate to yield a green body having a desired shape; carbonizing the green body at 900° C. to 1350° C. in an inert atmosphere; impregnating the carbonized body with a resin; firing the impregnated body again at 900° C. to 1350° C. in an inert atmosphere; performing the resin impregnation-carbonization procedure one to five times; subjecting the carbonized composite to reaction sintering at a temperature of 1300° C. or more in vacuo or in an inert atmosphere to form open pores, and finally infiltrating molten silicon into the sintered body having open pores at a temperature of about 1300° C. to 1800° C. in vacuo or in an inert atmosphere.
Owner:NAT INST OF ADVANCED IND SCI & TECH

Preparation method of water hyacinth-Fe biochar and application of water hyacinth-Fe biochar

The invention provides a preparation method of water hyacinth-Fe biochar and application of the water hyacinth-Fe biochar. The preparation method comprises the following steps: taking water hyacinth as a raw material and cultivating the water hyacinth with plant solution for one month, so as to obtain water hyacinth enriching 4-64 mg.L<-1> of Fe; performing low pyrolysis on the Fe-enriched water hyacinth at the temperature of 500-900 DEG C in a nitrogen atmosphere, so as to prepare a series of Fe-loaded water hyacinth biochar with different concentrations. A result shows that the water hyacinth biochar is rough in surface and has a lumpy structure on the surface, and Fe in the biochar exists in forms of two oxides: Fe2O3 and Fe3O4. A glassy carbon rotating disk electrode modified by various biochar particles is utilized to explore the electrocatalytic reduction reaction of H2O2 in a neutral medium on different biochar catalysts according to a cyclic voltammetry scanning method, the exploration discovers that a water hyacinth biochar sample has the maximum reduction current value and is most excellent in electro-catalytic property on H2O2, and different scanning experiments also verifies that the water hyacinth biochar sample also has the potential property of energy storage.
Owner:CHINA THREE GORGES UNIV
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