The invention belongs to the technical field of
water environment detection, and particularly relates to a heavy
metal concentration and
water body flow velocity
synchronous detection method for a dispersed drain outlet, which is used for synchronously detecting the heavy
metal cadmium concentration and the
water body flow velocity. The core of the method comprises a three-
electrode sensing system consisting of a
working electrode coated with a
tungsten oxide film, a
reference electrode and a counter
electrode, and is assisted by an electrochemical
workstation, a
peristaltic pump, a
flow cell and a
signal processing module. The
cadmium concentration is accurately measured through the
square wave anodic stripping voltammetry, the flow velocity is synchronously detected through the open circuit potentiometry, dual-function detection is achieved through integration of the
square wave anodic stripping voltammetry and the open circuit potentiometry, synchronous in-situ detection of the
cadmium concentration and the
water body flow velocity is achieved, and errors caused by measurement position differences are effectively eliminated. The result shows that the cadmium concentration and the
dissolution peak current are in a
linear relationship, and the
water flow velocity logarithm and the open-circuit potential are in a
linear relationship. The method designed by the invention is suitable for scattered and small
sewage draining exit scenes, and effectively solves the problems of time consumption and equipment redundancy of traditional step-by-
step detection. In an actual
water sample test, the cadmium
recovery rate is 80%-120%, the flow
velocity measurement RSD is smaller than or equal to 5.0%, high reproducibility, stability and anti-interference performance are achieved,
technical support is provided for real-time
online evaluation of the total heavy
metal emission amount, and the method has remarkable
environmental monitoring application potential.