3129 results about "Green body" patented technology

The invention discloses a carbon composite ceramic linear resistor and a preparation method thereof, and belongs to the technical field of power electronic components. The invention provides a preparation method of a carbon composite ceramic linear resistor, which comprises the following steps: uniformly mixing bentonite, silicon carbide and nano carbon black to obtain powder, uniformly mixing the powder and ethanol, drying, adding a binder solution, and carrying out green body forming to obtain a green body; carrying out heat preservation on the green body at 1150-1300 DEG C in a nitrogen-containing gas atmosphere to obtain a sample; and polishing the sample, and spraying aluminum to obtain the carbon composite ceramic linear resistor. According to the method for preparing the carbon composite ceramic linear resistor, the resistivity of the material can be reduced, and the thermal shock resistance of the ceramic resistor can be improved.

Disclosed in the present invention is a ceramic green body machining device, comprising a sedimentation tank, a supporting platform, a height-adjustment platform and a cleaning platform. According to the present invention, during use, when a counterweight plate is close to a distal end of a sweeping frame and a liquid dispensing chamber is fully loaded, the weight of a press block area exceeds the torsion of a torsion spring, and the liquid dispensing chamber and the press block would fall down from an accommodation groove until the liquid dispensing chamber and the press block are perpendicular to the accommodation groove; in this case, a cleaning liquid is sprayed from one side of the liquid dispensing chamber by means of a second spray head, thereby effectively rinsing an area to which a first spray head cannot spray; a polishing sand layer on an arc-shaped plate would be attached to a rough area on the surface of a ceramic green body and rotates along with the rotation of a mounting arm to rotationally grind the rough area, thereby improving ceramic green body manufacturing effects; and when a cooling liquid flows down from a contact area between the polishing sand layer and the surface of the ceramic green body, the cooling liquid cools the surface of the ceramic green body. The present invention is conducive to the discharging of dust generated in the grinding process and avoids cracking caused by excessive local drying of the surface of the ceramic green body.

The invention relates to the technical field of intelligent manufacturing, in particular to an HTCC ceramic defect automatic identification method based on industrial model assistance, which comprises the following steps: step 1, collecting sintering temperature gradient, lamination pressure and green body water content process parameters in the HTCC production process in real time; step 2, performing non-contact dielectric property scanning on the sintered HTCC substrate on a production line conveyor belt; 3, based on the coordinates of the dielectric abnormal region, controlling an annular polarization light source to inhibit the incident angle reflected by the metallization layer from irradiating the target region; 4, inputting the dielectric anomaly frequency band feature vector and the defect image texture feature in the step 3 into a cross-modal attention network to generate a fusion feature map; and 5, establishing an association mapping library of the defect type and the process deviation type. Through accurate real-time monitoring, intelligent defect identification and classification, automatic process adjustment and a continuously optimized feedback mechanism, the efficiency, quality and intelligent level of the ceramic production process are greatly improved.

The invention discloses a reaction-sintered silicon carbide setter plate and a preparation method thereof. The reaction-sintered silicon carbide setter plate product is obtained through powder granulation, compaction and reaction sintering. Wherein the silicon carbide powder of the four particle size sections is matched, the particle size sections are uniform, stacking is more reasonable, coarse particles form a frame, fine particles are filled among the coarse particles, the powder structure is compact in property, and the compactness of a green body obtained after blank pressing is guaranteed; and spray granulation is performed after ball milling, so that all the raw materials and auxiliary materials are uniformly mixed. The surface of the green body pressed by a set oil pressure mold is also provided with a concave-convex structure, so that the contact area between the load bearing plate and the bottom of the domestic porcelain is reduced, air circulation between the load bearing plate and the bottom of the domestic porcelain is increased, and adhesion is effectively avoided. The product has the advantages of long service life, high strength and fast heat conduction, solves the problems of low strength, low heat conductivity and short service life of mullite, and also solves the industrial pain point of adhesion of a reaction-sintered silicon carbide setter plate.

The invention discloses a preparation process of an aluminum oxide ceramic material, which comprises the following steps: S1, pretreatment of aluminum oxide powder: taking alpha-Al2O3 powder as a raw material, adding a dispersion medium, carrying out ball milling, transferring into an ultrasonic dispersion machine, dispersing, and further carrying out vacuum drying to obtain pretreated aluminum oxide powder; s2, chemical activation treatment: weighing pretreated aluminum oxide, magnesium oxide, nano silicon dioxide, calcium oxide, zirconium dioxide, titanium dioxide and modified nano silicon carbide in parts by weight, mixing, sequentially adding a dispersing agent absolute ethyl alcohol and a KH550 silane coupling agent, stirring at a high speed, adding a polyvinyl alcohol binder, and continuously stirring to obtain ceramic slurry; s3, sieving the ceramic slurry, filling the ceramic slurry into a mold, and performing isostatic pressing to obtain a ceramic green body; and S4, putting the ceramic green body into a box-type sintering furnace, sintering step by step, and cooling to room temperature along with the furnace to obtain the aluminum oxide ceramic material. The prepared aluminum oxide ceramic material has high compactness, excellent dielectric strength and mechanical property, low energy consumption and great application potential.

The present invention relates to the technical field of porous conductive ceramics. Disclosed are a selective laser sintering porous conductive ceramic 3D printing consumable and a preparation method. The selective laser sintering porous conductive ceramic 3D printing consumable comprises the following components in percentage by weight: 30-60 wt% of modified silicon carbide powder, 10-40 wt% of conductive phase powder, 10-30 wt% of a polymer binder, and 0.1-5 wt% of a lipid. The selective laser sintering porous conductive ceramic 3D printing consumable is obtained by means of a direct mixing ball milling method or a xylene solution mixed washing method. A porous conductive ceramic green body is printed by means of a laser 3D printer, and is subjected to thermal debinding and sintering to obtain a ceramic sintered part.

An ultrafine grain cemented carbide additive manufacturing method. WC-Co is used as a raw material, a crystal grain growth inhibitor is added, and a rare earth oxide is added as a reinforcing phase; paraffin and a trace amount of low-valence rare earth oxide powder are added, ball milling is carried out for coating cemented carbide powder, and oxygen control is carried out; the cemented carbide powder obtained by ball milling and an organic adhesive are loaded in a vacuum banbury mixer-granulator to prepare a printing feed, then a green body is printed using fused deposition modeling (FDM), and finally, degreasing and two-step sintering are carried out on the green body to prepare ultrafine cemented carbide. By means of the combined effect of the components and process optimization design, the powder properties are regulated, the process range of vacuum banburying and granulation and additive manufacturing is widened, and the problems of pores, interlayer cracks, and oxygen absorption in a printed green body, and abnormal grain growth, oxidation decarburization, and the formation of brittle η-phase in a sintered sample are solved. The prepared ultrafine grain cemented carbide exhibits high relative density, is free of metallurgical defects, possesses excellent mechanical properties, and is suitable for large-scale and mass production.

The invention belongs to the technical field of ceramics, and discloses a preparation method of fracture-resistant and wear-resistant ceramics. The preparation method comprises the following steps: weighing the raw materials in parts by weight; the preparation method comprises the following steps: mixing 40 parts of potassium feldspar, 10 to 25 parts of albite, 1 to 10 parts of kaolin, 1 to 10 parts of serpentine, 5 to 25 parts of dolomite, 2 to 9 parts of nano zirconium oxide, 0.1 to 1 part of nano cerium oxide, 0.1 to 1 part of nano molybdenum disulfide, 0.1 to 0.8 part of silicon carbide fiber, 0.5 to 2.5 parts of polyethylene glycol, 0.1 to 0.6 part of fullerene trifluoromethyl derivative, 0.1 to 3 parts of sodium dodecyl sulfate, 0.1 to 2 parts of sodium tripolyphosphate and 10 to 60 parts of solvent to obtain slurry; and carrying out spray granulation to obtain a blank, carrying out compression molding to obtain a green body, and sintering to obtain the fracture-resistant and wear-resistant ceramic. The breaking strength of the breaking-resistant and wear-resistant ceramic can exceed 70 MPa, and the length of a grinding pit does not exceed 8.5 mm.

The invention provides a NiTiNb shape memory alloy and a preparation method thereof, and the preparation method specifically comprises the following steps: (1) uniformly mixing a Ni source, a Ti source and a Nb source to obtain mixed powder; (2) carrying out cold mold compression molding on the mixed powder to obtain an alloy green body; and (3) the green body is sintered, and the NiTiNb shape memory alloy is obtained. According to the preparation method disclosed by the invention, the NiTiNb alloy with uniform components and high density can be prepared by introducing Nb source powder for sintering and regulating and controlling sintering temperature parameters, so that the strength of the NiTiNb alloy is improved to 1600 MPa or above, the density of the alloy is improved to 92%, the compression strength is higher than 2000 MPa, the fracture strain is higher than 30%, the 8% tensile recovery rate is higher than 50%, and the mechanical property of the alloy is greatly improved.

A method for improving the density of a copper alloy part comprises the following steps that forming is conducted, specifically, dry copper alloy powder is selected and laid layer by layer through a binder spraying 3D printing technology, and a binder is selectively sprayed through a slice pattern of the part till a 3D printing model is completed; curing is conducted, specifically, the printed 3D printing model is subjected to thermocuring, and after thermocuring, powder cleaning is conducted to obtain a copper alloy green body; degreasing: degreasing the copper alloy green body in a vacuum degreasing furnace to obtain a degreased green body; and sintering is conducted, specifically, the degreased blank is subjected to sectional type sintering and then cooled to the room temperature along with a furnace, and the copper alloy part is obtained. After the copper alloy powder is subjected to jet printing forming through a binding agent, under the vacuum thermocuring process, a printed model has certain strength, and oxidation cannot be generated; the binder is effectively removed through vacuum degreasing, the quality and performance of the subsequent sintering process are guaranteed, and the compactness of the part is remarkably improved through segmented sintering and furnace cooling.

The invention belongs to the technical field of building materials, and particularly relates to a preparation method of a high-strength sintered tile. The preparation method of the high-strength sintered tile comprises the following steps: (1) crushing green body raw materials, sieving, adding water, carrying out ball milling, and carrying out spray drying to obtain powder; (2) performing compression molding on the powder obtained in the step (1) to obtain a green body; drying the green body to obtain a tile blank; (3) coating the tile blank obtained in the step (2) with glaze, and drying to obtain a glazed tile blank; and sintering the glazed tile blank, and then cooling to room temperature to obtain the ceramic tile. The high-strength sintered tile obtained by the preparation method is high in bending strength, high in thermal stability, low in water absorption and good in freezing resistance, and has a wide application prospect.

The invention relates to the technical field of ceramics, in particular to a high-temperature-resistant glaze, a ceramic material and application of the ceramic material in a tea set, and the high-temperature-resistant glaze is prepared from the following raw materials in parts by weight: 30-35 parts of potassium feldspar, 15-20 parts of calcined talc, 8-12 parts of nano-zinc oxide, 10-15 parts of an enhanced additive and 5-8 parts of petalite. According to the high-temperature-resistant glaze disclosed by the invention, the potassium feldspar and the calcined talc are matched with the nano zinc oxide, the enhanced additive and the petalite to prepare the high-temperature-resistant glaze, and meanwhile, the albite, the illite, the tourmaline and other raw materials are matched with the strength stabilizer doped with the nano boric oxide to be blended and subjected to wet ball milling to prepare a green body; through joint cooperation and improvement of the strength stabilizer doped with nano boron oxide in the green body and the strength additive in the glaze, the high temperature resistance, the antibacterial property and the fracture toughness of the obtained product are harmoniously improved, and the scrubbing-resistant stability effect of the product is remarkable.

The invention relates to a preparation method of a high-precision gel injection pressureless sintering silicon carbide ceramic water jet cutter sand pipe, which comprises the following steps: pouring premixed liquid into a mold, and curing to obtain a green body; the inner mold is taken out of the cured blank, then the outer mold and the blank are put into a polyethylene glycol solution to be dried, the blank shrinks when being dried in the polyethylene glycol solution, and demolding is completed; drying the demolded green body on drying equipment, and carrying out vacuum heating to obtain a dried green body; and carrying out pressureless sintering on the dried blank to obtain the silicon carbide ceramic water jet cutter sand pipe. The premixed liquid comprises a monomer, a cross-linking agent, a dispersing agent, a defoaming agent, modified silicon carbide powder, a sintering aid and tetramethylammonium hydroxide, and the modified silicon carbide powder comprises graphene composite silicon carbide and modified carbon nanotubes. The water jet cutter sand pipe has the effect of improving the product quality of the prepared water jet cutter sand pipe.

The invention discloses a metal soft magnetic powder core and a preparation method thereof.The preparation method comprises the steps that cold sintering is conducted, under the ultrasonic-assisted condition, warm-pressing is conducted on mixed powder containing modified iron powder and a release agent, and a metal soft magnetic powder core green body is obtained; wherein the modified iron powder comprises iron powder and a coating layer, the surface of the iron powder is coated with the coating layer, and the coating layer comprises copper, hydrated ferric oxalate, hydrated cupric oxalate and iron oxide; and heat treatment is conducted, specifically, the metal soft magnetic powder core green body is subjected to heat treatment under the oxygen-containing condition, and the metal soft magnetic powder core is obtained. Ultrasonic assistance is introduced when the modified iron powder is subjected to cold sintering, and a mixed insulation coating layer of ferric oxide and copper oxide can be generated on the surfaces of powder particles in situ during heat treatment, so that the compactness, the strength, the resistivity and the magnetic conductivity of the magnetic core are improved while the pressing force is reduced and the pressing efficiency is improved.

The invention relates to the technical field of high-performance ceramic preparation, in particular to a partial pressure sintering method of a silicon nitride ceramic chip, which comprises the stages of charging, negative pressure degreasing, partial pressure sintering, pressure sintering and rapid cooling: during charging, charging a green body containing a silicon nitride raw material and Y2O3 and MgO auxiliaries into a furnace, and exhausting air; in the negative-pressure degreasing stage, low-pressure nitrogen and staged heating are used for promoting formation and volatilization of an auxiliary liquid phase; volatile matters are released through stepped nitrogen partial pressure in the partial pressure stage; in the pressurizing stage, gradient increase of pressure from low pressure to 35 bar is achieved through phase change buffering, high-temperature densification, ultra-high-temperature homogenization and slow cooling, and precise pressure control is achieved by combining dynamic pressure-static pressure mode switching; according to the method, the problems of cracking, uneven density and the like of a traditional process are effectively solved, the ceramic chip yield and the dimensional precision are improved, the microstructure and the mechanical property are optimized, the high-temperature applicability and the thermal property are enhanced, meanwhile, the use amount of auxiliaries is reduced, energy consumption is reduced, and practicability and economical efficiency are achieved.

The invention discloses a preparation method of a multilayer co-fired ceramic disc of an electrostatic chuck, and belongs to the technical field of electrostatic chucks, and the preparation method comprises the following steps: S1, preparing organic suspension ceramic slurry with certain viscosity and uniform dispersion; s2, the ceramic slurry is manufactured into a ceramic green sheet with a certain thickness in a tape casting mode; s3, various holes are formed in the ceramic green sheet; s4, preparing metal electrode slurry; s5, metal conduction slurry is filled in the interconnection conduction holes of the green body sheet in a hole filling mode, and an adsorption electrode layer, a heating electrode layer, a parallel electrode layer and an interconnection conduction Pad are manufactured in a silk-screen printing mode; s6, green body blocks are manufactured; s7, laminating together by using a laminating machine in a positioning and laminating manner; s8, the laminated green ceramic plates are placed in a debinding furnace for glue discharging; and S9, performing high-temperature sintering in a high-temperature sintering furnace to obtain the ceramic.

Preparation methods for multi-sheet porous ceramic matrices (10, 20, 30, 40) and an atomization core thereof. The preparation method for the multi-sheet porous ceramic matrices (10, 20, 30, 40) comprises: (1) the preparation of ceramic powders, involving: weighing a plurality of groups of components in parts by weight, comprising 25-55 parts of an aggregate, 5-40 parts of a pore former, 5-19 parts of a sintering aid, and 5-35 parts of a powder dispersing agent; (2) the preparation of casting ceramic slurries, involving: weighing a plurality of groups of components in parts by weight, comprising 40-65 parts of each group of ceramic powder, 30-50 parts of a solvent, 0.1-3 parts of a slurry dispersing agent, 1-8 parts of a plasticizer, and 1-10 parts of a binder; (3) the preparation of ceramic green bodies, involving: respectively making the plurality of groups of casting ceramic slurries into a plurality of groups of sheet-like ceramic green bodies by means of a casting process; and (4) the preparation of multi-sheet porous ceramic matrices (10, 20, 30, 40), involving: vertically stacking a plurality of ceramic green bodies of different groups and / or the same group in sequence and then laminating same into an integral body, then feeding same into a furnace for de-binding and sintering, and finally cutting same into required shapes to obtain the multi-sheet porous ceramic matrices (10, 20, 30, 40).

The invention discloses a wear-resistant and mildew-proof ceramic tile which comprises a green body and a glaze layer attached to the green body, and the wear-resistant and mildew-proof ceramic tile is obtained by coating the surface of the green body with a modified interface agent and then glazing, wherein the glaze layer is prepared from the following raw materials in parts by weight: 40 to 50 parts of silicon dioxide, 30 to 35 parts of aluminum oxide, 15 to 20 parts of modified titanium dioxide, 6 to 10 parts of barium carbonate, 6 to 10 parts of mullite, 5 to 8 parts of silver-loaded zirconium phosphate, 4 to 8 parts of potassium carbonate, 4 to 8 parts of sodium carbonate, 3 to 7 parts of limestone, 3 to 5 parts of sodium borate, 2 to 4 parts of zinc oxide and 0.5 to 1 part of sodium tripolyphosphate. According to the ceramic tile, the modified interface agent with specific composition is introduced between the ceramic tile green body and the glaze layer, modified titanium dioxide and inorganic components (such as aluminum phosphate, aluminum acetylacetonate and tetrapropyl zirconate) in the interface agent form oxides in the sintering process, and the interface bonding strength is remarkably enhanced through physical occlusion; and the long-term wear resistance and mildew resistance of the ceramic tile glaze layer are improved.

The invention discloses a samarium cobalt permanent magnet and a preparation method and application thereof. The preparation method comprises the following steps: (1) carrying out crushing and jet milling on an alloy ingot formed by raw materials required by the samarium-cobalt permanent magnet to obtain first alloy fine powder with D50 of 4-6 microns; (2) 15-30 wt% of the first alloy fine powder is taken out, then the taken-out first alloy fine powder is subjected to ball milling, and second alloy fine powder with D50 being 0.5-1.2 microns is obtained; (3) the remaining first alloy fine powder and the second alloy fine powder obtained in the step (2) are mixed, and mixed powder is obtained; 4) carrying out orientation molding and isostatic pressing on the mixed powder to obtain a green body; and the green body is subjected to sintering, solid solution and aging treatment, and the samarium-cobalt permanent magnet is obtained. By adopting the preparation method disclosed by the invention, the bending strength of the samarium-cobalt permanent magnet can be obviously improved on the basis that the magnetic performance of the samarium-cobalt permanent magnet is not reduced basically.

The invention relates to the field of architectural ceramics, and discloses a curved marble tile and a hot bending process thereof.The curved marble tile comprises a green body layer, and the green body layer is prepared from, by mass, 64-69% of SiO2, 18-22% of Al2O3, 0.3-0.8% of Fe2O3, 0-1% of CaO, 0-1.2% of MgO, 3-4% of K2O, 2-4% of Na2O, 0-0.5% of TiO2 and 4-6% of L.O.I; 0.1-10% of aluminum dihydrogen phosphate is additionally added into the preparation raw materials of the green body layer. The aluminum dihydrogen phosphate is added into the raw materials of the green body layer, the proportion range of oxides in the raw materials for preparing the green body layer is regulated and controlled, the silicon content is properly reduced, the aluminum content is increased, and the contents of calcium, magnesium and potassium in the formula are increased, so that a relatively low firing environment temperature can be obtained; the green body adopted in the scheme does not crack in the hot bending and firing process.

The invention relates to the technical field of architectural ceramics, and discloses an antifouling matte archaized brick with antiskid performance and a preparation method thereof, the preparation method comprises the following steps: A, preparing a green body layer; b, applying ground glaze to the surface of the green body layer; c, applying anti-skid and anti-fouling matte glaze to the surface of the ground coat layer; d, firing in a kiln after drying; the anti-slip and anti-fouling matte glaze comprises anti-fouling matte glaze, anti-fouling wear-resistant dry particles and anti-slip dry particles, the anti-fouling wear-resistant dry particles are composed of particles with the mesh number larger than or equal to 200 and smaller than 250 and particles with the mesh number ranging from 250 to 325, and the anti-slip dry particles are composed of particles with the mesh number larger than or equal to 150 and smaller than 160, particles with the mesh number larger than or equal to 160 and smaller than 200, particles with the mesh number larger than or equal to 200 and smaller than 250 and particles with the mesh number ranging from 250 to 325. According to the antifouling matte archaized brick with the anti-skid performance, the glossiness, the antifouling performance, the hardness, the abrasion resistance, the color development performance and the anti-skid performance can be considered at the same time under the existing firing condition, and the use satisfaction degree of consumers on the archaized brick is improved.

The present disclosure relates to embodiments of a method for manufacturing a ceramic material comprising the steps of (a) homogenizing aluminum oxide, niobium pentoxide and solvent; (b) ultrasonicating the blend obtained in step (a); (c) adding an aliquot of the prepared suspension to the empty cavity of a mold, particularly between the polymeric mold and the metal mold; (d) immersing the mold into a coolant liquid-containing bath for sufficient time to ensure that all parts are completely frozen; (e) removing the ceramic body from the mold; (f) removing the solidified phase by means of sublimation hence obtaining a green tube; and (g) sintering the green tube, so as to obtain a solid structure. The present disclosure further relates to embodiments of a ceramic material and its use to manufacture a microfiltration membrane and / or a membrane support for fluid separation.

The invention discloses a temperature field real-time monitoring method and system based on special ceramic sintering, and relates to the field of temperature monitoring of special ceramic sintering, and the method specifically comprises the following steps: S1, processing a sensor array; s2, construction of multi-parameter data acquisition; s3, a temperature field reconstruction and prediction model based on multi-physics field coupling; and S4, temperature field real-time monitoring and abnormity early warning are carried out. According to the temperature field real-time monitoring method and system based on special ceramic sintering, the temperature sensor is preset in the green body, a three-dimensional temperature field reconstruction function is combined, discrete sensor node real-time temperature data can be converted into a continuous three-dimensional temperature field cloud picture, temperature distribution of the surface of the green body can be clearly presented, and the temperature field can be monitored in real time. And the temperature gradient change from the surface layer to the core can be more accurately restored, so that an operator can intuitively master the temperature state of the whole green body, the situation that the whole process is misjudged due to local data is avoided, and the comprehensiveness and accuracy of temperature field monitoring are fundamentally improved.

The invention belongs to the technical field of heating bodies, and particularly relates to a method for preparing a sheet-shaped heating body. The preparation method comprises the following steps: stirring and dissolving lanthanum nitrate, strontium nitrate, manganese nitrate hexahydrate and a solvent to obtain a metal salt solution; preparing the metal salt solution into a precursor, wherein the precursor is a precursor solution or precursor sol; and carrying out tape casting and drying on the precursor to obtain a biscuit sheet, and carrying out glue removal treatment and sintering on the biscuit sheet to obtain the sheet-shaped heating body. According to the preparation method, a precursor system is optimized, the dispersion stability of the precursor is improved, casting, drying and sintering processes are matched, the problem of powder agglomeration is solved, the defects of green bodies are reduced, the drying shrinkage rate of green body pieces in the preparation process is reduced, the surface roughness is reduced, the stability and heat output uniformity of a heating body are improved, and the compactness is improved.

The invention discloses a continuous rotary discharging ceramic green body rolling forming device, and relates to the technical field of ceramic green body rolling forming, the continuous rotary discharging ceramic green body rolling forming device specifically comprises a rolling frame, a transverse driving table and a vertical driving table, the transverse driving table is installed at the top of the rolling frame, and the vertical driving table is installed at the top of the transverse driving table; the top of the vertical driving table is slidably connected with a sliding base plate. Through the 120-degree intermittent rotation design of the rotary table, circulating switching of the three stations of blank adding, rolling forming and discharging is achieved, the neutral position period of shutdown blank taking in the traditional technology is eliminated, compared with the prior art, the ceramic blank rolling forming efficiency is improved by 20%, uninterrupted continuous production is achieved, meanwhile, traditional pressing contact type rolling forming is different, and the production efficiency is improved. A mechanical linkage mechanism, a cam, a U-shaped tilting rod and a toothed plate are adopted to automatically control lifting and rotation of a female die, and a driving assembly is matched to drive a male die to synchronously rotate, so that the rolling precision is ensured.

The invention belongs to the technical field of silicon nitride ceramic preparation, and particularly relates to a method for preparing silicon nitride ceramic through lifting type LCD photocuring technology 3D printing, and the method comprises the following steps: carrying out oxidation pretreatment on silicon nitride powder; mixing a sintering aid silicon nitride powder to obtain mixed powder; mixing the mixed resin, a reactive diluent, a photoinitiator and a coloring agent to obtain photosensitive resin; mixing and ball-milling a dispersing agent, the mixed powder and photosensitive resin to obtain light-cured ceramic slurry; 3D printing is conducted on the photocuring ceramic slurry through a lifting type LCD photocuring technology, and a ceramic green body is obtained; dumping the ceramic body to obtain a ceramic green body; sintering the ceramic green body to obtain the silicon nitride ceramic. Compared with the prior art, the problems of low curing depth, curing efficiency and precision of the silicon nitride ceramic slurry formed by photocuring in the prior art are solved. According to the scheme, the silicon nitride ceramic is formed by using the lifting type LCD printing technology, so that the performance of the ceramic is ensured, the production efficiency is improved, and the production cost is reduced.

The invention belongs to the field of synthesis of inorganic non-metallic materials, and particularly relates to an equimolar-ratio seven-element high-entropy oxide and a preparation process thereof. The preparation process comprises the following steps: putting seven oxide powder Al2O3, Y2O3, TiO2, ZrO2, NiO, CuO and CeO2 into a ball milling tank according to a molar ratio of 1: 1: 2: 2: 2: 2: 2: 2, adding absolute ethyl alcohol and zirconium oxide grinding balls, performing ball milling in a ball mill, and fully drying and sieving after ball milling to obtain mixed powder; carrying out tabletting treatment on the mixed powder to obtain a to-be-sintered green body; and putting the to-be-sintered green body into an alumina crucible, and putting the alumina crucible into a microwave oven for microwave sintering. According to the method, the equimolar-ratio seven-element high-entropy oxide (AlYTiZrNiCuCe) Ox with good solid solution is obtained, the crystallinity and element uniformity of the seven-element high-entropy oxide are improved, all the raw materials react completely, meanwhile, the process efficiency is high, and energy consumption is low.

The invention discloses a method for preparing a light-transmitting gradient multicolor zirconium oxide material through photocuring, which comprises the following steps: preparing modified aluminum oxide which is formed by attaching a strontium element and a chromium element to the surface of aluminum oxide; preparing bottom-layer slurry, middle-layer slurry and upper-layer slurry from the zirconium-aluminum powder; the bottom layer slurry comprises zirconium aluminum powder and a coloring agent; the middle layer slurry comprises zirconium-aluminum powder, a light-transmitting auxiliary agent and a coloring agent; the upper-layer slurry comprises zirconium-aluminum powder, a light-transmitting auxiliary agent and a coloring agent; preparing a bottom layer green body by using the bottom layer slurry through 3D printing by using the photocuring slurry, preparing a middle layer green body on the surface of the bottom layer green body by using the middle layer slurry, and preparing an upper layer green body on the surface of the middle layer green body by using the upper layer slurry, so as to obtain a zirconium oxide material green body; the light-transmitting gradient multicolor zirconia material with gradient light transmission and gradient color is directly prepared through 3D printing, the color of the light-transmitting gradient multicolor zirconia material is closer to that of real teeth, and the strength and toughness are not reduced.

The invention relates to the technical field of rock plates, and particularly discloses a microcrystal colored crystal rock plate and a production process thereof, and the production process comprises the following steps: S1, cooling a pressed green body, and then spraying ground glaze; s2, a pattern layer is printed on the ground coat layer in an ink-jet mode, digital glue is printed after positioning, colored crystal dry particles are applied, drying is carried out after redundant dry particles are removed, transparent microcrystal dry particles are applied after fixing protection glue is sprayed, and drying is carried out after fixing protection glue is sprayed; and S3, polishing after firing. The rock plate has diamond-like gloss through the high refractive index of the colored crystal particles, the microcrystal dry particles can achieve fine texture and high glossiness, and the fixing protection glue is applied to the microcrystal dry particles and the colored crystal dry particles, so that the effect of fixing the dry particles can be achieved, and the wear resistance and the antifouling property can be improved.

The invention relates to the technical field of ceramic substrates, in particular to a ceramic substrate blank powder coating and sintering process. Comprising the following steps: step 1, uniformly stirring boron nitride powder, terpilenol, ethyl cellulose, butyl benzyl phthalate and phosphate, and grinding to obtain coating powder; step 2, printing powder on the surface of the green body by using a silk-screen printing technology to form a powder pattern; a powder coating green body is obtained; step 3, stacking N powder-coated green bodies to obtain laminated green bodies; 4, the laminated green body is subjected to glue discharging sintering and sand blasting in sequence; and obtaining the ceramic substrate.