The invention relates to the technical field of functional material manufacturing, and discloses a
polymerization-induced self-
assembly method and device based on
laser cavitation and photo-
initiation compositing, the method adopts focused
laser pulse to act on a solution containing a piezoelectric
monomer, a
chain transfer agent and a
photoinitiator, a predetermined position synchronously initiates photochemical
polymerization, and
cavitation bubbles are induced. And the
cavitation bubbles collapse the shock
waves to enable the new
polymer molecular chain to be oriented into a piezoelectric structure and excite the new
polymer molecular chain to generate a charge
signal. A high-sensitivity sensor collects charge
time response waveforms, controls center decoupling parameters, compares the parameters with a target, and performs closed-loop
feedback control on subsequent
laser parameters; the device can comprise a laser, a
light spot shaping device, a lens group, a constant-temperature water bath box, a sealed container, a target substrate, a three-dimensional moving device, a high-sensitivity charge sensor, a control center, a controller A and a controller B. According to the method, material manufacturing, structure induction and performance in-situ characterization are integrated, and accurate and point-by-point manufacturing of the
functionally graded material is achieved.