2486 results about "Cobalt" patented technology

The invention discloses a 500MPa-grade supercritical CO2 corrosion-resistant pipeline coil plate and a manufacturing method thereof, and the 500MPa-grade supercritical CO2 corrosion-resistant pipeline coil plate comprises the following chemical components: 0.05 to 0.10 percent of C, 0.6 to 0.9 percent of Si, 1.50 to 1.70 percent of Mn, less than or equal to 0.010 percent of P, less than or equal to 0.002 percent of S, 0.10 to 0.30 percent of Cr, 0.35 to 0.45 percent of Mo, 0.03 to 0.05 percent of Nb, 0.01 to 0.03 percent of Ti, 0.02 to 0.05 percent of Al, 0.20 to 0.30 percent of Co, less than or equal to 0.008 percent of N, 1.2 to 4.3 percent of Mo / Cr, 0.75 to 0.92 percent of Mo + Cr + Co, 2.8 to 3.9 percent of Si / Co and the balance of Fe and inevitable elements. The manufacturing method comprises the steps of smelting, slab continuous casting, continuous casting slab heating, rolling, cooling and coiling. In the transverse direction of the rolled plate, Rt0.5 is larger than or equal to 540 MPa, Rm is larger than or equal to 640 MPa, Rt0.5 / Rm is smaller than or equal to 0.87, A50 mm is larger than or equal to 36%,-40 DEG C impact energy KV8 is larger than or equal to 220 J, and-20 DEG C drop weight DWTT is larger than or equal to 95%; in the longitudinal direction, Rt0.5 is larger than or equal to 520 MPa, Rm is larger than or equal to 630 MPa, Rt0.5 / Rm is smaller than or equal to 0.86, and A50mm is larger than or equal to 38%; the average corrosion rate in a 14.5 MPa supercritical CO2 environment is 1t; and 0.05 mm / a. The low-carbon medium-manganese molybdenum-chromium-cobalt-containing alloy design is adopted, the low-temperature toughness of a weld joint is guaranteed, the CO2 corrosion resistance and the oxidation resistance are improved, and higher safety is achieved in pipeline engineering.

The invention provides a titanium-doped high-nickel ternary positive electrode material and a preparation method thereof. The titanium-doped high-nickel ternary positive electrode material comprises a high-nickel ternary positive electrode material and a titanium-doped element, and the content of the titanium-doped element accounts for 0.5-5wt% of the titanium-doped high-nickel ternary positive electrode material. The preparation method comprises the following steps: preparing a nickel-cobalt-manganese hydroxide precursor; uniformly mixing the nickel-cobalt-manganese hydroxide precursor with a lithium source, sintering and cooling to obtain a high-nickel ternary positive electrode material; and mixing and sintering the high-nickel ternary positive electrode material and a reducing titanium source to obtain the titanium-doped high-nickel ternary positive electrode material. Reducing titanium is used for modifying the high-nickel ternary material, more stable Ni < 2 + > is enriched on the surface of the material through an oxidation-reduction reaction to serve as a protective layer, corrosion of electrolyte to the material is reduced, and the surface stability of the material is improved; the titanium element can enter material crystal lattices more easily compared with a common doping method; the lattice structure strength of the material is improved through a relatively strong Ti-O bond, and excellent cycling stability and rate capability are obtained.

The invention relates to the technical field of high-entropy oxide and electrocatalyst synthesis, in particular to a double-phase hollow high-entropy oxide catalyst and a preparation method and application thereof, the double-phase hollow high-entropy oxide catalyst comprises metal elements and non-metal elements, the metal elements comprise ruthenium, nickel, cobalt, iron, manganese and chromium; the non-metallic element is oxygen; the chemical formula of the double-phase hollow high-entropy oxide catalyst is NiCoFeMnCrRuO. The invention further discloses a preparation method of the catalyst. The double-phase hollow high-entropy oxide catalyst has a multi-shell hollow structure, provides a larger specific surface area and exposes a large number of reaction active sites, so that the double-phase hollow high-entropy oxide catalyst has lower overpotential, higher reaction efficiency and good electrochemical stability; meanwhile, the preparation method of the double-phase hollow high-entropy oxide catalyst is simple in process, low in cost, high in repeatability and suitable for industrial mass production, and has a wide application prospect.

The invention relates to the technical field of tungsten alloy, and discloses a tungsten alloy material and a preparation method thereof.The tungsten alloy material comprises, by mass, 90-100 parts of modified tungsten powder, 8-10 parts of nickel powder, 5-7 parts of iron powder, 4-6 parts of cobalt powder and 1-3 parts of modified carbon fibers. The nickel powder, the iron powder and the cobalt powder in the molten state permeate into the tungsten powder through pores evenly distributed in porous carbon on the surface of the modified tungsten powder to form a uniform and compact alloy material, and the situation that due to the large melting point difference between the tungsten powder and the nickel powder, the iron powder and the cobalt powder, the nickel powder, the iron powder and the cobalt powder are distributed unevenly in the tungsten alloy material, and the mechanical strength of the alloy material is reduced is avoided; the pretreated silicon carbide whiskers are adhered to the surface of the carbon fiber loaded with the graphene oxide to form modified carbon fiber, so that interface stress can be absorbed and dispersed, stress concentration is reduced, cracks and debonding phenomena at an interface are prevented, and the mechanical performance of the tungsten alloy material is enhanced.

The invention provides an in-situ modified lithium-rich manganese-based precursor and a preparation method and application thereof.The preparation method comprises the following steps that a nickel-cobalt-manganese mixed metal salt solution, a precipitator solution and a complexing agent solution are introduced into a base solution for a first coprecipitation reaction, and after the first coprecipitation reaction is finished, feeding is stopped; and introducing a doped nickel-cobalt-manganese mixed metal salt solution, a precipitant solution, a complexing agent solution and a carbon source solution into a system after the first coprecipitation reaction is finished, and carrying out a second coprecipitation reaction to obtain the in-situ modified lithium-rich manganese-based precursor. According to the preparation method, doping elements and a carbon source are introduced when the lithium-rich manganese-based precursor is prepared through the coprecipitation reaction, in-situ uniform construction of oxygen vacancies and a carbon coating layer on the surface of the material is synchronously achieved, the in-situ modified lithium-rich manganese-based precursor is obtained, the treatment step of subsequent secondary coating can be reduced, the production cost can be reduced, and the method is suitable for industrial production. The technological process is shortened.

The invention discloses a negative temperature coefficient medium-entropy thermistor material as well as a preparation method and application thereof. According to the invention, manganese dioxide, nickel oxide, cobalt sesquioxide, zinc oxide and copper oxide are used as raw materials, and a solid-phase reaction method is adopted to prepare the negative temperature coefficient medium-entropy thermistor material with a chemical formula of (NiX1CoX2ZnX3CuX4) Mn2O4. Wherein the values of X1, X2, X3 and X4 are 0.075-0.425, and X1 + X2 + X3 + X4 = 1. The negative temperature coefficient medium-entropy thermistor material is of a single spinel structure. The material has the hysteresis diffusion effect of medium-entropy ceramic, and by combining the coordinated optimization effect of multiple components, the material constant and the resistivity of the thermal sensitive ceramic can be remarkably reduced, and the anti-aging performance can be improved.

The invention discloses a preparation method and application of an amorphous nickel-cobalt-iron phosphate anode catalyst, and belongs to the technical field of alkaline water electrolysis hydrogen production, the preparation method comprises the following steps: (1) dissolving transition metal salt in a solvent, and stirring to obtain a metal salt solution; (2) dissolving phosphate in a solvent, and stirring to obtain a phosphate solution; and (3) adding the phosphate solution into the metal salt solution for reaction, washing with deionized water and ethanol, centrifugally separating, and drying to obtain the amorphous nickel-cobalt-iron phosphate anode catalyst. According to the preparation method and application of the amorphous nickel-cobalt-iron phosphate anode catalyst, process safety improvement and environmental friendliness optimization are achieved through an all-water-phase green synthesis system, the obtained catalyst shows excellent performance in an AEM electrolytic cell, the cell voltage is only 1.87 V under the current density of 2 A / cm, and the method has remarkable industrial application prospects.

Provided in the present application are a lithium-rich manganese-based precursor material, and a preparation method therefor and the use thereof. The preparation method comprises the following steps: in a protective gas atmosphere, mixing a nickel-cobalt-manganese mixed salt solution, a precipitator solution and a complexing agent solution, subjecting same to a co-precipitation reaction until particles enter a growth stage, starting the introduction of an oxygen-containing gas, and then continuously subjecting same to the co-precipitation reaction, so as to obtain a lithium-rich manganese-based precursor material. In the preparation method of the present application, by introducing the oxidizing atmosphere in the growth stage of the precursor material, the problems of compact particle growth, being prone to agglomerating and poor morphology in the existing preparation process for a lithium-rich manganese precursor material are solved, and a lithium-rich manganese-based precursor material having high dispersity and a high specific surface area is obtained.

Disclosed herein is a catalytic comprising a hexacyano metal compound; wherein the hexacyano metal compound comprises a metal selected from the group consisting of cobalt, iron, copper, manganese, nickel, zinc, and combinations thereof; wherein the hexacyano metal compound comprises coordinatively unsaturated metal (II)—N—C centers for; and wherein the hexacyano metal compound is anchored onto an inorganic substrate. Also disclosed are a system including the catalytic material and a process for treating wastewater using the catalytic material.

The invention discloses a nickel-containing etching wastewater treatment process, which belongs to the technical field of environmental protection, and comprises a raw water regulating tank, a pH pre-regulating tank, a heterogeneous catalytic oxidation tower, a neutralization coagulation tank, an inclined tube sedimentation tank and a clean water tank which are connected in sequence. According to the process, under the neutral condition, a catalyst loaded with cobalt manganese oxide is used for activating sodium hydrogen persulfate, high-activity sulfate free radicals are generated, a Ni-EDTA complex structure is fractured in a targeted mode, free nickel ions are released in situ, organic ligands are synchronously mineralized, and the adding amount of sodium hydrogen persulfate is dynamically adjusted through a clean water pool closed-loop control system; and high-purity nickel hydroxide precipitate is generated through alkaline precipitation and coagulation, so that efficient solid-liquid separation is realized. The treatment process disclosed by the invention is compact in flow and stable in operation, effectively solves the problems of difficult complex breaking, low nickel removal efficiency, high sludge toxicity, difficult resource recovery and the like when the EDTA complex nickel wastewater is treated by a traditional method, realizes closed-loop recovery of nickel resources, and has the remarkable advantages of low cost, high efficiency and environmental friendliness.

The invention discloses a carbon-loaded high-entropy oxide and a preparation method thereof, the carbon-loaded high-entropy oxide is of a core-shell structure formed by coating carbon with a high-entropy oxide, and the high-entropy oxide comprises at least five metal elements of chromium, manganese, iron, cobalt, nickel and copper. The carbon-loaded high-entropy oxide has the advantages of low density, high dielectric loss and excellent wave-absorbing performance, and is expected to be widely applied to electromagnetic absorption and elimination in the fields of electronics, communication civil affairs and aerospace military.

The invention discloses a samarium cobalt permanent magnet and a preparation method and application thereof. The preparation method comprises the following steps: (1) carrying out crushing and jet milling on an alloy ingot formed by raw materials required by the samarium-cobalt permanent magnet to obtain first alloy fine powder with D50 of 4-6 microns; (2) 15-30 wt% of the first alloy fine powder is taken out, then the taken-out first alloy fine powder is subjected to ball milling, and second alloy fine powder with D50 being 0.5-1.2 microns is obtained; (3) the remaining first alloy fine powder and the second alloy fine powder obtained in the step (2) are mixed, and mixed powder is obtained; 4) carrying out orientation molding and isostatic pressing on the mixed powder to obtain a green body; and the green body is subjected to sintering, solid solution and aging treatment, and the samarium-cobalt permanent magnet is obtained. By adopting the preparation method disclosed by the invention, the bending strength of the samarium-cobalt permanent magnet can be obviously improved on the basis that the magnetic performance of the samarium-cobalt permanent magnet is not reduced basically.

The invention discloses a high-hardness tungsten carbide-cobalt hard alloy and a preparation method thereof. A production raw material formula comprises the following components in parts by mass: 100 parts of tungsten carbide powder, 6-20 parts of cobalt powder, 0.2-1.3 parts of a composite sintering aid, 0.5-4 parts of a wet grinding medium and 0.2-4 parts of a forming agent, the composite sintering aid is composed of rare earth oxide and cobalt phosphide according to the mass ratio of (1-5): 1. The method has the advantages that on the premise that the toughness of the tungsten carbide-cobalt hard alloy is slightly improved, the hardness and wear resistance of the alloy are remarkably improved, and the industrial problems that the hardness improvement of the tungsten carbide-cobalt hard alloy with a single sintering aid is limited and the toughness of the alloy is lost are solved.

The invention discloses a layered cobalt aluminum oxide / copper sulfide wave-absorbing material and a preparation method thereof, and belongs to the technical field of novel wave-absorbing materials, the wave-absorbing material is prepared through a two-step hydrothermal method, lamellar cobalt aluminum hydroxide is prepared through the hydrothermal method, then the lamellar cobalt aluminum oxide subjected to heat treatment is used as a substrate, and the lamellar cobalt aluminum oxide / copper sulfide wave-absorbing material is prepared through the two-step hydrothermal method. The preparation method comprises the following steps: growing nano flaky copper sulfide on the cobalt-aluminum oxide / copper sulfide composite material by adopting a hydrothermal method to form a layered cobalt-aluminum oxide / copper sulfide heterostructure, and adjusting the wave-absorbing property of the composite material by adjusting the content of the copper sulfide in the composite material. According to the layered cobalt aluminum oxide / copper sulfide wave-absorbing material and the preparation method thereof, the layered cobalt aluminum oxide / copper sulfide wave-absorbing material has the advantages that the density is relatively low, the effective absorption frequency band is relatively wide, the electromagnetic wave absorption performance is relatively high, the preparation method is simple, the morphology of the composite material can be regulated and controlled, and the like.

The invention belongs to the field of nickel-based alloy materials, and discloses a precipitation hardening type nickel-based alloy welding wire and a preparation method thereof.The precipitation hardening type nickel-based alloy welding wire comprises, by mass, 50%-60% of nickel, 15%-20% of chromium, 15%-20% of iron, 2%-4% of molybdenum, 2%-5% of niobium, 0.01%-2% of tantalum, 0.2%-2% of aluminum, 0.5%-1.2% of titanium, 0.03%-0.08% of carbon, 0.1%-0.5% of manganese, 0.1%-0.5% of silicon, 0.01%-0.05% of magnesium, 0.01%-0.05% of yttrium, 0.5%-2% of tungsten, 0.1%-0.6% of cobalt, 0.001%-0.02% of boron and the balance impurities; according to the precipitation hardening type nickel-based alloy welding wire and the preparation method thereof, through component optimization and process innovation, the nickel-based alloy welding wire with high-temperature strength, excellent hot crack resistance and welding toughness is provided.

The invention provides an improved treatment method for laterite-nickel ore. The improved treatment method comprises the following steps: S1, carrying out acid leaching on the laterite-nickel ore, and then filtering and washing to obtain a leached solution and first leached residues; step S2, the step S2 is selected from any one of a step S2-1, a step S2-2 and a step S2-3; s3, performing first-stage nickel and cobalt precipitation and dense filtration on the aluminum and scandium removed liquid or the iron and aluminum removed liquid by adopting a precipitator to obtain first-stage nickel and cobalt precipitation liquid and a nickel cobalt hydroxide product; and S4, carrying out second-stage nickel-cobalt precipitation on the first-stage nickel-cobalt precipitation solution by adopting a nickel-cobalt precipitation neutralizer and an oxidizing agent to obtain a magnesium sulfate manganese solution and nickel-cobalt-manganese slurry. In the traditional process, ferrous iron is oxidized by using compressed air, so that energy is wasted. According to the method, the manganese-containing substance is adopted as the oxidizing agent, ferrous iron is oxidized into ferric iron, the problems that the ferrous iron is low in oxidation rate under the low pH and compressed air is wasted are solved, and the scandium recovery rate is increased.

The invention relates to the technical field of zinc alloy materials, in particular to a corrosion-resistant zinc alloy material and a preparation method thereof. The invention relates to a corrosion-resistant zinc alloy material which comprises the following components in percentage by mass: 8%-11% of aluminum, 0.25%-0.45% of copper, 0.1%-0.3% of nickel, 0.01%-0.02% of titanium, 0.01%-0.03% of cobalt, 0.01%-0.03% of lanthanum, 0.001%-0.002% of dysprosium, 0.003%-0.005% of manganese silicide and the balance of zinc. Through alloy components in a specific ratio and a fine preparation process, not only are original good casting performance and mechanical strength of the zinc alloy maintained, but also the corrosion resistance of the zinc alloy material is remarkably improved, the service life is prolonged, and the application range of the zinc alloy material is widened.

The invention provides a purification and impurity removal method of a crude nickel-cobalt-manganese sulfate solution. The purification and impurity removal method comprises the following steps: (1) adding sodium thiosulfate into the crude nickel-cobalt-manganese sulfate solution to remove copper; (2) phosphate is adopted, the pH value is regulated, and titanium, iron, aluminum and the like are removed; (3) ferric sulfate is added, the pH value is regulated, and phosphorus and silicon are removed; (4) adding a bismuth agent and regulating the pH value to remove chlorine; (5) adding a fluorine agent to remove calcium and magnesium; and (6) adding a tillite mineral adsorbent to remove fluorine. According to the method, iron, aluminum, copper, fluorine, phosphorus, titanium, calcium, magnesium, chlorine, silicon and other elements can be efficiently removed from the rough nickel-cobalt-manganese sulfate solution, the loss of main metal is low, the prepared high-purity nickel-cobalt-manganese sulfate solution can directly meet the requirement of a precursor solution of a battery preparation level, the process is simple, the operation difficulty is low, industrial large-scale production is easy to achieve, and the method is suitable for industrial production. And the defects of the current preparation method of the high-purity nickel-cobalt-manganese sulfate solution are overcome.

The invention discloses a preparation method of FeCoNiMnAl series high-entropy alloy powder with wave absorbing performance, which comprises the following steps: (1) uniformly mixing iron powder, cobalt powder, nickel powder, manganese powder and aluminum powder to obtain alloy raw material powder; (2) adding the alloy raw material powder, absolute ethyl alcohol and grinding balls into a ball milling tank, and carrying out high and low rotating speed alternate ball milling under the protection of inert gas; (3) after ball milling is finished, the alloy raw material powder obtained after ball milling is subjected to vacuum drying, grinding and smashing, and an intermediate product A is obtained; (4) adding a sodium hydroxide solution into the intermediate product A, and performing corrosion modification by adopting a water bath heating method; after the water bath is finished, washing a solid product obtained by solid-liquid separation to be neutral to obtain an intermediate product B; and (5) carrying out vacuum drying on the intermediate product B, and grinding and crushing. The FeCoNiMnAl series high-entropy alloy powder prepared by the preparation method disclosed by the invention has relatively excellent wave absorbing performance under the condition that the thickness is relatively small.

The invention provides a high-hardness cobalt-based alloy welding wire and a preparation method thereof, and the high-hardness cobalt-based alloy welding wire comprises the following components in percentage by mass: less than or equal to 0.5% of C, 3-4% of Si, 15-20% of Cr, 1-4% of Ni, 25-30% of Mo, 45-55% of Co, less than or equal to 1% of Fe, less than or equal to 0.02% of La, less than or equal to 0.02% of B, less than or equal to 0.01% of S and less than or equal to 0.01% of P. According to the cobalt-based welding wire, through regulation and control of alloy elements, the hardness of the cobalt-based welding wire is remarkably improved, the uniformity of components of the welding wire is improved, the welding strength is improved, the size of the welding wire is extremely thin, and the welding manufacturability of the welding wire is improved.

A spherical ball joint has an outer ring 2 of a nickel based material with a carbonitriding layer on a spherical inner surface 2a sliding on an inner ring 3 of a cobalt-based or nickel-based material

The invention discloses a method for asynchronously recovering copper and cobalt in sulfur-oxygen mixed copper-cobalt ore tailings through dressing and smelting combination. The sulfur-oxygen mixed copper-cobalt ore tailings are divided into a coarse fraction, a medium fraction and a fine fraction according to particle sizes; the coarse fraction is subjected to ore grinding and copper sulfide flotation, part of copper and cobalt are recycled, and coarse fraction tailings are obtained; the medium fraction is subjected to copper sulfide flotation, copper oxide flotation and magnetic separation, part of copper and cobalt are recycled, and medium fraction tailings are obtained; the fine fraction is subjected to magnetic separation, part of copper and cobalt are recycled, and fine fraction tailings are obtained; and neutralizing one or more than two of the coarse-fraction tailings, the medium-fraction tailings and the fine-fraction tailings to recover part of copper and cobalt. According to the characteristics of the sulfur-oxygen mixed copper-cobalt ore tailings, the sulfur-oxygen mixed copper-cobalt ore tailings are divided into different size fractions, and different grading processes are adopted for treatment. And efficient enrichment and recovery of copper minerals and cobalt minerals with different properties in the sulfur-oxygen mixed copper-cobalt ore tailings are realized through a multi-process combined grading process.

The invention provides a cobalt-containing nickel-based high-temperature alloy GH4098 wide cold-rolled sheet and a manufacturing method thereof. The GH4098 cold-rolled sheet comprises, by mass, 17.50%-19.50% of Cr, 5%-8% of Co, 5.5%-7.0% of W, 3.5%-5.0% of Mo, 2.50%-3.0% of Al, 1.0%-1.5% of Ti, smaller than or equal to 3.00% of Fe, smaller than or equal to 1.50% of Nb, smaller than or equal to 0.30% of Mn, smaller than or equal to 0.30% of Si, smaller than or equal to 0.10% of C, smaller than or equal to 0.015% of S and smaller than or equal to 0.015% of P. The manufacturing method comprises the steps that S1, a plate blank is forged, the forging frequency and temperature are controlled in a light hammer and fast beating mode, and a uniform forged blank is prepared; s2, hot-rolling cogging: heating through a sheath and closing cooling water for rolling to obtain a hot-rolled semi-finished product; and S3, cold rolling machining is conducted, specifically, the wide cold-rolled sheet is manufactured through the repeated cold rolling and intermediate solution heat treatment alternating technology. Through component optimization and process improvement, the strength, plasticity and grain size uniformity of the material are remarkably improved, the manufactured wide cold-rolled sheet is smooth in surface and high in glossiness and can meet the performance requirements in the fields of aerospace and high-end manufacturing, and meanwhile the problems of edge cracking and non-uniform performance in wide plate production in the prior art are solved.

The invention relates to the technical field of high-temperature alloy preparation, and discloses a method for preparing nitrogen-containing cobalt-chromium-molybdenum alloy by a two-chamber vacuum induction furnace, which comprises the following specific steps: step 1, preparing materials according to components of the nitrogen-containing cobalt-chromium-molybdenum alloy; step 2, sequentially arranging a Si layer, a Mo layer, an N layer, a Cr layer and a Co layer from the bottom of the crucible to the top; and step 3, vacuum melting: S1, vacuumizing treatment; then filling nitrogen; s2, heating and melting, wherein the power of a smelting chamber is set to be 340-360 KW; the power of the smelting chamber is set to be 180-200 KW, and heat preservation refining is carried out; s3, power failure and standing; s4, electrifying again, and adding Mn into the molten steel when the power of the smelting chamber is increased to 300KW; and 4, pouring is conducted, specifically, pouring is started when the temperature of the molten steel rises to 1520-1530 DEG C. The nitrogen-containing cobalt-chromium-molybdenum alloy which is smooth in surface and free of pores inside can be prepared.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.15% ≤ Manganese ≤ 0.7% 3% ≤ Silicon ≤ 3.6% 0.7% ≤ Aluminum ≤ 1.3 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% with 3.85% ≤ Si+Al+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0% ≤ Nickel ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, from 30 to 40% when calculated in accordance with Bertotti method.

The invention provides a hydrogen storage catalyst, a preparation method thereof and application of the hydrogen storage catalyst in a hydrogen fuel cell, and belongs to the technical field of new energy. The preparation method of the hydrogen storage catalyst provided by the invention comprises the following steps: electroplating the surface of a nickel substrate to prepare a cobalt-phosphorus coating to obtain the hydrogen storage catalyst, the electroplating voltage ranges from 8.5 V to 9.5 V, the electroplating time ranges from 4.5 min to 5.5 min, and the electroplating temperature ranges from 25 DEG C to 35 DEG C. According to the method, the electroplating voltage, time and temperature are optimized, so that the quality of the cobalt-phosphorus coating can be improved, the cobalt-phosphorus coating is granular, and extending branches are formed at the protruding positions, so that the seawater corrosion resistance of the hydrogen storage catalyst is improved.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001 % ≤ Carbon ≤ 0.007 % 0.15% ≤ Manganese ≤ 0.2% 3% ≤ Silicon ≤ 3.6% 0.7% ≤ Aluminum ≤ 1.3 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% with 3.85% ≤ Si+AI+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1 % 0% ≤ Titanium ≤ 0.1 % 0% ≤ Vanadium ≤ 0.1 % 0% ≤ Chromium ≤ 1 % 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten ≤ 0.1 % 0% ≤ Cobalt ≤ 1 % 0% ≤ Arsenic ≤ 0.05% 0.001 % ≤ Calcium ≤ 0.01 % 0% ≤ Copper ≤ 1 % 0% ≤ Nickel ≤ 1 % 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, of 35 to 55% when calculated in accordance with Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.635T to 1.670T.

The invention discloses a high-entropy alloy system high-temperature brazing filler metal and a preparation method and application thereof, and relates to the technical field of welding materials.The preparation method comprises the following steps that iron powder, cobalt powder, nickel powder, copper powder and molybdenum powder are weighed and evenly mixed, and mixed metal powder is obtained; the mixed metal powder is put into a first ball milling tank, argon is introduced, ball milling is conducted for at least 15 h, and alloyed powder is obtained; the alloyed powder is put into a mold and sintered in the hydrogen atmosphere at the temperature of 1000-1200 DEG C, and a sintered blank is obtained; the sintered briquette is crushed into particles, the particles are put into a second ball milling tank, ball milling is conducted for at least 20 h in the argon atmosphere, and high-entropy alloy powder is obtained; and weighing the high-entropy alloy powder, borax and polyvinyl alcohol, and uniformly mixing to obtain the high-entropy alloy system high-temperature brazing filler metal. The prepared high-entropy alloy system high-temperature brazing filler metal has the advantages of being good in component uniformity, high in performance stability and excellent in wettability and filling performance, and the welding quality of a brazed joint can be effectively guaranteed.

The invention deals with a double cold rolled non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.2% ≤ Manganese ≤ 0.24% 3.1% ≤ Silicon ≤ 3.5% 0.8% ≤ Aluminum ≤ 1.1% Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0.001% ≤ Nickel ≤ 0.01 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, less from 30% to 35% when calculated in accordance of Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.645T to 1.660T.

The invention is suitable for the technical field of photocatalyst preparation, and provides a modified tubular g-C3N4 loaded Ni-CoP photocatalyst and a preparation method thereof. The preparation method comprises the following steps: calcining a carbon nitride precursor in stages to obtain tubular carbon nitride, stirring the tubular carbon nitride with a cobalt and nickel-containing compound and an alkaline compound, washing and drying to obtain a precipitate, calcining, mixing and grinding with a phosphorus-containing compound, calcining again, and modifying the product with polydopamine and polypyrrole to obtain the composite material. The photocatalyst modified by the polydopamine and the polypyrrole and loaded with the Ni-CoP by taking the tubular g-C3N4 as the carrier is obtained. According to the invention, three-in-one synergistic integration of'carrier-modifier-cocatalyst 'is realized, the prepared photocatalyst still keeps tubular morphology and has a larger specific surface area, the requirements of anode oxygen evolution reaction (OER) on rapid charge separation and transmission can be met, meanwhile, the light absorption range is widened, the solar energy utilization rate is increased, and a foundation is laid for efficient OER reaction.