1775 results about "Cobalt" patented technology

The invention relates to the technical field of high-entropy oxide and electrocatalyst synthesis, in particular to a double-phase hollow high-entropy oxide catalyst and a preparation method and application thereof, the double-phase hollow high-entropy oxide catalyst comprises metal elements and non-metal elements, the metal elements comprise ruthenium, nickel, cobalt, iron, manganese and chromium; the non-metallic element is oxygen; the chemical formula of the double-phase hollow high-entropy oxide catalyst is NiCoFeMnCrRuO. The invention further discloses a preparation method of the catalyst. The double-phase hollow high-entropy oxide catalyst has a multi-shell hollow structure, provides a larger specific surface area and exposes a large number of reaction active sites, so that the double-phase hollow high-entropy oxide catalyst has lower overpotential, higher reaction efficiency and good electrochemical stability; meanwhile, the preparation method of the double-phase hollow high-entropy oxide catalyst is simple in process, low in cost, high in repeatability and suitable for industrial mass production, and has a wide application prospect.

The invention discloses a preparation method and application of an amorphous nickel-cobalt-iron phosphate anode catalyst, and belongs to the technical field of alkaline water electrolysis hydrogen production, the preparation method comprises the following steps: (1) dissolving transition metal salt in a solvent, and stirring to obtain a metal salt solution; (2) dissolving phosphate in a solvent, and stirring to obtain a phosphate solution; and (3) adding the phosphate solution into the metal salt solution for reaction, washing with deionized water and ethanol, centrifugally separating, and drying to obtain the amorphous nickel-cobalt-iron phosphate anode catalyst. According to the preparation method and application of the amorphous nickel-cobalt-iron phosphate anode catalyst, process safety improvement and environmental friendliness optimization are achieved through an all-water-phase green synthesis system, the obtained catalyst shows excellent performance in an AEM electrolytic cell, the cell voltage is only 1.87 V under the current density of 2 A / cm, and the method has remarkable industrial application prospects.

Disclosed herein is a catalytic comprising a hexacyano metal compound; wherein the hexacyano metal compound comprises a metal selected from the group consisting of cobalt, iron, copper, manganese, nickel, zinc, and combinations thereof; wherein the hexacyano metal compound comprises coordinatively unsaturated metal (II)—N—C centers for; and wherein the hexacyano metal compound is anchored onto an inorganic substrate. Also disclosed are a system including the catalytic material and a process for treating wastewater using the catalytic material.

The invention discloses a nickel-containing etching wastewater treatment process, which belongs to the technical field of environmental protection, and comprises a raw water regulating tank, a pH pre-regulating tank, a heterogeneous catalytic oxidation tower, a neutralization coagulation tank, an inclined tube sedimentation tank and a clean water tank which are connected in sequence. According to the process, under the neutral condition, a catalyst loaded with cobalt manganese oxide is used for activating sodium hydrogen persulfate, high-activity sulfate free radicals are generated, a Ni-EDTA complex structure is fractured in a targeted mode, free nickel ions are released in situ, organic ligands are synchronously mineralized, and the adding amount of sodium hydrogen persulfate is dynamically adjusted through a clean water pool closed-loop control system; and high-purity nickel hydroxide precipitate is generated through alkaline precipitation and coagulation, so that efficient solid-liquid separation is realized. The treatment process disclosed by the invention is compact in flow and stable in operation, effectively solves the problems of difficult complex breaking, low nickel removal efficiency, high sludge toxicity, difficult resource recovery and the like when the EDTA complex nickel wastewater is treated by a traditional method, realizes closed-loop recovery of nickel resources, and has the remarkable advantages of low cost, high efficiency and environmental friendliness.

The invention discloses a carbon-loaded high-entropy oxide and a preparation method thereof, the carbon-loaded high-entropy oxide is of a core-shell structure formed by coating carbon with a high-entropy oxide, and the high-entropy oxide comprises at least five metal elements of chromium, manganese, iron, cobalt, nickel and copper. The carbon-loaded high-entropy oxide has the advantages of low density, high dielectric loss and excellent wave-absorbing performance, and is expected to be widely applied to electromagnetic absorption and elimination in the fields of electronics, communication civil affairs and aerospace military.

The invention discloses a high-hardness tungsten carbide-cobalt hard alloy and a preparation method thereof. A production raw material formula comprises the following components in parts by mass: 100 parts of tungsten carbide powder, 6-20 parts of cobalt powder, 0.2-1.3 parts of a composite sintering aid, 0.5-4 parts of a wet grinding medium and 0.2-4 parts of a forming agent, the composite sintering aid is composed of rare earth oxide and cobalt phosphide according to the mass ratio of (1-5): 1. The method has the advantages that on the premise that the toughness of the tungsten carbide-cobalt hard alloy is slightly improved, the hardness and wear resistance of the alloy are remarkably improved, and the industrial problems that the hardness improvement of the tungsten carbide-cobalt hard alloy with a single sintering aid is limited and the toughness of the alloy is lost are solved.

The invention provides a high-hardness cobalt-based alloy welding wire and a preparation method thereof, and the high-hardness cobalt-based alloy welding wire comprises the following components in percentage by mass: less than or equal to 0.5% of C, 3-4% of Si, 15-20% of Cr, 1-4% of Ni, 25-30% of Mo, 45-55% of Co, less than or equal to 1% of Fe, less than or equal to 0.02% of La, less than or equal to 0.02% of B, less than or equal to 0.01% of S and less than or equal to 0.01% of P. According to the cobalt-based welding wire, through regulation and control of alloy elements, the hardness of the cobalt-based welding wire is remarkably improved, the uniformity of components of the welding wire is improved, the welding strength is improved, the size of the welding wire is extremely thin, and the welding manufacturability of the welding wire is improved.

The invention provides a hydrogen storage catalyst, a preparation method thereof and application of the hydrogen storage catalyst in a hydrogen fuel cell, and belongs to the technical field of new energy. The preparation method of the hydrogen storage catalyst provided by the invention comprises the following steps: electroplating the surface of a nickel substrate to prepare a cobalt-phosphorus coating to obtain the hydrogen storage catalyst, the electroplating voltage ranges from 8.5 V to 9.5 V, the electroplating time ranges from 4.5 min to 5.5 min, and the electroplating temperature ranges from 25 DEG C to 35 DEG C. According to the method, the electroplating voltage, time and temperature are optimized, so that the quality of the cobalt-phosphorus coating can be improved, the cobalt-phosphorus coating is granular, and extending branches are formed at the protruding positions, so that the seawater corrosion resistance of the hydrogen storage catalyst is improved.

The invention is suitable for the technical field of photocatalyst preparation, and provides a modified tubular g-C3N4 loaded Ni-CoP photocatalyst and a preparation method thereof. The preparation method comprises the following steps: calcining a carbon nitride precursor in stages to obtain tubular carbon nitride, stirring the tubular carbon nitride with a cobalt and nickel-containing compound and an alkaline compound, washing and drying to obtain a precipitate, calcining, mixing and grinding with a phosphorus-containing compound, calcining again, and modifying the product with polydopamine and polypyrrole to obtain the composite material. The photocatalyst modified by the polydopamine and the polypyrrole and loaded with the Ni-CoP by taking the tubular g-C3N4 as the carrier is obtained. According to the invention, three-in-one synergistic integration of'carrier-modifier-cocatalyst 'is realized, the prepared photocatalyst still keeps tubular morphology and has a larger specific surface area, the requirements of anode oxygen evolution reaction (OER) on rapid charge separation and transmission can be met, meanwhile, the light absorption range is widened, the solar energy utilization rate is increased, and a foundation is laid for efficient OER reaction.

The invention relates to the technical field of nano materials and biological medicines, in particular to black phosphorus-loaded monatomic nano enzyme as well as a preparation method and application thereof. According to the monatomic nano-enzyme loaded with the black phosphorus, the monatomic nano-enzyme loaded with the black phosphorus takes a black phosphorus nanosheet as a carrier, and a metal simple substance is anchored on the surface of the carrier; wherein the metal elementary substance comprises any one of iron, cobalt and manganese. A metal active center is anchored on a black phosphorus nano-carrier, the catalytic activity of monatomic nano-enzyme and the photo-thermal conversion performance of a black phosphorus nano-material are effectively combined, the anti-tumor effect is jointly enhanced through chemical kinetic catalysis and photo-thermal, in addition, a loaded black phosphorus degradation product is mainly phosphate and has biological safety, and the application prospect is broad. The toxicity problem of the traditional nano-enzyme can be solved; the wide application is facilitated.

The invention provides a low-cost nickel-based high-temperature alloy and a preparation method thereof. The low-cost nickel-based high-temperature alloy comprises the following components in percentage by weight: 55%-65% of Ni, 12%-18% of Cr, 8%-15% of Fe, 3%-7% of Mo, 1%-3% of Al, 0.5%-2% of Ti, 0.5%-2% of Nb, 0.01%-0.1% of B and the balance of inevitable impurities. According to the low-cost nickel-based high-temperature alloy and the preparation method thereof, by reasonably adjusting alloy components, the usage amount of expensive elements such as cobalt and tungsten is reduced, meanwhile, relatively cheap iron is ingeniously used for replacing part of nickel, on the premise that the alloy performance requirement is met, the raw material cost is greatly reduced, and the alloy is high in tensile strength and good in mechanical property. And the anti-oxidation performance is good, and the use requirements under numerous medium-high temperature working conditions, such as manufacturing of key parts of equipment such as industrial boilers and heat exchangers, can be met.

A polishing liquid which reduces the occurrence of erosion and scratches on a surface to be polished of an object to be polished having a cobalt-containing film after polishing in a case where the polishing liquid is applied to CMP of the object to be polished is provided. In addition, a chemical mechanical polishing method using the above-mentioned polishing liquid is provided. The polishing liquid is a polishing liquid used for chemical mechanical polishing of an object to be polished having a cobalt-containing film. The polishing liquid includes colloidal silica, an organic acid, a specific nitrogen-containing aromatic heterocyclic compound and hydrogen peroxide, and has a pH of 8.5 to 12.

The invention discloses a cobalt-iron layered double-metal hydroxide water treatment catalyst, which is characterized in that the cobalt-iron layered double-metal hydroxide is doped with europium element. Compared with existing ferrocobalt layered double hydroxides, after europium is doped, europium can generate a synergistic interaction effect with iron and cobalt, so that the catalytic activity of the material is remarkably improved.

The invention relates to a ternary precursor oxide and a preparation method and application thereof, and the preparation method comprises the following steps: adding a nickel-cobalt-manganese mixed salt solution, a first precipitator solution and a complexing agent solution into a reaction base solution in a parallel flow manner, and carrying out a first co-precipitation reaction; stopping the first precipitant solution and the complexing agent solution, continuously adding a second precipitant solution and the nickel-cobalt-manganese mixed salt solution into the reaction solution in a parallel flow manner, and carrying out a second co-precipitation reaction; feeding of the second precipitant solution is stopped, the first precipitant solution, the complexing agent solution and the nickel-cobalt-manganese mixed salt solution continue to be added into the reaction solution in a parallel flow mode, and a third co-precipitation reaction is carried out; and calcining the reaction product to obtain the ternary precursor oxide. The preparation method comprises a nucleation stage, a growth stage, a finished product stage and a calcination stage, the impurity S element in the obtained ternary precursor oxide can be as low as 100 ppm or below, and the ternary precursor oxide is uniform in internal porosity, good in sphericity degree and free of cracking and nuclear explosion conditions.

The invention belongs to the technical field of new energy materials and bioelectrochemistry, and particularly relates to an iron-based multi-metal sulfide composite carbon anode material and a preparation method of the iron-based multi-metal sulfide composite carbon anode material. The preparation method is simple in process flow, convenient to operate, easy for large-scale production, wide in raw material source, low in cost and environment-friendly, and can be used for preparing the three-dimensional porous carbon matrix which is formed by foaming and carbonizing polyvinylpyrrolidone and is provided with interconnected carbon nanosheets. Through reasonable composition design and structural regulation, and optimization of metal ratio and vulcanization conditions, accurate regulation of material performance can be realized, electrochemical performance and biocompatibility are significantly improved, electricity generation performance and operation stability of a microbial fuel cell are improved, and good industrial application prospects are achieved.

The invention discloses an HVOF spraying coating and a preparation method and application thereof, and belongs to the technical field of high-end equipment manufacturing, and the preparation method of the HVOF spraying coating comprises the following steps that hypersonic flame spraying is adopted, and a transition layer and a working layer are sequentially sprayed on the surface of a base body; the transition layer is made of NiCr (nickel chromium)-CoCrFeNiMo (cobalt chromium) or NiCr (nickel chromium); and the working layer is at least one of the following components: 10 < CoCr > FeNi < 18 > NiCr < 72 > Cr3 < C2 >, 20 < CoCr > FeNi < 16 > NiCr < 64 > Cr3 < C2 >, 75 < NiCr > < 25 > Cr3 < C2 >, 25 < NiCr > < 75 > Cr3 < C2 > and 50 < NiCr > < 50 > Cr3 < C2 >. According to the HVOF spraying coating prepared through the method, collaborative optimization of high-temperature wear resistance and corrosion resistance is achieved, and an effective path is provided for design of a high-performance protective coating under the complex working condition.

The application discloses a method for preparing a metal organic framework film by magnetic field induction regulation control. The method comprises the following steps: vertically immersing a sheet carrier into a film forming solution of the metal organic framework film; placing a container provided with the film forming solution and the carrier into a uniform magnetic field; and standing for 4-24 hours to obtain the metal organic framework film prepared by the magnetic field induction regulation control. The metal organic framework film is a cobalt-based, nickel-based or iron-based metal organic framework film. The carrier material comprises alumina, porous carbon and porous organic material. The magnetic field direction is perpendicular to or parallel to the surface of the carrier. The metal organic framework film prepared by the application has excellent gas separation performance, and the film forming process is simple, convenient, easy to enlarge and popularize.

The invention belongs to the technical field of rhenium alloy materials, and particularly relates to a high-strength rhenium alloy material and a preparation method thereof. The rhenium alloy material is prepared from the following raw materials in percentage by mass: 12 to 24 weight percent of molybdenum, 6 to 9 weight percent of niobium, 2 to 5 weight percent of cobalt, 1 to 3 weight percent of tungsten, 0.5 to 1.2 weight percent of modified tantalum carbide, 3 to 6 weight percent of high-entropy rare earth and the balance of rhenium and other inevitable impurities. The modified tantalum carbide is prepared by the following preparation process: adding tantalum chloride, zirconium oxychloride and phenolic resin into a mixed solution of acetylacetone and n-butyl alcohol, stirring for 1-2 hours under a heating condition, dropwise adding ammonia water, continuously stirring for 0.5-1 hour, and drying to obtain a precursor; calcining the precursor, and cooling to obtain the modified tantalum carbide. The rhenium alloy prepared through the method has high hardness, good bending strength and excellent high-temperature mechanical property.

The invention provides a ternary positive electrode precursor material and a preparation method and application thereof. The ternary positive electrode precursor material sequentially comprises a nickel-cobalt-manganese core, a nickel-cobalt-manganese transition layer and a nickel-cobalt-manganese shell from inside to outside, wherein the surface of the nickel-cobalt-manganese core is coated with the nickel-cobalt-manganese transition layer, and the surface of the nickel-cobalt-manganese transition layer is coated with the nickel-cobalt-manganese shell; wherein the nickel-cobalt-manganese core is also doped with a boron element; the molar content of nickel in the surface, close to the nickel-cobalt-manganese core, of the nickel-cobalt-manganese transition layer is smaller than the molar content of nickel in the nickel-cobalt-manganese core, the molar content of nickel in the nickel-cobalt-manganese transition layer is gradually reduced from inside to outside, and the molar content of nickel in the surface, close to the nickel-cobalt-manganese shell, of the nickel-cobalt-manganese transition layer is larger than or equal to the molar content of nickel in the nickel-cobalt-manganese shell; and the molar content of manganese in the nickel-cobalt-manganese shell is the highest. According to the precursor material, the lithium-nickel mixing phenomenon is inhibited, stress cracking easily caused by sudden change of components between the core and the shell from the core to the shell is relieved, the effect of inhibiting the side reaction of an electrolyte is also achieved, and the cycling stability and safety of the battery are improved.

The invention provides a ternary precursor and a preparation method and application thereof. The preparation method comprises the following steps: providing a nickel-cobalt-manganese aqueous solution, a nickel unit solution, a cobalt unit solution and a manganese unit solution after co-extraction, and determining a nickel-cobalt-manganese molar ratio in a target ternary precursor; providing an integrated burdening and feeding automatic control system, and inputting the total concentration of nickel, cobalt and manganese in the co-extracted nickel, cobalt and manganese water solution, the metal concentrations of nickel unit liquid, cobalt unit liquid and manganese unit liquid, the total feeding flow and the molar ratio of nickel, cobalt and manganese in the target ternary precursor into the integrated burdening and feeding automatic control system; feeding is started, the co-extracted nickel-cobalt-manganese aqueous solution, the nickel unit liquid, the cobalt unit liquid, the manganese unit liquid, the precipitant and the complexing agent are introduced into a reaction kettle for a co-precipitation reaction, and the ternary precursor is obtained. According to the method disclosed by the invention, proportioning and feeding procedures are combined, so that the cost is reduced, the synthesis of the ternary precursor in a target proportion is realized in one step, and the consistency of economy and precursor quality is improved.

The invention discloses a method for extracting copper fine powder by flotation of copper-containing ore, which belongs to the technical field of mineral processing, and comprises the following steps: after copper-containing raw ore is crushed, ground and classified by a cyclone, overflow enters flotation, and settled sand is returned for regrinding; sodium carbonate is added into graded overflow to adjust the pH, a sodium hexametaphosphate-polyacrylamide composite dispersant is added, and copper sulfate is added and stirred after low-temperature microwave heating; gradient flotation is conducted, specifically, copper sulfide is roughly selected, the pH is adjusted, an amino-sulfonic acid group synergistic modified layered double metal hydroxide / cobalt ferrite composite collecting agent is added, and rough concentrate 1 is obtained through high-frequency pulse air inflation flotation; copper oxide roughing is conducted, clear water is supplemented to adjust the pH, and a collecting agent is supplemented to obtain rough concentrate 2; scavenging is performed for three times, a collecting agent is added for flotation, and concentrate returns to the previous stage; the rough concentrates are combined, and magnetic impurities are removed through high-gradient magnetic separation to obtain magnetic concentrates; and carrying out microbiological leaching on tailings to recover copper. The composite collecting agent is prepared through layered double hydroxide carrier synthesis, amino modification, sulfonic acid group grafting and cobalt ferrite anchoring.

The invention provides a laterite-nickel ore leaching solution catalytic oxidation-fractional precipitation method, and relates to the field of hydrometallurgy, the method comprises the following steps: adding a catalytic oxidant and a first neutralizer into a laterite-nickel ore leaching solution to obtain a first filtrate and iron slag; adding a catalytic oxidant, a second neutralizer and a first coalescing agent into the first filtrate to obtain a second filtrate and a second precipitate; adding a third neutralizer and a first reducing agent into the second filtrate to obtain a nickel-cobalt precipitate and a third filtrate; adding a fourth neutralizer and a second reducing agent into the third filtrate to obtain a fourth precipitate and a fourth filtrate; mixing the second precipitate with a third reducing agent, performing reduction leaching, and adding a second coalescing agent and a fifth neutralizing agent to obtain a silicon-aluminum precipitate and manganese-scandium filtrate; the manganese-scandium filtrate is extracted, and manganese enters raffinate; and adding a catalytic oxidant and a sixth neutralizer into the raffinate to obtain the manganese oxide. Elements are recycled step by step, and the method has the advantages of multiple types of recycled elements, less resource waste and the like.

The invention discloses a nickel-cobalt-selenium (Co1-xNixSe2) nano material for electrocatalytic oxidation of ethylene glycol as well as a preparation method and application of the nickel-cobalt-selenium (Co1-xNixSe2) nano material. The material is prepared by a hydrothermal method which comprises the following steps: (1) pouring 20mL of deionized water containing 475.9 mg of CoCl2. 6H2O into a 1mol / L NaOH solution containing 0.32 g of selenium powder to prepare a precursor solution; (2) placing in a stainless steel autoclave with a polytetrafluoroethylene lining, carrying out hydrothermal reaction at 180 DEG C for 18 hours, washing with absolute ethyl alcohol and deionized water, and carrying out vacuum drying at 60 DEG C to obtain a CoSe2 material; and (3) the molar feeding ratio of CoCl2. 6H2O to NiCl2. 6H2O is adjusted, so that the nickel / cobalt ratio x is 0.25, 0.50 or 0.75, and materials with different components, namely Co < 0.75 > Ni < 0.25 > Se < 2 >, Co < 0.50 > Ni < 0.50 > Se < 2 > and Co < 0.25 > Ni < 0.75 > Se < 2 >, are prepared. The series of materials are applied to ethylene glycol oxidation under the alkaline condition, the catalytic performance of Co < 0.50 > Ni < 0.50 > Se < 2 > is optimal, the current density reaches 111 mA cm <-2 > under the electric potential of 1.6 V vs.RHE, the total Faraday efficiency reaches up to 91.4%, and the application prospect in the field of PET plastic recovery is wide.

The application relates to a high-cobalt rare earth permanent magnet material and a preparation method thereof, and belongs to the technical field of rare earth permanent magnet materials. The high-cobalt rare earth permanent magnet material comprises the following components in percentage by mass: RE a Co b M c TM e Fe 100‑a‑b‑c‑d B d , 28<=a<=35, 15<=b<=30, 0.5<=c<=1.2, 0.95<=d<=1.2, 0.2<=e<=3; RE is one or a combination of Pr, Nd, La, Ce, Y, Gd, Tb, Dy and Ho; M is one or a combination of Cu and Al; TM is one or a combination of Cr, Nb, Zr, Ga, Ti, Zn, V, Mo and Mn; the microstructure comprises a main phase and a grain boundary phase, the Co-rich phase in the grain boundary phase accounts for less than or equal to 5% of the total volume fraction of the grain boundary phase; and the Co:M mass percentage in the Co-rich phase is 5:1-100:1. The microstructure of the magnet can be optimized, and the coercivity of the magnet is improved.

The invention discloses a neodymium-iron-gallium double-alloy heavy-rare-earth-free 54H sintered neodymium-iron-boron magnet and a preparation method thereof, and relates to the technical field of neodymium-iron-boron magnet preparation, and the neodymium-iron-gallium double-alloy heavy-rare-earth-free 54H sintered neodymium-iron-boron magnet comprises the following preparation raw materials: 170-175 kg of PrNd (praseodymium-neodymium alloy), 25-30 kg of BFe (iron white copper), 1-5 kg of Co (cobalt), 0.1-2 kg of Cu (copper), 1-5 kg of Zr (zirconium), 0.1-1 kg of Ga (gallium) and 380-420 kg of Fe (iron). According to the neodymium-iron-gallium double-alloy heavy-rare-earth-free 54H sintered neodymium-iron-boron magnet and the preparation method thereof, the 54H sintered neodymium-iron-boron magnet is prepared through a double-alloy technology with neodymium, iron and gallium as auxiliary alloy without adding dysprosium, terbium and other scarce type heavy rare earth elements, and performance optimization and cost optimization of the neodymium-iron-gallium double-alloy heavy-rare-earth-free 54H sintered neodymium-iron-boron magnet are achieved.

The invention relates to the technical field of grinding fluid, in particular to wafer polishing fluid containing graphene nanosheets and a preparation process of the wafer polishing fluid. A graphene modified abrasive; an oxidant; a complexing agent; a metal corrosion inhibitor; a pH adjusting agent; a dispersion stabilizer; an interface modifier; a defect repairing agent; a corrosion inhibition synergist; a wettability modifier; an anti-agglomeration agent; and deionized water. Through introduction of the graphene modified abrasive and multi-component collaborative design, the graphene modified abrasive polishing solution has high polishing efficiency, low corrosion rate and excellent dispersion stability, compared with a traditional polishing solution, the Cu / Co corrosion rate is reduced by 60% or above, the copper surface roughness Ra is smaller than or equal to 0.5 nm, polished wafers do not have obvious micro-scratches, and the lubricating property and the mechanical grinding property of graphene nanosheets are coordinated, so that the mechanical polishing effect is good. The copper / cobalt removal rate ratio is stabilized at 1: 1 + / -0.1, and the defects of dished pits and corrosion pits are effectively avoided.

The invention belongs to the technical field of catalytic materials, and particularly relates to a nickel-iron-cobalt entropy alloy nanowire three-dimensional interconnection grid film and a preparation method and application thereof. The preparation method comprises the following steps: taking an aluminum sheet containing copper impurities as a substrate, and preparing a three-dimensional ordered porous aluminum oxide template through anodic oxidation; then, the nickel-iron-cobalt entropy alloy nanowire is prepared in a pore channel limited range through direct current co-electrodeposition; the nickel-iron-cobalt entropy alloy nanowire three-dimensional interconnection grid film is obtained after the aluminum substrate and the 3D-AAO template are removed, the material is based on the mixed entropy effect and structural integrated design and can be directly used as a self-supporting electrode for efficiently and stably electrolyzing water for oxygen evolution, the three-dimensional grid structure and the self-supporting characteristic of the material promote electrolyte transmission and gas product desorption, and the oxygen evolution efficiency is improved. The mass transfer efficiency is improved, the use of a traditional binder is avoided, and the electrode stability is enhanced; the problems that an existing medium-entropy alloy catalyst is high in synthesis energy consumption, the catalytic activity is poor under the industrial-grade large-current working condition, active substances fall off in the reaction and the like are solved.

The invention provides a treatment method for synergistically enhancing the comprehensive performance of a neodymium-iron-boron magnet, and belongs to the technical field of magnetic materials. According to the method, a heavy rare earth layer and a corrosion-resistant metal layer such as copper, nickel and cobalt for promoting grain boundary diffusion of heavy rare earth are respectively deposited on the surface of the neodymium-iron-boron magnet by adopting a multi-layer electroplating method, the coercivity of the neodymium-iron-boron magnet is enhanced through grain boundary diffusion, and the corrosion resistance of the magnet is enhanced through a nickel-cobalt coating. The treatment method comprises the following steps: carrying out electrochemical deposition on the neodymium-iron-boron magnet in a heavy rare earth metal plating solution, and then respectively electroplating a copper plating layer and a nickel-cobalt plating layer to obtain a heavy rare earth-containing plating layer with strong corrosion resistance and good plating film binding force; the neodymium-iron-boron magnet containing the heavy rare earth coating is subjected to heat treatment, and the coercive force of the magnet is improved through heavy rare earth grain boundary diffusion. The neodymium iron boron grain boundary diffusion process and the surface corrosion prevention process are subjected to integrated treatment, the technological process of high-performance neodymium iron boron industrial preparation is shortened, and the coercive force and the corrosion resistance of the magnet are comprehensively enhanced.

The invention relates to the technical field of diamond saw blades, and provides a diamond saw blade and a preparation method thereof. The diamond saw blade comprises a disc base body and a tool bit fixed to the periphery of the disc base body, and the tool bit is prepared from, by weight, 30-45 parts of iron powder, 15-25 parts of copper powder, 8-12 parts of nickel powder, 8-15 parts of cobalt powder, 3-5 parts of tin powder, 2-5 parts of molybdenum powder, 1-3 parts of silicon-boron alloy powder, 0.5-2 parts of tungsten carbide powder, 20-25 parts of diamond particles and 0.05-0.1 part of liquid paraffin. According to the diamond saw blade provided by the invention, the scientificity and the accuracy of proportion matching of all the components in the raw material formula of the tool bit are improved, the stability of the sintering process is improved, and the condition that the hardness and the toughness of the tool bit are difficult to achieve the optimal balance is improved.

The invention discloses a cerium-zirconium-based high-entropy oxide as well as a preparation method and application thereof. According to the cerium-zirconium-based high-entropy oxide, cerium and zirconium serve as main bodies, and meanwhile rare earth elements (lanthanum, praseodymium, neodymium and samarium) and transition metal elements (manganese, iron, cobalt, nickel, copper and zinc) are introduced to form a high-entropy solid solution with the equal molar ratio and containing 3-8 kinds of metal. In the cerium-zirconium-based high-entropy oxide, the cerium element and the zirconium element respectively account for 20%-40% of the total amount, and the other elements are respectively 10%-30% in an equimolar ratio. The cerium-zirconium-based high-entropy oxide catalyst prepared by the invention has excellent oxygen storage and release capacity and CO oxidation capacity, and the CO complete conversion temperature is 181 DEG C. The method adopts a simple coprecipitation process, is mild in condition and low in cost, and is suitable for large-scale application in the field of tail gas purification.