3406 results about "Cobalt" patented technology

The invention discloses a method for activating and precipitating MHP through magnesium, and belongs to the technical field of hydrometallurgy. The method comprises the following steps: S1, mixing a magnesium-containing solution with a sodium hydroxide solution, and carrying out precipitation reaction for 3-5 minutes to obtain a precipitator; s2, immediately mixing a precipitator with the laterite-nickel ore iron and aluminum removed liquid, and then carrying out first-stage nickel and cobalt precipitation reaction to obtain first-stage nickel and cobalt precipitation slurry; s3, performing first thickening treatment on the first-section nickel and cobalt deposited slurry to obtain first dense underflow and first dense overflow; and S4, filtering the first dense underflow to obtain an MHP product. According to the method, after the magnesium-containing solution and the sodium hydroxide solution are mixed, the magnesium solution and the sodium hydroxide solution are controlled to be mixed and react for 3-5 min, then the nickel and cobalt precipitation reaction is immediately carried out, the MHP product with high purity and quality can be obtained, and the whole method is simple and convenient for large-scale industrial application.

A method for removing iron and aluminum from a lateritic nickel ore leachate by means of a goethite process, which method comprises the following steps: first-stage iron and aluminum removal, involving: adding a precipitant solution to a lateritic nickel ore leachate, reacting same for 45-90 minutes with the feeding speed controlled to be 5-80 mL / min, the pH controlled to be 3.0-3.2 and the reaction temperature controlled to be 60-70ºC, and performing solid-liquid separation, so as to obtain first-stage iron and aluminum residues and a filtrate; and second-stage iron and aluminum removal, involving: adding a precipitant solution to the filtrate, reacting same for 30-60 minutes with the pH controlled to be 4.3-4.4 and the reaction temperature controlled to be 60-70ºC, and performing solid-liquid separation, so as to obtain second-stage iron and aluminum residues and a purified liquid. Two-stage iron and aluminum removal is used; in the first stage, iron ions in the leachate are effectively separated at a relatively low pH value by controlling the feeding speed, generated residue particles are large, good filtering performance is achieved, and few valuable metals such as nickel, cobalt and manganese are entrained in the residues; in the second stage, the pH is adjusted to 4.3-4.4 to precipitate aluminum ions and the remaining iron ions; and the whole technological process is simple.

The invention discloses a 500MPa-grade supercritical CO2 corrosion-resistant pipeline coil plate and a manufacturing method thereof, and the 500MPa-grade supercritical CO2 corrosion-resistant pipeline coil plate comprises the following chemical components: 0.05 to 0.10 percent of C, 0.6 to 0.9 percent of Si, 1.50 to 1.70 percent of Mn, less than or equal to 0.010 percent of P, less than or equal to 0.002 percent of S, 0.10 to 0.30 percent of Cr, 0.35 to 0.45 percent of Mo, 0.03 to 0.05 percent of Nb, 0.01 to 0.03 percent of Ti, 0.02 to 0.05 percent of Al, 0.20 to 0.30 percent of Co, less than or equal to 0.008 percent of N, 1.2 to 4.3 percent of Mo / Cr, 0.75 to 0.92 percent of Mo + Cr + Co, 2.8 to 3.9 percent of Si / Co and the balance of Fe and inevitable elements. The manufacturing method comprises the steps of smelting, slab continuous casting, continuous casting slab heating, rolling, cooling and coiling. In the transverse direction of the rolled plate, Rt0.5 is larger than or equal to 540 MPa, Rm is larger than or equal to 640 MPa, Rt0.5 / Rm is smaller than or equal to 0.87, A50 mm is larger than or equal to 36%,-40 DEG C impact energy KV8 is larger than or equal to 220 J, and-20 DEG C drop weight DWTT is larger than or equal to 95%; in the longitudinal direction, Rt0.5 is larger than or equal to 520 MPa, Rm is larger than or equal to 630 MPa, Rt0.5 / Rm is smaller than or equal to 0.86, and A50mm is larger than or equal to 38%; the average corrosion rate in a 14.5 MPa supercritical CO2 environment is 1t; and 0.05 mm / a. The low-carbon medium-manganese molybdenum-chromium-cobalt-containing alloy design is adopted, the low-temperature toughness of a weld joint is guaranteed, the CO2 corrosion resistance and the oxidation resistance are improved, and higher safety is achieved in pipeline engineering.

The invention provides a titanium-doped high-nickel ternary positive electrode material and a preparation method thereof. The titanium-doped high-nickel ternary positive electrode material comprises a high-nickel ternary positive electrode material and a titanium-doped element, and the content of the titanium-doped element accounts for 0.5-5wt% of the titanium-doped high-nickel ternary positive electrode material. The preparation method comprises the following steps: preparing a nickel-cobalt-manganese hydroxide precursor; uniformly mixing the nickel-cobalt-manganese hydroxide precursor with a lithium source, sintering and cooling to obtain a high-nickel ternary positive electrode material; and mixing and sintering the high-nickel ternary positive electrode material and a reducing titanium source to obtain the titanium-doped high-nickel ternary positive electrode material. Reducing titanium is used for modifying the high-nickel ternary material, more stable Ni < 2 + > is enriched on the surface of the material through an oxidation-reduction reaction to serve as a protective layer, corrosion of electrolyte to the material is reduced, and the surface stability of the material is improved; the titanium element can enter material crystal lattices more easily compared with a common doping method; the lattice structure strength of the material is improved through a relatively strong Ti-O bond, and excellent cycling stability and rate capability are obtained.

The invention provides a method for precipitating nickel and cobalt in a solution containing nickel and cobalt and a cobalt nickel hydroxide product. The method comprises the following steps: step S100, carrying out a seed crystal pretreatment reaction on a nickel-cobalt-containing solution by adopting first nickel-cobalt precipitation underflow to form pretreated nickel-cobalt ore pulp; step S200, adding an alkaline precipitation inducer into the second nickel-cobalt precipitation underflow or the first nickel-cobalt precipitation overflow to carry out alkali conversion reaction to form alkali conversion crystal mush; s300, the pretreated nickel-cobalt ore pulp and alkali conversion crystal mush are continuously introduced into a reactor for a nickel-cobalt precipitation reaction, and nickel-cobalt precipitated ore pulp is obtained; step S400, continuously performing dense separation treatment on the ore pulp subjected to nickel-cobalt precipitation; s500, the third nickel-cobalt precipitation underflow is filtered and washed in sequence, a nickel-cobalt hydroxide product is obtained, and the problems that in the prior art, when nickel and cobalt are precipitated through a nickel-cobalt-containing solution, MHP is small in particle size and not prone to sedimentation, the water content of a filter cake is high, or the precipitation rate is poor, and the magnesium content is high before technical improvement are solved.

The invention relates to the technical field of high-entropy oxide and electrocatalyst synthesis, in particular to a double-phase hollow high-entropy oxide catalyst and a preparation method and application thereof, the double-phase hollow high-entropy oxide catalyst comprises metal elements and non-metal elements, the metal elements comprise ruthenium, nickel, cobalt, iron, manganese and chromium; the non-metallic element is oxygen; the chemical formula of the double-phase hollow high-entropy oxide catalyst is NiCoFeMnCrRuO. The invention further discloses a preparation method of the catalyst. The double-phase hollow high-entropy oxide catalyst has a multi-shell hollow structure, provides a larger specific surface area and exposes a large number of reaction active sites, so that the double-phase hollow high-entropy oxide catalyst has lower overpotential, higher reaction efficiency and good electrochemical stability; meanwhile, the preparation method of the double-phase hollow high-entropy oxide catalyst is simple in process, low in cost, high in repeatability and suitable for industrial mass production, and has a wide application prospect.

The invention relates to the technical field of tungsten alloy, and discloses a tungsten alloy material and a preparation method thereof.The tungsten alloy material comprises, by mass, 90-100 parts of modified tungsten powder, 8-10 parts of nickel powder, 5-7 parts of iron powder, 4-6 parts of cobalt powder and 1-3 parts of modified carbon fibers. The nickel powder, the iron powder and the cobalt powder in the molten state permeate into the tungsten powder through pores evenly distributed in porous carbon on the surface of the modified tungsten powder to form a uniform and compact alloy material, and the situation that due to the large melting point difference between the tungsten powder and the nickel powder, the iron powder and the cobalt powder, the nickel powder, the iron powder and the cobalt powder are distributed unevenly in the tungsten alloy material, and the mechanical strength of the alloy material is reduced is avoided; the pretreated silicon carbide whiskers are adhered to the surface of the carbon fiber loaded with the graphene oxide to form modified carbon fiber, so that interface stress can be absorbed and dispersed, stress concentration is reduced, cracks and debonding phenomena at an interface are prevented, and the mechanical performance of the tungsten alloy material is enhanced.

The invention provides an in-situ modified lithium-rich manganese-based precursor and a preparation method and application thereof.The preparation method comprises the following steps that a nickel-cobalt-manganese mixed metal salt solution, a precipitator solution and a complexing agent solution are introduced into a base solution for a first coprecipitation reaction, and after the first coprecipitation reaction is finished, feeding is stopped; and introducing a doped nickel-cobalt-manganese mixed metal salt solution, a precipitant solution, a complexing agent solution and a carbon source solution into a system after the first coprecipitation reaction is finished, and carrying out a second coprecipitation reaction to obtain the in-situ modified lithium-rich manganese-based precursor. According to the preparation method, doping elements and a carbon source are introduced when the lithium-rich manganese-based precursor is prepared through the coprecipitation reaction, in-situ uniform construction of oxygen vacancies and a carbon coating layer on the surface of the material is synchronously achieved, the in-situ modified lithium-rich manganese-based precursor is obtained, the treatment step of subsequent secondary coating can be reduced, the production cost can be reduced, and the method is suitable for industrial production. The technological process is shortened.

The invention discloses a negative temperature coefficient medium-entropy thermistor material as well as a preparation method and application thereof. According to the invention, manganese dioxide, nickel oxide, cobalt sesquioxide, zinc oxide and copper oxide are used as raw materials, and a solid-phase reaction method is adopted to prepare the negative temperature coefficient medium-entropy thermistor material with a chemical formula of (NiX1CoX2ZnX3CuX4) Mn2O4. Wherein the values of X1, X2, X3 and X4 are 0.075-0.425, and X1 + X2 + X3 + X4 = 1. The negative temperature coefficient medium-entropy thermistor material is of a single spinel structure. The material has the hysteresis diffusion effect of medium-entropy ceramic, and by combining the coordinated optimization effect of multiple components, the material constant and the resistivity of the thermal sensitive ceramic can be remarkably reduced, and the anti-aging performance can be improved.

The invention discloses a preparation method and application of an amorphous nickel-cobalt-iron phosphate anode catalyst, and belongs to the technical field of alkaline water electrolysis hydrogen production, the preparation method comprises the following steps: (1) dissolving transition metal salt in a solvent, and stirring to obtain a metal salt solution; (2) dissolving phosphate in a solvent, and stirring to obtain a phosphate solution; and (3) adding the phosphate solution into the metal salt solution for reaction, washing with deionized water and ethanol, centrifugally separating, and drying to obtain the amorphous nickel-cobalt-iron phosphate anode catalyst. According to the preparation method and application of the amorphous nickel-cobalt-iron phosphate anode catalyst, process safety improvement and environmental friendliness optimization are achieved through an all-water-phase green synthesis system, the obtained catalyst shows excellent performance in an AEM electrolytic cell, the cell voltage is only 1.87 V under the current density of 2 A / cm, and the method has remarkable industrial application prospects.

The invention discloses a magnesium-based cobalt precipitation agent and a preparation method and application thereof, and relates to the technical field of composite materials. The method comprises the following steps: performing calcination dissociation, enhanced leaching, carbonization separation, efficient pyrolysis, solid-liquid separation, drying and calcination on first magnesium ore to obtain active magnesium oxide; the second magnesium ore is subjected to calcination dissociation, hydration impurity removal, solid-liquid separation and low-temperature calcination, and then high-purity magnesium oxide is obtained; performing series-parallel modification on active magnesium oxide and high-purity magnesium oxide to obtain a magnesium-based cobalt precipitation agent; the mass ratio of the active magnesium oxide to the high-purity magnesium oxide is 1: (2-10), the modifier is quaternary ammonium salt organic powder, and the addition amount of the modifier is 0.02-1% of the total mass of the magnesium oxide. The magnesium-based cobalt precipitation agent prepared through the method is high in activity, has the advantages of being high in efficiency, low in price, low in unit consumption, environmentally friendly and the like in the aspect of nickel and cobalt precipitation through copper-cobalt ore and laterite-nickel ore wet smelting, and can greatly reduce the material cost in the nickel cobalt hydroxide production process.

The invention relates to the technical field of aluminum alloys, in particular to a high-fluidity corrosion-resistant aluminum alloy material for laser cladding as well as preparation and application of the high-fluidity corrosion-resistant aluminum alloy material. The material comprises the following components in percentage by mass: 3.12%-5.34% of nickel, 4.24%-6.76% of molybdenum, 6.54%-8.12% of cobalt, 10.45%-14.49% of silicon, 5.65%-8.45% of a functional additive, 1.25%-2.45% of cerium oxide, 3.46%-7.42% of yttrium oxide, 3.45%-7.58% of lanthanum oxide and the balance of aluminum, the functional additive is titanium carbide doped with Ti < 3 + >. The aluminum alloy material has high flowability during laser cladding and is well combined with a matrix, and related properties such as wear resistance, high temperature resistance, corrosion resistance and oxidation resistance of a coating formed by the aluminum alloy material are sufficiently uniform due to the high flowability of the aluminum alloy material.

The invention provides an MHP precipitation method based on a compound alkali precipitator and application of the MHP precipitation method, and the MHP precipitation method comprises the following steps: mixing laterite-nickel ore iron and aluminum removed liquid and a compound alkali solution for precipitation reaction to obtain cobalt nickel hydroxide slurry; the compound alkali in the compound alkali solution comprises a mixture of sodium carbonate and sodium hydroxide; and carrying out post-treatment on the cobalt nickel hydroxide slurry, and separating to obtain the MHP. According to the method, a sodium hydroxide and sodium carbonate compounded system is used as a precipitator, the MHP is prepared under the cooperation of sodium carbonate and sodium hydroxide, the content of manganese in the obtained MHP is remarkably reduced, the content of nickel and cobalt in the MHP is increased, the method has important significance for reducing the cost for preparing crystals through subsequent MHP refining, meanwhile, the reaction rate is more controllable, the obtained MHP is better in filtering performance, and the method is suitable for industrial production. The water content is lower.

A composite catalyst includes a nickel foam and cobalt, copper, or both electrodeposited on the nickel foam. Making the composite catalyst includes contacting the nickel foam with an aqueous solution comprising copper, cobalt, or both, and electrodepositing nanodomains of copper, cobalt, or both, respectively, on the nickel foam. Electrochemically converting nitrate to ammonia includes contacting an electrode and a cathode comprising the composite catalyst in an electrochemical cell with an aqueous solution including nitrate, adsorbing the nitrate onto the copper, the cobalt, or both, reducing the nitrate to yield nitrite, and reducing the nitrite to yield ammonia.

The invention discloses a seed layer induced FeCoNiCuMo high-entropy alloy nanocage electrocatalyst as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing and reacting iron, cobalt and nickel precursors to prepare a FeCoNi nanocage catalyst as a seed layer; adding copper salt and molybdate into the seed layer solution, carrying out ultrasonic mixing, adding a pH regulator and a reducing agent, carrying out ultrasonic treatment, putting the mixed solution into liquid nitrogen, cooling, carrying out primary nucleation, naturally unfreezing, standing for nucleation, cleaning, and freeze-drying to obtain the high-entropy alloy nanocage electrocatalyst. The catalyst is used for preparing urea through CO2 and NO3 <-> electro-catalysis, can effectively adjust the matching of CO2 and NO3 <-> reaction kinetics, and has extremely high Faraday efficiency and yield for synthesizing urea through C-N coupling.

The invention relates to the technical field of beneficiation of copper cobalt oxide ores, and discloses a flotation method for high-calcium-magnesium copper cobalt oxide ores and a combined collecting agent. The positive and negative mixed flotation technology is adopted, a combined collecting agent composed of oxidized paraffin soap, sodium oleate and divalent metal cations is adopted in the reverse flotation process, the total recovery rate of copper and cobalt reaches 90% or above, and the leaching acid consumption is 20-60 kg / t.feeding ore. The combined collecting agent adopted by the method is small in dosage, good in collecting performance and small in toxicity, compared with an existing copper oxide cobalt ore flotation technology, the method can improve the copper and cobalt recovery rate by 10% or above, leaching acid consumption is remarkably reduced, the production cost is remarkably reduced, the technological process is simple, and industrial application and popularization are easy.

The invention relates to the technical field of material science, in particular to a high-strength hard alloy and a preparation method and application thereof.The preparation method comprises the following steps that S1, raw materials of tungsten carbide, cobalt, tantalum carbide, niobium carbide, titanium carbide, yttrium oxide, nickel and trace strengthening elements are weighed according to the preset weight, and a mixture A is formed; s2, placing the mixture A in wet ball-milling equipment for ball-milling treatment; s3, the slurry obtained after ball milling is subjected to drying treatment; s4, carrying out plasma activation treatment on the dried powder; s5, pressing the activated powder to form a compact green body; s6, the green body is subjected to second-stage sintering treatment in a vacuum sintering furnace; s7, after sintering is completed, cooling treatment is conducted; by optimizing the alloy formula and innovating the preparation process, the hardness, toughness and high-temperature resistance of the high-strength hard alloy are improved, meanwhile, the production process is simplified, and the overall performance and application universality of the material are improved.

The invention discloses an iron-cobalt-based amorphous nanocrystalline soft magnetic alloy and a preparation method thereof, and relates to the technical field of nanocrystalline alloys.The iron-cobalt-based amorphous nanocrystalline soft magnetic alloy comprises an amorphous matrix and nanocrystalline distributed on the amorphous matrix in a dispersed mode, the chemical expression of the iron-cobalt-based amorphous nanocrystalline soft magnetic alloy is FexCoySiaBbPcCdCue, x, y, a, b, c, d and e in the formula respectively represent the atom percentage content of all corresponding components, wherein 6 < = c < = 10, 0 < = e < = 1, and x + y + a + b + c + d + e = 100. The preparation method comprises the following steps: mixing the raw materials according to the atomic percentage, smelting, preparing a molten master alloy ingot into an amorphous alloy strip by adopting a single-roller quenching method, cutting, wrapping with tinfoil, and carrying out annealing heat treatment in an annealing furnace. According to the iron-cobalt-based amorphous nanocrystalline magnetically soft alloy, a wide heat treatment process window can be obtained through component regulation and control, the iron-cobalt-based amorphous nanocrystalline magnetically soft alloy can be suitable for industrial production, and the iron-cobalt-based amorphous nanocrystalline magnetically soft alloy has good soft magnetic performance and can become a new material in the high-frequency working field.

The invention relates to a preparation method of a three-dimensional ferrocobalt metal oxide oxygen evolution catalyst. According to the method, foamed nickel is selected as a carrier, the foamed nickel is pretreated, a metal ion and ethanol mixed solution is evenly adsorbed to the surface of the foamed nickel, then open fire ignition is carried out, and a second-level self-limiting combustion process is carried out, so that metal ions form a ferrocobalt metal oxide material with a three-dimensional network structure in situ on the surface of the foamed nickel. The method is simple and easy to implement, a target product can be generated within second-level time, and the area of a foamed nickel matrix is adjusted according to needs, so that the three-dimensional ferrocobalt metal oxide catalyst is prepared on a large scale. The material obtained by the invention is used as an oxygen evolution anode catalyst, and the three-dimensional network-shaped ferrocobalt metal oxide oxygen evolution catalyst shows excellent electrochemical performance.

The invention relates to the technical field of electrochemistry, in particular to a high-entropy Prussian blue analogue positive electrode material, a preparation method and application. Preparing manganese source, iron source, cobalt source, nickel source and copper source solutions; the preparation method comprises the following steps: dispersing a potassium ferrocyanide precursor and a potassium citrate chelating agent in deionized water, adding quantitative manganese source, iron source, cobalt source, nickel source and copper source solutions after uniformly dispersing, and continuously stirring in the adding process until all the solutions are dropwise added; centrifugally washing the obtained mixed solution by using deionized water and absolute ethyl alcohol; drying the centrifugally washed colloid in a vacuum drying box; the obtained solid particles are ground into uniform powder, and the high-entropy Prussian blue analogue positive electrode material is prepared by adopting the preparation method; the material can be used as a sodium ion battery positive electrode material. The content of crystal water is reduced, and side reactions in the electrochemical process are reduced. Excessive crystal defects are improved; the structural stability is improved; and the sodium ion diffusion barrier is reduced.

Alloy elements are reasonably matched, N and nitrides are added to form elements such as tungsten W, vanadium V, niobium Nb, cobalt Co, rare earth RE and the like for microalloying smelting, a forged and rolled material finished product is subjected to proper heat treatment, and the stainless steel subjected to heat treatment has good heat treatment performance through metallographic observation. According to the stainless steel, nanoscale carbides are separated out in a solid solution state, and fine particles mainly containing nitrides are dispersed and separated out in crystals in a thermodynamic state, so that the material is strengthened and does not diffuse to a crystal boundary, and the room-temperature mechanical property and the high-temperature mechanical property of the material are greatly improved; and when the stainless steel material produced by the method is used for manufacturing related products, the thickness of the stainless steel material can be reduced, and the overall input of the stainless steel material is greatly reduced, so that the large-scale application of noble metal strategic resource nickel is saved, and the aims of saving resources, energy and investment are fulfilled.

Provided in the present application are a lithium-rich manganese-based precursor material, and a preparation method therefor and the use thereof. The preparation method comprises the following steps: in a protective gas atmosphere, mixing a nickel-cobalt-manganese mixed salt solution, a precipitator solution and a complexing agent solution, subjecting same to a co-precipitation reaction until particles enter a growth stage, starting the introduction of an oxygen-containing gas, and then continuously subjecting same to the co-precipitation reaction, so as to obtain a lithium-rich manganese-based precursor material. In the preparation method of the present application, by introducing the oxidizing atmosphere in the growth stage of the precursor material, the problems of compact particle growth, being prone to agglomerating and poor morphology in the existing preparation process for a lithium-rich manganese precursor material are solved, and a lithium-rich manganese-based precursor material having high dispersity and a high specific surface area is obtained.

The invention discloses a preparation method and application for preparing a cobalt-doped manganese dioxide material by taking Co3 [Co (CN) 6] 2 as a hard template, and belongs to the technical field of electrode material preparation. The preparation method comprises the following steps: firstly, preparing a Co3 [Co (CN) 6] 2 type Prussian blue nano cubic material through a liquid phase coprecipitation reaction method; and then preparing the cobalt-doped manganese dioxide material with a loose porous structure by taking the Co3 [Co (CN) 6] 2 type Prussian blue nano cubic material as a hard template and potassium permanganate as a reaction raw material and adopting a hydrothermal synthesis method, specifically, forming a submicron cube with the size of 200-700nm by combining nanosheets with the thickness of about 10-20nm, and preparing the cobalt-doped manganese dioxide material with the loose porous structure by adopting a hydrothermal synthesis method. And an optimization strategy of Co atom doping of manganese dioxide and nanosheet morphology control is synchronously completed. When the material is used as an electrode material, the conductivity of the manganese dioxide electrode material is greatly improved, the capacity of an aqueous zinc ion battery is improved, and the material has excellent charge-discharge cycle stability.

Disclosed herein is a catalytic comprising a hexacyano metal compound; wherein the hexacyano metal compound comprises a metal selected from the group consisting of cobalt, iron, copper, manganese, nickel, zinc, and combinations thereof; wherein the hexacyano metal compound comprises coordinatively unsaturated metal (II)—N—C centers for; and wherein the hexacyano metal compound is anchored onto an inorganic substrate. Also disclosed are a system including the catalytic material and a process for treating wastewater using the catalytic material.

The present disclosure discloses a multilayer annular pore nickel-cobalt-aluminum precursor and a preparation method and a positive electrode material thereof. The precursor D50 is 8 to 20 μm. It may be seen from a section diagram that there is a plurality of layers of annular pores in a secondary spherical particle structure, and a average porosity value of the section with a single particle or a plurality of particles is 6% to 14%. A co-precipitation reaction of nickel-cobalt mixed salt solution, alkali-aluminum solution, a complexing agent, and a precipitating agent is performed, a pH value and a concentration of aluminum solution at each stage are strictly controlled, and then working procedures of solid-liquid separating, washing, drying, mixing, sieving, and demagnetizing are performed to obtain the multilayer annular pore nickel-cobalt-aluminum precursor.

The invention discloses a nickel-containing etching wastewater treatment process, which belongs to the technical field of environmental protection, and comprises a raw water regulating tank, a pH pre-regulating tank, a heterogeneous catalytic oxidation tower, a neutralization coagulation tank, an inclined tube sedimentation tank and a clean water tank which are connected in sequence. According to the process, under the neutral condition, a catalyst loaded with cobalt manganese oxide is used for activating sodium hydrogen persulfate, high-activity sulfate free radicals are generated, a Ni-EDTA complex structure is fractured in a targeted mode, free nickel ions are released in situ, organic ligands are synchronously mineralized, and the adding amount of sodium hydrogen persulfate is dynamically adjusted through a clean water pool closed-loop control system; and high-purity nickel hydroxide precipitate is generated through alkaline precipitation and coagulation, so that efficient solid-liquid separation is realized. The treatment process disclosed by the invention is compact in flow and stable in operation, effectively solves the problems of difficult complex breaking, low nickel removal efficiency, high sludge toxicity, difficult resource recovery and the like when the EDTA complex nickel wastewater is treated by a traditional method, realizes closed-loop recovery of nickel resources, and has the remarkable advantages of low cost, high efficiency and environmental friendliness.

The invention provides a surface cubic-phase-rich functional modified hard alloy and a preparation method, and belongs to the technical field of hard alloy cutter materials. According to the method, tungsten carbide is subjected to yttrium doping treatment, boron-containing titanium carbide and cobalt-molybdenum composite powder are used together, a nitriding sintering process is combined, diffusion and permeation of nitrogen atoms are promoted, the microstructure of the alloy is regulated and controlled, enrichment of a cubic phase on the surface of the alloy is achieved, and the surface-rich cubic phase functional modified hard alloy is obtained; the Vickers hardness and the heat conductivity coefficient of the hard alloy material are effectively improved, and meanwhile the friction coefficient of the material is reduced; the surface layer rich cubic phase of the modified hard alloy material is provided with the functional gradient layer, the binding force of a coating of a tool material prepared from the modified hard alloy material and a matrix can be improved, and therefore the service life of the tool material is prolonged.

The invention provides a bio-based carbon material modified ternary precursor and a preparation method and application thereof.The preparation method comprises the following steps that 1, a nickel-cobalt-manganese mixed salt solution, a complexing agent, a precipitator and a doped metal source solution are injected into a base solution in a parallel flow mode to be subjected to a co-precipitation reaction, and an inner core solution is obtained; (2) adjusting the solid content of the inner core solution and the concentration of a complexing agent, injecting a nickel-cobalt-manganese mixed salt solution, the complexing agent, a precipitator and a doped metal source solution in a parallel flow manner, and carrying out a second coprecipitation reaction to obtain a doped ternary precursor; and (3) carbonizing a bio-based carbon source, mixing the carbonized bio-based carbon source with the doped ternary precursor, and sintering to obtain the bio-based carbon material modified ternary precursor. Doping elements in the ternary precursor effectively permeate into a matrix for doping, and a coating layer prepared from the bio-based carbon material is high in stability and good in rate capability.

A green method for producing a nickel-cobalt-manganese new energy raw material from laterite nickel ore based on hydrometallurgy, mainly comprising ore blending, ore washing, ore separation, pressurization leaching or oxygen pressure leaching, cyclic leaching and neutralization, counter-current washing, multi-segment removal of iron chromium aluminum, multi-segment synthesis of nickel-cobalt-manganese hydroxide, ion extraction, preparation of a nickel-cobalt-manganese mixed salt solution, preparation of a separate nickel-cobalt-manganese salt solution, preparation of a nickel-cobalt-manganese mixed salt crystal, preparation of a separate nickel-cobalt-manganese salt crystal, preparation of a ternary precursor, comprehensive treatment of wastewater, waste gas, and waste residue, and other techniques and processes. Efficient simultaneous extraction of nickel-cobalt-manganese is achieved; ferrochrome, copper, zinc, scandium and other valuable metal elements are effectively recovered; a nickel-cobalt-manganese raw material meeting the requirement of a high-nickel ternary battery is produced; and a ternary precursor material directly used for manufacturing of the ternary battery is manufactured.

The invention discloses a method for preparing a high-entropy spinel type oxide material through microwave hydrothermal treatment and a product and application of the high-entropy spinel type oxide material, and belongs to the technical field of material science and chemical engineering.The method comprises the following steps that six metal sources of iron, cobalt, nickel, chromium, zinc and copper are dissolved in water according to the metal ion equimolar ratio and stirred to be uniform, and a mixed solution is obtained; adding a precipitator into the mixed solution, and then sequentially carrying out microwave hydrothermal treatment, cooling, washing, centrifuging, drying and calcining treatment to obtain the high-entropy spinel type oxide material (FeCoNiCrZnCu) 3O4. According to the invention, the spinel type oxide is subjected to high-entropy design, and the high-entropy spinel material with excellent water electrolysis catalytic performance is synthesized. On one hand, the raw material for synthesizing the material is relatively cheap transition metal nitrate, the source is wide, and the cost is low; and on the other hand, the microwave hydrothermal method can efficiently synthesize the high-entropy spinel material under mild reaction conditions, and has the characteristics of greenness and environmental protection.