121 results about "Oxidation state" patented technology

The invention discloses a catalyst for preparing benzophenone compounds and a preparation method and application of the catalyst, the catalyst is alkaline manganese oxide and is expressed as aZOx.bMnO2, Z is any one of lithium, potassium, sodium, magnesium and calcium; x is the number of oxygen atoms required by the oxidation state of the metal element Z; a and b are respectively the atom number of Z and Mn in the catalyst, and the atom number ratio of Z to Mn in the catalyst is 0.2-10. According to the catalyst provided by the invention, the preparation method is simple, the benzophenone or halogenated benzophenone can be prepared by catalyzing efficient oxidation of diphenylmethane and halogenated diphenylmethane containing a passivation group, the catalyst activity is high, the product selectivity is high, the product is easy to separate, and the catalyst can be recycled.

The application provides a method for synthesizing adiponitrile by selective ammoxidation of epoxycyclohexane. The purpose of the application is to simulate and optimize the process of synthesizing adiponitrile by one-step direct ammoxidation of epoxycyclohexane, and to develop a new type of multiphase composite metal vanadium-based oxide catalyst, which is composed of Co a V b P c Mo d MNOx / TiO2, the active elements of which include vanadium element V, cobalt element Co, phosphorus element P and molybdenum element Mo, M is an auxiliary metal element (Mn, Cr, Fe or Ni), N is an alkali metal (Na, K or Cs); the value range of a is 0.2-1.2; the value range of b is 0.8-1.5; the value range of c is 0.1-0.23; the value range of d is 0.07-0.35; x is the proportion of oxygen atoms required to meet the oxidation state of metal. The catalyst has the advantages of simple preparation, good cycle stability, high yield and the like. The yield and product purity of adiponitrile are improved, the energy consumption in the production process of adiponitrile is reduced, and a breakthrough is realized in the production technology of adiponitrile.

This invention relates to the field of catalyst technology, specifically to an iron-based catalyst, its preparation method and application, and the FTO reaction. The catalyst comprises a support and an active component. The active component, expressed as an oxide, has the following general chemical formula: Fe 100 Mn a Nb b Cs c A d B e O x A is selected from Group VIII nonferrous metals and / or Group VIB elements; B is selected from La series elements; the value of a ranges from 30.0 to 130.0; the value of b ranges from 1.0 to 20.0; the value of c ranges from 0.1 to 10.0; the value of d ranges from 1.0 to 60.0; the value of e ranges from 0.1 to 10.0; x is the total number of oxygen atoms required to satisfy the oxidation states of each element in the catalyst. The iron-based catalyst of this invention exhibits excellent resistance to carbon deposition during use, and when used in the FTO reaction, it can achieve high CO feedstock conversion and C2-C4 olefin selectivity.

The application relates to a catalyst for catalytically synthesizing propylene acid from propane and application thereof, and the catalyst is represented by the following general formula: Mo a V b Te c Nb d Ni e O x Wherein, a, b, c, d and e respectively represent the atom numbers of Mo, V, Te, Nb and Ni, and the molar ratio of a:b:c:d:e is 7.0-9.0:1.7-2.5:1.0-1.5:1.7-2.3:0.1-1.0, and the value of x is determined by the oxidation state of each element; Ni is introduced by nickel molybdate, Mo is introduced by a molybdate and the nickel molybdate, and the nickel molybdate is prepared by co-precipitation of a molybdate and a nickel salt in the presence of an organic acid. According to the application, the content of different valence metals on the surface of the catalyst can be adjusted by introducing nickel into the catalyst through nickel molybdate, so that the content of high-valence elements Mo 6+ , V 5+ and Ni 2+ in the catalyst and the oxygen vacancy are increased, and the redox capacity of the catalyst is enhanced.

This invention relates to the field of encryption and anti-counterfeiting technology, specifically to a method for preparing and using an organic Sn(IV)-based metal halide reversible light-emitting conversion triple anti-counterfeiting material, comprising introducing organic ligands into a Sn(IV)X4 lattice and doping with ns 2 This invention uses Sn(IV) with a high oxidation state to replace Pb(II) in order to obtain anti-counterfeiting materials. 4+ The outer electron configuration is 4d 10 5s 0 The absence of unstable 5s orbitals gives Sn(IV)-based metal halides their typically excellent environmental and thermal stability, providing the compounds with a rigid crystal structure and stereochemical inertness. Furthermore, through ns... 2 Type Sb metal ions 3+ Doping strategies are employed to enhance the luminescence efficiency of low-dimensional organotin (IV)-based metal halides. This invention utilizes Sb... 3+ Ion doping methods are used to modulate the optical properties of compounds. Sb 3+ Ions belong to ns 2 Type metal ions and Sn 4+ With similar ionic radii and unique photophysical properties, it solves the problem of low luminous efficiency in existing luminescent materials.

A particulate cathode active material comprising (A) a base material according to the general formula Li1 + xTM1-xO2, where TM is a combination of Ni with at least one of Mn, Co and Al, and optionally at least another metal selected from the group consisting of Mg, Ti, Zr, Nb, Ta and W, and x is in the range of 0 to 0.2, and (B) crystallites of one or more cobalt compounds, where at least some of the cobalt is in the oxidation state of + III, where the base material (A) is a polycrystalline material, where x is greater than 0 and less than 1. The secondary particles of which consist of primary particles, and crystallites (B) of a cobalt compound are coated on the outer surfaces of these secondary particles, and one or more cobalt compounds are enriched at the surfaces of the primary particles in the voids between adjacent primary particles, and wherein 90% to 99.5% of the secondary particles exhibit such cobalt compound enrichment, all the detection results are determined through EDX and SEM / TEM imaging.

The invention discloses an automatic activator selection device and method based on the surface oxidation state of pyrite, and the method comprises the steps: carrying out the online detection of the spectrums of Fe, S and O elements on the surface of pyrite in ore pulp through laser-induced breakdown spectroscopy, constructing comprehensive oxidation criterion parameters according to the spectrums, and judging the oxidation grade of the parameters; then making a decision in real time and precisely adding a matched copper ion or lead ion activating agent; quantitative recognition of the mineral surface state and automatic control of activating agent adding are combined, so that objectification and precision of activating agent selection are achieved, agent waste caused by erroneous judgment of artificial experience is effectively avoided, the quick response capacity to ore property fluctuation is greatly improved, and the method is suitable for industrial production. Therefore, the flotation index of the pyrite is stabilized and optimized.

This invention relates to a selective gold-based oxidation catalyst, its preparation method, and its application; the catalyst comprises components represented by general formula (1): Au-Sc a / Si b Ce c X d O e In formula (1), a is the molar ratio of Sc to Au, with a value of 0.1 to 1.0; b is the molar ratio of Si to Au, with a value of 100 to 500; c is the molar ratio of Ce to Au, with a value of 1.0 to 30.0; d is the molar ratio of X to Au, with a value of 0.1 to 2.0; e is the number of oxygen atoms required to satisfy the oxidation states of each element in the active component; X is selected from at least one of Li, Na, K, Rb, and Cs. The catalyst of the present invention is used for selective oxidation, with high yield of target product and high conversion rate of raw materials. For example, it has the characteristics of high conversion rate of methacrolein and high yield of methyl methacrylate in the synthesis of alkyl acrylates.

The invention belongs to the technical field of water electrolysis hydrogen production catalysts, and relates to a metal monatomic hydrogen evolution catalyst and a preparation method thereof.The catalyst comprises a large number of metal monatomic and a small number of metal clusters, metal is in an oxidation state in the catalyst, and crystalline PMA exists in the catalyst; c60 and PMA structures coexist in the catalyst; the preparation method comprises the following steps: respectively dissolving an acetylacetone metal complex, phosphomolybdic acid and fullerene in a toluene solution of a 4A type molecular sieve, respectively and sequentially mixing, magnetically stirring, washing and centrifuging to obtain the metal monatomic hydrogen evolution catalyst; the metal monatomic hydrogen evolution catalyst disclosed by the invention has excellent HER performance, a PMA-M-C60 catalyst with high loading capacity and high dispersion of metal monatomic bridging C60 and PMA is realized through a room-temperature synthesis strategy, and the catalysis cost is lower.

The invention discloses a cobalt-doped ruthenium dioxide nanoparticle material as well as a preparation method and application thereof, and relates to a ruthenium dioxide nanoparticle material as well as a preparation method and application thereof. The nano-particle cluster is formed by irregularly distributing nano-particles; the nanoparticles have a single-phase crystal structure, and the spacing distribution of {110} crystal faces is 0.315 nm; the material is composed of three elements of Co, Ru and O, wherein Co is doped into RuO2 to form Co < 0.3 > Ru0. 7O2 nanoparticles; the material is of an octahedral structure, and Ru sites are replaced by Co doping; the chemical valence state of Ru on the surface of the material is a mixed valence state of + 3 and + 4; charge transfer occurs among three ions of Co, Ru and O, so that Ru is in a lower oxidation state. The cobalt-doped ruthenium dioxide nanoparticle material is used for electrolyzing water to produce hydrogen, and shows 2500-hour long-term stability under the current density of 10 mAcm <-2 >.

The present invention (A) General formula Li 1+x TM 1-x A core material made of O2, wherein TM is a combination of Ni, Al, at least one of Mn and Co, and at least one metal optionally selected from Mg, Zr, Ti, Nb, Ta and W, x is in the range of 0 to 0.2, and at least 80 mol% of TM is nickel. (B) A coating containing at least one boron compound in the oxidized state of (B)+III, Regarding cathode active materials containing, Here, the core material (A) is a polycrystalline material composed of primary particles as secondary particles, and the lattice constant ratio c / a determined by X-ray diffraction and Rietveld refinement is 4.9420 or less. 0.0009 ≤ λ ≤ 0.0024, where λ is the molar ratio of sulfate to TM determined by inductively coupled plasma spectroscopy (ICP), and the sulfate concentration is essentially constant across the secondary particle size.

The invention provides a rapid and high-precision determination method for reduction-state Os isotope. The method comprises the following steps: selecting a sample to be detected and carrying out ultrafine crushing; weighing the ground to-be-detected sample, and sealing and dissolving the sample; taking out the dissolved to-be-detected sample, and adding isometric hydrobromic acid to convert oxidation state Os into reduction state Os; carrying out acid removal and constant volume on the reduced-state Os solution; establishing a cup structure for static determination of the Os isotope, and performing MC-ICP-MS determination of the reduction state Os isotope according to the cup structure. According to the present invention, the dissolved to-be-tested sample is creatively taken out, and the isometric hydrobromic acid is added so as to convert the oxidation state Os into the reduction state Os, such that the memory effect can be substantially reduced, the efficiency can be improved, the research cost and the research time can be reduced when the MC-ICP-MS is adopted to rapidly and precisely measure the Os isotope, and the method is suitable for the mass sample test.

A compound having a formula M(LA)x(LB)y(LC)z, where ligand LA isligand LB isand ligand LC isis disclosed. In formula M(LA)x(LB)y(LC)z, M is a metal having an atomic number greater than 40; x is 1 or 2; y and z are independently 0, 1, or 2; x+y+z is the oxidation state of the metal M; A1-A8 are carbon or nitrogen; ring B is bonded to ring A through a C—C bond; M is bonded to ring A through a M-C bond; X is O, S, Se, CRR′, or NR1; rings C and D are each independently a 5 or 6-membered carbocyclic or heterocyclic ring; at least one R4 is a five-membered or six-membered heterocyclic ring which can be further substituted by RE; each R substituent is independently selected from the several substituents; and any adjacent R substitutents are optionally joined to form a ring.

The invention belongs to the technical field of two-dimensional nano materials, and relates to an MXene material as well as a preparation method and application thereof. The invention provides a novel and efficient MXene material preparation method which is characterized in that a precursor MAX phase material, a chalcogenide element simple substance and an iodine simple substance are mixed and then subjected to a high-temperature reaction in a vacuum environment. According to the method, a chalcogenide and iodine are ingeniously utilized to generate iodide (such as SeI2 or TeI2) with strong oxidizing property in situ at a high temperature, the chalcogenide in a high oxidation state can selectively oxidize A-site atoms (such as Al) in an MAX phase, the A-site atoms are converted into volatile iodide (such as AlI3) and escape from a system, and therefore selective stripping of an A layer is achieved; and a two-dimensional Mn + 1Xn skeleton is formed. Meanwhile, the reduced chalcogenide is directly bonded to the surface of MXene as a terminal group, and the functionalized MXene material with the chalcogenide terminal group (-S,-Se or-Te) is synthesized in one step.

The mineralogical, chemical, magnetic, and physical properties of a rock can be used to determine the amount of hydrogen that was generated during rock alteration and the remaining amount of hydrogen generation potential. The methodologies evaluate the hydrogen generation potential of geological samples and identify natural hydrogen source rocks. The mineralogy, elemental composition, iron content and oxidation state, and other properties of a geological sample may be determined. From the determined mineralogy and other properties of the geological sample, the amount of hydrogen which the geological sample may have generated may be quantified. This method can determine the maturity of hydrogen source rocks, the potential volume of hydrogen that can be generated in other parts of a given geologic province with higher degrees of hydrogen source rock maturity, and quantify the potential remaining volume of hydrogen that can be still be generated via secondary enhanced hydrogen stimulation processes.

Process for melting and / or refining glass, glass ceramic or glass that can be ceramized into glass ceramic, comprising the steps - Providing a mixture of raw materials, - heating the mixture until a melt is obtained, the mixture being heated at least in sections to a temperature above T3, which corresponds to a viscosity of the molten glass of 10 3 dPa*s corresponds to - refining the melt, whereby the melt is heated at least in sections to a temperature above T2.5, which corresponds to a viscosity of the molten glass of 10 2,5 dPa*s, and - Obtaining a refined glass, a refined glass-ceramic or a refined glass that can be ceramized into glass-ceramic, wherein at least one refining agent of the formula X n O m , where n = 1 or 2, where m = 2 or 5, where X = As, Sb, Sn, or Ce, and / or of the formula Mn SO4, where n = 1 or 2, and M = Na, K, Li, Mg, Ca, Sr, Ba and / or Zn, is used at a concentration of 2 wt% or less, based on the total mass of the mixture of raw materials, wherein the refining agent has the thermodynamic property that, in a melt of the same composition as the melt in the refining step, at an oxygen partial pressure p(O2) of 1 bar and a temperature T2, it has at least 30% conversion from a higher to a lower oxidation state, in particular according to the reaction of X n O m → X n O m-1 + 1 / 2 O2 and / or X n O m → X n O m-2 + O2, and / or according to the reaction of M n SO4 → M n O + SO2 + 1 / 2 O2, where the temperature T2 corresponds to a viscosity of the molten glass of 10 2 dPa*s corresponds to with the step of setting an oxygen partial pressure p(O2) during the refining of the melt, which is reduced by at least 60%, preferably at least 70%, based on the O2 saturation in the melt at the temperature T3.

Catalyst systems comprising a procatalyst having a structure according to Formula (I) where M is a metal selected from titanium, zirconium, and hafnium, the metal having a formal oxidation state of +2, +3, or +4; each X is a monodentate or bidentate ligand; n is 1 or 2; Q is a monoanionic spectator ligand that is different from each X; RY is (C1−C30)hydrocarbyl (C1−C30)heterohydrocarbyl, (C6−C30)aryl, or (C3−‍C30)heteroaryl; R1 is (C1−‍C50)hydrocarbyl, (C1−C50)heterohydrocarbyl, (C6−‍C30)aryl, or (C3−‍C30)heteroaryl; each of R2 and R3 is independently selected from the group consisting of (C1−C30)hydrocarbyl, (C1−C30)heterohydrocarbyl, (C6−‍C30)aryl, (C3−C30)heteroaryl, −ORC, −Si(RC)3, −Ge(RC)3, halogen, and –H, wherein R2 and R3 are optionally covalently linked to form an aromatic or non-aromatic ring; and each RC is independently selected from the group consisting of (C1−C30)hydrocarbyl, (C1−C30)heterohydrocarbyl, (C6−‍C30)aryl, (C3−‍C30)heteroaryl, and −H.

(A) General formula Li 1+x TM 1-x a core material based on O2, wherein TM is a combination of Ni and at least two of Mn, Co and Al, and optionally at least one further metal selected from Mg, Ti, Zr, Nb, Ta and W, where x is in the range of -0.05 to +0.05, and the nickel content is in the range of 80 to 99 mol% of TM; (B) particles of cobalt compound(s) in which at least some of the cobalt is in the +III oxidation state; (C) a shell containing at least one oxide of B or W 1. A cathode active material comprising: The core material (A) is a polycrystalline material in which secondary particles are composed of primary particles, and particles (B) of a cobalt compound are concentrated on the surfaces of the secondary particles.

The present invention relates in particular to an adhesive composition comprising i) microfibrillated cellulose and ii) at least one metal in oxidation state II or higher. The invention further relates to the use of such an adhesive composition and to products produced using such an adhesive composition. Furthermore, the invention relates to a method for producing corrugated paperboard or cardboard or solid paperboard or cardboard by using such an adhesive composition.

The invention belongs to the technical field of preparation of catalytic materials, and provides a high-density defective polyacid-based metal organic framework catalyst for hydroboration, a preparation method and application. According to the catalyst, a metal organic framework with defects is constructed by adopting a mixed ligand strategy, a polyacid cluster is introduced in situ on the basis of the metal organic framework, and through weak interaction between a cluster object and a subject framework, regulation and control of an oxidation state of a metal node and regulation and control of a supporting effect of an expanded pore space are realized at the same time; therefore, the problem of unstable structure caused by high defect content is overcome, the polyacid-based metal organic framework catalyst with high-density defects is successfully constructed, the catalyst solves the problems that the existing hydroboration reaction is high in temperature, the catalyst is difficult to recycle and the like, efficient conversion of the alkyne hydroboration reaction can be realized, and the yield of the alkyne hydroboration reaction is increased. Moreover, the structure is still stable after repeated cyclic utilization and use, and can be expanded to various alkyne substrates.

The invention discloses a method for calculating valence states of metal atoms in a metal organic framework material, which comprises the following steps of: firstly, acquiring. Cif files of original metal organic frameworks (MOFs) from a CSD database, carrying out bonding on the. Cif files by using an open-source xyz2mol program, outputting corresponding bonding information, and then deleting the metal atoms of the MOFs structure; calculating the RSD value of the non-metal framework according to the bonding information of all non-metal atoms, and calculating the total charge of the non-metal framework according to the relation between the RSD and the TSD of the elements; reversely deducing the oxidation state of the metal atoms by using the fact that the complete MOFs present charge balance; and finally, comparing the metal oxidation state numerical value with a numerical value provided by a CSD database, and evaluating the accuracy and feasibility of the method. According to the method, the metal center oxidation state value in the MOFs can be efficiently calculated, so that whether the MOFs meet the requirement of skeleton neutrality or not is judged.

The mineralogical, chemical, magnetic, and physical properties of a rock can be used to determine the amount of hydrogen that was generated during rock alteration and the remaining amount of hydrogen generation potential. The methodologies evaluate the hydrogen generation potential of geological samples and identify natural hydrogen source rocks. The mineralogy, elemental composition, iron content and oxidation state, and other properties of a geological sample may be determined. From the determined mineralogy and other properties of the geological sample, the amount of hydrogen which the geological sample may have generated may be quantified. This method can determine the maturity of hydrogen source rocks, the potential volume of hydrogen that can be generated in other parts of a given geologic province with higher degrees of hydrogen source rock maturity, and quantify the potential remaining volume of hydrogen that can be still be generated via secondary enhanced hydrogen stimulation processes.

Described is a process for preparing a catalyst precursor based on at least one transition metal belonging to groups 5 to 12, containing organic sulphur, in the form of sulfonate ions, and / or carboxylate ions, comprising the steps of - reacting an organic acid selected from a sulfonic acid, a carboxylic acid (of fossil or renewable origin), and their combination, with a source of said at least one transition metal, optionally in the presence of a reducing agent; - removing the water produced in the aforementioned reaction by azeotropic distillation, or by anhydrification with a drying agent, to obtain at least one carboxylate and / or sulfonate salt of said transition metal, with the condition that when the acid is only a carboxylic acid and the metal is only Mo, said Mo has an average oxidation state that varies from +6 to +4.

The invention belongs to the technical field of electro-catalytic materials, and discloses a cerium-doped core-shell series catalyst, a preparation method and an application in preparation of ethylene by electro-catalytic reduction of carbon dioxide, the catalyst is an Ag coated Cu2O catalyst taking Ag as a core and cerium-doped Cu2O as a shell layer; wherein the mole percentage of Ce is greater than 0% to 10%, and the mole percentage of Ce is calculated based on the total mole number of Cu and Ce. The rare earth element cerium (Ce) is creatively introduced as a doping agent. Ce is famous for unique Ce < 3 + > / Ce < 4 + > redox pairs and excellent oxygen vacancy regulation and control capability, and is often used as an electronic auxiliary agent or a structure stabilizer in the field of catalysis. If Ce can be introduced into the Ag-coated Cu2O core-shell structure, the oxidation state of Cu is dynamically stabilized in the reaction process by utilizing the electron interaction between Ce and Cu, so that the catalytic active center is protected, and the stability and ethylene selectivity of the catalyst are improved.

The application discloses a supported catalyst for low-temperature carbon dioxide hydrogenation and a preparation method and application thereof. The supported catalyst comprises a carrier and a metal Zr active component supported on the surface of the carrier; the Zr element is in a state of an element and / or an oxidation state, and the valence state ranges from 0 to +4; the high-dispersed metal zirconium nanoparticles are prepared by using a rotating sputtering method; compared with a traditional reduction method, the ZrO x The regulation range of x is larger; starting from the metal state zirconium, the oxidation treatment is gradually performed, so that the valence state of the zirconium can be controlled to change in a range from zero to four valences, and various unsaturated zirconium oxide catalyst materials with different valences can be obtained; the carbon dioxide is activated in a low-temperature range and catalyzes the hydrogenation reaction, and the carbon dioxide conversion rate and the methanol yield are higher than those of other metal catalysts.

The invention relates to a method for producing a composition X comprising at least one organopolysiloxane A, which contains at least one (meth) acrylate group, the method comprises the following steps: a) reacting at least one organopolysiloxane E comprising at least one epoxy group with acrylic acid or methacrylic acid or a mixture of both at a temperature of 50-130 DEG C, preferably 70-130 DEG C and even more preferably 90-125 DEG C, in the presence of:-a catalyst C, the invention relates to a complex of chromium, which is a complex of chromium in oxidation state (III) of the following formula (1) [Cr (L1) 3] (1) wherein the symbols L1, which are identical or different, represent a beta-diketoanion, and-a polymerization inhibitor of acrylic acid or methacrylic acid; b) devolatilizing the reaction medium obtained at the end of step a); c) obtaining said composition X comprising at least one organopolysiloxane A.

A cathode active material comprising (A) a core material according to the general formula Li1 + xTM1-xO2, where TM is a combination of Ni with at least two of Mn, Co and Al, and optionally at least one plurality of metals selected from the group consisting of Mg, Ti, Zr, Nb, Ta and W, and x is in the range of-0.05 to + 0.05, and where the nickel content is in the range of 80 to 99 mol-% of TM, and (B) particles of one or more cobalt compounds, wherein at least some of the cobalt is in the oxidation state of + III, (C) a shell comprising an oxide of at least one of B or W, and wherein the core material (A) is a polycrystalline material, the secondary particles of which consist of primary particles, and the particles (B) of the cobalt compound are enriched at the surface of said secondary particles.

This invention discloses a catalyst for the production of ethylene and propylene, its preparation method, and its applications. The catalyst comprises the following components: I) 1%–10% of chemical formula A x B y D z A compound of O4; in the chemical formula, the oxidation states of elements A, B, and D are m, n, and p, respectively, satisfying x·m + y·n + z·p = 8, where m, n, and p are integers not greater than 3; the A x B y D z O4 has a spinel structure; II) 0.5%–10% is selected from at least one oxide of rare earth elements, P, Mo, and W; III) 20.0%–55.0% is selected from at least one zeolite of ZSM-5 and ZSM-11; IV) 10%–30% is a binder; V) 25.0%–60.0% is clay. This catalyst is used in the catalytic cracking of petroleum hydrocarbons to produce ethylene and propylene, and features good catalyst stability, low methane yield, and high ethylene and propylene yields.

The present invention relates to a method for obtaining a bath of molten chloride salts comprising at least one actinide in which the oxidation state and / or degree of oxidation of said at least one actinide are predetermined according to the intended application, comprising the following steps: (a) establishing, for said at least one actinide, its potential-oxoacidity diagram at a given temperature T in a bath of molten chloride salts, (b) from the potential-oxoacidity diagram established in step (a), defining the potential-oxoacidity domain in which said at least one actinide is in the predetermined oxidation state and / or degree of oxidation, (c) selecting at least three different compounds which are different from said at least one actinide setting, at the temperature T, the potential and oxoacidity of the bath of molten chloride salts in the domain defined in step (b), it being possible for one of said at least three compounds to be the chloride ion contained in the bath of molten chloride salts, then (d) introducing, into a bath of molten chloride salts comprising said at least one actinide at the temperature T, said at least three compounds selected in step (c). The present invention relates to the use of various mixtures or compositions in the preparation of a nuclear fuel, during its operation or else during its reprocessing.

The invention discloses a nickel-molybdenum-silicon compound catalyst as well as a preparation method and application thereof. The nickel-molybdenum-silicon compound catalyst comprises the following components: (1) metal nickel and nickel oxide; (2) an oxide of molybdenum; (3) silicon oxide; wherein the molar ratio of Ni0 to Ni < 2 + > in the metallic state Ni and the oxidation state NiO in the component (1) is 0.03-0.40; the valence states of Mo in the molybdenum oxide in the component (2) comprise Mo < 5 + > and Mo < 6 + >, and the molar ratio of Mo < 5 + > to Mo < 6 + > is 0.2-1.2. When the catalyst provided by the invention is used for a reaction for preparing 2, 5-dimethylfuran by hydrogenolysis of 5-hydroxymethylfurfural in biomass deoxidation and hydrogenation, the catalyst has the characteristics of high catalytic activity and high product selectivity.