1811results about How to "Improve cycle stability" patented technology

A durable electrode material suitable for use in Li ion batteries is provided. The material is comprised of a continuous network of graphite regions integrated with, and in good electrical contact with a composite comprising graphene sheets and an electrically active material, such as silicon, wherein the electrically active material is dispersed between, and supported by, the graphene sheets.

The invention relates to a high-capacity lithium-ion electrolyte, a battery and a preparation method of a battery, in particular to the high-capacity lithium-ion electrolyte and the battery using the high-capacity lithium-ion electrolyte and the preparation method of the battery. The electrolyte disclosed by the invention comprises lithium salt and non-aqueous organic solvent, and also consists of the following components in weight percent in terms of the total weight of the electrolyte: 0.5-7% of film-forming additive, 0-15% of flame-retardant additive, 2-10% of antiovefill additive, 0.01-2% of stabilizer and 0.01-1% of wetting agent; the electrolyte can enable the anode with high Ni content to work stably, and reduce the battery cost; the high-capacity lithium-ion battery can perform high ratio capacity and excellent safety and high temperature property and cyclic life fully due to the addition and synergetic functions of various functional additives.

This invention discloses a silicon carbon compound negative material and its preparation method for Li ionic batteries, which takes silicon and carbon phase compound particles as the base of sphericity or its like covered by a carbon layer. The preparation method includes: crushing the carbon phase particles to be mixed with silicon phase particles and sized to become a compound particle matrix to be covered with the precursor of the organic pyrolyzed carbon then to be carbonized and crushed. Compared with the current technology, this invention takes the compound material of Si and C phase particles as the matrix covered by a compound negative material, in which, the reversible specific volume of which is greater than 450mAh/g, the first circulation coulomb efficiency is greater than 85% and the volume holding rate for 200 times is greater than 80% to greatly reduce the volume effect of the Si activated material when absorbing and discharging Li and improve the diffusion performance of Li in activated materials.

The invention discloses a grapheme/silicon composite material for a lithium ion battery cathode material and a preparation method thereof, belonging to the fields of electrochemistry and new energy materials. The method comprises the following steps of: using graphite as a raw material; oxidizing the graphite into oxidized graphite by adopting oxidants of concentrated sulfuric acid and potassium permanganate; then, ultrasonically stripping the oxidized graphite to prepare oxidized graphene; mixing oxidized graphene in different proportions with nano silicon powder; ultrasonically dispersing, filtering or directly drying into a cake/film; and roasting under a reduction atmosphere to prepare self-support graphene/silicon composite film materials in different proportions. Proved by electrochemistry tests, the graphene/silicon composite film material prepared by the method has higher specific capacity and cycle stability, simple preparation method and easy mass production and consequently is an ideal high-energy lithium ion battery cathode material.

A preparation method of a high power capacity lithium ion battery cathode material uses natural spherical graphite to serve as raw materials, uses concentrated sulfuric acid to serve as an inserting layer agent, uses potassium permanganate to serve as an oxidizing agent, conducts expansion treatment at high temperature to obtain micro-expanded graphite, then enables the micro-expanded graphite in different proportions to be mixed with nanometer ganister sand, conducts ultrasonic dispersion, suction filtration and dying to obtain the micro-expanded graphite with the nanometer ganister sand inserted in layers, enables the micro-expanded graphite to be mixed and coated with carbon source carbon source according to certain proportion, and finally conducts carburizing sintering under inert gas shielding to prepare completely coated silicon carbon composite cathode material with sufficient obligated obligate inside. Electrochemistry shows that the silicon carbon composite material prepared by the preparation method has high specific capacity and cycling stability and is the ideal high power capacity lithium ion battery cathode material.

The invention discloses a silicon-carbon negative electrode material of a lithium ion battery and a preparation method thereof, and solves the technological problem of improving the charge and discharge cycling stability of the electrode material. The silicon-carbon negative electrode material is prepared by mixing a silicon-carbon composite material and a natural graphite material, wherein the weight of the silicon-carbon composite material is 7-20% and the silicon-carbon composite material is prepared by depositing carbon nanotube and/or carbon nanofiber on the surface of nanometer silica fume and/or embedding into the nanometer silica fume to form core, the surface of which is covered with 3-15wt% of a carbon layer. The preparation method provided by the invention comprises steps of: precursor silicon powder preparation; chemical vapor deposition; liquid-coating roasting; crushing; and mixing. In comparison with the prior art, the reversible specific capacity of the silicon-carbon composite negative electrode material is greater than 500mAh/g; the coulombic efficiency for a first cycle is greater than 80%; the capacity conservation rate of cycling for 50 weeks is greater than 95%. The preparation method is simple, is easy to operate, requires low cost and is suitable for a high-volume negative electrode material of lithium ion batteries used for various portable devices.

The invention discloses a hard carbon material for a power and energy-storage battery and a preparation method thereof, and aims to solve the technical problem of improving high-rate charge-discharge performance of lithium-ion batteries. The material is provided with a hard carbon matrix, and a coating is coated outside the hard carbon matrix; and the surface of the hard carbon matrix has a honeycomb opening structure. The preparation method comprises the following steps of: dipping, washing, dewatering and drying, presintering at low temperature, crushing, pyrolyzing, crushing and coating. Compared with the prior art, the hard carbon material has the reversible specific capacity of more than 450mAh/g, the first cycle columbic efficiency of over 81 percent, 0.2C 300-cycles capacity-retaining rate of over 97 percent at the temperature of 60 DEG C, and the 0.2C 300-cycles capacity-retaining rate of over 88 percent at the temperature of -30 DEG C, has the advantages of excellent lithium intercalation and deintercalation capability and cycling stability, and simple preparation process, and is applicable to the lithium ion battery cathode materials for lithium ion power batteries, various portable devices and electric tools.

The invention relates to the field of negative electrode materials of lithium ion batteries, and specifically to a nanometer lithium titanate/graphene composite negative electrode material and a preparation process thereof. According to the invention, micron-sized lithium titanate prepared by the solid phase method is subjected to ultrafine ball milling to obtain nanometer powder, and the nanometer lithium titanate powder and graphene are uniformly compounded and subjected to heat treatment so as to obtain a high performance lithium ion battery negative electrode material; the invention is characterized in that uniform distribution of graphene in the nanometer lithium titanate powder is realized through in situ compounding; the weight of graphene in the composite negative electrode material accounts for 0.5 to 20%, and the weight of lithium titanate accounts for 80 to 99.5%. The lithium ion battery negative electrode material has good electrochemical performance, 1C capacity greater than 165 mAh/g, 30C capacity greater than 120 mAh/g and 50C capacity greater than 90 mAh/g. Nanometer lithium titanate in the lithium ion battery negative electrode material prepared in the invention has high phase purity; the preparation process of the material is simple and is easy for industrial production.

The invention provides a method for preparing a multilevel porous carbon base composite phase change material, and belongs to the field of composite phase change materials. The method comprises the following steps: at first, preparing an organic metal skeleton material by using such methods as a solution method, a solvothermal method or a stirring synthesis method; with the organic metal skeleton material as a template, high temperature carbonizing under the protection of an inert gas, and changing the carbonizing temperature and the post treatment manner to obtain a multilevel porous carbon material with a super-large specific surface area and a super-large pore volume; selecting proper solvents according to different kinds of phase change core materials, preparing the phase change core materials to a solution, dispersing the porous carbon material into the solution, removing the solvent by such manners as heating, and meanwhile the phase change core materials are adsorbed and limited in the porous carbon material. The composite phase change material prepared by the method provided by the invention has good thermal storage property, can effectively avoid the leakage problem of the phase change core material, and has the advantages of excellent heat transfer property, good cycling stability and wide application range, and the process is simple and is suitable for large-scale production.

The invention discloses a water system chargeable sodium-ion battery system. The system uses a concept of a 'rocking chair battery' of a lithium ion battery; and the entire battery system is formed by using sodium-based prussian blue matter as an embedded anode, titanium sodium phosphate as an embedded cathode, and sodium-contained inorganic salt solution as electrolyte. The system has the advantages of high discharge voltage, large specific capacity, good rate capability, long cycle life and the like, and further has the characteristics of green and environmental friendliness, and high security and no pollution. The system very hopefully becomes an electrochemical stored energy system with low price and environmental friendliness.

The invention relates to a preparation method of a silicon/graphene laminar composite material for lithium ion battery cathode. The composite material adopts a laminar sandwich structure, silicon nano-particles are dispersed on each lamina of the grapheme, the laminas of the grapheme are separated from one another by the silicon nano-particles and the edges of the laminas are in lapped joint so as to constitute a laminar conductive network structure. The preparation method thereof comprises the steps of: formulating anhydrous silicon tetrachloride, surface active agent, sodium naphthalene and graphite oxide to tetrahydrofuran solution, adding the tetrahydrofuran solution into a reactor for reaction in vacuum at the temperature ranging from 380 to 400 DEG C, filtering the reactant to result in the product, and then washing, drying and heating the product to obtain the silicon/grapheme composite material. The preparation method of the invention has the advantages of simple preparation process and great easiness for industrial production; and the silicon/graphene laminar composite material prepared according to the method includes excellent conductivity, power performance, electrochemical activity and cycle stability, and is particularly suitable for manufacturing lithium ion battery cathode.

The invention discloses a mixed positive electrode material, a positive plate using the same, and a lithium ion battery. The mixed positive electrode material comprises the following component by weight: 50-90 parts of a nickel-cobalt-manganese ternary material and 10-50 parts of lithium-manganese-iron phosphate. The mixed positive electrode material provided by the invention combines the nickel-cobalt-manganese ternary material with high energy density and lithium-manganese-iron phosphate with high safety performance, and plays complementary advantages of nickel-cobalt-manganese and lithium-manganese-iron phosphate, so that comprehensive performances of the positive electrode active material are improved. The positive plate prepared by using the mixed positive electrode material increases the safety performance and cycle performance of the lithium ion battery, increases average voltage of the lithium ion battery, and keeps relatively high energy density; and the lithium ion battery using the positive plate has excellent electrochemical performances, high energy density and high safety performances and long cycle life, and is suitable for popularization and application.

The invention provides a lithium ion battery cathode material and a preparation method of the lithium ion battery cathode material as well as a lithium ion battery. The lithium ion battery cathode material comprises an inner core, a middle layer outside the inner core and an outer shell wrapping the middle layer, the inner core is Si-C particles, the middle layer is a foam layer, the outer shell is an amorphous carbon layer and the Si-C particles are formed by Si particles and C materials. Compared with the prior art, a middle carbon foam layer existing between the Si-C particle inner core and the amorphous carbon outer shell can form an conductive network structure, thus improving conductivity of a material and buffering enormous volume change of Si particles in the charge-discharge processes; and the amorphous carbon outer shell layer can maintain the core-shell structure of the cathode material, and the cladding layer of the core-shell structure can buffer the volume change, improve cycling stability of electrodes, reduce contact between active substances and an electrolyte, improve first coulombic efficiency of an electrode, prevent nanoparticle aggregation and enhance electrode conductivity.

The invention discloses a nanostructured quasi-solid electrolyte applied to lithium ion batteries or lithium sulfur batteries and a preparation method and application thereof. The nanostructured quasi-solid electrolyte is a macro solid-state electrolyte material which is formed by an inorganic-organic hybrid framework material adsorbing ion conductive agent. The preparation method of the nanostructured quasi-solid electrolyte is as follows: in protective atmosphere, the inorganic-organic hybrid framework material is soaked in the ion conductive agent and sufficiently mixed, and redundant solvent is then volatilized. The prepared nanostructured quasi-solid electrolyte with high lithium ion conductivity can be substituted for both organic electrolyte and diaphragms in conventional lithium ion batteries, and thereby safety problems caused by the leakage of the organic electrolyte can be effectively prevented; a lithium battery assembled from the electrolyte can use a metal lithium plate as a cathode.

A process for preparing carbon coated graphite microparticles used as negative electrode material of Li-ion battery features use of spray granulating method. It can elongate the service life of Li-ion battery.

The invention discloses a carbon cladded ferriferrous oxide negative electrode material of a lithium ion battery and a preparation method thereof. The negative electrode material is a carbon cladded Fe3O4 composite material and has a particle size in a range of 1 to 100 nm. The preparation method comprises the following steps: with NaCl used as a dispersing agent and a supporter, fully mixing NaCl with a metal oxide source and a solid carbon source; drying an obtained mixed solution under vacuum to obtain a mixture; placing the mixture into a tubular furnace for calcination in an inert atmosphere so as to obtain a calcined product; and rinsing and grinding the calcined product to obtain carbon cladded metal oxide nanometer particles. The method is safe and non-toxic and is simple to operate; during charging and discharging tests of a lithium ion button cell made of the carbon cladded ferriferrous oxide negative electrode material, discharge specific capacity can be maintained at 620 to 900 mAh/g after 30 cycles of charging and discharging at a current of 0.1C (with current density being 92 mA/g), and discharge specific capacity can be maintained at 600 to 760 mAh/g after 50 cycles of charging and discharging at a current of 1C (with current density being 920 mA/g); and the negative electrode material of the lithium ion battery has high reversible capacity and good cycling stability.

The invention discloses a carbon-silicon composite material, a preparation method of the carbon-silicon composite material and a lithium ion battery containing the carbon-silicon composite material. The preparation method comprises the steps of: directly selecting silicon powder as a raw material, wrapping the silicon powder with a precursor of organic carbon to obtain a porous carbon layer wrapping silicon composite material, and using corrosive liquid to remove partial silicon in the porous carbon layer wrapping silicon composite material by corrosion, so as to obtain the carbon-silicon composite material, wherein a gap exists between a carbon shell and the silicon arranged in the carbon shell. The preparation process is simple. The carbon-silicon composite material prepared by the preparation method disclosed by the invention is good in electrochemical property, and the battery prepared from the carbon-silicon composite material is good in cycling performance.

A graphene-cladding manganese dioxide combination electrode material and a method for producing the same, belonging to the technical field of electronic functional materials, the graphene-cladding manganese dioxide combination electrode material comprises nano manganese dioxide particles and graphene cladded with manganese dioxide particles, wherein the mass ratio of graphene and the nano manganese dioxide particles is 1:(1.25-10). The method comprises the following steps: preparing the nano manganese dioxide particles and graphite oxide respectively, and mixing and ultrasonically dispersing to obtain the graphene-cladding manganese dioxide dispersing agent, finally, reducing the graphite oxide to obtain the graphene-cladding manganese dioxide combination electrode material. The graphene is used to clad the manganese dioxide, so the electrical conductivity and cycling stability of the electrode material parts can be improved; and meanwhile, the existence of the manganese dioxide particles also effectively prevents the graphene from reunion, so the specific capacity of the electrode material of a supercapacitor is obviously increased. The method has a simple technology, reaction products are easy to control, the purity is high, and the produced combination electrode material is suitable for producing an electrode plate of the supercapacitor.

The invention provides a composite anode of a multi-layer structure for a lithium-sulfur rechargeable battery and a preparation method, which is characterized in that: an anode active substance, a conductive agent, and a binder are uniformly mixed, and then are coated on a current collector, and after coat is dried, a layer of conductive film is sprayed on the surface. The anode surface film is used for conducting and cutting off the sulfur in a cyclic process, thereby effectively raising a first capacity conservation rate of the battery and the cyclic stability.

The invention discloses a novel lithium iron phosphate material which is adulterated /covered with conductive agents and a preparation method thereof. The lithium iron phosphate material of the invention comprises lithium source compounds, iron source compounds, phosphate radical source compounds and the conductive agents of lithium iron phosphates. The technology of the invention is simple; the material is clean and pollution-free; the cost of the material is low. The invention is suitable for industrialized mass production. Specific capacity of the obtained lithium iron phosphate material is high (more than 140 mAh/g); cyclical stability is good (more than 300 times); high rate charging and discharging performance of the lithium iron phosphate material is particularly prominent (5C capacity can still reach 80 mAh/g); conductivity and stacking density are high; diffusivity of protons is improved; contact between active materials and an electrode is increased; internal resistance of the electrode and a battery is reduced; discharging and cyclical stabilities of the electrode are obviously improved. The invention is widely applied to novel high performance lithium ion batteries.

The invention belongs to the field of lithium-ion batteries, and particularly relates to an application of a borate compound serving as an additive for high-voltage lithium-ion battery electrolyte. The borate compound is in a structure as described in formula 1. The invention also discloses the high-voltage lithium-ion battery electrolyte which is obtained by adopting a means of adding the functional additive into common electrolyte, wherein the weight of the added functional additive accounts for 0.1%-5% that of the common electrolyte; the common electrolyte consists of a cyclic carbonate solvent, a liner carbonate solvent and conductive lithium salt; the functional additive is the borate compound. By virtue of the added additive, on one hand, the interface of a positive electrode/the electrolyte is optimized, the surface activity of the positive electrode is lowered and the oxygenolysis of the electrolyte is inhibited; on the other hand, due to the introduction of boron, the safety of the electrolyte is enhanced remarkably. By virtue of the high-voltage lithium-ion battery electrolyte, the safety performance and the cycling performance of a high-voltage (3-4.9Vvs.Li/Li<+>) lithium battery can be enhanced.

The invention discloses a preparation method and application of a carbon-coated grapheme-based metal oxide composite in a two-dimensional core-shell structure. The carbon-coated grapheme-based metal oxide composite in the two-dimensional core-shell structure is prepared by taking the two-dimensional grapheme in a single-layer carbon atom structure as a carrier and the phenolic resin or polysaccharide as the carbon source precursor. The metal oxide nanoparticles obtained by the method are uniformly loaded on a graphene sheet and well coated in the carbon-coated layer. The preparation method has the advantages of simple process, mild condition and low cost. The Electrochemical tests prove that the carbon-coated grapheme-based metal oxide composite in the two-dimensional core-shell structure has excellent cycle stability and rate properties. The experiments prove that: under the charge and discharge current of 200mAhg<-1>, the tin dioxide material has the discharge capacity of 200mAhg<-1>, and the ferroferric oxide material has the discharge capacity of 930mAhg<-1>. Therefore, better experimental data and theoretical support are provided for the research and the application of the metal oxide in the field of electrochemistry.

The invention discloses a preparation method of biomass-based nitrogenous porous carbon, the porous carbon prepared by the method and the use of the prepared nitrogenous porous carbon in a super capacitor. The preparation method comprises the steps of (1) drying a biomass material, and grinding the biomass material into fine powders, (2) evenly mixing the biomass material powders and water or a dilute acid solution, (3) placing the above mixture into a reactor for hydrothermal reaction, and (4) drying and grinding an obtained hydrothermal reaction product, and calcining the hydrothermal reaction product in a tube furnace to obtain a nitrogen-doped porous carbon material with a large surface area. According to the method of the invention, cheap and renewable plant is used as carbon and nitrogen precursors, and the porous nitrogen-doped carbon material is prepared through a hydrothermal method. The method has the advantages of simple preparation process, no need of an activator or template agent, low cost, environmental protection, and convenient operation, problems of strong corrosion, a high price of transition metal and environmental pollution caused by heavy metal are avoided, and the method is suitable for mass production.

The invention discloses a preparation method of a carbon nanotube-MXene composite three-dimensional porous carbon material. According to the preparation method of the material, based on the hydrophilic property of the MXene material, the MXene material is dispersed in a carbon nanotube stabilizing solution, and then is added into a PVA water solution to form a uniformly dispersed stable system. The three-dimensional porous composite carbon material is obtained through freeze drying and carbonization. According to the preparation method, a carbon nanotube can be inserted into a two-dimensionallayer structure of MXene, so that sheet agglomeration is prevented. The specific surface area is increased, and the ion migration space is enlarged. The improvement of the unit capacity and the cycling stability is facilitated. The problem that an MXene material and a graphene material are not easy to disperse uniformly is solved. The mesoporous and macroporous composite three-dimensional porous carbon material is prepared. The preparation method is simple, green, environment-friendly, low in cost, high in yield and easy for industrial production.

The invention belongs to the technical field of nano-materials and chemical power sources and particularly provides a nano-Si or nano-Sn containing composite cathode material for a lithium ion battery and a preparation method thereof. The composite cathode material of the invention comprises the following components: cathode active substances, nano-Si or nano-Sn, and macromolecule polymers. The method taking the above components as raw materials comprises the following steps: firstly, preparing mixed solution; then, removing organic solvent; further coating the mixed solution with the macromolecule polymers; then, removing organic solvent; and finally, carrying out carbonization treatment to obtain the finished product. The invention has the advantages of fewer components, low cost, simple process and low energy consumption; and the composite cathode material prepared by the method of the invention has a core-shell structure and has the characteristics of high capacity, high stability and high capability of rapidly charging and discharging. Therefore, the composite cathode material of the invention is widely applicable to lithium ion batteries, super-capacitors and other components based on new energy resources and particularly applicable to lithium ion batteries for electric vehicles.

The invention provides a lithium ion battery negative electrode comprising a diamond-like thin film layer. The negative electrode comprises a conductive current collector, a negative electrode active material layer arranged on the conductive current collector and a diamond-like thin film layer deposited on the surface of the negative electrode active material layer; and the diamond-like thin film layer comprises doped elements, wherein the doped elements comprises one or more of Si, B, N, P, Al, Be, Mg, Ti, Cr, W, Fe, Zr, Pt, Mo, Co, Ni and Sb. According to the lithium ion battery negative electrode, the diamond-like thin film layer is deposited on the surface of the negative electrode active material layer, and the diamond-like thin film layer has excellent electrochemical inertness and conductivity and high mechanical strength, so that occurrence of an unstable SEI layer on the surface of the negative electrode active material is avoided, and the cycling stability of the electrode is greatly improved. The invention also provides a preparation method for the lithium ion battery negative electrode, and the lithium ion battery.

The invention discloses a method for preparing supercapacitor carbon aerogel by the utilization of bagasse. The method includes the steps that the bagasse is used for preparing cellulose powder without xylogen and hemicellulose; the cellulose powder is used for preparing cellulose aerogel; the cellulose aerogel is carbonized to obtain carbon aerogel; the carbon aerogel is activated to obtain the supercapacitor carbon aerogel. According to the method, the industrial waste bagasse is used as raw materials, the requirements for sustainable development and environmental protection are met, and the cost of electrode materials is effectively lowered. The product prepared through the method is of a three-dimensional hierarchical pore structure; compared with a product obtained through a conventional method, the product prepared through the method is large in specific area and good in repeatability, and has higher specific capacitance and better cycling stability. The method is more suitable for preparing supercapacitor electrode materials and has wide development prospects.

The invention relates to a method for preparing poly(3,4-ethylenedioxythiophene)/sulfonated graphene composite hydrogel with a porous structure through supramolecular self-assembly. The method comprises the following steps of: dissolving sodium polystyrene sulfonate and sulfonated graphene in water, stirring, performing ultrasonic dispersion to ensure that the sodium polystyrene sulfonate and thesulfonated graphene are dissolved, adding a 3,4-ethylenedioxythiophene monomer, uniformly stirring, adding polyvalent iron salt, standing at room temperature and reacting to obtain blocky poly(3,4-ethylenedioxythiophene)/sulfonated graphene composite hydrogel. The poly(3,4-ethylenedioxythiophene)/sulfonated graphene composite hydrogel with a controllable and porous structure is prepared by using the interaction and electrostatic action of a hydrogen bond and a pi-pi bond among the sulfonated graphene, the sodium polystyrene sulfonate and 3,4-ethylenedioxythiophene through supramolecular self-assembly. The prepared composite hydrogel has high electrical conductivity and mechanical strength, and high specific capacitance and cycle stability in electroactive electrolyte.

The invention relates to a high-performance silicon-carbon cathode material and a preparation method thereof. The preparation method comprises the following steps: (1) dispersing silicon into a solvent, carrying out liquid-phase ball-milling, so as to obtain nano-silicon dispersion liquid, adding graphite, and carrying out liquid-phase ball milling so as to uniformly mix nano-silicon with graphite; (2) carrying out granulation on slurry obtained the step (1), so as to obtain graphite/nano-silicon composite particles; (3) carrying out granulation on the product of the step (2) and asphalt by virtue of a mixed kneading-pressing-crushing method, so as to obtain graphite/nano-silicon/asphalt composite particles, and carrying out mechanical fusion so as to realize spheroidization and uniform coating of the graphite/nano-silicon/asphalt composite particles in one step; and (4) carrying out carbonization, scattering and sieving, so as to obtain the high-performance silicon-carbon cathode material. The preparation method is simple and low in cost and can be used for easily producing the high-performance silicon-carbon cathode material in large scale.

The invention discloses a modified high nickel ternary positive electrode material. The surface of a high nickel ternary positive electrode material is coated with a coating layer containing a fast ion conductor. The fast ion conductor has the chemical general formula of Li3x1La2/3-x1Ma1TiNz1O3, Li2+2x2Zn1-x2GeO4 or LiM'2(PO4)3, wherein M represents Ba<2+> and/or Sr<2+>, N represents Al<3+> and/orZr<4+>, x1 is greater than or equal to 0.04 and less than or equal to 0.167, a1 is greater than or equal to 0 and less than or equal to 1, z1 is greater than or equal to 0 and less than or equal to 1, x2 is greater than -0.3 and less than 0.8, and M' represents one or more of Zr, Ti, Ge and Hf. Compared with the existing positive electrode material, the modified high nickel ternary positive electrode material is provided with the coating layer containing the fast ion conductor and the coating layer can react with residual lithium on the surface of the material to reduce residual lithium on the surface of the material and inhibit side reactions of the residual lithium and the electrolyte so that material surface stability and cycle performances are improved. The modified high nickel ternary positive electrode material has good lithium ion deintercalation ability, improves the first discharge capacity of the material and first coulombic efficiency and has a good application prospect. The invention also discloses a preparation method of the modified high nickel ternary positive electrode material and a lithium ion battery.