The invention relates to a lithium ion secondary battery which consists of a shell, a positive electrode plate, a diaphragm, a negative electrode plate and electrolyte. The positive electrode plate consists of a positive electrode current collector and a negative electrode active material bonded on the positive electrode current collector; the negative electrode plate consists of a negative electrode current collector and a negative electrode active material bonded on the negative electrode current collector; the positive electrode active material is an iron phosphate ferrovanadium lithium composite material of a nano oxide doped with an M element; the negative electrode active material is a lithium titanate composite material; the M element is selected from any one or the combination of at least two of aluminum, lithium, boron, silver, copper, chromium, zinc, titanium, gallium, germanium, zirconium, tin, silicon, iron, cobalt, nickel, vanadium, magnesium, calcium, strontium, barium, tungsten, molybdenum, niobium, yttrium, lanthanum, selenium and cadmium; the lithium oil secondary battery has the obvious characteristics of excellent electrical chemical performance, high safe performance, long cycle service life, low cost, environment friendliness and the like, is beneficial to widening the application range of the lithium ion battery, and has important practical significance and wide market prospect.